List of Publications and Patents of Michel Boudart - The Journal of

List of Publications and Patents of Michel Boudart. J. Phys. Chem. B , 2005, 109 (6), pp 2039–2046. DOI: 10.1021/jp040703t. Publication Date (Web): ...
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J. Phys. Chem. B 2005, 109, 2039-2046

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List of Publications and Patents of Michel Boudart Publications of Michel Boudart 1. M. Boudart, Pauling’s Theory of Metals in Catalysis, J. Am. Chem. Soc., 72, 1040 (1950). 2. M. Boudart, The Mechanism of the Decomposition of N2O on ZnO as Catalyst, J. Chem. Phys., 18, 571 (1950). 3. M. Boudart and H. S. Taylor, The Slow Step in Chemisorption. [1.] The Possible Role of the Solid Adsorbent; p. 223 in Research Council of Israel Special Publication No. 1 (L. Farkas Memorial Volume), 1952. 4. M Boudart, Electronic Chemical Potential in Chemisorption and Catalysis, J. Am. Chem. Soc., 74, 1531 (1952). 5. M. Boudart, Heterogeneity of Metal Surfaces, J. Am. Chem. Soc., 74, 3556 (1952). 6. M. Boudart, Surface Structure from the Standpoint of Chemisorption and Catalysis; p. 400 in Structure and Properties of Solid Surfaces; R. Gomer and C. S. Smith (Eds.); University of Chicago Press: Chicago, IL, 1953. 7. M. Boudart, Heterogeneous Catalysis, Ind. Eng. Chem., 45, 898 (1953). (Fundamentals Review.) 8. M. Boudart, Sound Dispersion in cis-trans-Dichlorethylene Vapors, J. Chem. Phys., 21, 955 (1953). 9. R. J. Mikovsky, M. Boudart, and H. S. Taylor, HydrogenDeuterium Exchange on Copper, Silver, Gold and Alloy Surfaces, J. Am. Chem. Soc., 76, 3814 (1954). 10. A. Cimino, M. Boudart, and H. S. Taylor, Ethane Hydrogenation-Cracking on Iron Catalysts with and without Alkali, J. Phys. Chem., 58, 796 (1954). 11. M. Boudart, Les Centres Actifs en Adsorption et Catalyse He´te´roge`ne, Ind. Chim. Belge, 19, 489 (1954). 12. M. Boudart, Heterogeneous Catalysis, Ind. Eng. Chem., 46, 884 (1954). (Fundamentals Review.) 13. M. Boudart and J. T. Dubois, Stabilization of EnergyRich Molecules. I. Energy Transfer with Hydrogen, J. Chem. Phys., 23, 223 (1955). 14. J. D. McKinley, Jr., D. Garvin, and M. Boudart, Production of Excited Hydroxyl Radicals in the Hydrogen AtomOzone Reaction, J. Chem. Phys., 23, 784 (1955). 15. R. De Vogelaere and M. Boudart, Contribution to the Theory of Fast Reaction Rates, J. Chem. Phys., 23, 1236 (1955). 16. K. Tamaru, M. Boudart, and H. S. Taylor, The Thermal Decomposition of Germane. I. Kinetics, J. Phys. Chem., 59, 801 (1955). 17. P. J. Fensham, K. Tamaru, M. Boudart, and H. S. Taylor, The Thermal Decomposition of Germane. II. Mechanism, J. Phys. Chem., 59, 806 (1955). 18. G. Parravano and M. Boudart, Chemisorption and Catalysis on Oxide Semiconductors; p 47 in AdVances in Catalysis, Vol. VII; Academic Press: New York, 1955. 19. M. Boudart and T. Kwan, Heterogeneous Catalysis, Ind. Eng. Chem., 48, 562 (1956). (Fundamentals Review.) 20. M. Boudart, Kinetics on Ideal and Real Surfaces, AIChE J., 2, 62 (1956). 21. B. Stevens and M. Boudart, Vibrational Energy Transfer from Collisional Deactivation of Simple Molecules and Fluorescence Stabilization of Complex Molecules, Ann. N.Y. Acad. Sci., 67, 570 (1957).

22. K. Tamaru and M. Boudart, Chemisorption and Catalysis on Germanium; p. 699 in AdVances in Catalysis, Vol. IX; Academic Press: New York, 1957. 23. M. Boudart and G. Parravano, Chemisorption and Surface Catalysis, Ind. Eng. Chem., 49, 611 (1957). (Fundamentals Review.) 24. M. Boudart, Relaxation Times in Gases; p. 75 in Transport Properties in Gases; A. Cambel and J. B. Fenn, Eds.; Northwestern University Press, Evanston, IL, 1958. 25. M. Boudart and G. Parravano, Heterogeneous Catalysis, Ind. Eng. Chem., 50, 486 (1958). (Fundamentals Review.) 26. M. Boudart, Kinetics and Mechanism of Catalytic Reactions, Ind. Chim. Belge, 23, 383 (1958). 27. G. Parravano, H. G. Friedrick, and M. Boudart, The Slow Step in Chemisorption. II. The Possible Role of the Solid Absorbent, J. Phys. Chem., 63, 1144 (1959). 28. R. F. Hoffman and M. Boudart, Calculation of Equilibrium Yields, C. R. Congr. Int. Chim. Ind., 19th (Brussels 1959), Vol. II, p. 1 (1959). 29. L. Spenadel and M. Boudart, Dispersion of Platinum on Supported Catalysts, J. Phys. Chem., 64, 204 (1960). 30. V. Kevorkian, C. E. Heath, and M. Boudart, The Decomposition of Methane in Shock Waves, J. Phys. Chem., 64, 964 (1960). 31. M. Boudart, Adsorption and Chemisorption. The Surface Chemistry of Metals and Semi-Conductors; p. 409 in Volume Surface Reactions in Gaseous Media; H. Gatos, Ed.; Wiley, New York, 1960. 32. A. Ozaki, H. S. Taylor, and M. Boudart, Kinetics and Mechanism of the Ammonia Synthesis, Proc. R. Soc. London, Ser. A, A258, 47 (1960). 33. R. M. Koros, J. Deckers, and M. Boudart, More Experiments on Liquid Films, J. Appl. Phys., 31, 1129 (1960). 34. K. Tsu and M. Boudart, Surface Diffusion and Recombination of Hydrogen Atoms on Glass, Actes Congr. Int. Catal., 2nd, 1960, 1, 593 (1961). 35. K. Tsu and M. Boudart, Recombination of Atoms at the Surface of Thermocouple Probes, Can. J. Chem., 39, 1239 (1961). 36. M. Boudart, Correlations in Heterogeneous Catalysis, Chem. Eng. Prog., 57, 33 (1961). 37. W. J. Heideger and M. Boudart, Interfacial Resistance to Evaporation, Chem. Eng. Sci., 17, 1 (1962). 38. M. Boudart, Chemical Kinetics and Combustion; p. 43 in 8th International Symposium on Combustion, California Institute of Technology, Pasadena, CA, 1960; Williams and Wilkins Co., Baltimore, MD, 1960. 39. M. Boudart, Catalytic Kinetics in Theory and Practice, Chem. Eng. Prog., 58, 73 (1962). 40. M. Boudart, Gas Kinetics, Annu. ReV. Phys. Chem., 13, 241 (1962). 41. C. A. Eckert and M. Boudart, On the Use of Fugacities in Gas Kinetics, Chem. Eng. Sci., 18, 144 (1963). 42. A. J. Robell, E. V. Ballou, and M. Boudart, Surface Diffusion of Hydrogen on Carbon, J. Phys. Chem., 68, 2748 (1964).

