Now, what is it you want to know alal a applications about industrial of superphosphoric (105% Η3Ρθ4) and poiyphosphoricric (115% H3P04) acids ? TABLE OF CONTENTS Page USE OF PPA IN INDUSTRIAL APPLICATIONS
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USE OF PPA IN PHOSPHORYLATION REACTIONS
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A. Phosphorylation of Alcohols B. Phosphorylation of Amino Alcohols C. Phosphorylation of Hydroxy Acids, Esters, Amides and Nitriles D. Phosphorylation of Glucose E. Phosphorylation of Miscellaneous Compounds
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USE OF PPA AS A CATALYST IN ORGANIC REACTIONS A. Rearrangement Reactions 1. Beckmann rearrangement 2. Wagner-Meerwein rearrangement 3. Schmidt rearrangement 4. Lossen rearrangement B. Intermodular Acylation Reactions C. Intermodular Alkylation Reactions D. Polymerization Reactions E. Dehydration Reactions F. Hydrolysis Reactions G. Nitration Reactions H. Bromination Reactions I. Miscellaneous Organic Reactions J. Cyclization Reactions 1. Synthesis of nitrogen heterocycles a. Fisher indole synthesis b. Synthesis of isoquinolines and derivatives c. Synthesis of other nitrogen heterocycles 2. Synthesis of sulfur and oxygen heterocycles 3. Cyclization by intramolecular acylation 4. Cyclodehydration of aldehydes and ketones 5. Cyclodehydration of alcohols
Our new 27 page technical literature search, com piled especially for FMC by Jacques Tocatlian, contains synopses, with references, of all the perti nent literature on the above applications published through 1963. It's yours for the asking. And while you're at it, ask us for product literature on our 105% H3PO4, available in commercial quantities, and
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our 115% H3PO4, a development chemical presently available in limited quantities. You might as well have the whole story. It's all at Product Promotion Department 1742B.
FMC C O R P O R A T I O N NORGANIC CHEMICALS DIVISION 633 THIRD AVENUE, NEW YORK 17. NY. C&EN
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