One-Pot Conversion of Thebaine to Hydrocodone ... - ACS Publications

Jan 29, 2009 - “Thebaine, usually a minor constituent of opium and poppy straw, is isolated as a major component from mutant poppy plants introduced...
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Vol. 72, 2007

Vol. 74, 2009

Leo A. Paquette,* Gregory D. Parker, Takahiro Tei, and Shuzhi Dong. Pestalotiopsin A. Enantioselective Construction of Potential Building Blocks Derived from Antipodal Cyclobutanol Intermediates.

Robert J. Carroll, Hannes Leisch, Lena Rochon, Tomas Hudlicky,* and D. Phillip Cox. One-Pot Conversion of Thebaine to Hydrocodone and Synthesis of Neopinone Ketal.

Page 7127. The configurations at C-3 in 13 and its counterpart 14 were inadvertently reversed. As delineated previously (ref 8), the major aldol product 13 (9:1) has the anti configuration, while the minor component 14 is the syn diastereomer. The correct graphic is shown below. All subsequent transformation products should reflect this minor adjustment.

Page 747. We would like to correct following mistake. The first sentence in the second paragraph on page 747 originally reads: “Thebaine, usually a minor constituent of opium latex, is isolated as a major component from genetically engineered hybrids introduced by the company Tasmanian Alkaloids.5” The sentence should read: “Thebaine, usually a minor constituent of opium and poppy straw, is isolated as a major component from mutant poppy plants introduced by the company Tasmanian Alkaloids.5” JO9001036 10.1021/jo9001036 Published on Web 01/29/2009

JO9001382 10.1021/jo9001382 Published on Web 01/27/2009

1812 J. Org. Chem. 2009, 74, 1812