Downloaded by 80.82.78.170 on December 13, 2016 | http://pubs.acs.org Publication Date: January 1, 1965 | doi: 10.1021/ba-1965-0049.ix001
INDEX
A b s o r p t i o n spectrum, n i t r a t e 234 A b s t r a c t i o n of h y d r o g e n f r o m w a t e r . 146 Acetylene 181, 194, 198, 201 insertion reactions 194, 211 Acid-base reactions i n fused s a l t s . . . . 220 A c i d - c a t a l y z e d a q u a t i o n of Co(CN) N 42 Activation energy parameters 88 entropy .·.. 160 Acylcobalt carbonyl 195, 196 tetracarbonyl 186, 192 derivatives 188 ω-unsaturated 187 Adamson, Arthur W 28, 51, 72, 104, 235, 248, 254, 255, 256, 257 Addition t h r e e - or four-center 208 silicon h y d r i d e 218 Adjacent attack 122 rate of reaction b y 118 Aldimines, Cu(II)-catalyzed a u t o x i d a t i o n of 136 A l k a l i a n d a l k a l i n e earth ions 56 A l k a l i n e copper t a r t r a t e reagent 165 Alkoxides, tri-w-butyltin 203 Alkylcobalt carbonyl. 184, 195 tetracarbonyl 183, 186, 191, 192 derivatives 188 A l k y l m a n g a n e s e pentacarbonyls 182 Aliène 190 x-Allylcobalt tricarbonyl 187, 192 t r - A l l y l n i c k e l c a r b o n y l halide 196 A l p h a effect 23 D-Altrose 165 A m i n e c o b a l t ( I I I ) systems, s u b s t i t u t i o n reactions of 18 Amino acid Cu(III)-catalyzed oxidative d e a m i n a t i o n of 133 ester 155 hydrolyses 161 Anation 7, 73 of C o ( C N ) ( O H ) 31 A n b a r , M i c h a e l . . . .50, 105, 106, 142, 146 147, 151 A n i l i n e b y C u ( I I ) , o x i d a t i o n of 129 A n i o n replacement reactions 175 A n i o n i c catalysis 79 Aquation 7, 251 of K C r ( N H ) ( N C S ) 245 kinetics of C r ( e n ) ( H 0 ) 240 6
8
3
5
6
3
2
4
2
2
2
+ s
Archer, R o n a l d . Aromatic nitration Atkinson, Gordon Autoxidation of a l d i m i n e s , C u ( I I ) - c a t a l y z e d . . . . of c y s t e i n , C o ( I I ) - c a t a l y z e d ofFe(II) of i ^ - h y d r o x y e t h y l e n e d i a m i n e , c a t a l y z e d b y cobalt ions A z i d e ions, o x i d a t i o n of Cr(H 0) by A z i d e vs. t h i o c y a n a t o complexes, reaction rates of 2
e
+ 2
257 227 257 136 131 131 136 131 123
B a c t e r i a l resolution of diastereoisomers 177 Bailar, John C , J r 176 Base-catalyzed h y d r o l y s i s , rate constants of 22 Base h y d r o l y s i s 257 reaction 8, 17 Basolo, F r e d .94, 103, 105, 106 B e t a keto esters, b r o m i n a t i o n o f . . . . 162 B i m o l e c u l a r displacement 22 mechanism i n square p l a n a r complexes 85 B i p h i l i c reagent 88 l^