10.1021/jp040703t © 2005 Michel Boudart Published on Web 02/10/2005

2040 J. Phys. Chem. B, Vol. 109, No. 6, 2005 43. J. B. Anderson and M. Boudart, Sticking Probability of Oxygen Molecules on Single Crystals of Germanium. J. Catal., 3, 216 (1964). 44. H. W. Kohn and M. Boudart, Reaction of Hydrogen with Oxygen Adsorbed on a Platinum Catalyst, Science, 145, 149 (1964). 45. R. P. Andres and M. Boudart, Time Lag in Multistage Kinetics of Nucleation. J. Chem. Phys., 42, 2057 (1965). 46. R. W. Getzinger, J. R. Bowen, A. K. Oppenheim, and M. Boudart, Steady Detonations in Gaseous Ozone; p. 779 in 10th International Symposium on Combustion; The Combustion Institute, Pittsburgh, PA, 1965. 47. R. P. Chambers, N. A. Dougharty, and M. Boudart, A Reliable Noncontaminating Gas Recirculation Pump, J. Catal., 4, 625 (1965). 48. J. E. Benson and M. Boudart, Hydrogen-Oxygen Titration Method for the Measurement of Supported Platinum Surface Areas, J. Catal., 4, 704 (1965). 49. D. E. Mears and M. Boudart, The Dehydrogenation of Isopropanol on Catalysts Prepared by Sodium Borohydride Reduction, AIChE J., 2, 313 (1966). 50. J. E. Benson, H. W. Kohn, and M. Boudart, On the Reduction of Tungsten Trioxide Accelerated by Platinum and Water, J. Catal., 5, 307 (1966). 51. M. Boudart, A. Aldag, J. E. Benson, N. A. Dougharty, and C. G. Harkins, On the Specific Activity of Platinum Catalysts, J. Catal., 6, 92 (1966). 52. R. P. Chambers and M. Boudart, Selectivity of Gold Hydrogenation and Dehydrogenation of Cyclohexene, J. Catal., 5, 517 (1966). 53. J. C. Berg, M. Boudart, and A. Acrivos, Natural Convection in Pools of Evaporating Liquids, J. Fluid Mech., 24, 721 (1966). 54. R. P. Chambers and M. Boudart, Lack of Dependence of Conversion on Flow Rate in Catalytic Studies, J. Catal., 6, 141 (1966). 55. R. M. Koros, J. M. Deckers, R. P. Andres, and M. Boudart, The Sticking Probability of Water on Ice, Chem. Eng. Sci., 21, 941 (1966). 56. J. C. Berg, A. Acrivos, and M. Boudart, Evaporative Convection, AdV. Chem. Eng., 6, 61 (1966). 57. G. Parravano, J. D. Baldeschwieler, and M. Boudart, Diffusion of Water in Zeolites, Science, 155, 1535 (1967). 58. G. L’Homme, M. Boudart, and L. D’Or, Etude Cine´tique de la Catalyse par le Platine de l’Oxidation Lente d'un Noir de Carbone par l’Oxyge`ne Gazeux, Bull. Cl. Sci., Acad. R. Belg., 52, 1249 (1966). 59. G. L’Homme, M. Boudart, and L. D’Or, Etude Cine´tique de l’Oxidation Lente d’un Noir de Carbone par l’Oxyge`ne Gazeux, Bull. Cl. Sci., Acad. R. Belg., 52, 1206 (1966). 60. R. J. Madix and M. Boudart, The Sticking Probabilities by an Effusive Beam Technique: The GermaniumOxygen System. J. Catal., 7, 240 (1967). 61. J. E. Benson and M. Boudart, Reversible Adsorption of Hydrogen on Near-Faujasites, J. Catal., 8, 93 (1967). 62. G. L’Homme and M. Boudart, The Ignition of Carbon and Its Catalysis by Platinum; p. 197 in 11th International Symposium on Combustion; The Combustion Institute, Pittsburgh, PA, 1967. 63. M. Boudart, D. E. Mears, and M. A. Vannice, Kinetics of Heterogeneous Reactions, Ind. Chim. Belge, 32 (Part 1), 281 (1967). (Special Issue.)

64. J. E. Benson, K. Ushiba, and M. Boudart, Ammonia Adsorption on a Decationized Y-Zeolite, J. Catal., 9, 91 (1967). 65. M. Boudart, Initial Rate Approach on the Kinetics of Heterogeneous Catalytic Reaction, Chem. Eng. Sci., 22, 1387 (1967). (Short Communication.) 66. W. N. Delgass and M. Boudart, Applications of Mo¨ssbauer Spectroscopy to the Study of Adsorption and Catalysis, Catal. ReV., 2 (1), 129 (1968). 67. M. Boudart, A. Aldag, L. D. Ptak, and J. E. Benson, On the Selectivity of Platinum Catalysts, J. Catal., 11, 35 (1968). 68. W. N. Delgass, M. Boudart, and G. Parravano, Mo¨ssbauer Spectroscopy of Supported Gold Catalysts, J. Phys. Chem., 72, 3563 (1968). 69. E. J. Nowak, J. M. Deckers, and M. Boudart, Reaction Probabilities for Methane and Oxygen on (111) Silicon Single-Crystal Surfaces, J. Catal., 11, 177 (1968). 70. J. E. Benson, A. B. Walters, and M. Boudart, Activation of Hydrogen at 79 K by Supported Copper, J. Phys. Chem., 72, 4587 (1968). 71. S. Kurzius and M. Boudart, Kinetics of the Branching Step in the Hydrogen-Oxygen Reactions, Combust. Flame, 12, 477 (1968). 72. M. Boudart and D. F. Ollis, Sticking Probability of Light Hydrocarbons on Tungsten, Trans. Faraday Soc., 65, 519 (1969). 73. M. Boudart, J. E. Benson, and M. A. Vannice, Adlineation, Portholes and Spillover, Z. Phys. Chem. Neue Folge, 64, 171 (1969). 74. M. Boudart, Four Decades of Active Centers, Am. Sci., 57, 97 (1969). 75. Y. Y. Huang, J. E. Benson, and M. Boudart, Krypton as a Probe of Electrostatic Fields in Y-Zeolites, Ind. Eng. Chem. Fundam., 8, 346 (1969). 76. W. N. Delgass, R. L. Garten, and M. Boudart, Mo¨ssbauer Effect of Exchangeable Ferrous Ions in Y-Zeolite and Dowex 50 Resin, J. Chem. Phys., 50 (11), 4603 (1969). 77. W. N. Delgass, R. L. Garten, and M. Boudart, Dehydration and Adsorbate Interaction of Fe-Y Zeolite by Mo¨ssbauer Spectroscopy, J. Phys. Chem., 73, 2970 (1969). 78. M. Boudart and D. F. Ollis, LEED Investigation of the Carburization of Tungsten Single Crystals above 2000 K; Paper No. 63 in The Structure and Chemistry of Solid Surfaces; G. A. Somorjai, Ed.; Wiley, New York, 1969. 79. M. Boudart, Catalysis by Supported Metals, AdV. Catal., 20, 153 (1969). 80. M. Boudart and L. D. Ptak, Reactions of Neopentane on Transition Metals, J. Catal., 16, 90 (1970). 81. M. A. Vannice, J. E. Benson, and M. Boudart, Determination of Surface Area by Chemisorption: Unsupported Platinum, J. Catal., 16, 348 (1970). 82. M. A. Vannice, M. Boudart, and J. J. Fripiat, Mobility of Hydrogen in Hydrogen Tungsten Bronze, J. Catal., 17, 359 (1970). 83. M. Boudart, A. W. Aldag, and M. A. Vannice, On the Slow Uptake of Hydrogen by Platinized Carbon, J. Catal., 18, 46 (1970). 84. R. L. Garten, W. N. Delgass, and M. Boudart, A Mo¨ssbauer Spectroscopic Study of the Reversible Oxidation of Ferrous Ions in Y-Zeolite, J. Catal., 18, 90 (1970). 85. M. Boudart, Kinetics of Chemical Processes, Chem. Eng. Ed., 5, 166 (1970).

