Mercury Reduction and Cell-Surface Adsorption by Geobacter

Sep 10, 2013 - *E-mail: [email protected]; phone: (865)-574-7286; fax: (865)-576-8543. ... Depending on the Hg to cell ratio, maximum Hg(II) reduction was...
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Mercury Reduction and Cell-Surface Adsorption by Geobacter sulf urreducens PCA Haiyan Hu,†,‡ Hui Lin,‡ Wang Zheng,‡ Balaji Rao,‡ Xinbin Feng,§ Liyuan Liang,‡ Dwayne A. Elias,⊥ and Baohua Gu*,‡ †

State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, Guangdong, 510640, China ‡ Environmental Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37830, United States § State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, Guizhou 550002, China ⊥ Biosciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, United States S Supporting Information *

ABSTRACT: Both reduction and surface adsorption of mercuric mercury [Hg(II)] are found to occur simultaneously on G. sulf urreducens PCA cells under dark, anaerobic conditions. Reduction of Hg(II) to elemental Hg(0) initially follows a pseudo-first order kinetics with a half-life of