NEWS OF THE W EEK
SAFETY: Airplane battery fires thrust electrochemistry safety back in the spotlight
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UESTIONS ABOUT the safety of using lithium-
ion batteries for transportation applications have hit a zenith with two incidents in which such battery units onboard Boeing 787 Dreamliner airplanes caught fire or began to smolder. Airlines worldwide have grounded the new wide-body jets pending the outcome of investigations concerning the batteries and supporting equipment. Boeing says the batteries on its 787s feature multiple backups to ensure safety, including protections against overcharging and overdischarging. It has declined to comment on the investigations. Li-ion batteries can pack more energy into smaller and lighter weight units than other types of batteries. Those attributes have spurred enormous growth in their use for cell phones, laptop computers, and other portable electronic devices. Boeing selected the low-weight, high-energy-density batteries for the 787 Dreamliner to help reduce the new jetliner’s overall weight and bulk and thereby increase fuel efficiency. A downside of Li-ion cells, however, is that they contain a flammable electrolyte solution consisting of lithium salts in organic solvents such as ethylene carbonate and ethyl methyl carbonate. This is not the case for other commercial battery types. In Li-ion cells, heat generated by an internal or external short circuit, abusive electrical conditions, or other sources can, under some circumstances, ignite
the battery liquid or rapidly raise its vapor pressure until the cell bursts, says Daniel H. Doughty of Battery Safety Consulting in Albuquerque, N.M. Reports of fires in portable electronics caused by Li-ion batteries led manufacturers to recall millions of laptop batteries several years ago. The news shoved Liion battery safety issues into the spotlight. The recent incidents with the 63-lb battery units onboard Boeing jets have grabbed headlines in part because of the obvious difference from laptop computers in scale and potential danger. Investigators have not yet determined the cause of the Boeing battery pack incidents that occurred earlier this month. In one case, a Japan Airlines (JAL) 787 Li-ion battery that powers the plane’s auxiliary power unit caught fire on Jan. 7 as the empty plane sat on the tarmac at Boston’s Logan International Airport. In the other incident, All Nippon Airways (ANA) pilots made an emergency landing in central Japan on Jan. 16 because of alarms warning of an electrical problem and an unusual odor in the 787’s cockpit. Both the alarm and the odor were traced to a damaged Li-ion battery. The U.S. National Transportation Safety Board has ruled out excess voltage as the cause of the JAL fire. The agency says examination of flight recorder data indicates the auxiliary power unit battery did not exceed 32 V, the designed operating voltage. Likewise, Norihiro Goto, Japan’s Transport Safety Board chairman, says flight recorder data show that the ANA battery’s output voltage was normal before alarms sounded in the cockpit. Brian Barnett, a battery safety specialist at Lexington, Mass.-based technology development firm Tiax, says safety risks can be minimized with electronics to monitor battery performance.—MITCH JACOBY NTSB
NEW LITHIUM-ION BATTERY WOES
Li-ion battery units power various systems on Boeing 787 Dreamliner jets. This burnedout unit comes from a Japan Airlines plane.
ACS AWARDS Krzysztof Matyjaszewski wins AkzoNobel Award Krzysztof Matyjaszewski, the J. C. Warner University Professor of Natural Sciences at Carnegie Mellon University, has won the first AkzoNobel North America Science Award. The American Chemical Society selected Matyjaszewski for the $75,000 prize for his development of atom transfer radical polymerization (ATRP) and other polymer chemistry innovations. ATRP is widely used to make polymers and copolymers for applications including adhesives, sealants, pigment dispersants, and chromatography packings. The method is also being evaluated
for drug delivery, bone regeneration, and other biomedical applications. Through adjustments in temperature and other conditions, ATRP precisely controls polymer composition and architecture with the help of a catalyst that adds one or a few monomers at a time to a growing polymer chain. Citation data testify to the method’s enormous popularity and Matyjaszewski’s influence. His 1995 ATRP paper in the Journal of the American Chemical Society and his first review paper on the subject have together been cited more than 6,000 times. And in the
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past decade, scientists worldwide published more than 1,000 journal papers per year in which they discussed ATRP. “The main reason for this explosive development is the simplicity of ATRP and the unusual power to prepare tailor-made macromolecules for many special applications,” says Guy C. Berry, an emeritus professor of chemistry and polymer science at Carnegie Mellon. These features make ATRP an attractive technique for industrial practice, he adds. Matyjaszewski will receive the award at the spring 2013 ACS national meeting in New Orleans.—MITCH JACOBY