J. Phys. Chem. B, Vol. 109, No. 6, 2005 2041 86. D. F. Ollis and M. Boudart, Surface and Bulk Carburization of Tungsten Single Crystals, Surf. Sci., 23, 320 (1970). 87. M. Boudart, Active Centers in Heterogeneous Catalysis; In Proceedings of the Robert A. Welch Foundation Conference on Chemical Research XIV, November 1970. 88. M. Boudart, R. L. Garten, and W. N. Delgass, Mo¨ssbauer Spectroscopy: A New Tool for the Study of Catalytic Materials, Mem. Soc. R. Sci. Liege, Collect. 6, 1 (4), 135-148 (1971). 89. M. Boudart, Kinetics of Heterogeneous Catalytic Reactions; Section III in NATO International Summer School on Fundamental Principles in Heterogeneous Catalysis, Venice 1971. 90. J. C. Schlatter and M. Boudart, Hydrogenation of Ethylene on Supported Platinum, J. Catal., 24, 482 (1972). 91. J. C. Schlatter and M. Boudart, Selective Hydrogenolysis of Methylcyclopropane over Bifunctional Catalysts, J. Catal., 25, 93 (1972). 92. C. H. Bartholomew and M. Boudart, Preparation of a WellDispersed Platinum-Iron Alloy on Carbon, J. Catal., 25, 173 (1972). 93. M. Boudart, Two-Step Catalytic Reactions, AIChE J., 18, 465 (1972). 94. F. L. Williams, M. Boudart, and A. Frennet, Backstreaming of Hydrogen When Pumping Hydrocarbons with an Ion Pump, J. Vac. Sci. Technol., 9, 362 (1972). 95. M. Boudart, A. Delbouille, E. G. Derouane, V. Indovina, and A. B. Walters, Activation of Hydrogen at 78 K on Paramagnetic Centers of Magnesium Oxide, J. Am. Chem. Soc., 94, 6622 (1972). 96. E. G. Derouane, V. Indovina, A. B. Walters, and M. Boudart, Paramagnetic Defects at the Surface of Magnesium Oxide; pp. 703-716 in Proceedings of the 7th International Symposium on ReactiVity of Solids, Bristol, U.K., July 1972; J. S. Anderson, M. W. Roberts, and F. S. Stone, Eds.; Chapman and Hall, London, 1973. 97. K. A. Klinedinst and M. Boudart, Mo¨ssbauer Spectroscopy Applied to the Study of a Homogeneous Ziegler-Type Hydrogenation Catalyst, J. Catal., 28, 322 (1973). 98. H. Topsøe, J. A. Dumesic, and M. Boudart, Alumina as a Textural Promoter of Iron Synthetic Ammonia Catalysts, J. Catal., 28, 477 (1973). 99. C. H. Bartholomew and M. Boudart, Surface Composition and Chemistry of Supported Platinum-Iron Alloys, J. Catal., 29, 278 (1973). 100. A. Amirnazmi, J. E. Benson, and M. Boudart, Oxygen Inhibition in the Decomposition of NO on Metal Oxides and Platinum, J. Catal., 30, 55 (1973). 101. J. E. Benson, H. S. Hwang, and M. Boudart, HydrogenOxygen Titration Method for the Measurement of Supported Palladium Surface Areas, J. Catal., 30, 146 (1973). 102. R. L. Garten, J. Gallard-Nechtshein, and M. Boudart, Mo¨ssbauer Spectroscopic Studies and Catalytic Properties of Iron Mordenite, Ind. Eng. Chem. Fundam., 12, 299 (1973). 103. R. B. Levy and M. Boudart, Platinum-Like Behavior of Tungsten Carbide in Surface Catalysis, Science, 181, 547 (1973).

104. R. A. Dalla Betta and M. Boudart, Well-Dispersed Platinum on Y-Zeolite: Preparation and Catalytic Activity; in Proceedings of the Vth International Congress Catalysis, Palm Beach, FL, 1972; J. Hightower, Ed.; North-Holland/Elsevier, New York, 1973. 105. F. L. Williams and M. Boudart, Surface Composition of Nickel-Gold Alloys, J. Catal., 30, 438 (1973). 106. H. Topsøe and M. Boudart, Mo¨ssbauer Spectroscopy of CO Shift Catalysts Promoted with Lead, J. Catal., 31, 346 (1973). 107. R. B. Levy and M. Boudart, The Kinetics and Mechanism of Spillover, J. Catal., 32, 304 (1974). 108. M. Boudart and R. L. Burwell, Jr., Mechanism in Heterogeneous Catalysis; Chapter 12 in InVestigation of Rates and Mechanisms of Reactions; E. S. Lewis, Ed.; Wiley, New York, 1974. 109. M. Boudart, Surface Science and Catalysis, CHEMTECH, 4, 748 (1974). 110. H. Topsøe, J. A. Dumesic, and M. Boudart, Mo¨ssbauer Spectra of Stoichiometric and Nonstoichiometric Fe3O4 Microcrystals, J. Phys. (Paris), 35, C6-C411 (1974). 111. M. Boudart, Chemisorption During Catalytic Reaction on Metal Surfaces, J. Vac. Sci. Technol., 12 (1), 329 (1975). 112. M. Boudart, A. Delbouille, J. A. Dumesic, S. Khammouma, and H. Topsøe, Surface, Catalytic and Magnetic Properties of Small Iron Particles, Part I: Preparation and Characterization of Samples, J. Catal., 37, 486 (1975). 113. J. A. Dumesic, H. Topsøe, S. Khammouma, and M. Boudart, Surface, Catalytic and Magnetic Properties of Small Iron Particles, Part II: Structure Sensitivity of Ammonia Synthesis, J. Catal., 37, 503 (1975). 114. J. A. Dumesic, H. Topsøe, and M. Boudart, Surface, Catalytic and Magnetic Properties of Small Iron Particles, Part III: Nitrogen Induced Surface Reconstruction, J. Catal., 37, 513 (1975). 115. M. Boudart, Concepts in Heterogeneous Catalysis; Chapter 7 in Interactions in Metal Surfaces; R. Gomer, Ed.; Springer-Verlag, New York, 1975. 116. M. Boudart, E. G. Derouane, V. Indovina, and A. B. Walters, Preparation of Copper on Magnesia Catalysts: An Electron Spin Resonance Study, J. Catal., 39, 115 (1975). 117. M. Boudart and H. S. Hwang, Solubility of Hydrogen in Small Particles of Palladium, J. Catal., 39, 44 (1975). 118. J. J. Fripiat, K. T. Chow, M. Boudart, J. B. Diamond, and K. H. Johnson, The Structure and Bonding of Lithium Clusters, J. Mol. Catal., 1, 59 (1975). 119. M. Boudart, Heterogeneous Catalysis; Chapter 7 in Physical Chemistry: An AdVanced Treatise, Vol. 7; H. Eyring, W. Jost, and D. Henderson, Eds.; Academic Press, New York, 1975. 120. A. Amirnazmi and M. Boudart, Decomposition of Nitric Oxide on Platinum, J. Catal., 39, 383 (1975). 121. M. Boudart, H. Topsøe, and J. A. Dumesic, Catalytic and Magnetic Anisotropy of Iron Surfaces; pp. 337-362 in The Physical Basis for Heterogeneous Catalysis; E. Drauglis and R. I. Jaffee, Eds.; Plenum Press, New York, 1975. 122. A. Ozaki and M. Boudart, Comment: On Deuterium Isotope Effect of Ammonia Synthesis, Ber. BunsenGes., 80 (4), 352 (1977).

