Molecular mechanism of methane to methanol conversion in

[TPA'FeIV]-O2-[TPA'FeIII] Molecular mechanism of methane to methanol conversion in soluble ... mechanism of methane to methanol conversion ...
3 downloads 19 Views 160KB Size
Molecular mechanism of methane to methanol conversion in soluble  methane monooxygenase Serena DeBeer, Department of Chemistry and Chemical Biology, Cornell University Our goal is to use XES to obtain insight into the  mechanism of methane to methanol conversion  by methane monooxygenase (MMO).

[TPA’FeIV]-O2-[TPA’FeIII]

Preliminary model studies of  binuclear iron complexes show  that  XES provides a direct  probe of the Oxygen 2s‐based  molecular orbitals, providing a  direct probe of Fe‐O2 intermediates.