Important Source of Marine Secondary Organic ... - ACS Publications

Nov 7, 2008 - Kristine D. Arquero , R. Benny Gerber , and Barbara J. Finlayson-Pitts ... Barbara Nozière , Markus Kalberer , Magda Claeys , James All...
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Environ. Sci. Technol. 2008, 42, 9116–9121

Important Source of Marine Secondary Organic Aerosol from Biogenic Amines M A R I A C R I S T I N A F A C C H I N I , * ,† STEFANO DECESARI,† MATTEO RINALDI,† CLAUDIO CARBONE,† EMANUELA FINESSI,† MIHAELA MIRCEA,† SANDRO FUZZI,† FABIO MORETTI,‡ EMILIO TAGLIAVINI,‡ DARIUS CEBURNIS,§ AND COLIN D. O’DOWD§ Institute of Atmospheric Sciences and Climate, National Research Council, Bologna, I-40129, Italy, Department of Chemistry, University of Bologna, Bologna, I-40126, Italy, Centro Interdipartimentale di Ricerca per le Scienze Ambientali, University of Bologna, Ravenna, I-48100 Italy, and School of Physics and Centre for Climate and Air Pollution Studies, Environmental Change Institute, National University of Ireland, Galway, Ireland

Received July 3, 2008. Revised manuscript received September 28, 2008. Accepted September 30, 2008.

Relevant concentrations of dimethyl- and diethylammonium salts (DMA+ and DEA+) were measured in submicrometer marine aerosol collected over the North Atlantic during periods of high biological activity (HBA) in clean air masses (median concentration (minimum-maximum) ) 26 (6-56) ng m-3). Much lower concentrations were measured during periods of low biological activity (LBA): 1 (