LIMIT RESEARCH CORPORATION - Analytical Chemistry (ACS

LIMIT RESEARCH CORPORATION. Anal. Chem. , 1963, 35 (3), pp 32A–32A. DOI: 10.1021/ac60196a725. Publication Date: March 1963. ACS Legacy Archive...
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REPORT FOR ANALYTICAL CHEMISTS

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ANALYTICAL CHEMISTRY

procedures were used. One was based on measurements of the densities of various carbon-containing gases, rela­ tive to the density of oxygen. The re­ sults of the measurements were not very consistent and generally too low by 0.05 to 0.1 percent. Another pro­ cedure was based on determining the weight of carbon dioxide produced by the burning of selected hydrocarbons. There were two likely sources of er­ rors in this method—inadequate purity of the hydrocarbons and uncertainties in buoyancy corrections caused by changes in the density of the carbon dioxide absorbent. Over a compara­ tively short period of time, the accepted atomic weight of carbon changed from 12.00 to 12.005, then to 12.010, and finally to 12.011. It is not surprising that Renoll, Midgley, and Henne