Subscriber access provided by UNIV OF NEBRASKA - LINCOLN
Article
Large-scale hydrological modeling for calculating water stress indices: Implications of improved spatio-temporal resolution, surface-groundwater differentiation and uncertainty characterization Laura Scherer, Aranya Venkatesh, Ramkumar Karuppiah, and Stefan Pfister Environ. Sci. Technol., Just Accepted Manuscript • DOI: 10.1021/acs.est.5b00429 • Publication Date (Web): 30 Mar 2015 Downloaded from http://pubs.acs.org on April 4, 2015
Just Accepted “Just Accepted” manuscripts have been peer-reviewed and accepted for publication. They are posted online prior to technical editing, formatting for publication and author proofing. The American Chemical Society provides “Just Accepted” as a free service to the research community to expedite the dissemination of scientific material as soon as possible after acceptance. “Just Accepted” manuscripts appear in full in PDF format accompanied by an HTML abstract. “Just Accepted” manuscripts have been fully peer reviewed, but should not be considered the official version of record. They are accessible to all readers and citable by the Digital Object Identifier (DOI®). “Just Accepted” is an optional service offered to authors. Therefore, the “Just Accepted” Web site may not include all articles that will be published in the journal. After a manuscript is technically edited and formatted, it will be removed from the “Just Accepted” Web site and published as an ASAP article. Note that technical editing may introduce minor changes to the manuscript text and/or graphics which could affect content, and all legal disclaimers and ethical guidelines that apply to the journal pertain. ACS cannot be held responsible for errors or consequences arising from the use of information contained in these “Just Accepted” manuscripts.
Environmental Science & Technology is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Published by American Chemical Society. Copyright © American Chemical Society. However, no copyright claim is made to original U.S. Government works, or works produced by employees of any Commonwealth realm Crown government in the course of their duties.
Page 1 of 33
Environmental Science & Technology
1
Large-scale hydrological modeling for calculating
2
water stress indices: Implications of improved
3
spatio-temporal resolution, surface-groundwater
4
differentiation and uncertainty characterization
5
Laura Scherer1*, Aranya Venkatesh2, Ramkumar Karuppiah2, Stephan Pfister1
6
1
ETH Zurich, Institute of Environmental Engineering, 8093 Zurich, Switzerland
7
2
ExxonMobil Research and Engineering Company, Annandale, NJ, 08801, United States
8
*Phone: +41-44-632-31-72. E-mail:
[email protected].
9 10
ABSTRACT
11
Physical water scarcities can be described by water stress indices. These are often determined
12
at an annual scale and a watershed level; however, such scales mask seasonal fluctuations and
13
spatial heterogeneity within a watershed. In order to account for this level of detail, first and
14
foremost, water availability estimates must be improved and refined. State-of-the-art global
15
hydrological models such as WaterGAP and UNH/GRDC have previously been unable to
16
reliably reflect water availability at the subbasin scale. In this study, the Soil and Water
17
Assessment Tool (SWAT) was tested as an alternative to global models, using the case study
18
of the Mississippi watershed. While SWAT clearly outperformed the global models at the 1 ACS Paragon Plus Environment
Environmental Science & Technology
19
scale of a large watershed, it was judged to be unsuitable for global scale simulations due to
20
the high calibration efforts required. The results obtained in this study show that global
21
assessments miss out on key aspects related to upstream/downstream relations and monthly
22
fluctuations, which are important both for the characterization of water scarcity in the
23
Mississippi watershed and for water footprints. Especially in arid regions, where scarcity is
24
high, these models provide unsatisfying results.
25 26
TOC ART
27 28 29
INTRODUCTION
30
Water scarcity is a global issue affecting human and ecosystem health in many regions across
31
the world.1 Globalized markets mean that the distances between production and consumption
32
are large, making reliable information on the supply chain of products difficult to obtain.2 To
33
account for impacts related to water consumption, water stress indices (WSI) have recently
34
been integrated in water footprinting3 and life cycle assessment (LCA), a methodology to
35
quantify the cradle-to-grave environmental impacts of a product or service.4 Multiple methods
36
have been developed to assess the impacts of freshwater use,5 all of which utilize existing
37
water availability data from hydrological models at global scale. Several of these models were 2 ACS Paragon Plus Environment
Page 2 of 33
Page 3 of 33
Environmental Science & Technology
38
compared by Haddeland et al.6 who identify huge differences among the models, especially in
39
arid regions. This highlights the difficulty of hydrological modeling at a large scale, which, in
40
turn, demands a proper evaluation of model performance and uncertainty. These hydrological
41
models often lack transparency of algorithms and parameterizations after calibration.
42
Furthermore, model performance is only assessed in a simplified manner and uncertainty is
43
not communicated.
44
Several concepts have been proposed to improve the assessment of WSI. Loubet et al.7 split
45
watersheds into smaller units and analyzed WSI per subbasin, while Boulay et al.8
46
differentiated surface and groundwater in the stress assessment. A clear research gap is
47
identified, given that differentiation of water sources becomes more relevant at higher spatial
48
and temporal resolution and that the combined effect of these aspects on WSI is still missing.
49
While Boulay et al.9 tested the effect of using different global models to characterize the
50
uncertainty in WSI, they did not analyze the uncertainty in the underlying models themselves.
51
This study attempts to utilize large-scale hydrological modeling, using the Soil and Water
52
Assessment Tool (SWAT)10 to obtain improved estimates of WSI. This approach is an
53
alternative to using outputs from existing global hydrological models, while simultaneously
54
refining the spatial resolution from watershed to subbasin level. While SWAT was originally
55
developed for watershed simulations, it has already been used for larger scale simulations,
56
such as in Africa,11 Iran12 and the Danube watershed.13 This study also aims to estimate WSI
57
that differentiate between surface and groundwater use and availability, which has often been
58
ignored in previous LCA studies.
59
In order to analyze the model performance of global models in comparison to regional SWAT
60
results and to investigate additional insights afforded by higher spatial resolution in the
61
calculation of WSI, the tool was tested on the Mississippi watershed, which drains more than 3 ACS Paragon Plus Environment
Environmental Science & Technology
62
3,000,000 km2. Model performance and uncertainty were each assessed using a series of
63
methods. The resulting water availability was compared to outputs from the global models
64
WaterGAP6,14 and UNH/GRDC.15 The more detailed model set up in this work, providing
65
monthly results on subbasin level for ground and surface water, was used to estimate
66
alternate, improved WSIs. In addition, the modeling uncertainty was quantified and
67
propagated to these (new) WSI. Last but not least, scenario analysis was used to estimate
68
potential future water stresses following increased irrigation demand.
69 70
MATERIALS AND METHODS
71
Water balance modeling. Water balance simulations of the Mississippi watershed were
72
performed using SWAT version 2009.16 SWAT is a physically-based hydrological model that
73
simulates the water cycle within a watershed, using inputs such as temperature, precipitation,
74
and land use, along with extensive calibration and validation. The entire Mississippi
75
watershed was delineated into 451 subbasins and was run over a period of 30 years from 1971
76
to 2000, where the first five years were used as a warm-up period, i.e. the output was
77
disregarded during post-processing. Further details are presented in the Supporting
78
Information (SI).
