METAL-AMISE COMPLEXES IY IOY EXCHANGE. PI

Jail,, 1962. 2-AMIXOETHAKOL AND ETHYLENEDI-4MINE COMPLEXES. 75. TABLE IV. 0.8 N SULFURIC ACID. CONPARISOX. OF EXPERIMENTAL AXD ...
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Jail,, 1962

75

2-AMIXOETHAKOL AND ETHYLENEDI-4MINE COMPLEXES

TABLEIV CONPARISOX OF EXPERIMENTAL AXD CALCULATED G( &Os) AKD G(&) FOR PVI43ED ELECTRON IRRADIATIONS I N PTATER AND 0.8 N SULFURICACID g(H)

2.95

3.16 3.16 3.05

2.64 2.64 2.91

3.05 3.05

a

g(0H)

3.66

2.91 2.91

g(Hn)

0.45 a45 .39 .39 .41 .41 .41 .41 .41 .41 .39

~(HZOE)

bib

0.80alb .80 .652a -65 .48@ .48 .48

6 6 6 6 6

.48 .48 .48

.65

0.0,

0 6 0 6 6

h b

ksb

6 3 6 3 6 6 6 6 6 6 6

.41 .48 6 6 G(Hz)oalod. = G(H~Oz)oalod. k's in units of 1. mole-' sec.-l X

Solving t,hese six equations for G(H20a)on t'he analog computer gives a value of 1.70 and 1.58 for the conditions detailed in Table IV. I n this calculation we arbitrarily assume kg = kg = kIo and that lcll