Marston Taylor Bogert - Industrial & Engineering Chemistry (ACS

Marston Taylor Bogert. Harry L. Fisher. Ind. Eng. Chem. , 1933, 25 (5), pp 591–592. DOI: 10.1021/ie50281a032. Publication Date: May 1933. ACS Legacy...
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Mars ton Taylor. Noger t OX TAYLOR HOClmT sixty-five y e w s old’! I t cannot he! Buroly Fattier Time hasmnde :imistake, bocause, il ever a, msn found the secret of eternal youth, that man is Marston Taylor Iiogerl. Me t m h e n a veritable picture of g a d lrealth far so many yenrs, thrLI it is difficult, to thinkaf lrim in any other way. And yet RS :L lad, like Tlirodore Rocmevolt, he had a weak constitnlion. Also like tho g i e l t advocate of the “strenuous life,” u+mn tic admired greatly, he earls determined to build himself a stronp 1,enlthy body. He Iiterdly collected good health. In fact, he has collected all sorts of bhings. ‘IVhile ii young mim he made :t marvelous collection of birds’ eggs. Ife has rrlso eullerted hooks and joomnls, st,ockvnnd bonds, &(.re8 of land (around his summer home), degrees and titles, presidencies, chairmanships, editorships, and Inst, but by no nmms least, friends. 1Ie has done no hdfwuny job of these collections. The birds’ c g ~ q were put rrway long ago, but most of the others he keeps in l,lie open, guarding and constantly adding to them. Professor Bogort comes from 8 wcrdthy family of Flushiw, Long tslaral, bot unlike the proverbid rich man’s son he took full atlvarilage of si1 that aes,lt,li could bring him in education, travel, m d s tios. Ile nas e d u c n t e d in and lrns u.Iwnys l i v e d iii or near New Y o r k , y e t he is not p r o v i n c i a l . He spent eight year8 ut Columbia University, lour for his A.B. degree and four for hi8Ph.B. Tire Ph.U. degree in his ewe is froqucntdy tnkon 5s a mistake for P h B . As a matter of f w t . lit: never did any graduate work such 8 s he himself has directed for so many years. lIis only doctor’s degror, is t,he honorary 1,1..1). conferred upon him by Clark University in 1909. Ife used to joke about an “honorary degree,” a-Bich was given him at L: gzlhering of chemists about 1910 when several othcr prominent chemists d s o were given similar “degrees.” His aaard of Complicated Qiieerxsolones.” He was 1905, and recent,ly medalist of Ch;%rlesUnivcmity, I’rrigue, and of the Comensky University, Bratislam. He is also Commander of rhe Ordor of the White Lion of Ceeehos1ovaki:L. His toitching and administrative work hnve gone on simultnneously siiice the enrly days o l his career. Ile enjoys lecturing, heing eueful to explain every detail. H e has great :idmiration for tlie honuty a i the classification of organic compounds antl of tho methods used in building up the subject of his choice. lie likes to use his knowledge OS Greek to explain :md fix the meaning of a term in one.’smind and thus give an aasoehted fact l o help in remembering it,. 13s blnckbosrd work is writt,en in that clciir well-rounded script which is always perfectly defiriitc- fine o u ward evidence of i,he clarity and definiteness of Iris own thinking. In the classroom he wears a velvet maroon or blue lounging coat,. It should probably he errlled a smoking juckrt, Init IIC nevcr smokes. 4 t his desk this coat is discsrdrd, : ~ n dhc work. in his shirt slceves. He is particularly fond of wrniriiir rwrk informd quizzes which i n Organic structural formul liow he dors make B sdutlrrit mentally “stnnd on his head” in order to see these relationships and underit:md thPm! This dora not m i m that he thus triw to “get” a student. On the contrary,

