Introductory chemistry - ACS Publications

the "film" or Hatta Theory, the penetra- tion theory, chemical reaction in a turbu- lent boundary layer, ion diffusion, snt- pended e&dysts, fixed-hed...
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rived, and with this important matter now rrfwrru rs iwde I,? v m n t r y du not seem to rrfvr to p:trtivulavl,v tylrivul n illtempt to are treated in the following six ohapters. make certain that most of the major counChapter 12 consists of a thorough, tries are mentioned somewhere in the hook. modern, treatment of chemical kinetics. There are a number of diagrams and four A discussion of oollaids and surface chemdouble pages of pictures, likewise distribistry follows, notable for its attention to uted geographically. The hook also conthe mathematicsl details associl~tedwith tains a three-page glossary of standard this topio. In the remaining third of the terms. The booklet contains a few errors. One book emphasis is placed upon ohemical physios, beginning with atomic structure, reference is t o the gas diffusion isotope continuing through nuclear chemistry, separation in which the pamphlet states molecular structure, the solid state, photothat a mixture of isotopes passes through a chemistry, and radiation chemistry. (As wall which tends to retain the Lightest isomight be expected from the research tope. There is also a reference to GM interests of the authors, this chapter will counters which are reported to count beta he stimulating to the students.) The final or gamma radiation a t rates up to 10,000 chapter is on ohemical statistics. per second. A reference is also made to There are three features in this text that "Professor Galvin's" work on photosynindicate it was written for the student. thesis. There also seems to be some nnFirst, within each chapter are several certaintv ahout the definition of a hiological half life. On the whole, there are exercises clearly designed to help the sturemarkably few such errors, and likewise dent understand the material discussed in only a few tvpographieal errors. the chapter. I n general, the exercises are simpler than the a t the ends This pamphlet would probably he of JOHN J . MCKETTA considerable use as a rapid, semitechnical of the chapters mid thus they also prepare Univwsity of Tezas the student to meet the challenge of the introduction to the use of radioactive is* Austin problems. Second, a t the end of each topes in any situation in which such a survey would he useful. Since no suhstanchapter the materialis briefly summarized. tiating information is given other than the Third, there are frequent references to the literature throughout the text and a sestatement that a certain type of work is or Rodioisotoper in the Service of Man lected bibliography in an appendix lists has been done, it would not be part~ieularly valuable as a research reference. It a p several other texts and reference works. Fernand Lot. UNESCO, Paris, 1958. A reviewer, in order to convince the pears to have quite useful possibilities for 82 pp. 13.5 X 21.5 em. Paperhound. the casual reader with some technical reader of his objectivity, should find a 1 . (Available from UNESCO Public* background. few things wrong with a text under retions Center, 801 Third Ave., New York view. No doubt this text has its flaws but 22.) they are not very ohvions. Perhaps some will decide that the rigorous style of writing will not inform the student as well as dealing with various programs of this orhas been implied here. I would haveliked ganization. It might he charaoterized to see several references, ~ e r h a p as s a short heat by saying that it has the highest denbibliogrsphicd listing a t the end of each Principles of Physical Chemistry sity of isotope applications of any volume chapter, t o the many excellent articles with which I am familiar. I t is evident that have appeared in J. CHEM. EDUC. William H. Hamill, University of Notre that i t is not possible to treat in any detail from time to time. But these are minor Dame and Russell R. Williams, JT., most of the applications mentioned in the points. This text is recommended for Haverford College. Prentice-Hall, Inc. book, but it is of quite considerable usefulserious consideration to all who are looking Englewood Cliffs, New Jersey, 1959. ness in referring to a, wide variety of isofor a different text for the physical chemisx 607 pp. Figs. and tables. 16 X tape applications. try course. If not used in the classroom, 23.5 cm. $8.75. The volume is written with a somewhat i t should he available in the library. I t This book is addressed to the student popularized approach, although it mainwill also serve as a concise summary of who can think, or who is willing to try to tains a good technical level throughout modern ohemistry for others who learn to think. I t will be necessary, often, most of its pages. The first four chapters wish to refresh their understanding. are general statements having to do with to read a. sentence more than once, to diliJAY A. YOUNG the era of radioisotopes, natural radioamgently study a. table or a graph. But King's College once understood, there will be no need to tivity, the production of radioactive isoWilkes-Bawe, Pennsylvania learn a different interpretation in future topes (in the neutron furnace), and the detection of radiation. studies. There are no tacitly qualified statements in this text. The authors are Chapter V combines applications in physics, chemistry, biology, andagronomy; to he commended for their careful choice the following chapters have to do with the of preoise, informative, and accurate ststeIntroductory Chemistry therapeutical use of radioactive isotopes, ments. This text is outstanding for the Lillian Hoagland Mehleyw, Western Michindustry, and a potpourri ranging from the rigor of its treatment. igan University. 2nd ed. The Mecfight against insects to the study of meteThe material that should be disoussed in millan Co., New York, 1959. viii orites. Chaptcr IX contains a few pages an elementary treatment of physical chem528 pp. Figs. 14.5 X 22 cm. $6. on the effects of radiation on living beings, .istry is growing daily. For this reason, with the last chapter being comments relaperhaps, the authors havechosen to discard Tbere is great similarity in subject mattive to the 1957 UNESCO Conference on the traditional order of presentation. ter between this second edition and the Radioisotopes. This choice has enabled them t o include first one which appeared eight years ago. In general, i t can be said that the author the necessary new additions without extenThe book is of approximately the same attempted to balance not only the use of sive digressions t h a t would be forced into length. The chapter headings are alike. isotopes in various fields, but also to halthe older, classical, order of discussion. The material is directed toward the same lance the work being donc in various counAfter an introduction consisting of an group of students in home economicrr, tries. Most of the applications are not accurate, ordered choice of preliminary nursing, physical education, agriculture, identified as to where or by whom the topics, the First Law is explained in Chapand biology. However, the text haa been work is being done, although some ter 2. This is followed by s. discussion of brought up-to-date b y additions snd subspecific references are made to work in thermochemistry and the Second Law. I n both eastern and western countries. The Chapter 5 the free energy equation is dc(Cmtinued on page A704) mechanism of the transfer process. Any chemiod engineer who let the field of mass transfer slip from his grasp during the past years will appreciate this review t o bring him up to date in this important field. Even those who are familiar with this field will enjoy Professor Sherwood's method of presentation. The subjects covered are as follows: molecular diffusion, diffusion coefficients in gases, diffusion coefficients in liquids, eddy diffusion, transfer from s. solid to a. turbulent stream, generalized "andogy," some of the better-known "analogies," the Chilton-Colhurn analogy, compressible flow, mass transfer with chemioal reaction, the "film" or Hatta Theory, the penetration theory, chemical reaction in a turbulent boundary layer, ion diffusion, sntpended e&dysts, fixed-hedcatalysts, diffuion in porous eatttalpsts, mass transfer hetween two phases, and barriers a t phase boundaries. This presentation should be on every chemical engineers' work shelf.

