JANUARY 15, 1992 VOLUME 64 NUMBER 2 *>
ANCHAM The AUDIT 64(2) 63A-114A/113-240 (1992) eureau |SSN 0003-2700
Analytical® CHEMISTRY
Registered in U.S. Patent and Trademark Office; ©Copyright 1992 by the American Chemical Society EDITOR: ROYCE W. MURRAY ASSOCIATE EDITORS: Catherine C. Fenselau, Georges Guiochon, Robert A. Osteryoung, Edward S. Yeung Editorial Headquarters 1155 Sixteenth St., N.W. Washington, DC 20036 Phone:202-872-4570 Telefax: 202-872-4574 Bitnet: rmh96@cas Internet:
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REPORT
Contributing Editor: Marcia Vogel
I m m u n o c h e m i c a l m e t h o d s for e n v i r o n m e n t a l analysis. In the struggle to clean up our planet, many innovative technologies have been created, and one has been borrowed from the biomedical and clinical arenas. Jeanette M. Van Emon of the U.S. EPA and Viorica Lopez-Avilia of Midwest Research I n s t i t u t e outline t h e principles, applications, and promise of immunochemical techniques to characterize contaminants
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ANALYTICAL APPROACH
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On the cover. P r o b i n g the m y s t e r i e s of a n c i e n t Egypt. During the past 30 years, several research groups have used a wide variety of techniques to investigate m u m mies. Sarah U. Wisseman and coworkers at the University of Illinois at U r b a n a - C h a m p a i g n describe their investigation of hum a n tissue and m u m m y w r a p pings to l e a r n more about t h e h e a l t h and diseases of a n c i e n t Egyptians and the materials and methods used for embalming
COVER: Artist's rendering by Cory Correll of an Egyptian line drawing depicting the opening of the mouth ceremony. Based on the original hunefer papyrus scroll (circa 1290) from the British Museum, London.
UPCOMING RESEARCH
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NEWS
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Ray Clement, Norman Dovichi, and John Olesik are appointed to ANALYTICAL CHEMISTRY'S I n s t r u m e n t a t i o n Advisory P a n e l · 10th annual chemistry graduate students' s y m p o s i u m to be held at SUNY Buffalo
MEETINGS
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The 4th S y m p o s i u m o n C o m p u t e r - E n h a n c e d Analytical Spectrosc o p y will be held J u n e 1 7 - 1 9 at Snowbird, UT. · Fluorescence and photothermal spectroscopies are the subject of the 45th Annual S u m m e r S y m p o s i u m o n Analytical Chemistry, to be held J u n e 2 3 - 2 5 at Utah State University
BOOKS
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Critical r e v i e w s . Books on TLC, protein purification, affinity membranes, flow cytometry, and ion exchange are reviewed
NEW PRODUCTS & MANUFACTURERS' LITERATURE
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ANALYTICAL CHEMISTRY, VOL. 64, NO. 2, JANUARY 15, 1992 · 67 A
Analytical Chemistry ANALYTICAL CHEMISTRY (ISSN 0003-2700) is published semimonthly by the American Chemical Society at 1155 Sixteenth St., N.W., Washington, DC 20036. Editorial offices are located at the same ACS address (202-872-4570; fax 202-872-4574; Bitnet rmh96@cas; TDD 2028 7 2 - 8 7 3 3 ) . S e c o n d - c l a s s postage paid at Washington, DC, and additional mailing offices. Postmaster: Send address changes to ANALYTICAL CHEMISTRY, Member & Subscriber Services, P.O. Box 3337, Columbus, OH 43210. Canadian GST Reg. No. R127571347.