79
A few modifications were made to the existing SWAT model, in order to improve the
80
formulation and results. Firstly, to better simulate potential evapotranspiration, the Fortran
81
source code was adapted by modifying the Priestley-Taylor method that can be used to
82
estimate this parameter within SWAT. The original coefficient of 1.28 in the Priestley-Taylor
83
equation, representing both humid and arid climates, was replaced by a conditional statement
84
using different coefficients for humid (1.26) and arid (1.74) climates, where the latter was
85
defined by a condition of relative humidity < 60%.17 4 ACS Paragon Plus Environment
Page 4 of 33
Page 5 of 33
Environmental Science & Technology
86
Secondly, when using ArcSWAT18 as a pre-processing interface to provide input data to
87
SWAT, one weather station of each climate variable is typically assigned to each subbasin. In
88
this study, instead of using the weather station closest to the subbasin’s centroid, all available
89
weather information (time series of grid cells) within one subbasin was averaged. In addition,
90
since the original SWAT model restricts the number of weather stations for solar radiation
91
and relative humidity to 300 while the watershed was discretized into 451 subbasins, the
92
source code was modified to circumvent this restriction.
93
Thirdly, outflow from a reservoir was simulated based on a modified target release scheme.
94
The SWAT model assumes that all reservoirs are used for flood control and distinguishes
95
between flood and non-flood season. Since not all reservoirs conform to this assumption, the
96
scheme was modified to represent multi-purpose reservoirs according to Wu and Chen.19
97
The input data used in setting up the model are described in the SI section S2.
98
Calibration and validation. The model was calibrated against monthly river discharge at 131
99
gauges (Figure S1) within the watershed. Monthly time series at these gauges were split
100
equally into two parts and the more recent data were used for calibration, while the earlier
101
data were used for validation. The parameters selected for calibration are described in S3.
102
River discharge was calibrated manually and for each subbasin individually. The model
103
performance was evaluated based on visual inspection and four efficiency criteria: i) Nash-
104
Sutcliffe efficiency (NSE), ii) percent bias (PBIAS), and iii) root mean square error (RMSE)
105
normalized to standard deviation (RSR) as recommended by Moriasi et al.,20 as well as iv)
106
bR2 as suggested by Krause et al.21 All these criteria compare simulations to observations, and
107
provide goodness-of-fit metrics that emphasize different aspects of the hydrograph, such as
108
systematic or conditional bias. A further discussion on the relevance of these metrics is
5 ACS Paragon Plus Environment
Environmental Science & Technology
109
presented in the SI (section S3). Performance ratings based on these metrics are provided in
110
Table S2.
111
Overall model performance for the entire Mississippi watershed was determined by averaging
112
subbasin performance, measured by the four efficiency criteria, using three different
113
weighting criteria: (i) Equal weights (e.g., the NSE for the entire watershed is the simple
114
average of NSEs for the individual subbasins), (ii) weighted by catchment area and length of
115
time series of all observations for individual subbasins (using the square root of time series
116
length to lower its influence compared to the catchment area), or (iii) weighted by the
117
observed river discharge in individual subbasins. Since NSE and RSR are strongly affected by
118
outliers, the trimmed means22 (by removing the 5% highest and lowest values) or geometric
119
means23 were additionally calculated.
120
For comparison with manual calibration, automatic calibration was carried out using the
121
SWAT Calibration and Uncertainty Programs (SWAT-CUP) version 201224.
122
In addition, the observed evapotranspiration (ET)25 was compared to estimated
123
evapotranspiration. By evaluating a component of the hydrological cycle besides river
124
discharge, a deeper insight into the quality of the water balance is obtained. This is especially
125
interesting with regards to groundwater recharge, which cannot be directly validated by runoff
126
gauges. The overall model performance for ET was either averaged using equal weights or
127
weighted by the subbasin area.
128
Model uncertainty. In one of the algorithms implemented in SWAT-CUP’s automated
129
calibration procedure, SUFI-2, simulated river discharge is characterized by a prediction
130
uncertainty band. Overall model uncertainty is assessed by two metrics (i) the p-factor, which
131
refers to the percentage of observed data that is bracketed by the model predicted uncertainty
132
band, and (ii) the mean difference between the upper and lower limits of that band (r-factor) 6 ACS Paragon Plus Environment
Page 6 of 33
Page 7 of 33
Environmental Science & Technology
133
normalized by the standard deviation of the observed variable.26,27 Ideally, all measurements
134
would be bracketed by the band (i.e., p-factor of 100%) and its width (i.e., r-factor) would
135
approach zero. The prediction uncertainty band estimated by SUFI-2 is a result of the
136
algorithm used in automated calibration, which is not estimated in the case of manual
137
calibration. Therefore, in this study, uncertainty ranges were developed to include 75% or
138
95% of the observed data (i.e., p-factor of 75% or 95%). Measurement uncertainty was
139
considered by assuming a relative error of either 10%28,29 or 25%30 for the observed river
140
discharge data. Two cases for calculating r-factors were considered. Either i) it was inspected
141
if the two bands overlapped at all (simple overlap; SO), or ii) by how much the bands
142
overlapped on average (percentage overlap; PO).
143
Model comparison and spatial association analysis. The SWAT model outputs of river
144
discharge and groundwater recharge were spatially compared to the outputs from the
145
WaterGAP model14 as used in the WATCH project31 and from UNH/GRDC.15 WaterGAP
146
covers the entire simulation period while the UNH/GRDC model is only available for the
147
years 1986 to 1995. Both models have a resolution of 0.5°. The grid cells were disaggregated
148
to a finer resolution keeping the original cell values (i.e. without interpolation), and
149
subsequently aggregated to subbasins as defined in the SWAT model. A third global
150
modeling framework, Aqueduct32 was also evaluated. However, a proper comparison was
151
impeded by the aggregation of the available data to annual averages of a different time period
152
(1950 – 2008) at the level of subbasins larger than those delineated in this study (178
153
compared to 451 for the Mississippi). Only the 44 discharge gauges that were at most 100 km
154
from an outlet of a subbasin were included in the analysis.
155
The cross-correlation between the two datasets (i.e., water availability from two models) was
156
evaluated using the bivariate spatial association measure (BSA) developed by Lee,33 which
157
integrates Pearson’s correlation coefficient and Moran’s index for spatial autocorrelation. 7 ACS Paragon Plus Environment
Environmental Science & Technology
158
Values of BSA closer to ±1 typically indicate a strong positive correlation between two
159
spatial datasets. Furthermore, the level of agreement (LA) between water availabilities from
160
two models was also determined. Since exact matches of water availabilities between models
161
would be unrealistic LA refers to the percentage of observations that lie within the
162
intersection of two intervals, each representing 25% relative error in water availability from
163
the two models. If the bands overlap completely, 100% LA is expected.
