Page 1 of 40
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Energy & Fuels
July 23rd, 2015 Submitted to Energy & Fuel
Method for Determining the Effectiveness of Asphaltene Antifoulants at High Temperature. Application to Residue Hydroprocessing and Comparison with Thermal Fouling Test
Cesar Ovalles*, Estrella Rogel, Harris Morazan, and Michael E. Moir Chevron Energy Technology Co. 100 Chevron Way, Richmond, CA 94802. and Ghazi Dickakian Fouling and Coking Technology, Inc. 1911 Pleasant Creek Dr., Kingwood, TX 77345
*
To whom correspondence should be addressed. Telephone: (510)-242-2991. E-mail:
[email protected] ACS Paragon Plus Environment
1
Energy & Fuels
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Page 2 of 40
Abstract Using a new on-column filtration technique, the effectiveness of asphaltene antifoulants was determined by measuring the percentage of reduction of asphaltenes at process and near process conditions (up to 200°C such as heat exchangers). This methodology uses conventional HighPressure Liquid Chromatography apparatus (HPLC), is fast (