Nanoplasmonics‐Based Photovoltaics
O
O
O
O
O O
O
Ru
O
O O
O
O
8
O
2.0e+6
O
O O O
15000
10
O
O
O
O O
9-vinylanthracene Ru=VAN Ru=C8
2.5e+6
Ru O
nanoparticle functionalization based on metathesis reactions
O
20000
Ru=C8 Ru=VAN 1.5e+6
10000 1.0e+6
σ (nS/m)
Fluorescence Intensity
O
O
O
O
O
O
O
O
O
O
Shaowei Chen, Department of Chemistry and Biochemistry, University of California – Santa Cruz
6
4
5000 5.0e+5
0
0.0 300
350
400
450
λ (nm)
500
550
600
2
0 50
100
150
200
250
300
350
T (K)
Anthryl‐functionalized Ru nanoparticles (Ru=VAN) exhibit apparent differences in fluorescence (left) and electronic conductivity (right) as compared to the original carbene‐stabilized nanoparticles (Ru=C8).
