Occurrence and Profiles of Chlorinated and ... - ACS Publications

Feb 19, 2008 - Public Health, State University of New York at Albany, Empire. State Plaza, P. O. Box 509, ... 52-1 Yada, Shizuoka 422-8526, Japan. Rec...
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Environ. Sci. Technol. 2008, 42, 1904–1909

Occurrence and Profiles of Chlorinated and Brominated Polycyclic Aromatic Hydrocarbons in Waste Incinerators †



YUICHI HORII, GON OK, TAKESHI OHURA,§ AND K U R U N T H A C H A L A M K A N N A N * ,† Wadsworth Center, New York State Department of Health, and Department of Environmental Health Sciences, School of Public Health, State University of New York at Albany, Empire State Plaza, P. O. Box 509, Albany, New York 12201-0509, Department of Environmental Atmospheric Science, Pukyong National University, 599-1 Daeyeon 3-dong, Nam-Gu, Busan 608-737, Korea, and Institute for Environmental Sciences, University of Shizuoka, 52-1 Yada, Shizuoka 422-8526, Japan

Received December 1, 2007. Revised manuscript received January 4, 2008. Accepted January 4, 2008.

Chlorinated polycyclic aromatic hydrocarbons (ClPAHs) have been reported to occur in urban air. Nevertheless, sources of ClPAHs in urban air have not been studied, due to the lack of appropriate analytical methods and standards. In this study, we measured concentrations of 20 ClPAHs and 11 brominated PAHs (BrPAHs) in fly ash and bottom ash from 11 municipal/ hazardous/industrial waste incinerators, using analytical standards synthesized in our laboratory. Concentrations of total ClPAHs and BrPAHs in ash samples ranged from