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Material Exhibiting Efficient CO Adsorption at Room Temperature for Concentrations Lower Than 1000 ppm: Elucidation of the State of Barium-Ion Exchanged in an MFI-Type Zeolite Atsushi Itadani, Akira Oda, Hiroe Torigoe, Takahiro Ohkubo, Mineo Sato, Hisayoshi Kobayashi, and Yasushige Kuroda ACS Appl. Mater. Interfaces, Just Accepted Manuscript • DOI: 10.1021/acsami.6b00909 • Publication Date (Web): 18 Mar 2016 Downloaded from http://pubs.acs.org on March 19, 2016
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ACS Applied Materials & Interfaces
Material Exhibiting Efficient CO2 Adsorption at Room Temperature for Concentrations Lower Than 1000 ppm: Elucidation of the State of Barium-Ion Exchanged in an MFI-Type Zeolite Atsushi Itadani,†,‡ Akira Oda,†,§ Hiroe Torigoe,† Takahiro Ohkubo,† Mineo Sato,|| Hisayoshi Kobayashi,⊥ and Yasushige Kuroda*,†
†
Department of Chemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushima, Kita-ku, Okayama 700-8530, Japan
‡
Graduate School of Science and Technology, Niigata University, 8050 Ikarashi, 2-no-cho, Nishi-ku, Niigata 950-2181, Japan
§
Precursory Research for Embryonic Science and Technology (PREST), Japan Science and Technology Agency (JST), 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan
||
Department of Chemistry and Chemical Engineering, Niigata University, 8050 Ikarashi, 2-no-cho, Nishi-ku, Niigata 950-2181, Japan
⊥
Department of Chemistry and Materials Technology, Kyoto Institute of Technology, Matsugasaki,
Sakyo-ku, Kyoto 606-8585, Japan
ABSTRACT: Carbon dioxide (CO2) gas is well known as a greenhouse gas that leads to global warming. Many efforts have been made to capture CO2 from coal-fired power plants, as well as to reduce the amounts of excess CO2 in the atmosphere to around 400 ppm. However, this is not a simple task, particularly in the lower pressure region than 1000 ppm. This is because the CO2 molecule is chemically stable and has a relatively low reactivity. In the present study, the CO2 adsorption at room temperature on MFI-type zeolites exchanged with alkaline-earth-metal ions, with focus on CO2 concentrations
