Naming Hydrocarbons - C&EN Global Enterprise (ACS Publications)

Nov 6, 2010 - Naming Hydrocarbons. Draft on hydrocarbon nomenclature approved by ACS division. Chem. Eng. News , 1957, 35 (8), p 72...
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Naming Hydrocarbons Draft on hydrocarbon no­ menclature approved by ACS division

alkylarenesulfonates (C&EN, Oct. 2 7 , 1952, p a g e 4513.) The matter of hydrocarbon nomen­ clature has been under consideration b y die committee for some years. Cur­ rently, there is some divergence of u s ­ age of terms relating to groups or classes of hydrocarbons.

χ HE NOMENCLATURE COMMITE of

the ACS Division of Petroleum Chem­ istry has unanimously approved a draft statement o n the nomenclature of hy­ drocarbon classes. T h e statement de­ fines the classes a s :

• Hydrocarbons—Compounds con­ taining only hydrogen and carbon. • Saturated hydrocarbons—Those hy­ drocarbons whose carbon atoms are joined by single bonds only, a n d in which the unshared carbon valences are fully saturated with hydrogen. • Unsaturated hydrocarbons—Hydro­ carbons in which two or more carbon atoms are joined by bonds other than single bonds. • Paraffinic hydrocarbons (alkanes, paraffins)—Saturated open chain hydro­ carbons with the type formula, CnH&ita. • Naphthenic hydrocarbons (naphthenes, cycloalkanes, cycloparaffins)Saturated hydrocarbons wriich contain at least one ring. • Olefinic hydrocarbons (olefins, alkenes )—Unsaturated hydrocarbons which contain at least one double bond which is not in an aromatic ring. • Acetylenic hydrocarbons ( acetyl­ enes, alkynes)—Unsaturated hydrocar­ bons which contain a t least one triple bond. • Aromatic hydrocarbons (arenes)Unsaturated hydrocarbons which con­ tain at least one benzene nucleus. • Usage. The committee also states that in the discussion of hydrocarbons, the terms "saturates" and "unsaturates" may be used as abbreviations for the longer terms "saturated hydrocarbons" and "unsaturated hydrocarbons." Par­ affins, naphthenes, olefins, acetylenes, aromatics may also be used as abbrevia­ tions for t h e corresponding terms "par­ affinic hydrocarbons," "naphthenic hy­ drocarbons," "olefinic hydrocarbons," "acetylenic hydrocarbons," and "aro­ matic hydrocarbons." Some com­ pounds may properly be referred to as belonging to more than one class. For example, styrene and indene a r e both aromatics and olefins. Further, the noun "arene" applies to all hydrocarbons containing at least onearomatic ring a n d is especially recom­ mended in naming derivatives such as=

Final Call for Nominations March 4 is the deadline for receipt of suggestions of members t o be nom­ inated for ACS offices for 1958. T h e Committee on Nominations and Elec­ tions a n d the Council Policy Committee hope that members will a d d more names to those already received as a result of earlier requests. All suggestions, each accompanied by a biographical sketch a n d a state­ ment of reasons w h y the individual is recommended, preferably using a form which will be supplied by t h e commit­ tee secretary, should b e sent immedi­ ately t o William A. Pardee, Jr., Secre­ tary, A C S Committee on Nominations and Elections, Gulf Research a n d D e ­ velopment Co., P . O. Drawer 2038, Pittsburgh 30, Pa. Nothing can be a c ­ cepted after March 4. Your coopera­ tion i s requested,

Hayes Heads Central Pennsylvania Section John R. Hayes, associate professor of chemistry a t Pennsylvania State Uni­ versity, is 1957 chairman of t h e Central Pennsyl­ vania Section. Vice chairman is Donald M. Rockwell, head of the department of chemistry a t Juniata College. Secretary is A n ­ drew A. Benson, John R. Hayes associate professor of agricultural and biological chemistry at Pennsylvania State University; treas­ urer i s A. H. Holtzinger, associate pro­ fessor of chemistry at Pennsylvania State University. Councilors are Arthur Rose, professor of chemical engineering at Pennsylvania State University, a n d Lester Kieft, head of Bucknell's depart­ ment of chemistry. Alternate coun­ cilors are Philip L . Walker, Jr., pro­ fessor of fuel technology at Pennsyl­ vania State University, and John D a y , manager of research at Merck's Chero­ kee plant.