Molybdate- and Tungstate-Catalyzed Fixation of Nitrogen - Journal of

Molybdate- and Tungstate-Catalyzed Fixation of Nitrogen. G. P. Haight, and Ronald. Scott. J. Am. Chem. Soc. , 1964, 86 (4), pp 743–744. DOI: 10.1021...
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COMMUNICATIONS TO THE EDITOR

Feb. 20, 1964

TABLEI

0

H

JdP

Ia, R = O b, R=O-CHa

I1 0

I

0-CHI

IV

Ib

+ 2e

-

-0

-0

-

743

"4'

Reducing agent

Pt cathode Porous graphite cathode (PGC) PGC

Medium

3 MHCl 3 MHCl

formed, moles/l.

-10-4b 10-'io

-3*

Phosphate buffer, PH 7 Phosphate buffer,