Published Monthly.
Price $6.00 per
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T H E JOURNAL OF THE
AMERICAN CHEMICAL SOCIETY. VOL. X X V . — N O .
I.
JANUARY, 1903. W I L L I A M A. N O Y E S , Editor, E D W A R D H A R T , W . F . H I L L E B R A N D , J. H . L O N G , W M . M C M U R T R I E , A R T H U R A. N O Y E S , E D G A R F. S M I T H , H. N. S T O K E S , H. P. T A L B O T , H.
W.
WILEY.
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CONTENTS. Proceedings
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(I)-(4)
Τ*"·*PAPERS. R e p o r t of t h e I n t e r n a t i o n a l C o m m i t t e e o n A t o m i c W e i g h t s . By F . W , Clarke r S o m e C u b a n S o i l s of C h e m i c a l I n t e r e s t . By W m . F r e a r a n d C. P . B e i s t l e . 5 T h e Effects of F e r m e n t a t i o n u p o n t h e C o m p o s i t i o n of C i d e r a n d V i n e g a r . By C. A. B r o w n e , J r . 16 A C o n t r i b u t i o n t o t h e C h e m i s t r y of F a t i g u e . B y H e n r y W i n s t o n H a r per and Margaret Holliday 33 O n t h e F i x a t i o n of A m m o n i a a n d P o t a s h b y H a w a i i a n S o i l s . By J. T . C r a w l e y a n d R . A. D u n c a n 47 A P r o b a b l e C a u s e of t h e D i f f e r e n t C o l o r s of I o d i n e S o l u t i o n s . By Arthur Lachman 50 P r u s s i c A c i d in S o r g h u m . By H e n r y B. S l a d e 55 D e r i v a t i v e s of P h e n y l e t h e r . V . B y A l f r e d N . C o o k 60 A n I n v e s t i g a t i o n of A m m o n i o - S i l v e r C o m p o u n d s in S o l u t i o n . By W . R . W h i t n e y a n d A . C. M e l c h e r 69 T h e E l e c t r o l y t i c E s t i m a t i o n of B i s m u t h a n d I t s S e p a r a t i o n f r o m O t h e r Metals. By Alfred Lewis K a m m e r e r 83 T h e A l k a l o i d s of I s o p y r u m a n d I s o p y r o i n e . By G e o r g e Bell F r a n k f o r t e r . 99 N E W B O O K S : T h e E l e c t r o - P l a t i n g a n d ' E l e c t r o - R e f i n i n g of M e t a l s ; H i g h e r M a t h e m a t i c s for S t u d e n t s of C h e m i s t r y a n d P h y s i c s ; T e x t B o o k of E l e c t r o c h e m i s t r y ; P h y s i c s — T e x t - B o o k for S e c o n d a r y Schools ; Essays in Historical Chemistry ; Chemisches Practicum ; F i r s t B o o k of Q u a l i t a t i v e C h e m i s t r y for S t u d i e s of W a t e r S o l u t i o n a n d M a s s A c t i o n ; L o g a r i t h m i s c h e R e c h e n t a f e l n fur C h e m i k e r ; T h e A n a l y s i s of S t e e l W o r k s M a t e r i a l ; I n t e r n a t i o n a l C a t a l o g u e of Sci entific L i t e r a t u r e ; Q u a l i t a t i v e A n a l y s i s ; T h e E l e m e n t s of P h y s i c s . 102 REVIEW
OF AMERICAN
Entered
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at the Post-office,
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Easton,
Pa., as Second-class
1-62
Matter.
Everything intended for insertion in t h e Journal should be addressed to t h e Editor, William A. Noyes, Terre Haute, Ind. Ordersifor back numbers of the Journal should be addressed to t h e Librarian, E. O. Love, 108 West 55th Street, New York City. Changes of address should be sent to t h e Secretary, W. A. Noyes, Rose Polytechnic Institute, Terre Haute, Indiana. The dues for 1903 ($5.00) should be sent to Dr. Al bert P. Hallock, Treasurer, 440 First Ave., New York, Ν. Υ. Remittances may be by money order or by check on a bank in a n y of t h e principal cities of t h e U. S.