164
The goodness of the SWAT model (evaluated by the efficiency criteria) was spatially
165
correlated to various parameters that might explain the weaknesses of the model: the aridity
166
index (AI) as the ratio of mean annual precipitation to mean annual potential
167
evapotranspiration34, the average slope of the main river channel within each subbasin as
168
retrieved from the SWAT model, the average number of days with snowfall per year (SD), i.e.
169
precipitation days with below zero temperatures, and the fragmentation of the river network
170
caused by upstream reservoirs (RF). For the RF metric, all 52 reservoirs within the
171
Mississippi watershed available in the Global Lakes and Wetlands Database (GLWD)35 were
172
considered.
173
Water stress indices. Water stress indices (WSI) were calculated according to Pfister et al.36
174
and Pfister and Bayer37 for 24 different cases (see also SI section S6) taking into account (i)
175
total water, surface water or groundwater resources, (ii) annual or monthly resolution, (iii)
176
water withdrawal or water consumption and (iv) upstream level or subbasin level.
177
At the upstream level, the upstream water use was added to the local water use as both lessen
178
the local water availability.7 In contrast, at the subbasin level only local water use was
179
considered, and only the surface runoff generated in the subbasin was taken into account
180
instead of total river discharge.
8 ACS Paragon Plus Environment
Page 8 of 33
Page 9 of 33
Environmental Science & Technology
181
Surface and groundwater availability uncertainties were estimated and propagated to the
182
resulting WSI: for surface water, absolute uncertainty was set to the value for which 75% (p-
183
factor) of the measurement band (assuming 10% measurement uncertainty) overlapped with
184
the simulation band (PO). For groundwater recharge, no direct measurements were available
185
and the uncertainty was assessed by averaging the relative difference between model results
186
and measurement for two proxies for groundwater recharge that can be retrieved from the
187
river hydrograph: the 90% flow duration value (Q90) which is exceeded 90% of the time, and
188
the ratio Q90/Q50.38 Uncertainties of ungauged subbasins were set equal to the uncertainties
189
of the next downstream gauge. Finally, the uncertainties of water availability were propagated
190
to the WSI according to the Gaussian law of error propagation (S6).39
191
Scenario analysis. While WSI are calculated based on past data, potential future changes in
192
climate conditions and water demand can impact WSI.40 The impacts of potential changes in
193
precipitation, temperature and irrigation demand in 2040 to 2069 on WSI were examined as
194
part of a scenario analysis. Data on climate change projections were retrieved from an
195
ensemble average of 23 general circulation models at a 0.5° resolution41 and downscaled to
196
0.125° for the US,42 covering most of the Mississippi watershed. The IPCC emission scenario
197
A1B42 was considered and data were provided as monthly averages. Changes in irrigation
198
demand were obtained from Pfister et al.40 as monthly averages for the 2050s for four
199
scenarios.
200 201
RESULTS
202
Calibration and validation. The calibrated SWAT model performed well throughout the
203
watershed according to PBIAS, suggesting low systematic bias. On the other hand, NSE, RSR
204
and bR2 exhibited a clear East-West spatial pattern (Figure 1). Overall Mississippi watershed 9 ACS Paragon Plus Environment
Environmental Science & Technology
Page 10 of 33
205
model performance strongly depended on the weighting procedure. PBIAS and bR2 yielded
206
satisfactory results for calibrated river discharge in all cases, whereas NSE and RSR only
207
produced satisfactory results when weighted by the mean observed discharge (Table 1). NSE
208
and RSR were greatly influenced by outliers, so trimming 5% at each side or calculating
209
geometric means improved the results.
210
Model performance was lower for the validated time series, as expected. Satisfactory results
211
could only be produced with regard to PBIAS and bR2 (Table S3). The performance after
212
autocalibration was significantly lower than after manual calibration (Table S4 - Table S5)
213
and model results from autocalibration were therefore disregarded from further analyses.
214 215
Figure 1. Model performance of calibrated river discharge using four different criteria (green
216
indicates good performance and red indicates poor performance). 10 ACS Paragon Plus Environment
Page 11 of 33
Environmental Science & Technology
217 218
Table 1. Mississippi model performance of calibrated river discharge for different criteria and
219
weighting of subbasins (satisfactory values in bold).
NSE NSE (trimmed) PBIAS RSR RSR (geometric) bR2
No weight -0.91 0.14 8.43 0.99 0.84 0.51
Area / Length 0.15 0.30 4.29 0.79 0.71 0.64
Discharge 0.59 0.59 3.77 0.59 0.57 0.73
220 221
Actual evapotranspiration was not calibrated. Nevertheless, the model yielded satisfactory
222
results using all efficiency criteria, with the exception of the untrimmed NSE where outliers
223
had a strong influence (Table S6).
224
Model uncertainty. Like model performance, the overall uncertainty depended on the
225
weighting procedure. r-factors could only yield satisfactory values (< 1)26,27 when 75% of the
226
data were bracketed by the uncertainty band, instead of 95%. Lower r-factors were obtained
227
when measurement uncertainty was considered as a binary decision based on whether there
228
was an intersection or not of the uncertainty bands of simulated and measured river discharges
229
(SO). The higher the measurement uncertainty, the more likely the two bands intersect which
230
leads to an apparently lower overall uncertainty. On the other hand, r-factors increased with a
231
higher measurement uncertainty when taking into account the percent overlap (PO) of the
232
bands (Table 2, Figure S2).
233 234
11 ACS Paragon Plus Environment
Environmental Science & Technology
Page 12 of 33
235
Table 2. Uncertainty of surface water availability combining different procedures and for
236
different weighting of subbasins (satisfactory values in bold).
p-factor (%) 75 75 75 75 75 95 95 95
Measurement uncertainty (%) 0 10 10 25 25 0 10 10
r-factor Strategy SO SO PO SO PO SO SO PO
No weight
Area / Length
Discharge
0.93 0.77 0.93 0.56 0.97 2.01 1.81 2.03
1.17 0.94 1.18 0.60 1.24 2.00 1.75 2.03
1.10 0.84 1.12 0.48 1.20 1.85 1.57 1.87
237 238
Model comparison and spatial association analysis. The SWAT model performed
239
considerably better than the global models WaterGAP and UNH/GRDC (Table S7). The
240
global models did not produce satisfactory values for any of the efficiency criteria.
241
Nevertheless, WaterGAP yielded excellent results for the furthest downstream gauge close to
242
the watershed outlet and outperformed the SWAT model in that case. The reason for this
243
improved performance lies in the fact that WaterGAP matches the runoff results to
244
measurement stations.14 Likewise, Aqueduct yielded a low PBIAS at the gauge closest to the
245
outlet, but an unsatisfactory result when considering internal gauges (S5). The same test could
246
not be carried out for the UNH/GRDC model because observation and simulation periods did
247
not overlap for the gauge closest to the outlet.
