Letters. Opacity - Environmental Science ... - ACS Publications

Opacity. A. Weir, D G. Jones, L T. Papay, S. Calvert, and Shiu Chow. Yung. Environ. Sci. Technol. , 1976, 10 (10), pp 964–965. DOI: 10.1021/es60121a...
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LETTERS Power plants Dear Sir: I was pleased to read the story on the Southwestern power plants (€S&T, June 1976, p 532), especially since San Onofre 2 and 3, Palo Verde 1-3, Cholla 1-4, Mohave 1 & 2, and Navajo 1-3 are all C-E fossil or nuclear-fueled units. One minor error appeared, however. On the top of page 537 you refer to the (now cancelled) Kalparowits plant as being the largest coal-fired plant in the world, at 4 X 750 = 3000 MW. There is a larger station currently operating with C-E units and two more planned with C E units. They are: (1) Plant Bowen, Units 1-4 Georgia Power Co. (operating) 2 X 750 and 2 X 880 = 3260 MW (2) Plant Scherer, Units 1-4 Georgia Power Co. (planned) 4 X 810 = 3240 MW (3) White Bluffs, Units 1-4, Arkansas Power & Light Co. (planned) 4 X 850 = 3400 MW S. D. Barreit

Combustion Engineering, Inc. Windsor, Conn. 06095 Southwest power plants Dear Sir: We refer to the informative special report “A Southwest Power Plant Saga” (€S&T, June 1976, p 532). We believe that the final program report on the Navajo Generating Station SO;!Field Monitoring Program will lead to the answer to your concluding question as to the requirement for western utilities to scrub (Rockwell International, Meteorology Research, Inc., and Systems Applications, Inc., “Navajo Generating Station SO2 Field Monitoring Program” v. 1. Final Program Report. Salt River Project, Phoenix, Ariz., September 1975). The answer to this question is approached by addressing an earlier query. You state, . . one might still ask what the emissions will be.” The report addresses this important matter. After lengthy analyses of the Black Mesa mine core-sample data and the mining and coal handling procedures, it was established that the highest 3-h SOz emissions will occur during the 1982-85 period. On the average, Navajo’s emission rate will be 1004 g/s per unit during full-load operations, which is equivalent to 1.1 1 lbs/106 Btu compared to the national new source performance standard of 1.2 lbs/106 Btu. This rate is based on the characteristics of the 1982-85 coal as burned: average sulfur content 0.675 % , standard deviation 0.083 YO,and heat content 12 204 Btu per pound. (It is noted that the plant at times operates in, excess of rated capacity and, since the study was completed, is reI‘.

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ported to have used other than Black Mesa coal.) Based on the air-quality data collected, analyses of the dispersion potential of the Lake Powell area and the expected future emission rate at full-load operations, it was concluded that highest SO2 concentrations occur about 15 miles from the plant and the expected frequency of exceeding a 3-h average of 1300 ~ g / m 3is less than twice per year. Wor‘sbcase analysis, assuming that only Black Mesa coal is burned, indicated the second highest concentration at 1285 pg/m3; best estimates were in the 1000-1150 pg/m3 range. Based on these analyses, national ambient air quality standards for SO2 are unlikely to be violated. This conclusion may or may not apply to other facilities of western utilities. Navajo is isolated. It uses some of the best quality coal available in the entire nation. Certainly, if a facility is larger than Navajo, if its coal has a higher sulfur content or a lower heat content, or if it is less favorably located than Navajo, measured to reduce the emissions by coal or flue gas treatment are likely to be in order. H. H. Slater, W. P. Freas, 111, T. C. Curran EPA

Research Triangle Park, N.C. 277 11 .I. Van der Hoven Air Resources Lab. NOAA Silver Spring, Md. 20910

Opacity Dear Sir: The authors are pleased that Wolbach and Key of the Source Evaluation Section of the Texas Air Control Board feel that, “no responsible control agency, especially the Texas Air Control Board, would attempt to enforce a mass emission regulation” by means of opacity measurements (Letter, €S& T, September 1976, p 847) and that, we are “laying to rest a technique which should not be considered as a serious option.” Unfortunately, not all regulatory agencies share this view. For example, the response of the EPA to public comments on “Opacity Provisions under Standards of Performance for New Stationary Sources of Air Pollution” states, ”EPA believes that the use of opacity standards to control emissions is within the intent of the Act and that the standards are subject to an accurate, reproducible and objective test procedure.” (Ref. 1) The EPA also stated, “any source which is meeting the applicable concentration or mass standards will also be meeting the applicable opacity standard. If the source is exceeding the opacity standard, it is due to failure of that source to properly maintain its air pollution control equipment, and if tested, the source

