industrial and engineering chemistry - ACS Publications - American

Manuscript Editor: G. GLADYS GORDON. Manuscript ... Dwight Williams and George S. Haines 538 ... George G. Marvin and Lawrence B. Woolaver 554...
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INDUSTRIAL AND ENGINEERING CHEMISTRY ANALYTICAL E D I T I O N WALTER J . MURPHY, EDITOR

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ISSUED SEPTEMBER 27, 1945 ·

VOL. 17, NO. 9

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CONSECUTIVE NO. 18

Lawrence T. Hallett, Associate Editor Manuscript Editor: G. GLADYS GORDON

Manuscript Assistant:

STELLA ANDERSON

Make-up Assistant:

CHARLOTTE C. SAYRE

Advisory Board R. P. CHAPMAN J. R. CHURCHILL B. L. CLARKE

T. R. CUNNINGHAM G. E. F. LUNDELL M. G. MELLON

Determination of Chlorate in Caustic Soda Solutions By Reduction with Ferrous Sulfate Dwight Williams 533 Iodometric Method Dwight Williams and C. C Meeker 535 Colorimetric Method Dwight Williams and George S. Haines 538 Determination of Small Amounts of Silica . . . . M. F. Adams 542 Determination of Hydrogen, Carbon, and Nitrogen in Magnesium Alloys E. G. Bobalek and S. A. Shrader 544 Determination of Sodium and Potassium in Silicates George G. Marvin and Lawrence B. Woolaver 554 Agar-Streak Method for Assaying Antibiotic Substances . Selman A. Waksman and H. Christine Reilly 556 Determination of Vitamin A . . . Bernard L. Oser, DanielMelnick,MortonPader,RoslynRoth, andMonaOser 559 Quantitative Determination of Carbon Disulfide Richard L. Bishop and E. Louise Wallace 563 Analysis of Cyclopropane-Propylene Mixtures by Selective Hydrogénation E. S. Corner and R. N. Pease 564 Ternary Mixtures of Three Isomeric Hecanes . . . Verle A. Miller 566 Identification of Sulfonated Azo-2-naphthol Dyes . Robert F. Milligan, Samuel Zuckerman, and Louis Koch 569 Quantitative Determination of Bases by Means of Calomel L. N. Markwood, H. D. Mann, and R. H. Carter 570 Metallo-Organic Complexes i n Organic Analysis . . Frederick R. Duke 572

R. H. MÜLLER B. L. OSER H . H. WILLARD

Colorimetric Determination of Molybdenum in Iron and Steel . . . Mitchell Kapron and Paul L. Hehman 573 Anhydrous Sodium Carbonate as a Standard of Reference in Acidimetry . . . Walter R. Carmody 577 Laboratory Distillation at Atmospheric Pressure of Normally Liquid Hydrocarbons H. J. Hepp and D. E. Smith 579 Cell for Determination of Dielectric Properties of Liquids L. I. Berberich 582 New Cutting-Wire Plastometer Luther L. Lyon and Robert D. Void 585 Backward-Feed Distillation Column W. M. Langdon 590 Constant-Volume Pump for Circulating Gases . . I. E. Puddington 592 MICROCHEMISTRY Microscope Goniometry J. D. H. Donnay and W. A. O'Brien 593 NOTES ON ANALYTICAL PROCEDURES Oxygen-Absorbing Solution for Scholander Quick Gas Analyzer Charles D. Stevens, Paul VanFossen, JaneK.Friedlander, Betty Jane Rattermann, and Masahiro Inatome Determination of Copper i n Copper Naphthenate ' A. A. McLeod Lundegârdh Air-Acetylene Burner Mary A. Griggs Addition of Solids to Reaction Mixtures Elijah Swift, Jr., and John H. Billman All-Glass Stirrer Robert P. Yeck Electrically Operated Buret . Frederick C. Nachod Titration of Boric Acid i n Presence of Mannitol . Max Hollander and William Rieman III Recommended Practice for Microscopical Reports on Crystalline Materials, in A.C.S. Publications . C. W. Mason, Chairman NBS Spectrographs Steel Standards

598 599 599 600 601 602 602 603 604

The American Chemical Society assumes no responsibility for the statements and opinions advanced by contributors to its publications. 31;9O0 copies of this issue printed. Copyright 1945 by American Chemical Society.

Published by the American Chemical Society at Easton, Pa. Editorial Office: 1155 18th Street, N. W., Washington β. D. C ; telephone. Republic 5301; cable, Jiechem (Washington). New York Editorial Branch: 60 East 42nd Street, New York 17, N. Y.; telephone, Murray Hill 2-4662. Chicego Editorial Branch: 310 South Michigan Avenue, Chicago 4, 111.; telephone, Wabash 7376. Business Office: American Chemical Society, 1155 16th Street, N. W., Washington β, D. C. Advertising Office: 332 West 42nd Street, New York 18, Ν. Υ.; telephone, Bryant 9-4430. Entered as second-class matter at the Post Office at Easton, Pa., under the Act of March 3, 1879, as 24 times a year—Industrial Edition monthly on the 1st, Analytical Edition monthly on the 15th. Acceptance for mailing at special rate of postage provided for in Section 1103, Act of October 3, 1917, authorized July 13, 1018. Remittances and orders for subscriptions and for single copies, notices of changes of address and new professional connections, and claims for missing numbers should be sent to the American Chemical Society, 1155 16th Street, N. W., Washington 6, D. C. Changes of address for the Industrial Edition

must be received on or before the 18th of the preceding month and for the Analytical Edition not later than the 30th of the preceding month. Claims for missing numbers will not be allowed (1) if received more than 60 days from date of issue Cowing to the hazards of wartime delivery, no claims can be honored from subscribers outside of North America), (2) if loss was due to failure of notice of change of address to be received before the dates specified in the preceding sentence, or (3) if the reason for claim is "missing from files". Annual subscription—Industrial Edition and Analytical Edition sold only as a unit, members S3.00, nonmembers $4.00. Postage to countries not in the Pan-American Union $2.25; Canadian postage $0.75. Single copies— current issues, Industrial Edition $0.75, Analytical Edition $0.50; back numbers, Industrial Edition $0.80, Analytical Edition prices on request; special rates to members. The American Chemical Society also publishes Chemical and Engineering News, Chemical Abstracts, and Journal of the American Chemical Society. Kates on request.