Lewis base properties of 1,3-diphosphadithiatetrazocines: crystal and

Lewis base properties of 1,3-diphosphadithiatetrazocines: crystal and molecular structures of 1,3-Ph4P2N4S2Me+CF3SO3-. Tristram Chivers, Stephen W...
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Inorg. Chem. 1988, 27, 4344-4349

4344

Contribution from the Department of Chemistry, The University of Calgary, Calgary, Alberta, Canada T2N 1N4

Lewis Base Properties of 1,3-Diphosphadithiatetrazocines: Crystal and Molecular Structures of 1,3-Ph4P2N4S2MefCF3S03Tristram Chivers,* Stephen W. Liblong, John F. Richardson, and Tom Ziegler Received May 10, 1988 The behavior of I,3-Ph4P2N4S2 toward Lewis and Bransted acids has been investigated, and the following adducts have been isolated: 1,3-Ph4P2N4S2H+X(X- = BFC, CF3SOC), 1,3-Ph4P2N4S2Me+CF3SO