his cliirs xurk is nlways carried on in a kiiidly spirit and is often enlivened with dry hits of humor. 11;s work with graduate students is different lronr the European type. Ile helicves in making a man do his own urork. This a t times may be somewhat discouraging, but, it makes far independencr of thought and action. In the fine rel:Ltionship of profmmr mid rpsemrrh st,udenI,, R man has a g(iod opportunit,y to learn of rile great, ferti1il.y of Professor Bogert’s mind. It is alwtiys act,ive a,nd ready with new ideas, in spite of his attention t o the details of many bime-consuming duties which often prcvmt :is frequent 1nbor:itor.y cont,iicts xs might seem desirhle. The s u b j e c t s of h i s r e s e s r c h e s itre chiefly s y n t h e t , i c a n d lie mostly in the heterocyclic E i e l d s of q u i r3 a s oli nos and thiazoles. Thirty-eight papers hnve been prdilished on quinauolines m d eighteen on thiazoles. In addition, Ire hiis done much work on the dcrivetives 01 such typical :romatic eompountlq sw the :Lminohenzonit r i l e s , gallic acid, piperonylic a(:id, pyrogdlol, diaminophenyl oxide, t h i o p h e n e , terephthelic acid, phenacetin, cinnamic ddehycle, phenyl et!iyl alcohol, acriflavine, unsaturated ketonic acids, etc. This work has involved studies in dyestuffu, phbrrnaceotieals, and terpenes, and especially the relationship bctween odor and rnoleculnr structurc. This lrrtt,er work on perfumes h a taken much of his time in recent years and has yielded interesting and important results. The number of eomuounds ssntheskml under his direotion is logion. Ile bas never believed in hiding his profesmrial light under n univeisit,y bushel but, nlwiiys kcopa himseli in the open where hc ooiated aitli mcii outside thc university Imlk and where others em know him. It has never been no earn money outside in order t o kecp “carping rare” away; ins t m d , fie hnii given of Iris time freely snd lavishly for the good of others i n mzuy fields. lle is a prodigious worker, ten to four1,een hours n rlny being his regdnr allotment, arid he has a rcrnerkablo memory. With such a backgroimd and EL desire t o work with others nnd serve them, it is no wonder that his time nnd energy are called upon lor over-videning opportunities. This is especially true of ammittees of all kinds. IIe never accepts 5 place on 1~ committee, howrvor, with the idea of his being only B figure head. For him it is another opportunity ior work. l’nrfessor Bogert’s public services m e many. I-Te is an excellent lecturer, a11 ininritalh toastmaster, and a marvelous chairm a n of i i irrceting o i conference. On the lecture platform he talks for tire usual clxss “hour” of fifty minutes, generally wi!kiout using a notc End never faltering for t: word or phrase. Ile senses what h i s audience likes and embellishes his p i n t s with \?ell-chosen humorous stories. Those who m:re so fortuntito as to be present at the dinner of tho delPg:;itesto the meeting of the International Union of Pure :md Applied Chemistry in Wnsllrington in 19% will long remomber the wonderful manner in which lie greeted overyone, how be graciously e;tlloil q m n tlie rpe:rher from each cormfry, :ind how e:isily he addrewsd them in Frencl m, or Ihglish, RS the ion demanded. Oood to;wtm re rare antl Professor Rogert, is one of the rarest. As chiirmirn of a meeting he slrows his eourt~ge,sense of proportion, unfniliiq gmd Irutnor, thooghtfulners, and h c t . These

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qualities were especially required of him a t the time he presided a t the organic sectional meetings during the sessions of the Eighth International Congress of Applied Chemistry in New York in 1912, and particularly when W. H. Perkin, Jr., gave his lecture on “Synthetic Rubber.” At the close, a member of the audience climbed on the platform and volubly tried to pick a quarrel with the lecturer about who were the first to synthesize or German chemists-but Professor Bogert rubber-English handled the situation so admirably that he prevented any trouble. Many will recall other meetings when nothing more serious happened than his wearing a mauve tie with a full dress suit. This he always does when, as senior past president of the English Society of Chemical Industry, he annually presents the Perkin medal. The mauve tie, the color of the first synthetic dye, was worn by all those present a t the dinner in 1907 in Kew York, when Sir William H. Perkin, Sr., was awarded the first Perkin medal for his pioneer work on synthetic dyes. Professor Bogert joined the AMERICAN CHEMICAL SOCIETY in 1894 as soon as he completed his collegiate work, and he always urges his students in the first lecture of the school year to do the same. He has continued to be a loyal and devoted member of our organization, serving it in many official capacities. He was president in 1907 and 1908. He it was who conceived and inaugurated the divisional system-the signal contribution which has kept the SOCIETY together and stimulated its growth. The record of Professor Bogert’s accomplishments takes many inches of space in “Who’s Who,” and only a few more will be mentioned here. Almost a year before the United States entered the World War he was called to Washington as a member of the National Academy of Sciences to organize the Chemistry Committee of the National Research Council. He was the first chairman of this committee and the thoroughness with which he did that work is well known. He remained in Fashington during the war and was active in several departments, finally becoming a colonel in the Chemical Warfare Service. In 1908 Theodore Roosevelt invited him to be a member of the White House Conference on Conservation of Natural Resources. He was one of the incorporators and a president of the Chemists’ Club. In