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BOOK REVIEWS stitutions both in large and small degree depending upon the extent of adwncement in the different branches of chemistry according to the author's preface. The text shows most change in hiochemistry, textileehemistry, and radiochemistry for the reason given b y Dr. Meyer. These changes have been made without increasing the length of the sections. Certain pictures and diagrams have been omitted without apparent loss in the reviewer's opinion. The chemical structure of proteins and carhahydrates receives more emphasis. Some interesting applications have been added. The relationship is given between different blood groups and the heteropolysaecharides occurring on the surface of the red blood cells. In the textile field the information on detergents is expandcd to include new ones of interest to home economics students. Moreover, solid bleaches and fabric softeners are new additions to this section. Modernization has been effected by substituting more recent data in charts as well as by rearranging material, rewriting it, and adding exercises and problems. The section on atomic theory which includes radioactivity has been rearranged and rewritten in part. Numerous small changes appear throughout the hook reflecting a careful review of the material by the author in the light of chemical advancement as well as the reactions of students to the contents as noted above. The hook should appeal to those who found the first edition useful. I t should win new friends among teachers who have not tried the first one beesuse it meets the needs of the students for whom it was written. HELENI . MINER 770 Lake Road 'Miami, Florida

Using Chemistry

Oscar E. Lanford, Dean, State University of New York, College for Teachers. Revised ed. McGraw-Hill Book Co., 738 pp. Ine., New Yark, 1959. xiii Figs. and tables. 16.5 X 23.5 cm. $5.48.

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It should he said a t once that the revised edition of "Using Chemistry," copyright 1959, shows praetioally no change from the 1955 edition. Change in color of the cover, the introduction of several colorful pages which illustrate by means of a take-apart mechanism the ilrwture of a nurl&r power plnnr, and 250 nddirionzl que\tions apprnr to he rhv only real diffvrrncr. Thi5 is not to tin\.. however, that this text compares unfavdr: shly with other "new" high school chemistry hooks. This hook is strong in severs1 ways: the emphasis is on principles of science rather than on descriptive material; the language is direct and uncomplicated; the descriptive material is significant, and is presented in interesting fashion; there is an attempt made to look a t the most recent (Continued on page A706)

A704

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Journal of Chemical Education