5314
The Journal of Physical Chemistry, Vol. 92, No. 18, 1988
Additions and Corrections
ADDITIONS AND CORRECTIONS 1988, Volume 92 Richard E. Stanton* and Marshall D. Newton*: Normal Vibrational Modes of Buckminsterfullerene. Page 2144. The equation in the third paragraph of the Discussion section should read
Jdjl/dQ(MNDO = 0.1
+ 0.51djl/dQlC,,,
f 0.2 ( D / A amu’/*)
1987. Volume 91
D. Frenkel: Onsager’s Spherocylinders Revisited.
1988, Volume 92
D. Frenkel: Structure of Hard-core Models for Liquid Crystals. Page 4912 of Vol. 91 and page 3280 of Vol. 92. The values for the third to fifth virial coefficients of spherocylinders as reported in the above papers were incorrect, due to a systematic bias in our Monte Carlo sampling scheme. Table I contains the corrected values for these virial coefficients. Note that the new values differ by a small but significant amount from the earlier results. The other results presented in the above papers made no use of these higher order virial coefficients and were therefore not affected. Moreover, the corrected virial coefficients exhibit qualitatively the same dependence on LID as described in the above papers. I am extremely grateful to Dr. M. Rigby for pointing out the discrepancy between the virial coefficients in the above papers and his most recent, unpublished results. TABLE I: Virisl Coefficients of Hard Spherocylinders LID 0 5 10 102 10’ 104 105 106
B3lB22 0.625 0.4194 (3) 0.3133 (3) 0.0698 (1) 0.01060 (5) 0.00145 (2) 0.000172 (7) 0.000021 (2)
B4IBz’ 0.28695 0.0528 (4) -0.0157 (4) -0.0291 (2) -0.00450 (7) -0.00050 (2) -0.000049 (7) -0.000005 (2)
BSIB24 0.1 1025 0.0110 (7) 0.0229 (7) 0.0325 (5) 0.0051 (2) 0.00061 (6) 0.00003 (1) 0.000011 (6)