2042 J. Phys. Chem. B, Vol. 109, No. 6, 2005 123. R. A. Dalla Betta, R. L. Garten, and M. Boudart, Infrared Examination of the Reversible Oxidation of Ferrous Ions in Y-Zeolite, J. Catal., 41, 40 (1976). 124. K. J. Lim and M. Boudart, Discussion of Catalytic Decomposition of Nitric Oxide on Zirconia by Electrolytic Removal of Oxygen, J. Electrochem. Soc., 123 (6), 839-840 (1976). 125. R. A. Dalla Betta and M. Boudart, Hydroxyl Exchange on H-CaY and Pt/H-CaY Zeolites with Deuterium, J. Chem. Soc., Faraday Trans. 1, 72, 1723-1732 (1976). 126. M. Boudart, J. A. Cusumano, and R. B. Levy, New Catalytic Materials for the Conversion of Coal; pp. 591637 in Critical Materials Problems in Energy Production; C. Stein, Ed.; Academic Press, New York, 1976. 127. M. Boudart, Consistency between Kinetics and Thermodynamics, J. Phys. Chem., 80, 2869 (1976). 128. M. Boudart, D. M. Collins, F. V. Hanson, and W. E. Spicer, Reactions between H2 and O2 on Pt at Low and High Pressures: A Comparison, J. Vac. Sci. Technol., 14 (1), 441-443 (1977). 129. M. Boudart, Catalysis by Metals: Concepts, Factors, and Reactions; pp. 5-12 in The Electron Factor in Catalysis on Metals, NBS Special Publication 45; National Bureau of Standards, Washington, DC, April 1977. 130. M. Boudart, J. A. Dumesic, and H. Topsøe, Surface, Catalytic and Magnetic Properties of Small Iron Particles, Proc. Natl. Acad. Sci., 74, 806-810 (1977). 131. Y.-L. Lam and M. Boudart, Oxidation of Small Palladium Particles, J. Catal., 47, 393-398 (1977). 132. C. Naccache, Y. Ben Taarit, and M. Boudart, ESR Study of Bivalent Rhodium Complexes Formed in Zeolites; pp. 156-165 in Molecular SieVes II, ACS Symposium Series, No. 40; American Chemical Society, Washington, DC, 1977. 133. Y.-L. Lam and M. Boudart, Preparation of Small Au-Pd Particles on Silica, J. Catal., 50, 530-540 (1977). 134. Y.-L. Lam, J. Criado, and M. Boudart, Enhancement by Inactive Gold of the Rate of the H2-O2 Reaction on Active Palladium: A Ligand Effect, NouV. J. Chim., 1, 461-466 (1977). 135. M. Boudart, Effects of Surface Structure on Catalytic Activity; pp 1-9 in Proceedings of the VIth International Congress on Catalysis, Vol. 1; G. C. Bond, P. B. Wells, and F. C. Tompkins, Eds.; The Chemical Society, London, 1977. 136. E. Segal, R. J. Madon, and M. Boudart, Catalytic Hydrogenation of Cyclohexene 1. Vapor-Phase Reaction on Supported Platinum, J. Catal., 52, 45-49 (1978). 137. M. Boudart, Kinetics and Catalysis: The Role of Fundamental Research, CHEMTECH, 8 (4) (1978). 138. B. N. Kuznetsov, Yu. I. Yermakov, M. Boudart, and J. P. Collman, The Conversion of Neopentane on Supported Catalysts, J. Mol. Catal., 4, 48-57 (1978). 139. E. E. Gonzo and M. Boudart, Catalytic Hydrogenation of Cyclohexene 3. Gas-Phase and Liquid-Phase Reaction on Supported Palladium, J. Catal., 52, 462-471 (1978). 140. P. Gallezot, A. I. Bienenstock, and M. Boudart, The Atomic Structure of Platinum Clusters, NouV. J. Chim., 2 (3), 263 (1978). 141. F. V. Hanson and M. Boudart, The Reaction between H2 and O2 over Supported Platinum Catalysts, J. Catal., 53, 56-67 (1978).

142. S. Ladas, R. A. Dalla Betta, and M. Boudart, The Magnetic Susceptibility of Small Palladium Particles, J. Catal., 53, 356-365 (1978). 143. R. J. Madon, J. P. O’Connell, and M. Boudart, Catalytic Hydrogenation of Cyclohexene 2. Liquid-Phase Reaction on Supported Platinum in a Gradientless Slurry Reactor, AIChE J., 24 (5), 904-912 (1978). 144. P. Gallezot, R. Weber, R. A. Dalla Betta, and M. Boudart, Investigation by X-ray Absorption Spectroscopy of Platinum Clusters Supported on Zeolites, Z. Naturforsch., 34a, 40-42 (1978). 145. C. H. Bartholomew, J. H. Anderson, Jr., and M. Boudart, Magnetic Properties of Supported Platinum-Iron Alloys, J. Chem. Soc., Faraday Trans. 1, 75, 157-261 (1979). 146. L. Leclercq, K. Imura, S. Yoshida, T. Barbee, and M. Boudart, Synthesis of New Catalytic Materials: Metal Carbides of the Group VI B Elements; pp. 627-639 in Preparation of Catalysts II: Scientific Bases for the Preparation of Heterogeneous Catalysts, Proceedings of the Second International Symposium, Louvain-la-Neuve, Belgium, September 4-7, 1978; Elsevier, Amsterdam, New York, 1979. 147. E. L. Kugler and M. Boudart, Ligand and Ensemble Effects in the Adsorption of Carbon Monoxide on Supported Palladium-Gold Alloys, J. Catal., 59, 201-210 (1979). 148. K. Fujimoto and M. Boudart, Preparation of Supported Iron Clusters and Their Mo¨ssbauer Effect Spectra, J. Phys. (Paris), 40, C2-81-C2-84 (1979). 149. R. Weber, M. Boudart, and P. Gallezot, Electron Deficiency in Platinum Clusters Supported on Y-Zeolites; pp. 415-420 in Growth and Properties of Metal Clusters; J. Bourdon, Ed.; Elsevier Scientific Publishing Company, Amsterdam, The Netherlands, 1980. 150. R. A. Dalla Betta, M. Boudart, P. Gallezot, and R. S. Weber, Reply to the Comments of P. H. Lewis on “Net Charge on Platinum Cluster Incorporated in Y-Zeolite”, J. Catal., 69, 514-515 (1981). 151. S. Ladas, H. Poppa, and M. Boudart, The Adsorption and Catalytic Oxidation of Carbon Monoxide on Evaporated Palladium Particles, Surf. Sci., 102, 151-171 (1981). 152. M. Boudart, Kinetics and Mechanism of Ammonia Synthesis, Catal. ReV.sSci. Eng., 23 (1&2), 1-15 (1981). 153. S. T. Oyama and M. Boudart, Ammonia Synthesis on Surface Layers of Molybdenum Nitride, J. Res. Inst. Catal., Hokkaido UniV., 28 (3), 305-320 (1980). 154. M. Boudart, S. T. Oyama, and L. Leclercq, Molybdenum Oxycarbide and Nitride as Catalysts in the Activation of C-O, N-N, C-C, and H-H Bonds; pp. 578-590 in Proceedings of the 7th International Congress on Catalysis, Volume 1, 1981. 155. G. Leclercq and M. Boudart, Catalytic Hydrogenation of Cyclohexene 4. The Effect of Sulfur on Supported Platinum, J. Catal., 71, 127-135 (1981). 156. W. L. Holstein and M. Boudart, Hydrogenolysis of Carbon and Its Catalysis by Platinum, J. Catal., 72, 328-337 (1981). 157. M. Boudart, C. Egawa, S. T. Oyama, and K. Tamaru, Nitrogen Adsorption and Ammonia Decomposition on Polycrystalline Molybdenum, J. Chim. Phys., 78 (11/ 12), 987-994 (1981). 158. W. L. Holstein and M. Boudart, Uncatalyzed and Platinum Catalyzed Gasification of Carbon by Water and Carbon Dioxide, J. Catal., 75, 337-353 (1982).