248
Spatial patterns agreed relatively well between the models with correlations, more precisely
249
bivariate spatial associations (BSA), larger than 0.4 (Table S8). The high BSA for
250
groundwater availability was due to the more homogeneous spatial distribution of recharge
251
which is favored by the measure.33 The level of agreement (LA) between models was
252
observed to be low, indicated by values of 40% and lower (Table S8). Groundwater
12 ACS Paragon Plus Environment
Page 13 of 33
Environmental Science & Technology
253
availabilities agreed better in arid regions whereas no trend was notable for surface water
254
availabilities.
255
The poor performance of the SWAT model was mainly observed in regions of high aridity
256
(with low aridity indices; Table S9). The aridity index and slope of the main channel in
257
subbasins both depicted an East-West gradient (Figure S3) similar to the model efficiency
258
criteria in Figure 1. However, the relationship between model efficiency and slopes was less
259
evident when determining the partial BSA, in a manner analogous to the partial correlation
260
coefficient,43 and thereby removing the influence of aridity. The partial BSA between model
261
efficiency criterion bR2 and slope, for instance, only amounted to -0.11. In contrast, the partial
262
BSA between bR2 and AI when controlling for slopes still amounted to 0.66. Snowfall (or
263
SD) and dams (or RF) hardly influenced the model performance (Table S9).
264
Water stress indices. The mean WSI for the Mississippi watershed ranged from 0.3 to 0.8
265
(Table 3), depending on the source of water, the temporal and spatial scales as well as the
266
type of water use (consumption or withdrawal). The ranges for individual gauges were even
267
broader (Table S11). Water stress was higher in the arid West than in the humid East (Figure
268
2, Figure S4 - Figure S9). The annual averages of monthly WSI mostly exceeded the overall
269
annual average. Likewise, WSI at the upstream level generally surpassed WSI at the subbasin
270
level. No clear tendency of WSI could be observed between surface and groundwater or
271
withdrawal and consumption. Annual WSI related to water consumption at the subbasin level
272
were quite high.
273
Uncertainties (relative errors) of annual WSI were mostly lower than the monthly WSI.
274
Likewise, relative uncertainties in WSI for total water resources were lower than for surface
275
and groundwater resources alone, since it was considered unlikely that availabilities of both
13 ACS Paragon Plus Environment
Environmental Science & Technology
Page 14 of 33
276
were simultaneously over- or underestimated to the full extent. This follows from the law of
277
error propagation which is explained in more detail in the SI (section S6).
278
Table 3. Consumption weighted water stress indices and their uncertainties.
Withdrawal Consumption
Upstream Subbasin Upstream Subbasin
Annual WSI (Uncertainty in %) Total Surface Groundwater water water 0.48 (21) 0.49 (31) 0.47 (15) 0.40 (20) 0.45 (28) 0.29 (20) 0.51 (13) 0.43 (15) 0.56 (21) 0.80 (10) 0.76 (16) 0.72 (12)
Average monthly WSI (Uncertainty in %) Total Surface Groundwater water water 0.70 (15) 0.72 (19) 0.62 (26) 0.62 (19) 0.69 (22) 0.45 (31) 0.71 (15) 0.61 (20) 0.71 (14) 0.64 (18) 0.57 (25) 0.60 (17)
279
280 281
Figure 2. Distributed average water stress indices of the Mississippi watershed considering
282
water consumption and upstream level (a: annual total water resources, b: monthly total water
283
resources, c: monthly surface water resources, d: monthly groundwater resources). 14 ACS Paragon Plus Environment
Page 15 of 33
Environmental Science & Technology
284 285
While the severity of water stress differed most when comparing annual to monthly WSI,
286
spatial patterns differed most when comparing surface water and groundwater WSI (Table
287
S12).
288
Scenario analysis. Between 2040 and 2069, precipitation in the Mississippi watershed was
289
projected to increase by ~2%. On the other hand, temperature was projected to rise by more
290
than 1°C, leading to enhanced evapotranspiration. As a result, total water availability was
291
simulated to increase by about 5% whereas groundwater availability would slightly decrease.
292
Water consumption was assumed to increase due to an increase in agricultural activities as
293
assessed by four scenarios. This increase ranged from being negligible in the expansion
294
scenarios (< 1%) to high in case of intensification of current agricultural areas (> 10%).
295
Altogether, the scenarios led to a slightly lower water stress (Table S13) compared to current
296
averages. This trend was more pronounced at the monthly time scale. Only groundwater stress
297
may increase when considered at an annual time scale. Differences between the scenarios
298
were insignificant.
299 300
DISCUSSION
301
Calibration. Sound calibration and validation combines multiple criteria since different
302
criteria focus on different aspects of a hydrograph and no single one performs ideally.20,21,44,45
303
In this study, model performance was judged based on NSE, PBIAS and RSR as
304
recommended by Moriasi et al.20 and bR2 as suggested by Krause et al.21 (see also S3). The
305
SWAT model of the Mississippi watershed mostly performed well in the Eastern humid
306
region but poorly in the Western arid region, which is explained in part by the spatial 15 ACS Paragon Plus Environment
Environmental Science & Technology
Page 16 of 33
307
association between aridity index and model performance (Table S9). The overall model
308
efficiency depended on the weighting procedure of the subbasins. It could be argued that it is
309
more relevant to simulate high discharges well as they contribute more to the total water
310
availability. When weighting by discharge, the SWAT model performed satisfactorily (NSE)
311
to very well (PBIAS, Table 1). However, weighting by discharge is subjective. Area and time
312
series length would be more objective weighting parameters from a data perspective, but it
313
might be less relevant from a water resource perspective. In that case, the model performed
314
very well regarding PBIAS, satisfactorily regarding bR2, but poorly regarding RSR and the
315
most comprehensive measure, NSE. This highlights that model evaluation using a single
316
criterion can be misleading and supports the recommendation of combining multiple criteria,
317
as mentioned above. Considering the large watershed and high climatic diversity, the model
318
performance is considered satisfactory.
319
PBIAS was the criterion which indicated best model performance. However, several
320
parameters influence “losses” in the system and enable the modeler to match the water
321
balance.46 Such losses are recharge to deep aquifers, which do not contribute baseflow to
322
rivers, capillary rise, which is better described as evapotranspiration from shallow aquifers,
323
and soil evaporation. Although care was taken that the parameters maintained physical
324
meaning as much as possible (Table S1), controlling all these parameters in conjunction still
325
resulted in highly influencing the water balance and therefore might result in overfitting the
326
model. This is also reflected in the lower performance during the validation period.
327
Calibration of the SWAT model given the large number of unknown parameters is a
328
mathematically ill-posed problem, as available observations do not constrain the model
329
sufficiently to find a unique solution. Instead, different parameter sets can fit the observed
330
discharge records in a similarly satisfactory way, and this creates an equifinality problem.47
331
This stresses that a good discharge representation does not necessarily mean that the entire 16 ACS Paragon Plus Environment
Page 17 of 33
Environmental Science & Technology
332
water balance including groundwater recharge is represented well. It is therefore important to
333
also validate against evapotranspiration as an alternate water balance component. Equifinality
334
is higher, the more parameterized a model is. Physical-based, distributed models such as
335
SWAT are particularly prone to be overparameterized. In order to get results closer to
336
physical reality than mathematical convenience, Kirchner48 and Beven47 advocate reducing
337
model complexity and minimizing the number of calibration parameters. This is especially
338
relevant for scenario analyses where conditions significantly deviate from the previously
339
experienced and calibrated conditions.
