Ligand redox studies. II. Formation of cyano ... - ACS Publications

Formation of cyano complexes by oxidation of captive thiocyanate. Kenneth Schug, Birute Miniatas, Anthony J. Sadowski, Tairoku Yano, and Keihei Ueno. ...
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NOTES 1669

Vol. 7, No. 8,August 1968 ing sodium chloride and shown to have visible, ultraviolet, and infrared spectra identical with those of an authentic sample of [ C O ( N H ~ ) ~ C N ] C The I ~ . ionexchange technique permitted a quantitative evaluation of the amounts of Co(NH3)&+and Co(NH8)bCN2+formed in the reaction as indicated in Table 111. Small amounts (