Ozone Decomposition in Water Studied by Pulse Radiolysis 1. HO2

k2 appear to be of the same order of magnitude, two relaxation frequencies well separated in the frequency spectrum (by more than 1 order of magnitude...
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5450 The Journal of Physical Chemistry, Vol. 88, No. 22, 1984

Additions and Corrections

Similarly, linear regression applied to the data of Figure 4b plementary material). The straight line calculated by linear gave s12 = 4.3 X 10l6 and Z2 = 2.4 X One has then kl = regressions forcing the intercept through the origin (r2 = 0.99, 9.2 X lo7 M-I s-l and k-, = I, - s12/s11= 3.6 X lo8 which give sl = 5.9 X seems also to describe the behavior of the data. K, = k l / k - , = 0.25 M-l. Further, as k-1k-2= I2 = 2.4 X lOI5, Notice that [B]