340
While manual calibration is time-consuming and tedious, it allows combining multiple
341
numerical performance criteria with visual inspection. On the other hand, it also involves
342
subjectivity.49 In contrast, automation tremendously speeds up calibration and makes it more
343
objective. The autocalibration procedure tested in this study was based on a single criterion
344
objective function. As discussed above, a single criterion is inadequate for evaluation or
345
optimization as there can be substantial trade-offs among performance criteria.49 Yet the
346
model even performed worse in terms of bR2 which was selected as objective function. This
347
might be explained by the fact that the Mississippi watershed is huge and encompasses high
348
spatial variability which could not be captured by simply autocalibrating based on
349
parameterizing soil texture and land use classes similarly for the entire region. Although the
350
manual calibration clearly outperformed autocalibration, it is infeasible on a global scale with
351
limited efforts. Hence the automated procedure has to be improved. Automated multicriteria
352
optimization could be more promising. It would provide a set of Pareto optimal solutions
353
from which a specific solution could be singled out based on further analyses and priorities
354
according to model application.22,49
355
Existing global hydrological models were mostly calibrated against gauges at watershed
356
outlets, with a lesser emphasis on internal spatial heterogeneity. Therefore, WaterGAP 17 ACS Paragon Plus Environment
Environmental Science & Technology
Page 18 of 33
357
performed very well at the gauge closest to the outlet, but performed poorly when considering
358
internal gauges (Table S8). The same trend was observed for Aqueduct. Therefore, state-of-
359
the-art global models should be used for applications at subbasin scale with caution. In
360
contrast to global models, internal gauges were used to calibrate the SWAT model (131 in
361
total). As a result, the SWAT model outperformed the global models at the subbasin level
362
(Table S8) and is expected be a more suitable basis for estimating more robust, spatially-
363
explicit WSI.
364
An additional problem that exists for all hydrological models is man-managed reservoirs,
365
which confound the calibration processes. Reservoirs are operated in many different ways and
366
it is challenging to gather information on individual operation rules for large scales such as
367
the Mississippi watershed, continents or the entire world.50,51 In our study, a generic operation
368
equation was used, but parameters were fitted separately for each reservoir.
369
Uncertainty. Hydrological models inherit uncertainty from multiple sources: errors in forcing
370
data and boundary conditions, sub-optimal parameterizations, flaws in model structure and
371
errors in recorded model output.28 The difficulty lies in the fact that these uncertainties
372
interact and cannot easily be disaggregated from residual time series.52 There is currently no
373
consensus on a particular uncertainty estimation method. The method chosen in this study was
374
a modified version of the algorithm in SUFI-2.26,27 Estimates of measurement uncertainty
375
were based on literature, and vary greatly between 3% and 42% depending on measurement
376
strategy and river channel conditions.29 Moreover, it should be kept in mind that some
377
strategies of including measurement uncertainty may lead to a poor model appearing
378
satisfactory,53 as can be the case when uncertainty is considered as a binary decision on
379
intersection of the simulation and observation uncertainty bands. Such strategies should
380
therefore be avoided. Although the SWAT model generally exhibited uncertainties exceeding
381
a satisfactory level (Table 2), they might still be within acceptable limits when propagated to 18 ACS Paragon Plus Environment
Page 19 of 33
Environmental Science & Technology
382
WSI (Table 3). In terms of LCA or water footprinting, it is essential to provide results with
383
uncertainty. Complete uncertainty analyses were beyond the scope of this study. However, it
384
should be noted that uncertainties in water use and function choice for the WSI would
385
increase uncertainty.54
386
The large differences among global hydrological models as found by Haddeland et al.6 were
387
confirmed by this study. Although the spatial patterns agreed relatively well between the
388
models with BSA larger than 0.4, the LA was unsatisfactory (Table S8). Thus, the choice of
389
water availability model entails a major source of uncertainty for assessing water scarcity.
390
One possibility to deal with that would be to consider multiple models as suggested by
391
Haddeland et al.6
392
Water stress. WSI varied greatly depending on the type of water resource, the temporal
393
resolution, the spatial level and the water use type considered (Table 3). The severity of water
394
stress differed most when comparing annual to monthly WSI (Table S12); hence, annual WSI
395
as typically applied can be misleading. However, temporal resolution should be seen in
396
conjunction with travel time. While water flows for about four months from the source of the
397
Missouri to the outlet of the Mississippi watershed, travel time is much lower in individual
398
subbasins. Therefore, an increase in spatial resolution should be accompanied by an increase
399
in temporal resolution and vice-versa. Spatial patterns varied most when comparing surface
400
water and groundwater WSI (Table S12, Figure 2). Considering also their disparities in
401
anthropogenic and ecological significance, it is essential to assess water stress separately.
402
Water stress was already differentiated in a study by Boulay et al.,8 which, however, lacks the
403
spatial and temporal details of this work.
404
Loubet et al.7 were the first to calculate WSI at the subbasin level and they considered
405
upstream water availability and use. In case of transboundary water resources, water 19 ACS Paragon Plus Environment
Environmental Science & Technology
Page 20 of 33
406
availability and use within a subbasin might be more appropriate to ensure independence from
407
upstream users. The same coefficients were used to calculate WSI at both spatial levels which
408
might be improper and needs further analysis. Currently, most WSI used in LCA incorporate
409
water withdrawal instead of water consumption (e.g., ref 37). This can be justified by the fact
410
that water released back to the environment might be of degraded quality and that the point of
411
release might be located in a different spatial unit than the point of extraction. Additionally, it
412
is argued that water consumption estimates are generally derived from withdrawals and might
413
be less accurate. On the other hand, if the spatial units are not too small, it can be assumed
414
that the points of extraction and release are situated in the same spatial unit and the water
415
released is unlikely to be of such a low quality that it is unusable for any user. The water
416
consumption seems more relevant when addressing water scarcity issues.7 All the above
417
highlights that further development of WSI is required and that a consensus needs to be
418
reached.
419
The indices calculated by Pfister et al.36 mostly underestimated water stress compared to those
420
in this study (Figure S12), which could be explained by the overestimation of water
421
availability in WaterGAP (Table S7). Aqueduct, on the other hand, comprises simplistic water
422
risk indicators such as WTA based on annual averages. The underlying model GLDAS is a
423
land surface model which focuses on vertical fluxes rather than hydrological processes and
424
whose evaluation against river discharge is limited (only 66 gauges at the global scale and R2
425
as a performance measure).55 It is likely less suitable to analyse WSI at a higher resolution
426
(spatially and temporally) than models such as those implemented in this study.
427
Future scenarios. Current analysis for the Mississippi watershed as a whole shows that the
428
dominant East-West trend requires high water consumption reductions in the West in order to
429
avoid high stress levels. Based on the analyzed future scenarios, this trend is expected to
430
decrease slightly. 20 ACS Paragon Plus Environment
Page 21 of 33
Environmental Science & Technology
431
The calibrated SWAT model was also used for analyzing irrigation demand scenarios.