~ OFFICERS OF THE AMERICAN CHEMICAL
SOCIETY.~
President : J o h n H . L o n g , 2421 D e a r b o r n S t r e e t , C h i c a g o , Ill. Vice-Presidents : T h e P r e s i d i n g Officers of t h e L o c a l S e c t i o n s ; s e e b e l o w . Secretary : W i l l i a m A. N o y e s , R o s e P o l y t e c h n i c I n s t i t u t e , T e r r e H a u t e , I n d . Treasurer : A l b e r t P . H a l l o c k , 440 F i r s t A v e . , N e w Y o r k C i t y . Librarian : E . G . L o v e , 108 W . 5 5 t h S t . , N e w Y o r k C i t y . Committee on Papers and Publications : W i l l i a m A. Noyes, E d i t o r ; E d w a r d H a r t , W . F . H i l l e b r a n d , J . H . L o n g , W m . M c M u r t r i e , A r t h u r A. N o y e s , E d g a r F . S m i t h , H . N . Stokes, H. P. Talbot, H. W. Wiley. Committee on Membership : W m . M c M u r t r i e ; C. L . R e e s e ; E . G . L o v e . Finance Committee: J . H . W a i n w r i g h t ; D u r a n d W o o d m a n ; C. F . M c K e n n a . Directors. Members ex-officio : I r a R e m s e n , P r e s . ; A l b e r t C. H a l e , S e c . ; A l b e r t P . H a l l o c k , T r e a s . T e r m expires December, I902 : C. A. D o r e m u s , C B. D u d l e y . Term expires December, 1903 : C. F . C h a n d l e r , Ε . Ε . S m i t h . Council. Members ex-officio : I r a R e m s e n , P r e s . ; A l b e r t C. H a l e , S e c . ; A l b e r t P . H a l l o c k , T r e a s . ; W . A. N o y e s , E d i t o r ; S . W . J o h n s o n , C. F . C h a n d l e r , J . W . M a l l e t , A . B . P r e s c o t t , C. A . G o e s s m a n n , G . F . B a r k e r , G . C. C a l d w e l l , H . W . W i l e y , E . F . S m i t h , C. B . D u d l e y , C. E . M u n r o e , E d w a r d W . M o r l e y , W m . M c M u r t r i e , F . W . C l a r k e , P a s t P r e s i d e n t s . Councilors at large,— T e r m expires December, 1902: C. F . M a b e r y , W . B . R i s i n g , S . P . S a d t l e r , F . P . V e n a b l e . T e r m expires December, 1903 : F . A . G o o c h , E d w a r d H a r t , T . W . R i c h a r d s , H . L . W e l l s . T e r m expires December, 1904: T . M . D r o w n , C. F . M c K e n n a , A. A. N o y e s , Ε . Ε . S m i t h . Councilors from Local Sections.—Rhode Island Section : C h a r l e s A . C a t l i n . Cincinnati Section: Thomas Evans. New York Section: L e o B a e k e l a n d , A . A . B r e n e m a n , C. A . D o r e m u s , T . J. P a r k e r , G. C. S t o n e . Washington Section : W . F . H i l l e b r a n d , Η . Ν . S t o k e s . Lehigh ValleySection : P . W . S h i m e r . Chicago Section : J . H . L o n g . Nebraska Section : H . H . N i c h o l s o n . North Carolina Section : B . W . K i l g o r e . Columbus Section: Wm. McPherson. North Eastern Section: W . L J e n n i n g s , A. D . L i t t l e , H . P . T a l b o t . Philadelphia Section: H . W . J a y n e , J o h n M a r s h a l l . Michigan Section : E . D . C a m p b e l l . Kansas City Section: J. R o b t . M o e c h e l . California Section: J. M. Stillman. Local Sections. Rhode Island Section : W a l t e r M . S a u n d e r s , P r e s . ; W a l t e r E . S m i t h , S e c . , 158 D o y l e A v e . , P r o v i d e n c e , R . I . Cincinnati Section: R . W . H o c h s t e t t e r , P r e s . ; J. F . S n e l l , S e c . , U n i v e r s i t y of C