I-Carvone from d-Limonene - Industrial & Engineering Chemistry (ACS

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INDUSTRIAL AND ENGINEERING CHEMISTRY DERIVATION OF THE METHOD

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It may be shown that, like the X axis, every line in the hyperbolic plane may be described as having a hyperbolic subdivision such that the distance from the Y axis of any point on that line is given by 2‘ = p z / ( p z T ~ ’ ) where , p , is the hyperbolic abscissa r g ) . In of the point and rr‘ has the value T,’ = ( p ‘ # rp)/(p’; this expression p’, and p’- are the y and intercepts of the line, while r y and r; are the hyperbolic constants of the Y and % . axes, respectively. The length of the line segment bounded by the Y and axes is taken as unit length for any line in the plane, It may also be shown that the necessary and sufficient condition that two lines (a)and ( b ) be parallel is that r,,(a) = r,(b)Le., that their hyperbolic constants be equal. I t is this principle which is applied in determining the values of r y and T (and, in turn, which must be employed to render the opposite sides of a quadrilateral parallel. , The above value of rz is given in terms of its y and Z intercepts. These, however, are known if any two points on the line are known. It is a simple matter t o substitute for these intercepts ’ values in terms of the coordinates in the expression for T ~ their of the four given points. There is a pair of such substitutions for each side of the quadrilateral, resulting in a separate expres’ opposite sides of sion for rr’ for each side. The values of T ~ for the quadrilateral are then equated, and the equations thus obtained are solved for r y and r;; r, is given by the expression rz = ru/r;. It is the resulting expressions for rz and r y which are evaluated by the above steps involving the a’s, b’s, and c’s.

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Vol. 43, No. 5

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Figure 6. Nomograph for Retaining Wall Formula with Moduli and Positions of Scales Adjusted to Rectangular Form

present function, p , and v to represent the present function, L, the values of these coordinates are inserted in the above formulas to determine the values of the a’s, b’s, and c’s, as follows: al= 0, a2 = - 2 , bl = l / 6 , bz = 25/6, a3 = 0 , a4 = 1/ 3 , b3 = 3/4, bq = - 1 /IZ, cz = -I/a, and c4 = l / 4 . Then r y = 1/2 and rz = - 4 / 7 . The negative sign of r z indicates merely that positive values of p are t o be located in the negative region of the scale, and vice T ) 3 -p/( -p - T ) . The nomograph is versa, since p / ( p constructed using these values of T~ and r y . From a preliminary plot it is apparent that an angle of 30” between the X and Y axes will convert the parallelogram to a rectangle and that the length-to-width ratio desired may be achieved by setting the length (or modulus) of the X axis approximately twice as great as that of the Y axis. The nomograph thus constructed and rotated to place the scales in vertical position is shown in Figure 6.

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LITERATURE CITED

(1) Allcock, H. J., and Jones, J. R., “The Nomogram,” p. 107 ff. London, Sir Isaac Pitman & Sons, 1932, (2) Burrows, W. H., IND.ENQ.CHEM.,38, 472 (1946). (3) Ibid., 43, 158 (1951).

R E c n w E D September

25, 1960.

LCARVONE FROM d-LIMONENE CARL BORDENCA AND RUFUS I