1348
Organometallics 2003, 22, 1348
Additions and Corrections 2003, Volume 22 Claudia Trage, Detlef Schro1 der, and Helmut Schwarz*: Fe+-Mediated Interconversion of n- and i-C3H7OH Preceding Their Gas-Phase Dehydrations: Experimental and Computational Evidence for Memory Effects and Inherent Asymmetry of Constitutionally Equivalent Methyl Groups. Pages 699, 700, and 706. Due to an error made by editorial staff during galley correction, eqs 2, 4, and 9 are incorrect. They should appear as follows:
H2O
fs )
1 6
(
7
HDO fs
H2O
fs )
HDO
xi ∑ i)2
6-
1 2
1
)
+ (1 - fs)
7
7 1
(
7
xi ∑ i)1
7-
7
)
KIE (2)
xi ∑xi + (1 - fs) 7 ∑ i)1
6 i)2
(
1
2-
fs KIEs
4
∑ i)3 ×
)
xi + (1 - fs)
1
4
1 7
1 - fs
∑xi + KIE 2 i)3
(
7
7-
×
x
1
xi ∑ i)1
)
7
∑ xi 7 i)1
(4)
H 2O
) D2O 1 4 4 1 f f + (1 - fs) + (1 - fprim) fs + (1 - fs) 2 prim s 4 + 3cas 2 7 1 - fs fprim 2 × × 2KIEins KIEx 4 + 3cas
[
]
[
]
(9) OM030094W 10.1021/om030094w Published on Web 02/21/2003
