Mapping Strategies in Chemical Oceanography - ACS Publications

Library of Congress Cataloging in Publication Data. Mapping strategies in chemical oceanography. (Advances in chemistry series, ISSN 0065-2393; 209). ...
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Downloaded by UNIV OF NEWCASTLE on March 30, 2017 | http://pubs.acs.org Publication Date: August 1, 1985 | doi: 10.1021/ba-1985-0209.fw001

Mapping Strategies in Chemical Oceanography

Zirino; Mapping Strategies in Chemical Oceanography Advances in Chemistry; American Chemical Society: Washington, DC, 1985.

Zirino; Mapping Strategies in Chemical Oceanography Advances in Chemistry; American Chemical Society: Washington, DC, 1985.

Downloaded by UNIV OF NEWCASTLE on March 30, 2017 | http://pubs.acs.org Publication Date: August 1, 1985 | doi: 10.1021/ba-1985-0209.fw001

ADVANCES

IN

CHEMISTRY

SERIES

Downloaded by UNIV OF NEWCASTLE on March 30, 2017 | http://pubs.acs.org Publication Date: August 1, 1985 | doi: 10.1021/ba-1985-0209.fw001

Mapping Strategies in Chemical Oceanography Alberto Zirino, EDITOR Naval Ocean Systems Center

Based on a symposium sponsored by the Division of Analytical Chemistry at the 185th Meeting of the American Chemical Society, Seattle, Washington, March 20-25, 1983

American Chemical Society, Washington, D.C. 1985 Zirino; Mapping Strategies in Chemical Oceanography Advances in Chemistry; American Chemical Society: Washington, DC, 1985.

209

Library of Congress Cataloging in Publication Data

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Mapping strategies in chemical oceanography. (Advances in chemistry series, ISSN 0065-2393; 209) "Papers originally presented at the Analytical Chemistry Division Symposium 'Analytics for Mesoscale and Macroscale Processes' "—Pref. Bibliography: p. Includes index. 1. Chemical oceanography—Congresses. I. Zirino, Alberto, 1941. II. American Chemical Society. Division of Analytical Chemistry. III. American Chemical Society. Meeting (185th: 1983: Seattle, Wash.) IV. Analytical Chemistry Division Symposium "Analytics for Mesoscale and Macroscale Processes" (1983: Seattle, Wash.) V. Series. QD1.A355 no. 209 540 s [551.46'01] ISBN 0-8412-0862-X

[GC110] 85-20265

Copyright © 1985 American Chemical Society All Rights Reserved. The appearance of the code at the bottom of the first page of each chapter in this volume indicates the copyright owner's consent that reprographic copies of the chapter may be made for personal or internal use or for the personal or internal use of specific clients. This consent is given on the condition, however, that the copier pay the stated per copy fee through the Copyright Clearance Center, Inc., 21 Congress Street, Salem, M A 01970, for copying beyond that permitted by Sections 107 or 108 of the U.S. Copyright Law. This consent does not extend to copying or transmission by any means— graphicor electronic—for any other purpose, such as for general distribution, for advertising or promotional purposes, for creating a new collective work, for resale, or for information storage and retrieval systems. The copying fee for each chapter is indicated in the code at the bottom of the first page of the chapter. The citation of trade names and/or names of manufacturers in this publication is not to be construed as an endorsement or as approval by ACS of the commercial products or services referenced herein; nor should the mere reference herein to any drawing, specification, chemical process, or other data be regarded as a license or as a conveyance of any right or permission, to the holder, reader, or any other person or corporation, to manufacture, reproduce, use, or sell any patented invention or copyrighted work that may in any way be related thereto. Registered names, trademarks, etc., used in this publication, even without specific indication thereof, are not to be considered unprotected by law. PRINTED IN THE UNITED STATES OF AMERICA

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Zirino; Mapping Strategies in Chemical Oceanography Washington, 20036 Advances in Chemistry; American ChemicalD.C. Society: Washington, DC, 1985.

Advances in Chemistry Series

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M . Joan Comstock, Series Editor Advisory Board Robert Baker U.S. Geological Survey M a r t i n L. G o r b a t y Exxon Research and Engineering Co.

