Novel metal complexes involving a multiply bridged nitrogen atom

Complexes Involving a Multiply. Bridged Nitrogen Atom 261. Table VIII. Calculation of E° for. V(bipy)32+'3 +. Using the. Marcus Theory". Oxidant sec'...
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COMPLEXES INVOLVING A Mu”x

Vol. 7 , No. 2, Februuvy 196‘8 TABLE VI11 OF E o FOR V(bipy),2ti3+ CALCULATION USINGTHE MARCUST H E O R Y ~ Oxidant

kn, ‘V1-1 sec-1

R U ( ~ ’ H ~ ) ~0~. 1+2 C~(bipy),~+ 6.4 F e ( E D T A ) - 23

kri

-1 X 1036 -20c

> 104

Eli’

E210

-0.1Ob 0.37e

-0.81

-0.75

( > l o 3 a t 0’) -0.12f