In every industry there are problems you can solve with Armour Etho

Nov 6, 2010 - ACS Publications Enhances ACS Mobile App. As a service to our global audience of chemistry researchers, students, and ... of Self-Assemb...
0 downloads 8 Views 247KB Size
In every industry there ON Look what t h e s e versatile "chemicals

STIVE STOCK!

with t h e answers*' a r e doing n o w !

M .50 82.0 37.5 flf 62 « 39 105.0 43.0 Κ ι « o 7 2 9 .S

Emulsion cleaners for c o n t a m i n a t e d metal surfaces

âfe .10

Emulsifiers for buffing c o m p o u n d s Anti-static agents for h y d r o p h o b i c fibers Additives for soluble c u t t i n g oils Softening agents f o r textiles Oil emulsifiers for p r o t e c t i o n of metal surfaces from corrosion Emulsifiers for " f a t l i q u o r i n g " oils in leather t a n n i n g Dispersants for gellation a g e n t s in oils

i aBrb 1.5 H 12 » 0 c 24 Sfe 214 R2 4 WT β β 30 8 β •60 7 H S H2.20 1 ï p 4 .10 E1.60 8 I 1» Β .20 L25p 3 8 1.20 6 1.50 15

S3.2 24.7 14.6 31-0 5.0

32.β 8.3

f 200 1Î 88

32.5 36.2 6.2

21.4 86.5 32.0 7 5 51.1 11.2 17.3 37.4

Emulsifiers for w a x e s and silicones Emulsifiers for insecticides a n d herbicides Re-wetting agents for paper L a t e x stabilizers f o r r u b b e r Suspension agents for de-inking paper

Pwl.50 9 'Cera 2 2 nî 3 190 wl.50 3

Coupling agents b e t w e e n w a t e r a n d water insoluble a g e n t s

Ρ 2.04 2.00

&L· 1.50 2 MRay 30 land 3a 6 ndSti 2 · β

Dispersing aids for p i g m e n t s in paints a n d e n a m e l s

•irCo .50e 4 2

rcherrt 2.60 1 ierlakl .35e 6 0 tîBM 2.60 2 6 tHarr 2 64

"ο ρ 7

iayt 2 . *K> 1.20

*CotTE

ConKilnd 2 Con Foods 1 14 Ο ConGasUl .90 4 iConNGas 2 3 4 .TonRRCub Ρ .1 Ο JonCoal 1 2 0 S 3 onsPw 2.40 1 9 Do ρ 4.50 .SO 3 Container 1 *> 7 ontBak 2 4β , O o p 5 50 , Ι Ο ] ifontCan 1.80 4 7 tCup&S -17r 3 4 iontins _2_ _ Ι Ο

hDan 2 „.faoOil 1 b ^rracoStl 3 3 ι Artnour&Co lArmstC 12J2 I Art loom lArvinlrtd ! •AshiOil 1 iSRProd . IssdDryG 1

kssoclnv 21 §Atcbisl.2q[ . Do ρ .Γ>θ1 Λ t! Cst U n j MlRefio 2 Î -60 21 H>o ρ 1 ;î 2.40 4 pst Sic .20d 32 lit€ 1.80b 210 fccoMf .20c 64 2.25 2 •Wtt 38 J C & W lb* 1 4 5

[dLima .60 62 »ΛΕ 1.80 «2 5 tSeOh 1 63 t 4 A r 2.40 .τΟ 2.50 JP 1.10* . , Π ν 2.60 I I ch&L l b 2 kCis 1 P d 1.8» lM .625e , P4.T5 .4 1.2âf 41 . .A 1.20 21 ^ c c c h C r k 2 .3< Kiccbï*H 1.5© BeldHera .70 l , BellAirc .35e 3 Bcll&How lb 1 BendiA 2 4 0 91 BcnefFin 1 Do ρ 2.50 Benguet B e t t F d s 2a Bo , 9.3 + Gamev 4Π.β~ .#*3> GarWjj K . 4 + . 1 Gardn«( Η . 4 . Garrets S 6 - 0 4 - i.Vi GenAcf 0 2 . 6 + . 3 GeoAri E l . 7 + . 5 GAmlnv ,35e 22 W 0 . 2 + .6 GAmOil .35e 18 H t J *> ... GAmTr 3.50a 5 • ? ! o + 1.1 GenBak .60 8 • 5 . 3 + . 3 GcnCable 2 34 B.Ï.3— .3 Do 1 ρ 4 .3 0 B 9 . 4 + . 50 GComract .40e 7 Œ5.6 + GControls .60 1 02.1 + . 1 GcnDynam 2 82 WtiT.T— lî 2 162 •."..4— .3 iGcnElec GcnFinan 1 7

•s 0

.TnZcll iTÏÏÎT 3^9 yCrucSt.20e 2B3 ï'ubaRR ρ U f l f'ubAmSJ .50» f « j(*udah>} k 74 ; 'tiïw>Pn?«it 4« "unnDr 1 60a 1 *urtPub 't5c_2:« FurWr 1.' ~~ Do A —,...>^,^ DutlerH » J ^ Î |