would have emissions in excess of the applicable concentration or mass standard.” (Ref. 2) Thus the EPA position is that opacity can be used to enforce mass emission regulations. This is also the case with several other regulatory agencies. It appears that Wolbach and Key assume that transmissometer measurements are synonymous with opacity measurements. The EPA position is, “Method 9 is being retained as the primary and accepted means for determining compliance in order to have a consistent regulatory enforcement approach for all stationary sources. Data from in-stack transmissometers are not accepted as a means for demonstrating compliance with opacity standards . . . . However, in-stack transmissometer data may be submitted as probative, (but not conclusive) evidence of the actual opacity of emissions.” (Ref. 2) The requirement for visual observation to determine opacity is also stated in a number of local regulations. There was no extrapolation from “EPA work with transmissometers on opacity/ mass correlations for an asphalt concrete plant” as Wolbach and Key stated. The EPA based the “Functional Opacity-Mass Relationship for an Asphalt-Concrete Plant,” on visual opacity measurements, not transmissometer data. The Public Comment Summary confirms this. “The opacity standard for asphalt concrete plants is based on observations at three well-controlled asphalt-concrete plants.” (Ref. 4) “The opacity observations of emissions were taken according to practices taught at EPA smoke schools and Method 9 as it was then written . . . . Specifically, the observers read the emission points from a position with the sun located in the quadrant to their back.” (Ref. 5 ) Secondly, our paper was based on experimental data, including plume opacity observations by trained smoke observers, which correlated well with light scatting theory. Our only “extrapolation” was to use U S . Navy publications to calculate the sun’s altitude as a function of time and date in Florida, Washington, Alaska, and Hawaii. We did not make visual observations in those states, but used the correlation between opacity and sun altitude obtained in Nevada (and confirmed experimentally again in California), to predict the opacity that would occur if the same power plant were located in different parts of the U S . We are concerned with Wolbach and Key’s statement, ”A control agency concerned with the appearance and visibility of a plume will choose to regulate the worst case without regard for time of day, season or geographic location, providing that the proper observation conditions are met.” Our data have established

that visual opacity is directly related to the sun’s altitude. Because of the greater altitude of the sun, a plant in Brownsville, Texas, would have a more difficult time meeting opacity regulations than an identical plant in Amarillo, Texas, yet presumably the Texas Air Control Board would apply the same opacity standard to both of these plants. References (1) Goodwin, D. R., “Public Comment Summary: Opacity Provisions Under Standards of Performance for New Stationary Sources of Air Pollution,” US. EPA, Office of Air Quality Planning and Standards, Research Triangle Park, N.C. 27711, August 1975; p 23. ( 2 ) Ibid., p 24. (3) Ibid., p 5. (4) Ibid,. p 17. (5) Ibid., p 10. A. Weir, Jr., D. G. Jones, L. 1.Papay

Southern California Edison Co. Rosemead, Calif. 91770 S. Calvert, Shiu Chow Yung Air Pollution Technology, Inc. San Diego, Calif. 92117 Social relevance Dear Sir: The editorial “Universities and Social Relevance” (€S&T, July 1976, p 625) should bring an interesting response from the readership. The three principal functions of a public university, i.e., education, research, and public service, are interdependent. The first two cannot proceed in isolation from the third and retain essential social relevance. This implies an active and meaningful contribution to the solution of social problems. I cannot agree that the great universities at large have “staunchly resisted this notion.” I certainly agree that the first and most important function of the university is to educate and that environmental scientists and engineers must first of all have disciplinary depth and technical competence. But environmental scientists and engineers must eventually practice their professions and their training must include some bridging of the gaps between disciplines and an orientation toward environmental problems. Most will end up being problem-solvers and need to be trained as such. “The advances of the last few decades in agriculture, medical science, engineering, and the natural sciences” you cite can be credited primarily to the relevance of their education and research. This is most clearly demonstrated in agriculture with its chain of communication between the farmer, extension agent, research scientist, and engineer. You will agree, I am sure, that truth is not the sole possession of the university. This is particularly true with the environmental sciences and engineering, where very little knowledge is absolute. Socially acceptable solutions to the very complex problems facing us cannot occur in a vacuum and continuing interaction between university investigators, front-line

problem-solvers, and decision-makers is essential. Research administrators soon realize that good research involves trade-offs between the need to solve a problem and a good university investigator’s primary research interests. The problem is to strike a balance between payoff in related education of graduate students, the advancement of basic knowledge, and a meaningful contribution to the solution of social problems. The capacity of university faculty members at large for original research is not a continuum. I dare say it could be illustrated by a normal distribution with the marginally talented at one end and the truly gifted at the other. Very little is accomplished by the first group. The broad center provides the many incremental advances that collectively represent a strong central thrust toward the advancement of science and technology. It would be my argument that this work can best proceed within the framework of social relevance where good science and needed problem solving converge. The truly original and creative thinkers at the other end of the distribution should have the financial means to work in either the socially relevant or basic sciences as they desire. We need additional funding for this work. The problem is how to accomplish this with some degree of efficiency. Basic, non-problem-oriented research is far less demanding of the in-

vestigator in the sense of external pressures and can provide a haven for lessgifted investigators who simply want to avoid the demands of problem solving. In other words, the socially-oriented research usually requires some kind of product-some indication of acceptable performance within a reasonable time. By its very nature, basic research cannot anticipate breakthroughs on a predetermined time scale and the investigator must be allowed to pursue his efforts uninhibited by product completion dates. But for the broad center group there is no more excuse for the avoidance of tangible evidence of performance than for any other segment of our society. Lawyers must properly represent their clients, engineers design structures, physicians treat their patients, and so on. The taxpayers who support public institutions are entitled to some evidence of productivity by university faculty researchers. They expect it and increasingly demand it. In rereading your editorial, I am not so sure that we are very far apart. But many readers may interpret the editorial to say that universities have no need to be socially relevant and no obligation for public service. I strongly disagree with that interpretation and hope that this is not the impression you intended to leave. David H. Howells, Director U. of N.C. water Resources Research Institute Raleigh, N.C. 27607

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