J. Phys. Chem. B, Vol. 109, No. 6, 2005 2043 159. M. Boudart, Prediction, Explanation, and Design in Heterogeneous Catalysis, Acc. Chem. Res., 15, 163 (1982). 160. D. C. Silverman and M. Boudart, Surface Composition of Promoted Iron Catalysts, J. Catal., 77, 208-220 (1982). 161. R. J. Madon and M. Boudart, Experimental Criterion for the Absence of Artifacts in the Measurement of Rates of Heterogeneous Catalytic Reactions, Ind. Eng. Chem. Fundam., 21, 438-447 (1982). 162. W. L. Holstein, R. D. Moorhead, H. Poppa, and M. Boudart, The Palladium Catalyzed Conversion of Amorphous to Graphitic Carbon; pp. 139-171 in Chemistry and Physics of Carbon, Vol. 18; P. Thrower, Ed.; Marcel Dekker: New York, 1982. 163. W. L. Holstein and M. Boudart, Transition Metal and Metal Oxide Catalyzed Gasification of Carbon by Oxygen, Water, and Carbon Dioxide, Fuel, 62, 162165 (1983). 164. W. S. Borghard and M. Boudart, The Textural Promotion of Metallic Iron by Alumina, J. Catal., 80, 194-206 (1983). 165. L. Volpe, S. T. Oyama, and M. Boudart, Synthesis, Surface Reactivity, and Catalytic Activity of High Specific Surface Area Molybdenum Nitride Powders; pp. 147158 in Preparation of Catalysts III: Scientific Bases for the Preparation of Heterogeneous Catalysts, Proceedings of the Third International Symposium, Louvain-la-Neuve, Belgium, September 6-9, 1982; G. Poncelet and P. A. Jacobs, Eds.; Elsevier, Amsterdam, 1983. 166. E. Iglesia and M. Boudart, Decomposition of Formic Acid on Copper, Nickel, and Copper-Nickel Alloys. I. Preparation and Characterization of Catalysts, J. Catal., 81, 204-213 (1983). 167. E. Iglesia and M. Boudart, Decomposition of Formic Acid on Copper, Nickel, and Copper-Nickel Alloys. II. Catalytic and Temperature-Programmed Desorption of Formic Acid on Cu/SiO2, Cu/Al2O3, and Cu Powder, J. Catal., 81, 214-223 (1983). 168. E. Iglesia and M. Boudart, Decomposition of Formic Acid on Copper, Nickel, and Copper-Nickel Alloys. III. Catalytic Decomposition on Nickel and Copper-Nickel Alloys, J. Catal., 81, 224-238 (1983). 169. J. E. Benson and M. Boudart, Sir Hugh Taylor, the Man; pp. 33-44 in Heterogeneous Catalysis: Selected American Histories, ACS Symposium Series 222; B. H. Davis and W. P. Hettinger, Jr., Eds.; American Chemical Society, Washington, DC, 1983. 170. M. Boudart, Thermodynamic and Kinetic Coupling of Chain and Catalytic Reactions, J. Phys. Chem., 87, 2786 (1983). 171. M. Boudart, J. Sa´nchez-Arrieta, and R. A. Dalla Betta, Correlation between Thiophene Hydrodesulfurization Activity and the Number of First Sulfur Neighbors as Determined by EXAFS in Sulfided CoMo/γ-Al2O3 Samples, J. Am. Chem. Soc., 105, 6501-6502 (1983). 172. W. L. Holstein and M. Boudart, The Temperature Difference between a Supported Catalyst Particle and Its Support during Exothermic and Endothermic Catalytic Reactions, ReV. Latinoam. Ing. Quim. Quim. Apl., 13, 107-120 (1983).

173. S. Ichikawa, H. Poppa, and M. Boudart, The Effect of Particle Size on the Reactivity of Supported Palladium; pp. 439-451 in Catalytic Materials: Relationship between Structure and ReactiVity, ACS Symposium Series 248; E. T. Whyte, Jr., R. A. Dalla Betta, E. G. Derouane, and R. T. K. Baker, Eds.; American Chemical Society, Washington, DC, 1984. 174. M. Boudart and M. A. McDonald, Structure Sensitivity of Hydrocarbon Synthesis from CO and H2, J. Phys. Chem., 88, 2185 (1984). 175. E. Iglesia and M. Boudart, Decomposition of Formic Acid on Copper, Nickel, and Copper-Nickel Alloys. IV. Temperature-Programmed Decomposition of Bulk Nickel Formate and of Formic Acid Preadsorbed on Nickel Powder, J. Catal., 88, 325-332 (1984). 176. M. Boudart, W. L. Holstein, R. D. Moorhead, and H. Poppa, In Situ Electron Microscope Study of the Palladium-Amorphous Carbon Interaction in Carbon Dioxide and Oxygen Atmospheres, J. Appl. Catal., 11, 117 (1984). 177. M. Boudart and D. G. Lo¨ffler, Surface Structure of Iron Catalysts for Ammonia Synthesis, J. Phys. Chem., 88, 5763 (1984). 178. M. Boudart, R. A. Dalla Betta, K. Foger, and D. G. Lo¨ffler, In Situ EXAFS of CoMo/γ-Al2O3 Catalysts During Hydrodesulfurization of Benzothiophene; pp. 187-189 in Proceedings in Physics 2: EXAFS and Near Edge Structure III; K. O. Hodgson, B. Hedman, and J. E. Penner-Hahn, Eds.; Springer-Verlag, Berlin, 1984. 179. R. A. Dalla Betta, M. Boudart, K. Foger, D. G. Lo¨ffler, and J. Sa´nchez-Arrieta, Cell Fitted with Thin Beryllium Windows for X-ray Absorption under Pressures up to 14 MPa and Temperatures up to 700 K, ReV. Sci. Instrum., 55 (12), 1910-1913 (1984). 180. S. Ichikawa, H. Poppa, and M. Boudart, Disproportionation of CO on Small Particles of Silica-Supported Palladium, J. Catal., 91, 1-10 (1985). 181. M. Boudart, Heterogeneous Catalysis by Metals, J. Mol. Catal., 30, 27-38 (1985). 182. M. Boudart and G. Meitzner, An X-ray Absorption Study of Gold/Y-Zeolite; pp. 217-221 in Proceedings in Physics 2: EXAFS and Near Edge Structure III; K. O. Hodgson, B. Hedman, and J. E. Penner-Hahn, Eds.; Springer-Verlag, Berlin, 1984. 183. M. Boudart, R. A. Dalla Betta, K. Foger, D. G. Lo¨ffler, and M. G. Samant, Study by Synchrotron Radiation of the Structure of a Working Catalyst at High Temperatures and Pressures, Science, 228, 717-719 (1985). 184. D. J. O’Rear, D. G. Lo¨ffler, and M. Boudart, Catalytic Hydrogenation of Cyclohexene 6. Turnover Rate of the Gas-Phase Reaction on Unsupported Platinum Powders, J. Catal., 94, 225-229 (1985). 185. L. Volpe and M. Boudart, Compounds of Molybdenum and Tungsten with High Specific Surface Area I. Nitrides, J. Solid State Chem., 59, 332-347 (1985). 186. L. Volpe and M. Boudart, Compounds of Molybdenum and Tungsten with High Specific Surface Area II. Carbides, J. Solid State Chem., 59, 348-356 (1985). 187. M. Boudart, D. G. Lo¨ffler, and J. C. Gottifredi, Comments on the Linear Relation between Reaction Rate and Affinity, Int. J. Chem. Kinet., 17, 1119-1123 (1985). 188. L. Volpe and M. Boudart, Topotactic Preparation of Powders with High Specific Surface Area, Catal. ReV.s Sci., Eng., 27 (4), 515-538 (1985).

