More Electricity from Heat - C&EN Global Enterprise (ACS Publications)

The best the Los Alamos team has done to date, however, is 5%. ▻ Cesium Used. The plasma is generated when heat from the heat source ionizes cesium ...
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static tandem, except for two ISO de­ gree magnets. These magnets are to bend the final beam, bringing it back to the negative ion source region. Here, it is accelerated u p to the high voltage terminal of the first seetion. In this setup, the test area winds u p in the first high voltage terminal area. But this is not so simple as it sounds, experts point out. While rigging up a target inside the high voltage terminal is by no means impossible, it t*ertainl\ is a w k w a r d and requires some pains­

taking design work. Van tie Craaff says. • Not Far Off· Most conference members shared Van d e Craalf's confi­ dence that three-stage tandems a r e a nuclear research tool of the not-toodistant future. But m u m \ oiced skep­ ticism about the feasibility of t h e four stage setup. It is sound in principle. the> concur. But is it practical in light of the delicate job necessar\ to line up the magnets and target accurate!) ? Is this extra energy output needed at present?

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M o r e Electricity f r o m H e a t Los A l a m o s scientists d e v e l o p p l a s m a t h e r m o ­ c o u p l e ; t h e o r e t i c a l c o n v e r s i o n efficiency is o v e r 3 Q % ./Y c.HOLP of fixe scientists at Los Alamos National Laboratory. Los Alamos, N. M., have come u p with a new wrinkle in direct conversion of heat to electricity (C&KX, \ o \ . 3 , page 19). T h e device, called a plasma thermocouple, bears some resemblance to General Electrics thermionic con­ verter ( C & E X , Dec. 2, 1957, page 22) but has some important differences. T h e plasma thermocouple replaces the standard metal-metal junction of a thermocouple with a metal-plasma junc­ tion. It is theoretically capable of con­ verting heat to electricity with an effi­

ciency of 30'< or better, according to calculations by two Los Alamos con­ sultants. The best the Los Alamos team has done to date, however, is 5 ' ? . • Cesium Used. T h e plasma is gen­ erated when heat from the heat source ionizes cesium \ apor in a cell at a pres­ sure of from 0 . 1 - to 2-mm. mercury. Cesium is used because it vaporizes at a low t e m p e r a t u r e ( 6 7 0 ° C.) and, more important, because it has the lowest ionization potential (3.88 volts) of any element. But there are other possibili­ ties—rubidium, potassium, sodium, and lithium, for example.

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This schematic shows a plasma t h e r m o c o u p l e capable of converting h e a t t o electricity with a theoretical efficiency" of 3 0 % . T h e plasma thermocouple uses one metal plus a gas instead of t w o metals used in n o r m a l thermocouples

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New Help for Lubes Additives m a k e silicone l u b ­ ricants more effective a t high temperatures

• By 1907, Foremost's El Dorado Division was already a prize supplier of coconut oil and its by-products to American industry. El Dorado is still foremost in the purity and uniformity of its products.

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In the prototype, the electrode iii the hot end of the plasma is tanliclum. al­ though the researcher!» are investigating other materials, ('tipper and t-utitulum both have worked well in the cold e n d . Typical temperature of the pl-asma at the licit end is 2600 C ; at the cold e n d . 300 C. Resulting potential i s about «me millivolt per degree of tempera­ ture difference between the liot a n d cold ends; this means that t> pical vnltages that Los Alamos obtained are about 2 volts. An important advantage ol the plasma thermocouple over a vacuum cell (such as the thermionic converter » or a semiconducter thermocouple is the low impedance ol the plasma. .-Kndw ith its device, the Los Alamos group has been able to generate electricity con­ tinuously when it has put in L\ steady amount of heat. The research team, headed l>yC. M. Grover, has not yet tried to reach effi­ ciencies even approaching tlu>se theo­ retically possible», but it is continuing its studies. (anient tests are aimed at developing a plasma thermopile- that is, a unit which will convert the heat generated by fission directly to elcctricitv.

A NEW approach to develop ment of antioxidants for high temperature luhrieants has turned up a group ol con­ densed four- and five-ring aromatic compounds that hold viscosity increase in fluid silicone lubricants to only a moderate amount at tempera, tines as high as 550 F. How ever, Stanford Research Institute, which did the work, found no antioxidants that were effec­ tive on mineral oil. silane fluid, or syn­ thetic ester lubricants. Eilectivencss of the antioxidants was measured by reduction in viscosity increase com­ pared with a blank. Using General Electric's F-5C silicone fluid, condensed ring aromatic com­ pounds held the viscosity increase to only a moderate amount during; the test period. In blank experiments without an additive, the fluid was completely