... during the reaction in our recent publication and have illustrated and expanded the synthetic utility for the protocol by using a variety of nucleophilic ...
Nov 16, 2010 - Department of Chemistry, Western Illinois UniVersity, Macomb,. Illinois 61455, United States. [email protected]. Received October 2, 2010.
Nov 16, 2010 - Substrates Used in Head-to-Head Competitive Oxidative Cleavage Reactions with ..... Travis , B. R.; Narayan , R. S.; Borhan , B. J. J. Am. Chem.
and High Technology Research Center, Kansai University,. Suita, Osaka 564-8680, Japan [email protected]. Received February 1, 2002. Abstract: ...
Nov 16, 2010 - Department of Chemistry, Western Illinois UniVersity, Macomb,. Illinois 61455, United States. [email protected]. Received October 2, 2010.
Robert W. Murray*, and Megh Singh. Department of Chemistry, University of MissouriâSt. Louis, St. Louis, Missouri 63121. Chem. Res. Toxicol. , 1998, 11 (5), ...
formed to isolate sufficient quantities of metabolites for structure elucidation. The organism achieves 1 1-0-demethylation of dihydrovindoline, and it performs a ...
T. Sega, A. Pollak, B. Stanovnik, and M. Tisler. J. Org. Chem. , 1973, 38 (19), pp 3307â3311. DOI: 10.1021/jo00959a013. Publication Date: September 1973.
Mar 12, 2007 - Pd(II)-Catalyzed Asymmetric Oxidative 1,2-Diamination of Conjugated Dienes with Ureas ..... Pd(0)-Catalyzed Sequential CâN Bond Formation via Allylic and Aromatic ...... Chemical Communications 2015 51 (19), 4101-4104 ...
Dec 9, 2017 - The organic solvent free auto-oxidative radical hydroxysulfenylation of olefins in a micellar system was presented which enables the simultaneous CâO and CâS couplings to be performed in a green .... Interestingly, 1H NMR tracking r
Oxidative Transformations of Alkenes Using Environmentally Benign Reagents T. K. Vinod Department of Chemistry Western Illinois University Macomb, IL 61455
Selective and differential functionalization of the two double bonds in dienes Sequential use of DAIB and BTI as oxidants for elemental iodine have allowed us to selectively and differentially functionalize two double bonds in dienes. The differences in the elctrophilic nature of iodine atom in the in –situ generated acetyl hypoiodite and trifluoroacetyl hypoidite accounts for the noted difference in reactivities.
Development of a green chemistry experiment for undergraduate curriculum Experimental demonstration of oxidative cleavage of alkenes is not a common exercise in any undergraduate curriculum. Based on our previously reported procedure, we have now developed and optimized an experiment for oxidative cleavage of alkenes demonstrating several green chemistry principles including the use of safer solvents and catalytic use of reagents.