2044 J. Phys. Chem. B, Vol. 109, No. 6, 2005 189. J. S. Lee and M. Boudart, Hydrodesulfurization of Thiophene over Unsupported Molybdenum Carbide, J. Appl. Catal., 19, 207-210 (1985). 190. M. Boudart, A Postscript; In Proceedings of the 8th International Congress on Catalysis, Berlin 1984; Vol. VI, 3-10, DECHEMA, Verlag-Chemie, Weinheim, 1985. 191. M. Boudart, Some Applications of the Generalized De Donder Equation to Industrial Reactions, Ind. Eng. Chem. Fundam., 25, 70-75 (1986). 192. M. Peuckert, T. Yoneda, R. A. Dalla Betta, and M. Boudart, Oxygen Reduction on Small Supported Platinum Particles, J. Electrochem. Soc., 133 (5), 944-947 (1986). 193. K. J. Lim, D. G. Lo¨ffler, and M. Boudart, Nitrogen Desorption in the Reaction of Nitric Oxide on CarbonSupported Platinum Catalysts, J. Catal., 100, 158-166 (1986). 194. M. Boudart, M. G. Samant, and R. Ryoo, Atomic and Electronic Structure and Chemical Reactivity of Metal Clusters, Ultramicroscopy, 20, 125-134 (1986). 195. M. Boudart, Single Crystals: Standards for Industrial Catalysts, CHEMTECH, (November), 688-692 (1986). 196. M. Boudart, Classical Catalytic Kinetics: A Placebo or the Real Thing?, Ind. Eng. Chem. Fundam., 25, 656658 (1986). 197. E. Iglesia and M. Boudart, Unimolecular and Bimolecular Formic Acid Decomposition on Copper, J. Phys. Chem., 90, 5272-5274 (1986). 198. M. A. McDonald, D. A. Storm, and M. Boudart, Hydrocarbon Synthesis from CO-H2 on Supported Iron: Effect of Particle Size and Interstitials, J. Catal., 102, 386-400 (1986). 199. H. Hamada, M. G. Samant, and M. Boudart, X-ray Absorption Spectroscopy of Silica-Supported IridiumRuthenium Bimetallic Clusters, Chem. Lett., 885-888 (1986). 200. L. Volpe and M. Boudart, Ammonia Synthesis on Molybdenum Nitride, J. Phys. Chem., 90, 4874-4877 (1986). 201. M. Boudart, J. S. Lee, K. Imura, and S. Yoshida, The Effect of Surface Composition on the Chemisorption of Hydrogen on Tungsten Carbide, J. Catal., 103, 30-36 (1987). 202. K. J. Lim and M. Boudart, Nitrogen Desorption in the Reaction of Nitric Oxide on Carbon-Supported Platinum Catalysts, J. Catal., 105, 263-265 (1987). (Letter to the Editor.) 203. M. Boudart and W.-C. Cheng, Catalytic Hydrogenation of Cyclohexene 7. Liquid-Phase Reaction on Supported Nickel, J. Catal., 106, 134-143 (1987). 204. J. S. Lee, S. T. Oyama, and M. Boudart, Molybdenum Carbide Catalysts 1. Synthesis of Unsupported Powders, J. Catal., 106, 125-133 (1987). 205. M. Boudart and F. Rumpf, The Catalytic Oxidation of CO and Structure Insensitivity, React. Kinet. Catal. Lett., 35 (1-2), 95-105 (1987). 206. M. Boudart, La Catalyse et ses Applications, Bull. Cl. Sci., Acad. R. Belg., 5 (23), 303-308 (1987). 207. M. Boudart, Kinetics Assisted Design of Catalysts, Catal. Lett., 1, 21-26 (1988). 208. F. R. Rumpf, H. Poppa, and M. Boudart, Oxidation of Carbon Monoxide on Palladium: The Role of the Alumina Support, Langmuir, 7, 722-728 (1988).

209. D. J. Sajkowski and M. Boudart, Structure Sensitivity of the Catalytic Oxidation of Ethene by Silver, Catal. ReV.sSci. Eng., 29 (4), 325-360 (1987). 210. M. G. Samant, G. Bergeret, G. Meitzner, and M. Boudart, Anomalous Wide Angle X-ray Scattering and X-ray Absorption Spectroscopy of Supported Pt-Mo Bimetallic Clusters 1. Experimental Technique, J. Phys. Chem., 92, 3542-3546 (1988). 211. M. G. Samant, G. Bergeret, G. Meitzner, P. Gallezot, and M. Boudart, Anomalous Wide Angle X-ray Scattering and X-ray Absorption Spectroscopy of Supported PtMo Bimetallic Clusters 2. Atomic and Electronic Structure, J. Phys. Chem., 92, 3547-3554 (1988). 212. M. G. Samant, L.-C. de Me´norval, R. A. Dalla Betta, and M. Boudart, Nuclear Magnetic Resonance of Xenon Occluded in NaY-Zeolite, J. Phys. Chem., 92, 38373938 (1988). 213. M. Boudart, G. P. Valenc¸ a, L.-C. de Me´norval, and J. Fraissard, Study by Xenon-NMR of Platinum Particles Supported on Alumina, J. Phys. Chem., 92, 4033-4035 (1988). 214. J. S. Lee, L. Volpe, F. H. Ribeiro, and M. Boudart, Molybdenum Carbide Catalysts: 2. Topotactic Synthesis of Unsupported Powders, J. Catal., 112, 44-53 (1988). 215. R. S. Weber, M. Peuckert, R. A. Dalla Betta, and M. Boudart, Oxygen Reduction on Small Supported Platinum Particles II. Characterization by X-Ray Absorption Spectroscopy, J. Electrochem. Soc., 135 (10), 25352538 (1988). 216. M. Boudart, Response to “Classical Catalytic Kinetics: What Is the Point of the Matter?”, Ind. Eng. Chem. Res., 28, 379 (1989). 217. M. Boudart, The Virtual Pressure of Atomic Hydrogen in a Palladium Cathode Away from Equilibrium, Catalytica Highlights, 15 (1) 1989. 218. M. Boudart and C. M. McConica, Catalytic Hydrogenation of Cyclohexene 8. Gas-Phase Reaction on Supported Nickel, J. Catal., 117, 33-41 (1989). 219. R. J. Davis, S. M. Landry, J. A. Horsley, and M. Boudart, X-Ray Absorption Study of the Interaction of Hydrogen with Clusters of Supported Palladium, Phys. ReV. B, 39 (15), 10580-10583 (1989). 220. M. Boudart, Virtual Pressure and Virtual Fugacity in Catalysis and Electrocatalysis, Catal. Lett., 3, 111-116 (1989). 221. M. Avalos-Borja, D. Su, F. A. Ponce, J. C. Tramontana, Q.-C. Guo, K. Heinemann, H. Poppa, and M. Boudart, Applications of In-Situ UHV and High Resolution TEM to the Study of Small Particles; pp. 81-86 in High Resolution Microscopy of Materials, Materials Research Society Symposium Proceedings, Vol. 139; W. Krakow, F. A. Ponce, and D. J. Smith, Eds.; Materials Research Society, Warrendale, PA, 1989. 222. M. Boudart, Kinetics Assisted Design of Catalytic Cycles; pp 141-162 (Chapter 6) in Catalyst Design: Progress and PerspectiVes; L. L. Hegedus, Ed.; Wiley, New York, 1987. 223. D. J. O’Rear, D. G. Lo¨ffler, and M. Boudart, Stoichiometry of the Titration by Dihydrogen of Oxygen Adsorbed on Platinum, J. Catal., 121, 131-140 (1990). 224. S. M. Landry, R. A. Dalla Betta, J. P. Lu¨, and M. Boudart, Catalytic Oxidation of Carbon Monoxide on Palladium 1. Effect of Pressure, J. Phys. Chem., 94 (3), 12031206 (1990).