432
Changes in evapotranspiration were considered in the hydrological modeling, but not in the
433
scenario generation of irrigation demand.40 Increased evapotranspiration partly offsets the
434
effect of increased precipitation on water availability and thereby amplifies irrigation demand
435
and consequently aggravates water stress. Also, the model was evaluated by a split sample
436
test where the observation records were divided into two equivalent time periods. Since both
437
time periods used for calibration and validation usually represent similar conditions, such a
438
test is not very insightful for extrapolations into the future.48 Furthermore, model
439
overparameterization can affect projections of hydrological impacts in scenario analyses.51
440
Nevertheless, the scenarios foresee relatively low increase in water demand and climate
441
effects appear less severe compared to current anthropogenic stress levels, but this in itself
442
varies depending on the region of the world.56
443
Practical implications. Global water stress has typically been analyzed at the country or
444
watershed level. These scales mask the spatial variability, most notably in large countries or
445
watersheds.57 Global hydrological models such as WaterGAP, UNH/GRDC and GLDAS
446
(underlying Aqueduct) are currently challenged to reliably reflect water availability at the
447
subbasin scale. Such models could improve their transparency by moving beyond model
448
evaluation based on single criteria, and more robust uncertainty analyses. Although the
449
SWAT model of the Mississippi watershed clearly outperformed the global models, it is
450
unlikely to substitute them on a global scale. First, manual calibration as carried out in this
451
study would be infeasible for global coverage in the short-term and could at most be applied
452
to hotspots of severe water scarcity. Second, the SWAT model with its complexity is prone to
453
be overparameterized. This increases equifinality and reduces the reliability, especially of
454
scenario analyses. Therefore, the modeling algorithms of the global models need to be
455
improved and more observational data such as internal gauges have to be incorporated in the 21 ACS Paragon Plus Environment
Environmental Science & Technology
Page 22 of 33
456
calibration process. Until such improvements take place it is recommended that (i) global
457
models be evaluated based on multiple performance criteria, (ii) the uncertainty of these
458
models be assessed, (iii) the weaknesses of the models be related to other spatial factors such
459
as aridity index in order to set priorities as to where to improve the models, and (iv) an
460
ensemble average be derived from multiple hydrological models. While improved
461
representations of water availability are a prerequisite for spatially and temporally higher
462
resolved WSI, LCA practitioners should focus on developing indices and impact assessment
463
methods that distinguish surface and groundwater. In the meantime, any global water scarcity
464
indicator should be considered carefully, taking into account the high uncertainties and spatial
465
differences presented in this paper. This is especially relevant for global analyses of supply
466
chains as done by water footprint or LCA studies.
467 468
ASSOCIATED CONTENT
469
Supporting Information
470
Input data, further method descriptions, full results, and maps of water stress indices as well
471
as SHP files of water stress indices are available free of charge via the Internet at
472
http://pubs.acs.org.
473 474
AUTHOR INFORMATION
475
Corresponding Author
476
*Phone: +41-44-632-31-72. E-mail:
[email protected].
477 22 ACS Paragon Plus Environment
Page 23 of 33
Environmental Science & Technology
478
ACKNOWLEDGEMENTS
479
The authors thank Karim Abbaspour for his support in using ArcSWAT and SWAT-CUP,
480
Stefanie Hellweg and Adam Usadi for their helpful comments and Catherine Raptis for proof-
481
reading the manuscript. This work was funded by ExxonMobil Research and Engineering,
482
Corporate Strategic Research.
483 484 485 486
REFERENCES
487
(1) UNEP. Measuring water use in a green economy. A report of the working group on
488
water efficiency to the International Resource Panel; United Nations Environment
489
Programme, 2012.
490
(2) Hubacek, K.; Feng, K.; Minx, J. C.; Pfister, S.; Zhou, N. Teleconnecting Consumption
491
to Environmental Impacts at Multiple Spatial Scales. J. Ind. Ecol. 2014, 18 (1), 7–9; DOI
492
10.1111/jiec.12082.
493 494
(3) ISO 14046:2014. Water footprint requirements and guidelines working group TC 207/SC5/WG8. http://www.iso.org/.
495
(4) Hellweg, S.; Milà i Canals, Llorenç. Emerging approaches, challenges and
496
opportunities in life cycle assessment. Science 2014, 344 (6188), 1109–1113; DOI
497
10.1126/science.1248361.
498
(5) Kounina, A.; Margni, M.; Bayart, J.-B.; Boulay, A.-M.; Berger, M.; Bulle, C.;
499
Frischknecht, R.; Koehler, A.; Milà i Canals, Llorenç; Motoshita, M.; Núñez, M.; Peters, G.;
500
Pfister, S.; Ridoutt, B.; Zelm, R.; Verones, F.; Humbert, S. Review of methods addressing
23 ACS Paragon Plus Environment
Environmental Science & Technology
Page 24 of 33
501
freshwater use in life cycle inventory and impact assessment. Int. J. Life Cycle Ass. 2013, 18
502
(3), 707-721; DOI 10.1007/s11367-012-0519-3.
503
(6) Haddeland, I.; Clark, D. B.; Franssen, W.; Ludwig, F.; Voß, F.; Arnell, N. W.;
504
Bertrand, N.; Best, M.; Folwell, S.; Gerten, D.; Gomes, S.; Gosling, S. N.; Hagemann, S.;
505
Hanasaki, N.; Harding, R.; Heinke, J.; Kabat, P.; Koirala, S.; Oki, T.; Polcher, J.; Stacke, T.;
506
Viterbo, P.; Weedon, G. P.; Yeh, P. Multimodel Estimate of the Global Terrestrial Water
507
Balance: Setup and First Results. J. Hydrometeorol. 2011, 12 (5), 869–884; DOI
508
10.1175/2011JHM1324.1.
509
(7) Loubet, P.; Roux, P.; Núñez, M.; Belaud, G.; Bellon-Maurel, V. Assessing Water
510
Deprivation at the Sub-river Basin Scale in LCA Integrating Downstream Cascade Effects.
511
Environ. Sci. Technol. 2013, 47 (24), 14242–14249; DOI 10.1021/es403056x.
512
(8) Boulay, A.-M.; Bulle, C.; Bayart, J.-B.; Deschênes, L.; Margni, M. Regional
513
Characterization of Freshwater Use in LCA: Modeling Direct Impacts on Human Health.
514
Environ. Sci. Technol. 2011, 45 (20), 8948–8957; DOI 10.1021/es1030883.
515
(9) Boulay, A.-M.; Motoshita, M.; Pfister, S.; Bulle, C.; Muñoz, I.; Franceschini, H.;
516
Margni, M. Analysis of water use impact assessment methods (part A): evaluation of
517
modeling choices based on a quantitative comparison of scarcity and human health
518
indicators. Int. J. Life Cycle Ass. 2015, 20 (1), 139-160; DOI 10.1007/s11367-014-0814-2.