R o b e r t Ory USDA, Southern Regional Research Center G e o f f r e y D. Parfitt Carnegie-Mellon University

R o l a n d F . Hirsch U.S. Department of Energy

J a m e s C. R a n d a l l Phillips Petroleum Company

H e r b e r t D. K a e s z University of California—Los Angeles

C h a r l e s N. Satterfield Massachusetts Institute of Technology

R u d o l p h J. M a r c u s Office of Naval Research

W . D. S c h u l t z Oak Ridge National Laboratory

V i n c e n t D. M c G i n n i s s Battelle Columbus Laboratories

C h a r l e s S. T u e s d a y General Motors Research Laboratory

D o n a l d E. M o r e l a n d USDA, Agricultural Research Service

D o u g l a s B . Walters National Institute of Environmental Health

W. H. Norton J. T. Baker Chemical Company

C . Grant Willson IBM Research Department

Zirino; Mapping Strategies in Chemical Oceanography Advances in Chemistry; American Chemical Society: Washington, DC, 1985.

FOREWORD Downloaded by UNIV OF NEWCASTLE on March 30, 2017 | http://pubs.acs.org Publication Date: August 1, 1985 | doi: 10.1021/ba-1985-0209.fw001

The

A D V A N C E S I N C H E M I S T R Y S E R I E S was founded in 1949

by

the American Chemical Society as an outlet for symposia and collections of data in special areas of topical interest that could not be accommodated in the Society's journals. It provides a medium for symposia that w o u l d otherwise be fragmented because their papers w o u l d be distributed among several journals or not published at all. Papers are reviewed critically according to A C S editorial standards and receive the careful attention and processing characteristic of A C S publications. Volumes in the A D V A N C E S I N C H E M I S T R Y S E R I E S maintain the

integrity of the symposia on which they are based; however, verbatim reproductions of previously published papers are not accepted. Papers may include reports of research as well as reviews, because symposia may embrace both types of presentation.

Zirino; Mapping Strategies in Chemical Oceanography Advances in Chemistry; American Chemical Society: Washington, DC, 1985.

ABOUT T H E EDITOR

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A L B E R T O Z I R I N O was first introduced to

"chemical" mapping in 1964 while working as a technician at the Scripps Institution of Oceanography (Food Chain Group) and simultaneously pursuing an M.S. degree in spectroscopy at San Diego State College. A t that time, bubble-segmented colorimetric analysis was being adapted to ocean mapping b y F. A . J. Armstrong and J. D . H . Strickland. Zirino became interested in the eleetrometric measurement of trace metals in seawater while completing a Ph.D. thesis on the measurement of zir^c in seawater b y anodic stripping voltammetry at the University of Washington. There he was able to carry out voltammetric determinations at sea on several major oceanic mapping expeditions led b y R. C . Dugdale, F. A . Richards, and M . L . Healy. In 1970, he joined the Naval Ocean Systems Center as a National Research Council Postdoctoral Fellow. H e became Head of the Center's Marine Environment Branch in 1979. Since 1978, he has been teaching Introductory Oceanography and Chemical Oceanography as an adjunct professor at San Diego State University. Zirino has presented numerous invited papers at national and international meetings on such diverse subjects as chemical speciation of trace metals in seawater, voltammetric techniques, real-time methods in chemical oceanography, and, recently, satellite chemical oceanography. In June 1984, he was a visiting professor at the Institute of Biophysics ( C . N . R . ) at the University of Pisa. H e has authored or coauthored over 25 journal articles and research papers, and he is a member of the American Chemical Society and the American Geophysical Union.

Zirino; Mapping Strategies in Chemical Oceanography Advances in Chemistry; American Chemical Society: Washington, DC, 1985.

Downloaded by UNIV OF NEWCASTLE on March 30, 2017 | http://pubs.acs.org Publication Date: August 1, 1985 | doi: 10.1021/ba-1985-0209.fw001

This book is dedicated to the memory of Prof. F. A. Richards (1917-1984), mentor, friend, and colleague, who clearly understood, loved, and encouraged interdisciplinary oceanic exploration.

Zirino; Mapping Strategies in Chemical Oceanography Advances in Chemistry; American Chemical Society: Washington, DC, 1985.