J. Phys. Chem. B, Vol. 109, No. 6, 2005 2045 225. M. Boudart, Catalysis: Concepts and Applications; In Catalysis: Concepts and Applications, Proceedings of the Ninth National Symposium on Catalysis, December 15-17, 1988; B. Viswanathan and A. Meenakshisundaram, Eds.; Tata McGraw-Hill, New Delhi, India, 1989. 226. J. S. Lee, S. Locatelli, S. T. Oyama, and M. Boudart, Molybdenum Carbide Catalysts. 3. Turnover Rates for the Hydrogenolysis of n-Butane, J. Catal., 125, 157170 (1990). 227. M. Boudart and S. T. Oyama, Interstitial Compounds of Molybdenum and Tungsten as Potential Catalytic Materials; In Proceedings of the 12th Iberoamerican Symposium on Catalysis, Rio de Janeiro, Brazil (JulyAugust 1990), Vol. 2; Instituto Brasileiro de Petro´leo, Brazil, 1990. 228. M. Boudart and D. G. Lo¨ffler, Rate of Adsorption to and Desorption from a Langmuir Surface: The Case of Zero Activation Barrier to Adsorption without Dissociation, Catal. Lett., 6, 317-320 (1990). 229. J. S. Lee and M. Boudart, Reactivity of Tungsten Carbides I. Catalytic and Temperature-Programmed Reactions of Methanol, Catal. Lett., 8, 107-114 (1991). 230. R. J. Davis and M. Boudart, Uses of Synchrotron Radiation in Heterogeneous Catalysis; pp. 293-336 in Proceedings of Symposium on Applications of Synchrotron Radiation, Pohang Institute of Science and Technology (August 17-19, 1989); Pohang Institute of Science and Technology, Korea, 1991. 231. M. Boudart, Science and Its Applications: How to Succeed; pp. 77-83 in Technology and Economics, Proceedings of Symposium on “Technology and Economics”, April 4-5, 1990; National Academy Press, Washington, DC, 1991. 232. G. P. Valenc¸ a and M. Boudart, Titration by H2 and O2 of Bare or Covered Pt Surfaces Followed by 129Xe NMR, J. Catal., 128, 447-457 (1991). 233. M. Boudart, Kinetics and Catalysis; pp. 178-184 in PerspectiVes in Catalysis; J. M. Thomas and K. I. Zamaraev, Eds.; Blackwell, Oxford, U.K., 1991. (IUPAC Monograph.) 234. M. Boudart and K. Tamaru, The Step That Determines the Rate of a Single Catalytic Cycle, Catal. Lett., 9, 15 (1991). 235. M. G. Samant and M. Boudart, Support Effects on Electronic Structure of Platinum Clusters in Y-Zeolite, J. Phys. Chem., 95, 4070 (1991). 236. M. Boudart, Supported Metals in Heterogeneous Catalysts; pp. 289-318 in Precious Metals Science and Technology; L. S. Benner, T. Suzuki, K. Meguro, and S. Tanaka, Eds.; International Precious Metals Institute, Allentown, PA, 1991. 237. R. J. Davis and M. Boudart, Hydrogenation of Alkenes on Supported PdAu Clusters; pp. 129-134 in Catalytic Science and Technology, Volume 1, Proceedings, TOCAT-1 (Tokyo, 1990); Kodansha, Ltd., Tokyo, 1991. 238. F. H. Ribeiro, R. A. Dalla Betta, M. Boudart, J. Baumgartner, and E. Iglesia, Reactions of Neopentane, Methylcyclohexane, and 3,3-Dimethylpentane on Tungsten Carbides. The Effect of Surface Oxygen on Reaction Pathways, J. Catal., 130, 86-105 (1991).

239. F. H. Ribeiro, M. Boudart, R. A. Dalla Betta, and E. Iglesia, Catalytic Reactions on n-Alkanes on β-W2C and WC: The Effect of Surface Oxygen on Reaction Pathways, J. Catal., 130, 498-513 (1991). 240. E. Iglesia and M. Boudart, Structure-Sensitivity and Ensemble Effects in Reactions of Strongly Adsorbed Intermediates. Catalytic Dehydrogenation and Dehydration of Formic Acid on Nickel, J. Phys. Chem., 95, 7011-7016 (1991). 241. E. Iglesia, J. E. Baumgartner, F. H. Ribeiro, and M. Boudart, Bifunctional Reactions of Alkanes on Tungsten Carbides Modified by Chemisorbed Oxygen, J. Catal., 131, 523-544 (1991). 242. F. H. Ribeiro, R. A. Dalla Betta, G. J. Guskey, and M. Boudart, Preparation and Surface Composition of Tungsten Carbide Powders with High Specific Surface Area, Chem. Mater., 3, 805-812 (1991). 243. Y. C. Kim and M. Boudart, Recombination of O, N and H Atoms on Silica: Kinetics and Mechanism, Langmuir, 7, 2999-3005 (1991). 244. M. Boudart, Submitted as a Letter to the Editor of Catalysis Letters, Catal. Lett., 13, 153-154 (1992). 245. F. J. Rivera-Latas, R. A. Dalla Betta, and M. Boudart, Fraction of Pt Surface Covered with Coke Following Hydrogenolysis of Hexane, AIChE J., 38 (5), 771-780 (1992). 246. M. Boudart and D. J. Sajkowski, Catalytic Hydrogenation of Cyclohexene: Liquid-Phase Reaction on Rhodium, Faraday Discuss., 92, 57-67 (1991). 247. E. Iglesia, F. H. Ribeiro, M. Boudart, and J. E. Baumgartner, Synthesis, Characterization, and Catalytic Properties of Clean and Oxygen-Modified Tungsten Carbides, Catal. Today, 15, 307-337 (1992). 248. D. A. Arthur, D. L. Meixner, M. Boudart, and S. M. George, Adsorption, Desorption, and Surface Diffusion Kinetics of NH3 on MgO(100), J. Chem. Phys., 95 (1), 8521-8531 (1991). 249. J. T. Wrobleski and M. Boudart, Preparation of Solid Catalysts: An Appraisal, Catal. Today, 15, 349-360 (1992). 250. E. Iglesia, F. H. Ribeiro, M. Boudart, and J. E. Baumgartner, Tungsten Carbides Modified by Chemisorbed Oxygen. A New Class of Bifunctional Catalysts, Catal. Today, 15, 455-458 (1992). 251. L. Kieken and M. Boudart, Rate of Oxidation of CO on Pd at Pressure between 10-1 and 102 mbar, Catal. Lett., 17, 1-10 (1993). 252. M. Boudart, R. Ryoo, G. P. Valenc¸ a, and R. Van Grieken, Chemisorption of H2 on Supported Pt Clusters Probed by 129Xe NMR, Catal. Lett., 17, 273-283 (1993). 253. J. S. Lee and M. Boudart, In Situ Carburization of Metallic Molybdenum during Catalytic Reactions of CarbonContaining Gases, Catal. Lett., 20, 97-106 (1993). 254. G. J. Guskey, M. Boudart, and A. Frennet, The Reaction between H2 and O2 over Tungsten Carbide Catalysts, Eur. Comm. [Rep] EUR, EUR 14039, 274-285 (1992). (Hydrogen Behavior of Mitigation Water-Cooled Nuclear Power Reactors (Engl. Transl.).) 255. R. J. Davis and M. Boudart, Structure of Supported PdAu Clusters Determined by X-ray Absorption Spectroscopy, J. Phys. Chem., 98 (21), 5471-5477 (1994). 256. M. Boudart and G. Dje´ga-Mariadassou, Kinetic Coupling in and Between Catalytic Cycles, Catal. Lett., 29, 7-13 (1994).

