Organometallics 1996, 15, 2393-2398
2393
New Examples of Half-Sandwich (Borylcyclopentadienyl)titanium Trichloride Complexes and an X-ray Structural Characterization of the Homobimetallic Complex [TiCl3{η5-C5H4}]2BPh Scott A. Larkin,† Jeffery T. Golden,† Pamela J. Shapiro,*,† Glenn P. A. Yap,‡ David Ming Jin Foo,† and Arnold L. Rheingold‡ Departments of Chemistry, University of Idaho, Moscow, Idaho 83844-2343, and University of Delaware, Newark, Delaware 19716 Received February 1, 1996X
A new series of half-sandwich (borylcyclopentadienyl)titanium trichloride complexes have been prepared which include the boryl substituents [1,2-(C6H4O2)]B-, Ph(Cl)B-, Ph2B- and a (PhB
