Infrared Multiphoton Dissociation Spectrum of ... - ACS Publications

C-F stretching mode of E-type symmetry has decreased from 1043 cm-' for CF3Mn(CO)S to 945 cm-' for CF,Mn(CO),-. Ligand Displacement Reaction Mechanism...
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J . Am. Chem. SOC.1990, 1 12, 2066-2069


to observe that the symmetric C-F stretching mode has changed very little in frequency from 1063 cm-' for CF3Mn(CO)5to 1052 cm-' for CF,Mn(CO)