2046 J. Phys. Chem. B, Vol. 109, No. 6, 2005 257. M. Boudart, The Science of Catalysis by Precious Metals; pp 115-120 in Precious Metals 1994, Proceedings of the 18th International Precious Metals Conference, Vancouver, B.C., Canada, June 1994; J. G. Peacey, Ed.; International Precious Metals Institute, Allentown, PA, 1994. 258. M. Boudart, Fine Tuning Metal Clusters, Nature, 372, 320 (1994). 259. M. Boudart, Ammonia Synthesis: The Bellwether Reaction in Heterogeneous Catalysis, Top. Catal., 1, 405414 (1994). 260. M. Boudart, Thermodynamics and Kinetics for ZeroEmission Catalytic Devices, Ind. Eng. Chem. Res., 33 (12), 2900-2903 (1994). 261. M. Boudart and G. Djega-Mariadassou, Kinetic Coupling in and between Catalytic Cycles, Catal. Lett., 35 (1,2), 191 (1995). 262. M. Boudart, Turnover Rates in Heterogeneous Catalysis, Chem. ReV. (Washington, D. C.), 95 (3), 661-666 (1995). 263. G. A. Somorjai and M. Boudart, Surface Chemistry and Catalysis, J. Catal., 152 (2), 420-421 (1995). 264. G. Djega-Mariadassou, M. Boudart, G. Buglil, and C. Sayag, Modification of the Surface Composition of Molybdenum Oxynitride during Hydrocarbon Catalysis, Catal. Lett., 31 (4), 411-420 (1995). 265. H. S. Kim, C. Sayag, G. Bugli, G. Djega-Mariadassou, and M. Boudart, Preparation, Characterization and Catalytic Activity of Niobium Oxynitride and Oxycarbide in Hydrotreatment; pp 3-14 in Synthesis and Properties of AdVanced Catalytic Materials, Materials Research Society Symposium Proceedings, Vol. 368; Materials Research Society, Warrendale, PA, 1995. 266. M. Boudart, The Relevance in Practice of Data Obtained on Heterogeneous Model Catalysts, Z. Phys. Chem. (Munich), 197 (1/2), 21-35 (1996). 267. J. M. Thomas, W. J. Thomas, J. R. Anderson, and M. Boudart, Principles and Practice of Heterogeneous Catalysis, Angew. Chem., Int. Ed. Engl., 36 (23), 26892690 (1997). 268. V. Ponec, G. C. Bond, J. R. Anderson, and M. Boudart, Catalysis by Metals and Alloys, J. Catal., 165 (2), 285286 (1997). (Also in Stud. Surf. Sci. Catal., Volume 95.) 269. M. Boudart, Heterogeneous Molecular Catalysis: Oxymoron or Reality?, J. Mol. Catal. A: Chem., 120 (13), 271-280 (1997). 270. W. L. Holstein and M. Boudart, Application of the De Donder Relation to the Mechanism of Catalytic Reactions, J. Phys. Chem. B, 101 (48), 9991-9994 (1997). 271. J. A. J. Rodrigues, G. M. Cruz, G. Bugli, M. Boudart, and G. Djega-Mariadassou, Nitride and Carbide of

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Molybdenum and Tungsten as Substitutes of Iridium for the Catalysts Used for Space Communication, Catal. Lett., 45 (1,2), 1-3 (1997). L. Salin, C. Potvin, J.-F. Tempere, M. Boudart, G. DjegaMariadassou, and J.-M. Bart, Percentage of Metal Exposed on Commercial Three-Way Catalysts, Ind. Eng. Chem. Res., 37 (12), 4531-4535 (1998). M. Boudart, Kinetic Coupling in and between Catalytic Cycles, Catalysis, 14, 93-109 (1999). M. Boudart, Adsorption Assisted Desorption in Catalytic Cycles, J. Mol. Catal. A: Chem., 141 (1-3), 1-7 (1999). M. Boudart, On the Nature of Spilt-Over Hydrogen, J. Mol. Catal. A: Chem., 138 (2-3), 319-321 (1999). M. Boudart, A Catalyst is a Resilient Self-Assembly in Space and Time, NATO Sci. Ser., Ser. C, 560, 459465 (2000). M. Boudart, Model Catalysts: Reductionism for Understanding, Top. Catal., 13 (1,2), 147-149 (2000). M. Boudart, From the Century of the Rate Equation to the Century of the Rate Constants: A Revolution in Catalytic Kinetics and Assisted Catalyst Design, Catal. Lett., 65 (1-3), 1-3 (2000). M. Boudart and A. Varma, James J. Carberry, 1925-2000, Catal. ReV.sSci. Eng., 43 (1&2), v (2001). M. Boudart, Kinetic Generalities in Catalysis, Top. Catal., 14 (1-4), 181-185 (2001). A. Aramata, M. Boudart, Y. Moro-oka, K. Tamaru, K. Tanaka, A. Yamagishi, and Editors, Dedicated to Professor Juro Horiuti in Commemoration of His Centennial Birthday and His Contribution to Science, J. Mol. Catal. A: Chem., 199 (1-2) (2003). (242 pp.) M. Boudart, A Tribute to John Sinfelt, Ind. Eng. Chem. Res., 42 (8), 1537 (2003). G. Djega-Mariadassou and M. Boudart, Classical Kinetics of Catalytic Reactions, J. Catal., 216 (1-2), 89-97 (2003).

Patents of Michel Boudart 1. Y. Lam and M. Boudart, High Active Pd-Au Catalyst, U.S. Patent No. 4,136,062, Jan. 23, 1979. 2. L. Leclerq and M. Boudart, High Surface Area Molybdenum Oxycarbide Catalysts, U.S. Patent No. 4,271,041, June 2, 1981. 3. L. Volpe, S. Oyama, and M. Boudart, High Specific Surface Area Carbides and Nitrides, U.S. Patent No. 4,515,763, May 7, 1985. 4. L. Volpe, S. Oyama, and M. Boudart, Methods and Compositions Involving High Specific Surface Area Carbides and Nitrides, U.S. Patent No. 4,851,206, July 25, 1989.