Nitrosylmetalloporphyrins. II. Synthesis and molecular stereochemistry

Jade B. Aitken, Sushila E. Thomas, Roland Stocker, Shane R. Thomas, ..... John Galley, Magrey DeVega, Kara Linna, Leigh Caron, Elizabeth Anderson, ...
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dein. and W. B. Fox, J. Org. Chern., 35,3730 (1970); D. E. Young, L. R. Anderson, D. E. Gouid, and W. B. Fox, J. Arner. Chern. SOC., 92, 2313 (1970); D. E. Young, L. R. Anderson, and W. B. Fox, horg. Chem., 10, 2810 (1971). W. Maya, C. J. Schack, R. D. Wilson and J. S. Muirhead, Tetrahedron Left., 3247 (1969). K. B. Kelloggand G. H. Cady, J. Arner. Chern. SOC.,70,3786(1948). A. Smithand A. W. C. Menzies, J. Arner. Chern. SOC.,32,897 (1910). P. Torkington and H. W. Thompson, Trans. Faraday Soc., 41, 236 (1945). The second example is FsSOOCi,D. D. DesMarteau, to be submitted for publication. R. L. Talbott. J. Org. Chem., 33,2095 (1968). The direction of addition follows Markownikof's rule for CF2CH2and is ~

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accord with the polarity of the reagents for the other unsymmetricalolefins. (17) R. D. Chambers and R. H. Mobbs, Advan. Fluorine Chem., 4, 50 (1965). (18) 8.L. Dyatkin, E. P. Mochalina, and J. L. Knunyantz, Nuorhe. Chern. Rev., 3,45 (1969). (19) R. D. Chambers, "Fluorine in Organic Chemistry," Wiley, New York, N. Y., 1973, p 173, and references therein. (20) L. M. Jackman and S. Sternheil, "Applications of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry," 2nd ed,Pergamon Press. New York, N.