new Use the theories of orbital symmetry to better plan the easiest, most efficient, and most productive route to get a desired product
Orbital Symmetry Concept in Organic Chemistry An Audio Course Produced by the American Chemical Society This ACS Audio Course is designed for chemists who are studying the theory and mechanisms behind organic reactions. You'll learn the elementary theories behind the topology and symmetry of molecular orbitals and how to combine theoretical concepts with practical applications. Using the nodal properties of Huckel molecular orbitals, this course shows you how to construct correlation diagrams and analyze transition states of pericyclic reactions as Hùckel or Mobius delocalized arrays, "ibu'll understand how the application of these concepts can be used to develop selection rules that can predict the course of pericyclic reactions.
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Marye Anne Fox is the Rowland Pettit Professor of Chemistry at the University of Texas. Her research interests lie in physical organic chemistry with particular emphasis on mechanistic photochemistry and organic electrochemistry. Of particular interest in her research group have been investigations of the excited states of carbanions, organic photoelectrochemistry, chemically modified surface catalysis, and the synthesis and characterization of polymers for directional energy and electron transfer.
American Chemical Society, Distribution Office, Priority Code 86, 1155 Sixteenth Street, N.W., Washington, DC 20036
BRIEF COURSE CONTENTS Introduction: Purpose of the Course; Principle of Conservation of Orbital Symmetry; Symmetry; Types of Pericyclic Reactions Nodal Properties of Molecular Orbitals: Nodal Properties; Hûckel Theory; Symmetry in Molecular Orbital Phasing Theoretical Analysis of Chemical Reactivity: Aromatic Transition States; Huckel's Rule; Transition State Aromacity; Construction of Correlation Diagrams; Electrocyclic Correlation Diagrams; Cycloaddition Correlation Diagrams; Cheletropic Correlation Diagrams; Sigmatropic Shift Correlation Diagrams; Summary of Woodward-Hoffman Selection Rules Illustrative Chemical Examples: Electrocyclic Reactions; Cycloaddition Reaction; Cheletropic Reactions; Sigmatropic Rearrangements; Dyotopic Reactions; Pericyclic Reactions of Radical Ions; Synchronous and Nonsynchronous Reactions; Suggested Problems for Synthetic Applications of Pericyclic Reactions
UNIT (Catalog No. 98) Four cassettes (4.1 hours playing time) and 182-page manual; U.S. & Canada, $315.00; export, $380.00. Additional Manuals: U.S. & Canada, $24.00 each; export, $29.00 each.
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Complete Course(s) Orbital Symmetry, at $315.00 (U.S. & Canada) or $380.00 (export). Catalog No. 98 Additional manuals at $24.00 each (U.S. & Canada) or $29.00 each (export). $_ TOTAL $_ Π Payment Enclosed (make checks payable to ACS). • Purchase Order Enclosed. P.O. # Charge My D Visa/MasterCard D American Express D Diners Club/Carte Blanche D ACCESS Π Barclaycard Account # Expires . Interbank #.
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