519
(10) Arnold, J. G.; Srinivasan, R.; Muttiah, R. S.; Williams, J. R. Large area hydrologic
520
modeling and assessment part I: Model development. J. Am. Water Resour. As. 1998, 34 (1),
521
73–89; DOI 10.1111/j.1752-1688.1998.tb05961.x.
522
(11) Schuol, J.; Abbaspour, K. C.; Yang, H.; Srinivasan, R.; Zehnder, Alexander J. B.
523
Modeling blue and green water availability in Africa. Water Resour. Res. 2008, 44 (7),
524
W07406; DOI 10.1029/2007WR006609.
24 ACS Paragon Plus Environment
Page 25 of 33
Environmental Science & Technology
525
(12) Faramarzi, M.; Abbaspour, K. C.; Schulin, R.; Yang, H. Modelling blue and green
526
water resources availability in Iran. Hydrol. Process. 2009, 23 (3), 486–501; DOI
527
10.1002/hyp.7160.
528
(13) Pagliero, L.; Bouraoui, F.; Willems, P.; Diels, J. Large-Scale Hydrological
529
Simulations Using the Soil Water Assessment Tool, Protocol Development, and Application
530
in the Danube Basin. J. Environ. Qual. 2014, 43 (1), 145–154; DOI 10.2134/jeq2011.0359.
531
(14) Döll, P.; Kaspar, F.; Lehner, B. A global hydrological model for deriving water
532
availability indicators: model tuning and validation. J. Hydrol. 2003, 270 (1–2), 105–134;
533
DOI 10.1016/S0022-1694(02)00283-4.
534
(15) Fekete, B. M.; Vörösmarty, C. J.; Grabs, W. High-resolution fields of global runoff
535
combining observed river discharge and simulated water balances. Global Biogeochem. Cy.
536
2002, 16 (3), 15-1; DOI 10.1029/1999GB001254.
537
(16) Neitsch, S. L.; Arnold, J. G.; Kiniry, J. R.; Williams, J. R. Soil and Water Assessment
538
Tool. Theoretical documentation version 2009. Texas Water Resources Institute Technical
539
Report No. 406; Texas Water Resources Institute, 2011.
540 541
(17) Shuttleworth, W. J. Evaporation. In Handbook of hydrology; Maidment, D. R., Ed.; McGraw-Hill: New York, 1993; pp 4.1–4.53.
542
(18) Olivera, F.; Valenzuela, M.; Srinivasan, R.; Choi, J.; Cho, H.; Koka, S.; Agrawal, A.
543
ArcGIS-SWAT: A geodata model and GIS interface for SWAT. J. Am. Water Resour. As.
544
2006, 42 (2), 295–309; DOI 10.1111/j.1752-1688.2006.tb03839.x.
545 546
(19) Wu, Y.; Chen, J. An Operation-Based Scheme for a Multiyear and Multipurpose Reservoir to Enhance Macroscale Hydrologic Models. J. Hydrometeorol. 2012, 13 (1).
547
(20) Moriasi, D. N.; Arnold, J. G.; van Liew, M. W.; Bingner, R. L.; Harmel, R. D.; Veith,
548
T. L. Model evaluation guidelines for systematic quantification of accuracy in watershed
549
simulations. T. ASABE 2007, 50 (3), 885–900.
25 ACS Paragon Plus Environment
Environmental Science & Technology
Page 26 of 33
550
(21) Krause, P.; Boyle, D. P.; Bäse, F. Comparison of different efficiency criteria for
551
hydrological model assessment. Adv. Geosci. 2005, 5, 89–97; DOI 10.5194/adgeo-5-89-
552
2005.
553 554 555
(22) Ruppert, D. Trimming and Winsorization. Encyclopedia of Statistical Sciences; John Wiley & Sons, Inc, 2004. (23) Limpert, E.; Stahel, W. A.; Abbt, M. Log-normal Distributions across the Sciences:
556
Keys
557
3568(2001)051[0341:LNDATS]2.0.CO;2.
558 559
and
Clues.
BioScience
2001,
51
(5),
341–352;
DOI
10.1641/0006-
(24) Abbaspour, K. C. SWAT-CUP 2012: SWAT Calibration and Uncertainty Programs. A user manual, 2013.
560
(25) Zhang, K.; Kimball, J. S.; Nemani, R. R.; Running, S. W. A continuous satellite-
561
derived global record of land surface evapotranspiration from 1983 to 2006. Water Resour.
562
Res. 2010, 46 (9), W09522; DOI 10.1029/2009WR008800.
563
(26) Abbaspour, K. C.; Johnson, C. A.; van Genuchten, M. Th. Estimating Uncertain Flow
564
and Transport Parameters Using a Sequential Uncertainty Fitting Procedure. Vadose Zone J.
565
2004, 3 (4), 1340–1352; DOI 10.2113/3.4.1340.
566
(27) Abbaspour, K. C.; Yang, J.; Maximov, I.; Siber, R.; Bogner, K.; Mieleitner, J.;
567
Zobrist, J.; Srinivasan, R. Modelling hydrology and water quality in the pre-alpine/alpine
568
Thur
569
10.1016/j.jhydrol.2006.09.014.
watershed
using
SWAT.
J.
Hydrol.
2007,
333
(2–4),
413–430;
DOI
570
(28) Butts, M. B.; Payne, J. T.; Kristensen, M.; Madsen, H. An evaluation of the impact of
571
model structure on hydrological modelling uncertainty for streamflow simulation. J. Hydrol.
572
2004, 298 (1–4), 242–266; DOI 10.1016/j.jhydrol.2004.03.042.
573
(29) Harmel, R. D.; Cooper, R. J.; Slade, R. M.; Haney, R. L.; Arnold, J. G. Cumulative
574
uncertainty in measured streamflow and water quality data for small watersheds. T. ASABE
575
2006, 49 (3), 689. 26 ACS Paragon Plus Environment
Page 27 of 33
576 577
Environmental Science & Technology
(30) Di Baldassarre, G.; Montanari, A. Uncertainty in river discharge observations: a quantitative analysis. Hydrol. Earth Syst. Sc. 2009, 13 (6).
578
(31) Centre for Ecology and Hydrology, Wageningen UR. WATCH 20th century model
579
output datasets. ftp://ftp.iiasa.ac.at/WorkBlock6/WaterGap/WFD_1963_2001/ (accessed
580
April 11, 2014).
581 582 583
(32) Reig, P.; Shiao, T.; Gassert, F. Aqueduct Water Risk Framework. Working Paper; World Resources Institute: Washington, DC, 2013. (33) Lee, S.-I. Developing a bivariate spatial association measure: An integration of
584
Pearson's
r
and
Moran's
585
10.1007/s101090100064.
I.
J.
Geogr.
Syst.
2001,
3
(4),
369-385;
DOI
586
(34) UNEP. World atlas of desertification; Arnold: London, 1992.
587
(35) Lehner, B.; Döll, P. Development and validation of a global database of lakes,
588
reservoirs
and
wetlands.
