Introduction to qualitative analysis (Layde, Durward C.) - Journal of

Introduction to qualitative analysis (Layde, Durward C.) W. D. Larson. J. Chem. Educ. , 1962, 39 (12), p 656. DOI: 10.1021/ed039p656.4. Publication Da...
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ment of the physical properties of the elements is extensive in each case. The numerous advances of recent years make it difficult to collect comprehensive data, on these elements, and their inclusion in one location makes this volume a valusble addition to reference materials availrtble on inorganic chemistry. This is particularly true of the organic compounds of boron.

A Short Textbook of Colloid Chemislry

B. J i ~ g e n s a sM. , D. Anderson Hospital and Tumor Institute, University of Texas, Austin, and M. E. Sbaumanis, School of Mines and Metallurgy, University of Missouri, Columbia. 2nd ed. Macmillan Co., Inc., New York, 1962. xvi + 500 pp. Figs. and tables 14.5 X 22.5 cm. $10.75.

ROGERV. K R U ~ Those familiar with the first edition of this text will findlittle change in the frameUniversity of Florida work and the textual makerial. The only Gainesville significant changes are the inclusion of references to the literature in the period 195&9 and corresponding discussions added to the m&terial in the earlier edition. These additions include brief accounts of the thermodynamics of polymer solutions, protein structure, sewage sludge flocculaQuimica ~ n a l h i c aCualitativa tion, isotactic polymers, X-ray diffraction of organic gels, optical activity and anisoJ . Ramiez-Muiioz and G. Salcedotropy of polymer solutions, and slight Escobar. Universidad Industrial de exprtnsions are evident in discussions of Santander, Bucaramanga, Colombia, foams, muscle contraction, rotational South America, 1961. 348 pp. Figs. viscometry and solid sols. Considerably and tables, 21 X 29.5 em. $5.50. more detailed discussions of emulsifiers, emulsion polymerization, and aerosols are This work is unique in that it is the first given. A few new illustrations of more textbook of its kind published in Comodern instrumentation are evident. lomhia; hence it marks a milestone toward Notable omissions are the Coulson Counter ending that country's dependence on for particle counting and the method of foreign language texkbooks. Its title determining pore sizes from desorption is somewhat misleading, since it is in fact isotherms. Several other topics might be a laboratory manual for qualitative noted in the missing category, but in view andyz4s; its actual reading material of the level of the text these are not serious. occupies not more than 110 of its 348 The hook is adequate for the short pages, the rest being used for the entry of course in colloids at the undergraduate labomtory notes and observations. level for students ~lanningto specialize Whereas in the U. S. the tendency is to in such areas as ~harmacy,medicine, and merge qualitative analysis with general engineering. It is purposely devoid of chemistry, in Latin America the former most mathematical and theoretical backremains a separate course. The hook was ground, yet provides an operational level designed for use in the macro or semiof information that should make it possible micro ranges. The use of the equipment to employ many techniques of colloids is carefully explained; it also gives detailed without further reference. On the other explanations on the preparation of reahand, much that is vital to modern colloids gents and it has a chapter on safety and -light scattering, ultracentrifugiug, and accident prevention. I t was written to adsorption-are treated in only rudimake the student less dependent on the mentary fashion. The present book apinstructor, a feature, I run sure, Colombian peam to he slightly more attractive than professors would appreciate, since the use its predecessor by virtue of being printed of assistants for labaratorv suoervision is on heavier paper and with holder typevirtuail\. unknowu in the co8l'ntry. The script but the bindings are of almost equal tmuk in;tker little use of organic rrxyents, quality. rwt sirrg brwr1d Jimrth~lplyoxinw:!nd rhodmine B. W. H. SLABAUGH The senior author of the textbook, Dr. J. Oregm State University Ramlrez-Muiioz, a Spaniard now living in Corudlis Colombia. is also the co-author of a treatise on flame photometry; he i8 a professor of a,ntnalytical chemistry and director of the Research Division of the Industrial University of Santander. He is one of the organiaers of the "Latin American Society Initiation & la Chimie Physique (Chimie for Analytical Chemistry." Colldidale en Particulier) The book is very well printed, on good H . R . K r u y and J. Th. G. Overbeek, quality paper, profusely illustrated and both of the University of Utrecht. remarkably free of errors. I t makes, Masson et Cie., Paris, 1961. 236 pp. therefore, a valuable contribution to the Fige. and tables. 13.5 X 22 em. teaching of the subject in Colombia. Cartonne 25 NF. This work could he useful to American chemists heading for assignments in This book is a translation of the fifth Spanish speaking countries who would Dutch edition of 1958 of "Inleidung tot de want to acquaint themselves with the Physische Chemie," hut it offers a brief, chemical nomenclature and laboratory modern viewpoint of colloidal phenomena practices of the Latin American m~ntries. clearly written in contemporary French. J. VIKIN It is not to be confused with the major reference text in two volumes, "Colloid Xew Yo& City Community College Science,"composed by Kmyt. Brooklyn ,

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Journal of Chemical Educofion

The present book offera in condensed farm the rudiments of claesical physical chemistry with an emphasis on modern colloids indicative of the significant contribution the authors have made to this area in the last 35 years. The primary aim of the text appears to fill the need by biological and biochemical scientists for an introduction to electrochemistrv.. surf x e p h t n ~ n w m electrokinrtica, , and hydruphilic.nrld lgdruphobic colloids.

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W. H. SLABAUOH Oregon State University Coruallis

Introduction to Qualitative Analysis

Durward C. Layde, University of Wisconsin-Milwaukee. Allyn and Bacon, Inc., Boston, 1961. 350 pp. Figs. and tables. 15.5 X 23.5 em. $3.75. This book is intended for use in the teaching of qualitative analysis in the second semester of freshman chemistry. I t is divided into three parts: Theory, The Metals, The Laboratory. The first part contains the topics usually treated in courses in qualitative analysis. In addition there are two good chapters, one on nomenclature of inorganic compounds and one on chemical equations. The first gives a goad elementary summary for naming compounds and ions; the second encourages the use of net ionic equations. The author is to he commended for inclusion of this material. The second i art includes metallurev

may not realize how much material is covered. For example, oxidation potentials for the wrious metals and their ions are often given, hut only in one case are they used in the text to show their use in the prediction of properties. Part three gives what appear to be satisfactory procedures for the classical methods. There are no experiments which familiarize the student with the properties of the ions before plunging him into worked-out procedures. This seems to be a serious lack, since it is likely to encourage a slavish following of the proeedures without an appreciation of the reasons for the directions and precautions given. The book is free from gross errors; one may wonder why the author writes an equation for the hydrolysis of thioacetamide in 0.5 M strong acid solution with one of the products acetate ion. Similarly, he is careful to write SnC4'- as the principal species of tin in the + 4 oxidation state in hydrochloric acid medium, hut writes Sns+ for the principal species of tin in the + 2 state in the same medium.

W. D. LARSON College of St. Thomas St. Paul, Minne~ota (Continued on page A970)