Mechanistic and Exploratory Organic Photochemistry - American

H. E. Zimmerman: The MetarOrtho Effect in Organic. Photochemistry; Mechanistic and Exploratory Organic Photo- chemistry. Page 5619. In Table 3, kdtot ...
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Additions and Corrections

J. Phys. Chem. A, Vol. 102, No. 39, 1998 7725

ADDITIONS AND CORRECTIONS

1998, Volume 102A H. E. Zimmerman: The Meta-Ortho Effect in Organic Photochemistry; Mechanistic and Exploratory Organic Photochemistry Page 5619. In Table 3, kdtot for anisole should be 1.25 × 108 s-1 rather than 0.13 × 108 s-1. Page 5619. In the second column, the third new paragraph, 0.31 kcal/mol should be 0.031 kcal/mol and 16.8 kcal/mol should be 1.68 kcal/mol. The corresponding values in Table 1 are correct. The point here is that the ground state and the first excited state surfaces of the radical approach one another only at a point 164 kcal/mol above the ground state minimum.

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