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1927-8, he was the first visiting Carnegie professor of international relations to Czechoslovakia. He has a kindly and friendly disposition. He enjoys a good joke and even more thoroughly enjoys telling one. He is also a great punster. I recall that in his former office he had a box which was used for reaching the high shelves in the file behind his desk, and many years ago when he asked me to come in and talk over the matter of my becoming laboratory assistant the next year, he greeted me with, “Have a box seat.” In a gathering he is always a center of attraction because his witty conversat,ion, his great memory of faces and events, and his engaging smile draw people to him. He is punctual and never wastes time. He is one of the most even-tempered men I have known. Once in the classroom he was preparing to demonstrate the instability of iodoxybenzene when, as he was opening the bottle, it exploded and flying glass wounded him severely. Though in great physical pain and in mental anguish from the thought of the possible loss of his sight, he managed to get to the telephone and talk to his wife about the accident in order that she would not be unduly alarmed. He and Mrs. Bogert are gracious hosts in sharing their happy home life with their friends in New York and a t “Charlana!ise Camp,” their summer home a t Belgrade Lakes, Maine. The name “Charlanalise” is characteristically made up from the first names of his wife and two daughters. You can imagine his smiling as he listens to people trying to place the name as a French word. There during the summer he fishes, tramps, and works. Professor and Mrs. Bogert are wonderful guests also, as my wife and I know. Well do we remember their coming to dinner in our humble S e w York apartment when I was a struggling young instructor. The very walls seemed to recede, and we felt not only honored but really blessed. He is a staunch member of the Reformed Church in America. His charities are many, and no one but himself will ever know their extent. To anyone who knows him, there is no doubt as tu his sincerity of purpose. Underneath the external dignity there is a kind, friendly, and generous nature.

HARRY L. FISHER

CORRESPONDENCE Relationship between Mole Fractions and Absolute Viscosities of Blended Lubricating Oils SIR: The interesting paper by Epperson and Dunlap on the above subject [IND. ENG. CHEM.,24, 1369 (1932)l suggested the use of their data for the examination of other methods for the calculation of the Saybolt viscosities of blended lubricating oils. Preliminary calculations, however, showed that the authors had made an unfortunate error in their calculations of the absolute viscosities corresponding to their experimentally determined Saybolt efflux times a t 210’ F., for, assuming that the Herschel equation

1.8 ; 0.0022t - =

t

may apply t o their Saybolt Universal viscosimeter a t 210” F.; even then it was misused, inasmuch as the authors substituted for D the specific gravities a t 60’ F. instead of those a t 210’ F., the nominal temperature of their tests. This appears to be a valid assertion; otherwise, for instance, Pennsylvania oil 4 (Saybolt

Universal at 210” F. = 170 seconds) would have a specific gravity of 0.948 a t 60” F. if the reported figure of 0.8969 in their Table I refers to a temperature of 210’ F. All the values of TI and n1’3 in Tables I and I1 were recalculated using (1) Herschel’s equation and (2) the recently published A. S.T. M. equations for the Saybolt Universal viscosimeter, but when these were plotted graphically they did not conform any better to the cube root rule of Kendall and Monroe than did those given in Tables I and I1 by the authors. Another blending rule [Larson, Oil Gas J., 30, 37 (h’ov. 24, 1932)] was tested by plotting the Saybolt Universal seconds a t 210’ F. of the thirty-four binary blends (calculated from Table 11) on an A. S. T. M. viscosity-temperature chart (modified for blending). Here again the linear law was not rigidly followed. In a few cases the curves were reasonably straight lines, but others, which showed appreciable divergence from the straight line when plotted on the cube root principle, showed almost equal arching by this second method. This applies also to other data available in the literature. For instance, the figures given by Calderwood [Oil Gas J., 30, 98 (March 31, 1932)] for his blends a t 210” F. lie on a straight line \Then plotted on a modified A. S. T. M. chart as also do certain of