On a New Volumetric Method of Determining Florine - Journal of the

Publication Date: April 1879. ACS Legacy Archive. Cite this:J. Am. Chem. Soc. 1, 4, 113-114. Note: In lieu of an abstract, this is the article's first...
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ABSTRALTS

:

113

AMERICAN CIIEMICAL JOURNAL.

The atomic ratios approximately represented hy the above results are : For u ........................... N : I =1: 3 " h ........................... N : I = 2 : 5 c

"

...........................

x : 1-1:

2

Owing to these results and the experiments of other chemists, the author is of the opinion that the molecule of these compounds coiitains two parted nitrogen atoms, and considers the existence of the following substituted products established.

I\ I-N I/

= N-I

II-N \ I

= N-I

I\ I-N I/

= N-H-

/I

\I /H

\.I

/'

-

/ €1

Product

Also obtained by Stahlachmidt, using aqueous ammonia.

U.

Product h.

Also prepared { product).

by Uuiiseii (2d

Also obtained by Bunsen, Gladstone and others, using alcholic solirtions of ammoriia and iodine.

Product c.

\I

1

Obtained by Bunsen (first product), using anhydrous alcoholic solations of ammonia and iodine. I/ \H It appears, then, that the formation of theRe different products is dependent on the conditions under which the explosive cornpound iw prepared, as well as upon its decomposition by water.

I\ I-N

/H

= N-ri

Diacuendon of the H'orktng H~jpotkeniethrrt the 80-called W e are Compouwd Bodfee,* by J. NORMAN LOCKYER, F. R. S.

ment8

Otb Lockljer'8 66 H ~ p o t h e s ht h d the so-culled Elements ave C'ortcpound Bodies,"+ by C. S. HAYTINRS, Assistant Prof. of Phyw-

ics, .Johns Hopkins University. 0 t h a New Ydurnetr.lc method of Determintmg FZmwirre, by S A M V E L L. PENFIELD, Assistant in the Sheffield Laboratory. The reaction 3 SiF, 2 H,O 2 H&F, SiO, is made the basis of a volumetric determination of fluorine, the amount of hydrofluo-silicic acid formed from a given weight of a fluoride, being estimated by a standard alkali solution.

+

-

+

+Ahstmcted from the Amer. Jour. Sci., vol. xvii, p. 93.

+ A review of the preceding paper.