NEW ROUTE TO PHTHALIC ACID! - C&EN Global Enterprise (ACS

Nov 6, 2010 - Advertisements that appeared within the print issues of Chem. Eng. News have been included in the C&EN Archives to provide a ...
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NEW ROUTE TO PHTHALIC ACID!.

In a report to the Petroleum Division of the ACS, Dr. William G. Toland of the California Research Corporation recently announced the development of a new method for p r o d u c i n g Phthalic Acid, with the following over-all reaction : C6H4(CH3)2 + 6S + 4H 2 0 = C6H4(C02H)2 + 6H2S

Note that the presence of Sulphur right smack in the middle of this reaction is necessary for its comple­ tion. The Sulphur leaves the process at this point. The hydrogen sulphide can be oxidized to elemental Sulphur and returned to the initial reaction. It is thus operable in a closed cycle. According to Dr. Toland, who de­ veloped this new route to phthalic acid, the process is simple and cap­ able of high recoveries. Here is another good example of how strongly Sulphur is in the proc­ essing picture. Together with its many derivatives it enters into count­ less reactions.

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