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Articles Ultramicroelectrode Voltammetry in a Drop of Solution: A New Approach to the Measurement of Adsorption Isotherms at the Solid-Liquid Interface Patrick R. Unwin and Allen J. Bard*
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Ferrioxalate Solutions for Calibration in Oxygen and Carbon Dioxide Measurements Gary S. Calabrese* and Lynn Christian-Maillet
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Problems of Quantitative Injection in Capillary Zone Electrophoresis Eric V. Dose and Georges Guiochon *
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Enzymatic Flow Injection Analysis in Nonaqueous Media Lorenzo Braco, José A. Darós, and Miguel de la Guardia * Electrochemical Actinometry Using the Assembled Monolayer Film of an Azo Compound Zhong-Fan Liu, Kenichi Morigaki, Kazuhito Hashimoto, and Akira Fujishima * Electrochemical Immobilization of Enzymes. 3. Immobilization of Glucose Oxidase in Thin Films of Electrochemically Polymerized Phenols Philip N. Bartlett*, Peter Tebbutt, and Claire H. Tyrrell
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Peroxidase Model Electrodes: Sensing of Imidazole Derivatives with Heme Peptide-Modified Electrodes Tetsu Tatsuma* and Tadishi Watanbe*
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Determination of Ascorbic Acid Using an Organic Conducting Salt Electrode Ulrich Korell and R. Bruce Lennox*
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Mercury-Coated Carbon-Foam Composite Electrodes for Stripping Analysis of Trace Metals Joseph Wang*, Albert Brennsteiner, Lucio Angnes, Alan Sylwester, Robert R. LaGasse, and Nils Bitsch
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Calibration of a Windowless Photoacoustic Cell for Detection of Trace Gases György Z. Angeli*, Anikó M. Sólyom, András Miklós, and Dane D. Bicanic
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Optimization of Comprehensive Speciation of Organotin Compounds in Environmental Samples by Capillary Gas Chromatography/ Helium Microwave-Induced Plasma Emission Spectrometry Ryszard Lobiński, Wilfried M. R. Dirkx, Michiel Ceulemans, and Freddy C Adams *
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Role of Electron-Donating/Withdrawing Character, pH, and Stoichiometry on the Chemiluminescent Reaction of Tris(2,2'-bipyridyl)ruthenium(III) with Amino Acids Stephen N. Brune and Donald R. Bobbitt* Apodization Functions in Fourier Transform Ion Mobility Spectrometry Robert H. St. Louis*, William F. Siems, and Herbert H. Hill, Jr.
*Corresponding author
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ACS membership Information: Lorraine Bowlin (202-872-4567)
ANALYTICAL CHEMISTRY, VOL. 64, NO. 2, JANUARY 15, 1992 · 69 A
Analytical® CHEMISTRY
Editorial Information Instructions for authors of AC RESEARCH are published in the January 1 issue, p. 107. Guidelines for the INSTRUMENTATION, REPORT, ANALYTICAL APPROACH, and A/c INTERFACE features are
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Elimination of Axial Ejection during Excitation with a Capacity Coupled Open Trapped-Ion Cell for Fourier Transform Ion Cyclotron Resonance Mass Spectrometry Steven C. Beu and David A. Laude, jr. * Determination of Human Serum Alcohol Dehydrogenase Using Isozyme-Specific Fluorescent Substrates Jack Wierzchowski, Barton Holmquist, and Berth Vallée"
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Thermal Degradation of a Thermolabile Serratia marcescens Nuclease Using Capillary Electrophoresis with Stacking Conditions 187 Anders Vintner*, Henrik Seeberg, Lars Nielsen, Jytte Pedersen, andKirsten Biedermann Waveform Fidelity in Pulsed-Field Capillary Electrophoresis D. N. Heiger, S. M. Carson, A. S. Cohen, and B. L. Karger Instrumentation for the Breath-by-Breath Determination of Oxygen and Carbon Dioxide Based Nondispersive Absorption Measurements . Peter R. Arnoudse, Harry L. Pardue ", Joe D. Bourland, Robert Miller, and Leslie A. Geddes Labile Hydrogen Counting in Biomolecules Using Deuterated Reagents in Desorption Chemical Ionization and Fast Atom Bombardment Mass Spectrometry Alessandro Guarini", Gianfranco Guglielmetti, Nunzio Andriollo; and Marco Vincenti Novel Triangle Scheme for Classification of Gas Chromatographic Phases Based on Solvatochromic Linear Solvation Energy Relationships Jianjun Li, Yunke Zhang, and Peter W. Can" High-Performance Capillary Isoelectric Focusing with a Concentration Gradient Detector Jiaqi Wu andjanusz Pawliszyn "
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Correspondence Universal Detection for Capillary Isoelectric Focusing without Mobilization Using a Concentration Gradient Imaging System Jiaqi Wu andjanusz Pawliszyn "
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Analytical Solution for Dispersion in Capillary Liquid Chromatography with Electroosmotic Flow James P. McEldoon and Ravindra Datta "
227
Technical Notes Spontaneous Reaction for Acid Dissolution of Biological Tissues in Closed Vessels Ram N. Sah " and Robert O. Miller
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Supercritical Fluid/Super sonic Jet Spectroscopy with a Sheath-Flow Nozzle Chung Hang Sin, Matthew R. Linford, and Steven R. Goates*
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Derivatization in Trace Organic Analysis: Selection of an Inert Solvent Kariman Allam, Samy Abdel-Baky, and Roger W. Giese"
238
Author Index
240
ANALYTICAL CHEMISTRY, VOL. 64, NO. 2, JANUARY 15, 1992 · 71 A
