MARCH 15, 1992 VOLUME 64 NUMBER 6 The Audit Bureau
Analytical
®
CHEMISTRY
ANCHAM 64(6) 363A-410A/577-704 (1992) ISSN 0003-2700
Registered in U.S. Patent and Trademark Office; ©Copyright 1992 by the American Chemical Society EDITOR: ROYCE W. MURRAY ASSOCIATE EDITORS: Catherine C. Fenselau, Georges Guiochon, James W. Jorgenson, Robert A. Osteryoung, Edward S. Yeung Editorial Headquarters 1155 Sixteenth St., N.W. Washington, DC 20036 Phone: 202-872-4570 Telefax: 202-872-4574 Bitnet: rmh96@cas Internet:
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Assistant Editor: Felicia Wach
REPORT
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On the cover. Diabetes a n d gluc o s e s e n s o r s . Continuous blood glucose monitoring as an aid to diabetes therapy has been an elusive goal despite 10 years of ext e n s i v e r e s e a r c h to d e v e l o p biosensors. Gérard Reach of Hôtel-Dieu Hospital and George S. Wilson of the University of Kansas describe the nature of the analytical problem from chemical and clinical perspectives and explore possible solutions
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FOCUS
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Mass s p e c t r o m e t e r - e l e c t r o n spectrometer: e x c h a n g e intera c t i o n . Both MS and electron spectrometry are based on ionization processes and/or interactions of charged particles with matter. Victor L. Talrose of the Institute of Energy Problems of Chemical Physics and Gennadij V. Karachevtsev and Igor A. Kaltashov of the Moscow Institute of Physics and Technology discuss the synergy between mass and electron spectrometers and the interrelationship of physical and analytical chemistry
UPCOMING RESEARCH
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NEWS
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Nominations sought for the 1993 D i v i s i o n of Analytical Chemistry Awards. · Nominations requested for the 1992 Statistics in Chemistry Award
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MEETINGS
The 203rd ACS spring national m e e t i n g will be held April 5 - 1 0 in San Francisco. The technical program will feature the presentation of awards to Larry R. Faulkner, Joseph F.K. Huber, Burnaby Munson, and Milos V. Novotny. · Conferences. · Short courses and workshops. · Call for papers
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BOOKS
Volumes on biosensors with fiber optics and molten salt techniques are reviewed
NEW PRODUCTS & MANUFACTURERS' LITERATURE
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ANALYTICAL CHEMISTRY, VOL. 64, NO. 6, MARCH 15, 1992 · 367 A
Analytical CHEMISTRY
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Articles In Vivo Calibration of Microdialysis Probes for Exogenous Compounds Stanley Menacherry, Walt Hubert, and Joseph B. Justice, Jr. * Separation and Detection of Aliphatic Anionic Surfactants Using a Weak Anion Exchange Column with Indirect Photometric and Indirect Conductivity Detection ShahbazA. Maki, Julie Wangsa, and Neil D. Danielson* Interpretation of Retention Behaviors of Transition-Metal Cations in Micellar Chromatography Using an Ion-Exchange Model Tetsuo Okada Surface Studies of the Copper/Silver Sulfide Based Ion-Selective Electrode Membrane Roland De Marco, Robert W. Cattrall *,John Liesegang, Graeme L. Nyberg, and Ian C. Hamilton Generalized Rank Annihilation Method Using Similarity Transformations ShousongLiJ. Craig Hamilton, and Paul J. Gemperline*
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Separation of Isotopes of Sodium during Anion Radical Production Gerald R. Stevenson *, Troy D. Halvorsen, Kerry A. Reidy, and James T. Ciszewski
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The Predominant Role of Swelling-Induced Modulus Changes of the Sorbent Phase in Determining the Responses of Polymer-Coated Surface Acoustic Wave Vapor Sensors Jay W. Grate *, Mark Klusty, R. Andrew McGill, Michael H. Abraham, Gary Whiting, andjenik Andonian-Haftvan
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Model Analysis of Enzyme Monolayer- and Bilayer-Modified Electrodes: The Steady-State Response Tetsu Tatsuma * and Tadashi Watanabe *
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Model Analysis of Enzyme Monolayer- and Bilayer-Modified Electrodes: The Transient Response Tetsu Tatsuma, Tadashi Watanabe *, and Yusuke Okawa
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Overoxidized Polypyrrole Films: A Model for the Design of Permselective Electrodes Allan Witkowski and Anna Brajter-Toth *
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Potentiometric and Voltammetric Investigations of H 2 /H + Catalysis by Periplasmic Hydrogenase from Desulfovibrio gigas Immobilized at the Electrode Surface in an Amphiphilic Bilayer Assembly Thierry Parpaleixjean Marc Laval, Marcin Majda *, and Christian Bourdillon *
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A Hole Can Serve as a Microelectrode Keith B. Oldham
Corresponding author
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continued on p. 371 A
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ANALYTICAL CHEMISTRY, VOL. 64, NO. 6, MARCH 15, 1992 · 369 A
Analytical CHEMISTRY
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Optoelectrochemical Thin-Film Chlorine Sensor Employing Evanescent Fields on Planar Optical Waveguides Christophe Piraud, Eustace Mwarania, George Wylangowski, James Wilkinson, Kieran O'Dwyer, and David J. Schiffrin * Expert System Based on Principal Components Analysis for the Identification of Molecular Structures from Vapor-Phase Infrared Spectra. 2. Identification of Carbonyl-Containing Functionalities Erik J. Hasenoehrl, Jonathan H. Perkins, and Peter R. Griffiths* Identification of Chemical Constituents by Multivariate Near-Infrared Spectral Imaging Paul Robert*, Dominique Bertrand, Marie Françoise Devaux, and Alain Sire Prereduction of Arsenic(V) to Arsenic(III), Enhancement of the Signal, and Reduction of Interferences by L-Cysteine in the Determination of Arsenic by Hydride Generation Hengwu Chen, Ian D. Brindle *, andXiao-chun Le Sensitivities of Inductively Coupled Plasma Optical Emission Spectrometry for Dry and Wet Aerosols Alfred P. Weber, RolfKeil, Leo Tobler, and Urs Baltensperger* Spray Extraction of Volatile Organic Compounds from Aqueous Systems into the Gas Phase for Gas Chromatography/Mass Spectrometry Gokhan Baykut* and Annette Voigt Microscopic Organic Analysis Using Two-Step Laser Mass Spectrometry: Application to Meteoritic Acid Residues Laurie J. Kovalenko, Claude R. Maechling, Simon J. Clemett, Jean-Michel Philippoz, Richard N. Zare *, and Conel M. O'D. Alexander Quantitative Determination of Catecholamines in Individual Bovine Adrenomedullary Cells by Reversed-Phase Microcolumn Liquid Chromatography with Electrochemical Detection Bruce R. Cooper, Jeffrey A. Jankowski, David J. Leszczyszyn, R. Mark Wightman, and James W. Jorgenson *
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Correspondence Heparin-Responsive Electrochemical Sensor: A Preliminary Study Shu-Ching Ma, Victor G Yang*, and Mark E. Meyerhoff
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Trace Analysis in Solution Using Zeolite-Modified Electrodes M. D. Baker* and Chandana Senaratne
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Technical Notes Molecular-Optical Viscometer Based on Fluorescence Depolarization Angela M. Williams and Dor Ben-Amotz *
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Author Index
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ANALYTICAL CHEMISTRY, VOL. 64, NO. 6, MARCH 15, 1992 · 371 A