i n c i n n a t i , C i n c i n n a t i , O . New York Section: T h o m a s J. P a r k e r , P r e s . ; F r a n c i s D . D o d g e , 360 W a s h i n g t o n A v e n u e , B r o o k l y n , Ν . Υ . Washing ton Section : W . F . H i l l e b r a n d , P r e s . ; L . S . M u n s o n , S e c . , D e p t . of A g r . , W a s h i n g t o n , D . C. Lehigh Valley Section : J o s e p h W . R i c h a r d s , P r e s . ; R . K . M e a d e , S e c . , L a f a y e t t e C o l l e g e , E a s t o n , P a . Chicago Section: E d w a r d G u d e m a n , P r e s . ; W . A. C o n v e r s e , S e c . , 27-34 R i a l t o B l d g . , C h i c a g o . Nebraska Section: H . H . N i c h o l s o n , P r e s . ; R. S. H i l t n e r , Sec., U n i v e r s i t y of N e b r a s k a , L i n c o l n , N e b . North Carolina Section: C. E . B r e w e r , P r e s . ; C. B . W i l l i a m s , S e c . , N o r t h C a r o l i n a D e p t . of A g r . , R a l e i g h , N . C. Columbus Section: H . A. W e b e r , P r e s . ; W . E . H e n d e r s o n , S e c . , O h i o S t a t e U n i v e r s i t y , C o l u m b u s , O . North Eastern Section: A u g u s t u s H. Gill, Pres.; A r t h u r M. Comey, Sec., 12 P e a r l S t . , B o s t o n , M a s s . Philadelphia Section: H e n r y Leffmann, P r e s . ; F . E. D o d g e , S e c . , W o r k s of B a r r e t t M f g . C o . , F r a n k f o r d , P h i l a d e l p h i a . Michigan Section : E . D . C a m p b e l l , P r e s . ; A l f r e d H . W h i t e , S e c . , 1003 E . U n i v e r s i t y A v e . , A n n A r b o r , M i c h . Kansas City Section : E. H . S. B a i l e y , P r e s . ; A r m a n d R . M i l l e r , S e c . , M . T . H i g h S c h o o l , K a n s a s City, Mo. California Section : E d m o n d O ' N e i l l , P r e s . ; H a r r y E a s t M i l l e r , Sec., 331 P i n e S t . , S a n F r a n c i s c o , C a l . PAPERS ACCEPTED FOR PUBLICATION, L i q u i d B a t h s for T e m p e r a t u r e s u p to 600°. By H e y w a r d S c u d d e r . T h e P r e v e n t i o n of B u m p i n g By H e y w a r d S c u d d e r . T h e . C o l o r i m e t r i c D e t e r m i n a t i o n of S m a l l Q u a n t i t i e s of P h o s p h o r i c Acid a n d Silica. By F . P. Veitch. A S t u d y of t h e D o u b l e C y a n i d e s of Zinc w i t h P o t a s s i u m a n d S o d i u m . By W. J. Sharwoocl. A S t u d y of M a g n e s i u m a n d M a n g a n o u s H y d r o x i d e s w i t h R e g a r d to t h e P h e n o m e n a of A d h e s i o n a n d S o l u t i o n . By H . E . P a t t e n . T h e D i s t r i b u t i o n of H y d r o g e n S u l p h i d e to L a b o r a t o r y Classes. By C. L. P a r s o n s . T h e G r a v i m e t r i c D e t e r m i n a t i o n of M e r c u r y a n d its S e p a r a t i o n from A r s e n i c , A n t i m o n y a n d Cop per. By C h a r l e s J. Pretzfeld. N o t e C o n c e r n i n g t h e Calculation of T h e r m o c h e m i c a l R e s u l t s . By T h e o d o r e W. R i c h a r d s . A P l a t i n u m C r u c i b l e for Carbon C o m b u s t i o n . By J o h n V. R. S t e h m a n . A R a p i d M e t h o d for D e t e r m i n i n g S u l p h u r in Coal a n d C o k e . By Carl S u n d s t r o m . Copyright, 1902, by William
A. Noyes, Chairman of the Committee on Papers and Publications A merican Chemical Society.
of the