Investigating the Micro-Mechanical Properties of Hydrogel Glasses Using Confocal-Rheology Daniel L. Blair PhD 49778-DNI7 Georgetown University Department of Physics and Institute for Soft Matter pH = 3.0
10 µm
pH = 3.5
10 µm pH = 4.0
10 µm
pH = 4.5
We create N-Isopropylacrylamide microgel particles that are large, stable and fluorescent. This new synthesis technique provides us with unprecedented access to the microscopic behavior of these systems through the use of laser scanning confocal microscopy and rheology
900
10 µm
800 Measurements Average
Radius (nm)
Using laser light scattering methods, we are able to characterize the sizes and osmotic compressibility through the inclusion of non-adsorbing polymers. The dynamic range of volume fractions of these systems is ideal for studying the glass transition like never before
700
600
500
400
300
200 25
27
29
31
33
35
37
Temperature (C)
39
41
43
45