589
10.1016/j.jhydrol.2004.03.028.
J.
Hydrol.
2004,
296
(1–4),
1–22;
DOI
590
(36) Pfister, S.; Koehler, A.; Hellweg, S. Assessing the Environmental Impacts of
591
Freshwater Consumption in LCA. Environ. Sci. Technol. 2009, 43 (11), 4098–4104; DOI
592
10.1021/es802423e.
593
(37) Pfister, S.; Bayer, P. Monthly water stress: spatially and temporally explicit
594
consumptive water footprint of global crop production. J. Clean. Prod. 2013 (0); DOI
595
10.1016/j.jclepro.2013.11.031.
596
(38) Nathan, R. J.; McMahon, T. A. Evaluation of automated techniques for base flow and
597
recession
598
10.1029/WR026i007p01465.
599 600
analyses.
Water
Resour.
Res.
1990,
26
(7),
1465–1473;
DOI
(39) Drosg, M. Basics on uncertainties. Dealing with Uncertainties; Springer, 2009; pp 17– 48.
27 ACS Paragon Plus Environment
Environmental Science & Technology
Page 28 of 33
601
(40) Pfister, S.; Bayer, P.; Koehler, A.; Hellweg, S. Projected water consumption in future
602
global agriculture: Scenarios and related impacts. Sci. Total Environ. 2011, 409 (20), 4206–
603
4216; DOI 10.1016/j.scitotenv.2011.07.019.
604
(41) Meehl, G. A.; Covey, C.; Taylor, K. E.; Delworth, T.; Stouffer, R. J.; Latif, M.;
605
McAvaney, B.; Mitchell, John F. B. THE WCRP CMIP3 Multimodel Dataset: A New Era in
606
Climate Change Research. B. Am. Meteorol. Soc. 2007, 88 (9), 1383–1394; DOI
607
10.1175/BAMS-88-9-1383.
608
(42) Maurer, E. P.; Brekke, L.; Pruitt, T.; Duffy, P. B. Fine-resolution climate projections
609
enhance regional climate change impact studies. Eos T. Am. Geophys. Un. 2007, 88 (47),
610
504; DOI 10.1029/2007EO470006.
611 612
(43) Kleinbaum, D.; Kupper, L.; Nizam, A.; Rosenberg, E. Applied regression analysis and other multivariable methods; Cengage Learning: Boston, 2013.
613
(44) Legates, D. R.; McCabe, G. J. Evaluating the use of “goodness-of-fit” measures in
614
hydrologic and hydroclimatic model validation. Water Resour. Res. 1999, 35 (1), 233–241;
615
DOI 10.1029/1998WR900018.
616
(45) Boyle, D. P.; Gupta, H. V.; Sorooshian, S. Toward improved calibration of hydrologic
617
models: Combining the strengths of manual and automatic methods. Water Resour. Res.
618
2000, 36 (12), 3663–3674; DOI 10.1029/2000WR900207.
619
(46) van Griensven, A.; Meixner, T.; Grunwald, S.; Bishop, T.; Diluzio, M.; Srinivasan, R.
620
A global sensitivity analysis tool for the parameters of multi-variable catchment models. J.
621
Hydrol. 2006, 324 (1–4), 10–23; DOI 10.1016/j.jhydrol.2005.09.008.
622
(47) Beven, K. A manifesto for the equifinality thesis. The model parameter estimation
623
experiment
MOPEX
MOPEX
624
10.1016/j.jhydrol.2005.07.007.
workshop
2006,
320
28 ACS Paragon Plus Environment
(1–2),
18–36;
DOI
Page 29 of 33
Environmental Science & Technology
625
(48) Kirchner, J. W. Getting the right answers for the right reasons: Linking measurements,
626
analyses, and models to advance the science of hydrology. Water Resour. Res. 2006, 42 (3),
627
W03S04; DOI 10.1029/2005WR004362.
628
(49) Madsen, H. Automatic calibration of a conceptual rainfall–runoff model using
629
multiple objectives. J. Hydrol. 2000, 235 (3–4), 276–288; DOI 10.1016/S0022-
630
1694(00)00279-1.
631
(50) Meigh, J. R.; McKenzie, A. A.; Sene, K. J. A Grid-Based Approach to Water Scarcity
632
Estimates for Eastern and Southern Africa. Water Resour. Manag. 1999, 13 (2), 85-115;
633
DOI 10.1023/A:1008025703712.
634 635 636 637
(51) Hanasaki, N.; Kanae, S.; Oki, T. A reservoir operation scheme for global river routing models. J. Hydrol. 2006, 327 (1–2), 22–41; DOI 10.1016/j.jhydrol.2005.11.011. (52) Beven, K. On doing better hydrological science. Hydrol. Process. 2008, 22 (17), 3549–3553; DOI 10.1002/hyp.7108.
638
(53) Harmel, R. D.; Smith, P. K. Consideration of measurement uncertainty in the
639
evaluation of goodness-of-fit in hydrologic and water quality modeling. J. Hydrol. 2007, 337
640
(3–4), 326–336; DOI 10.1016/j.jhydrol.2007.01.043.
641
(54) Pfister, S.; Hellweg, S. Uncertainty in LCIA of water impacts on human health.
642
Surface
water
use
–
human
643
http://www.ifu.ethz.ch/ESD/downloads/reports/index_EN, 2011.
health
impacts;
644
(55) Zaitchik, B. F.; Rodell, M.; Olivera, F. Evaluation of the Global Land Data
645
Assimilation System using global river discharge data and a source-to-sink routing scheme.
646
Water Resour. Res. 2010, 46 (6), W06507; DOI 10.1029/2009WR007811.
647
(56) Gerten, D.; Heinke, J.; Hoff, H.; Biemans, H.; Fader, M.; Waha, K. Global Water
648
Availability and Requirements for Future Food Production. J. Hydrometeorol. 2011, 12 (5),
649
885–899; DOI 10.1175/2011JHM1328.1.
29 ACS Paragon Plus Environment
Environmental Science & Technology
Page 30 of 33
650
(57) Jeswani, H. K.; Azapagic, A. Water footprint: methodologies and a case study for
651
assessing the impacts of water use. J. Clean. Prod. 2011, 19 (12), 1288–1299; DOI
652
10.1016/j.jclepro.2011.04.003.
30 ACS Paragon Plus Environment
Page 31 of 33
Environmental Science & Technology
TOC Art 84x47mm (220 x 220 DPI)
ACS Paragon Plus Environment
Environmental Science & Technology
Model performance of calibrated river discharge using four different criteria (green colors indicate good performance and red colors indicate poor performance). 152x127mm (220 x 220 DPI)
ACS Paragon Plus Environment
Page 32 of 33
Page 33 of 33
Environmental Science & Technology
Distributed average water stress indices of the Mississippi watershed considering water consumption and upstream level (a: annual total water resources, b: monthly total water resources, c: monthly surface water resources, d: monthly groundwater resources). 152x114mm (220 x 220 DPI)
ACS Paragon Plus Environment