40.β 155 4 9.0 &.:\.'z 4 5.0 2 «.;*

11.4 + . 6 155.4 + .4 9-2 . 64.0 + 3 / 6 45,0 , 27.0 + **7

.10

ε Miner 1.60 2 9 ntXi 2.60a 7 4 tPacIc .5Ug 4 . ntPaper 3 b 3 1 '«tRysCAm 3 E>o ρ ,20 Im,Salt 3« 1 111-0 IntShoe 2.40 5 38.7 IntSilver .75» 4 30.6 Oo ρ 1.75 1 30.4 ΙοεΤ&Τ 1.S0 4 4 34.5 int ναι ι a IntersD-S 2.50 2 iitterstPw .85 5 iowIG 1.80 b 2 6 IowP&L 1.60 3 IslCrkCoai 2 1 7 Do.p 6 .10 I-T-ECB .90e 4

sue Cond Con» ConJ 0)zH

I

*(Crl 2 CH a O)xH

R—N—CH2CH2—CH2N .(CrI 2 CH 2 0)yH

Ethoduomeens are also cationic in nature, and react as the Ethomeens do—but with increased cationic properties. Gen­ erally, their water solubility is somewhat greater than that of the corresponding Ethorneen containing the same ethylene oxide content. Mono- and di- substituted ammonium salts can be prepared by reacting the Ethoduomeens with organic or inor­ ganic acids.

Ethoquads a r e water soluble, cationic surface-active agents. They differ from usual quaternary ammonium compounds since the quaternized nitrogen holds two polyoxyethylene and two alkyl groups instead of four alkyl groups. T h e two polyoxyethylene groups impart additional water solubility over that obtained with similar Arquads or Ethomeens. At present Ethoquad 0/12, 0/15, C/12, C/15, 18/12, and 18/25 derived from t h e corresponding Ethomeens are available.

T h e E t h o m i d s ® are N , N-substituted fatty acid amides. The substituents being polyoxyethylene groups, T h e Ethomids are chemically neutral and rather unreactive.

T h e E t h o m e e n s " 3 are prepared from n-alkyl primary amines. They have a n ethylene oxide content ranging from 2 t o 50 moles per mole of amine.

Ethomids are stable in acid or alkaline solutions. They can be hydrolyzed with concentrated bases and acids under strenuous reaction conditions—the products of such hydrolysis are fatty acids and di-polyoxyethylene amines.

/(CH2CH20)xH RN \(CH2CH20)yH

There are four Ethorneen groups, differing in t h e chain length and unsaturatioo of the n-alkyl chain. Members in each group differ in polyoxyethylene content. The " C " series comes from a primary coco amine; t h e " S " series from primary soya amine; the " T " series from tallow amine; the " 1 8 " series from stearylamine. The Ethomeens are cationic in nature, the degree depending on the ethylene oxide content. By reacting them with either organic or inorganic acids, substituted ammonium salts can be formed. T h e E t h o d u o m e e n s R } like Ethomeens, are reaction products of amines and ethylene oxide. The difference: Etfao-

Leader in Progressive Fatty Acid

? ^{CH2CH20)xH RCN \(CH2CH20)yH

T h e E t h o f a t s ® are a series of mono-fatty or rosin acid esters of polyoxyethylene glycols. These surface actrve agents are essentially 100 % active materials and being nonionics, they are compatible with anionic and cationic agents. RC—Ο

(CH 2 CH 2 0)xH

The Ethofats have emulsifying properties and some may be used alone as emulsifiers, whereas other members may be used with other agents to obtain improved emulsions. Besides serving as emulsifiers, the Ethofats are used as wetting a n d dispersing agents. Although fairly stable in mildly acid or alkaline solu­ tions, the Ethofats can be hydrolyzed with strong acids or alkalies. We urge you to investigate the Ethoquads, Ethomeens, Etho­ duomeens, Ethomids and Ethofats. Send today for samples and detailed information. Please indicate the application you are interested in so our technical staff can recommend specific chemicals for your testing.

Chemistry

CE 7-58

SEND FOR DATA A N D SAMPLES TODAY! 3 5ÎI7F 1 6 6 0 . 5 βοΊΓ L-lb 1 18.1 38.1 80b 4 3 36.1 35.6 2 l b 3 1 7 . 6 17.5 -4.80 5 » 3 . 2 9 2 . » ,20b 5 15.0 14.7 7 5 e 4 » 2 0 . 2 18.7 lOe 1 5 70.2 69.6 6.4 25p 35 6.5 26 16.4 16.0 5 1 4 2f>.7 2 9 . 6 ,40p 4 18.0 17.6 20b 2 9 52.2 50.5 Î.S0 4 28.0 27.7 10 5 1 3 3 . 5 33.1 60e 4 23.2 22.β .20 7 1 61.7 60.4 S75e 5 1 7 . 3 17.2 1.20 1 0 2 5 . 5 2 5 . 2 2 1 2 60.5 60.S 1.80 2 4 5 . 4 4 5 . 0 fto a s 3