Importance of ion association in the induced reactions of cobalt (III

Jan 1, 1988 - David A. Buckingham, Charles R. Clark, Margot J. Gaudin. Inorg. Chem. , 1988, 27 (2), pp 293–301. DOI: 10.1021/ic00275a014. Publicatio...
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Znorg. Chem. 1988, 27, 293-301

Contribution from the Department of Chemistry, University of Otago, Dunedin, New Zealand

Importance of Ion Association in the Induced Reactions of Cobalt (111)-Acido Complexes. 3.' Hg2+- and Ag+-Catalyzed Reactions of the t-[Co(tren) (NH3)SCNI2+ Ion David A. Buckingham,* Charles R. C l a r k , and Margot J. Gaudin Received May 21, 1987 The Hg2+-inducedreaction of t-[Co(tren)(NH,)SCNl2+ (hereafter CoSCN2+)in the presence and absence of added anions Y(NO,-, Clod-, CF,SO