Communication Cite This: Chem. Mater. 2018, 30, 2208−2212
pubs.acs.org/cm
Organosilica with Grafted Polyacrylonitrile Brushes for High Surface Area Nitrogen-Enriched Nanoporous Carbons Jianan Zhang,†,‡,§ Yang Song,‡,∥ Yepin Zhao,† Shuo Zhao,‡ Jiajun Yan,‡ Jaejun Lee,† Zongyu Wang,‡ Siyuan Liu,† Rui Yuan,‡ Danli Luo,† Maciej Kopeć,‡ Eric Gottlieb,‡ Tomasz Kowalewski,‡ Krzysztof Matyjaszewski,*,‡ and Michael R. Bockstaller*,† †
Department of Materials Science and Engineering and ‡Department of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, United States § School of Chemistry and Chemical Engineering, Anhui University and Anhui Province Key Laboratory of Environment-friendly Polymer Materials, Hefei 230601, China ∥ Collaborative Innovation Center of Advanced Nuclear Energy Technology, Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China S Supporting Information *
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Herein we report on a novel and versatile approach for the synthesis of nanosized polymer-tethered silica particles for hard-templating of NPCs with SSA exceeding 1000 m2/g.34−36 This technique is based on the direct synthesis of Br-containing organosilica NPs with diameter
