New synthesis of aldehydes via vinylsilanes - Journal of the American

Gilbert Stork, and Ernest Colvin. J. Am. Chem. Soc. , 1971, 93 (8), pp 2080–2081. DOI: 10.1021/ja00737a057. Publication Date: April 1971. ACS Legacy...
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2080 w

2

M

t

+

D2

trimethylsilyla~etylene~ followed by semihydrogenation (Scheme 11).

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Scheme I

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D

A'

,/'

H

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D

H

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I11 Scheme I1

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y

HD

Me3SiCECR

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Me,SiC=C-C