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International Chemical Congress of Pacific Basin St&ieHes Dec. 14-19

try, bioscience and technology, chemis try and the community, environmental chemistry, inorganic chemistry, macromolecular chemistry, medicinal chemis try, organic chemistry, and physical and theoretical chemistry. More than 8,000 he 2000 International Chemical presentations will be given in 794 tech Congress of Pacific Basin Societ nical sessions (see page 66). ies (Pacifichem 2000) will be held Sponsored jointly by the American Dec. 14-19 in Honolulu. The technical Chemical Society, the Chemical Society program is organized into 10 topic ar of Japan, the Canadian Society of Chemis eas: agrochemistry, analytical chemistry, the Royal Australian Chemical Insti tute, and the New Zealand Institute of Chemistry, the congress will be hosted by Meeting information on the Web ACS. Twenty chemical so Up-to-date information on housing availability, cieties headquartered in travel arrangements, local arrangements, and Pacific Basin countries are other aspects of the 2000 International Chemi official participants. cal Congress of Pacific Basin Societies in HonoAn exposition at Pacifi lulu is available on the ACS Meetings chem 2000 is expected to Pacifichem website: http://www.acs.org/ feature displays by more meetings/pacific2000. The preliminary pro gram for POLY Millennial 2000 can be found at than 40 organizations (see http://www.chem.umr.edu/~poly/. page 161). Located in the Coral Foyer of the Hilton

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OCTOBER 2,2000 C&EN

Classification of registrant

Fee iIdvance On-site

Pacifichem 2000 Registration deadline: Nov. 10 Member of sponsoring $340 or participating society Nonmember: technical professional eligible for membership in sponsor ing or participating society Spouse/guest

$410

420

505

50

50

Student

75

90

Abstract book

45

55

POLY Millennial 2000 Registration deadline: Oct. 15 Member of Division of $475 Polymer Chemistry

$525

Nonmember

525

575

Student member

250

300

Nonparticipating guest

250

300

Special events Congress Opening Ceremony. Thursday, Dec. 14, 7-9 PM, at the Sheraton Waikiki. Opened by a traditional Hawaiian chant, the ceremony will also include welcoming remarks by officers of the sponsoring societies, the governor of Hawaii, and the mayor of Honolulu. Exposition. Friday, Dec. 15, and Saturday, Dec. 16, from 9 AM to 2 PM, and Sunday, Dec. 17, from 9 AM to 1 PM, Hilton Hawaiian Village in the Coral Foyer. Student Poster Competition. Friday, Dec. 15, Session No. 1: 1-3 PM, Hilton Hawaiian Village; Session No. 2 : 4 - 6 PM, Hilton Hawaiian Village. Glenn T. Seaborg Padfichem 2000 Plenary Lecture. Saturday, Dec. 16, 7:30-8:30 PM, featuring Ronald Breslow, professor of chemistry, Columbia University, Sheraton Waikiki. Millennium Mixer. Saturday, Dec. 16, 8:30-10:30 PM, featuring native Hawaiian music and a fireworks display, Sheraton Waikiki. Paul J. Scheuer Testimonial Program. Sunday, Dec. 17, 5:30-7:30 PM, Sheraton Waikiki. Gaussian Inc. Open Reception. Sunday, Dec. 17, 7 AM-10 PM, Gaussian Inc. Hospitality Suite, Hilton Hawaiian Village.

Hawaiian Village, the exposition will be held Friday, Dec. 15, and Saturday, Dec. 16, from 9 AM to 2 PM, and on Sunday, Dec. 17, from 9 AM to 1 PM.

Honolulu • j f REGISTRATION Pacifichem 2000. The deadline for registration is Nov. 10. The registration fee includes the opening ceremony, the Pacifichem Lecture, the Millennium Mixer, and all technical sessions. Use of the hospitality center and participation in tours prearranged by the congress are available to registrants only. Members of the sponsoring and official participating societies receive discounts on registration.

Anticipating that many Pacifichem 2000 attendees will also attend POLY Millennial 2000, the Organizing Committee is offering the option to register for both meetings at the same time. Registration Procedure. Registration can be done via Internet at h t t p : / / www.acs.org/meetings/pacific2000/. A registration form is also included on page 65 for your convenience. Payment in U.S. dollars or authorization to charge to a credit card must accompany the registration. International bank transfers must include bank charges in addition to the fee due. Purchase orders cannot be honored. Please allow at least four weeks to process your request. Your badge and receipt will be mailed to the address shown on the registration form. Badge cases and programs will be available on-site.

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TOURS

Tour participation is open to registered attendees only. Tickets will also be sold onsite, but some tours may be sold out. Tours may be canceled if participation does not reach a required minimum. In that event, full refunds will be made. Prices include transportation, taxes, and entrance fees. Children through the age of 12 are eligible for the reduced prices as indicated. On-site, refunds may be obtained until 48 hours before the scheduled tour. After that time, staff will attempt to resell your ticket Just prior to the meeting, the Hawaii Volcano Field Trip will be held on Tuesday, Dec. 12, through Wednesday, Dec. 13, with accommodations at the Hawaii Naniloa Re sort in Hilo, on the island of Hawaii. Refer to the Pacifichem website: http://www.acs. org/meetings/pacific2000 for details.

the serenity of Punchbowl, enjoy the drive through downtown Honolulu's highlights. Cost: $44 adult, $33 child (limit 100 people). 4.1/Adult, 4.2/child. 11:50 AM to 10:30 PM. Polynesian Cultural Center. At Laie, on the windward side of Oahu, the center includes re-created villages of the six countries of Polynesia— New Zealand, Tonga, Fiji, Samoa, Tahiti, and Hawaii. Visitors will be able to observe or participate in the arts and crafts of Polynesia. A buffet dinner and show will cap the day. Cost: $62 adult, $50 child includes round-trip transfers, Hawaiimax Theater admission, dinner, and show (limit 100 people). Friday, Dec. 15 5.1/Adult, 5.2/child. 8:30 AM to 12:30 PM. Pearl Harbor Coastal Cruise. Narrated cruise to Pearl Harbor passes Hickam Field, Ford Island, Battleship Row, the Mighty MO, and the U.S.S. Arizona monument Cost: $25 adult, $13 child (limit 100 people). 6.1/Adult, 6.2/child. 6:30to10:30 AM. Arizona Memorial Excursion. Participants will tour the National Park Center, view afilmof the Pearl Harbor attack of Dec. 7,1941, and board the Arizona Memorial where history stands still for the crew members entombed there. Shirts and shoes are required; children must be at least 45 inches tall. Cost: $15 adult, $13 child (limit 100 people). 7.1/Adult, 7.2/child. 8:45to12:45 AM. Arizona Memorial Excursion. (See 6.1 for details.) 8.1/Adult, 8.2/child. 10 AM to 2 PM. Arizona Memorial Excursion. (See 6.1 for details.)

9.1/Adult, 9.2/child. 7:30 AM to 3:45 PM. Grand Circle Island Tour. Sights on this all-day tour of Oahu will include Diamond Head Crater, Kahala resiThursday, Dec. 14 dential area, Hanauma Bay, Blowhole, and 1.0/Adult 8:15 AM to 2 PM. Hawai- Sandy Beach. A visit to Nuuanu Pali Lookian Ocean Thrills. The only floating is- out will provide a panoramic view. Other land of its kind, featuring jet skis, race memorable sights will include Kaneohe boats, bumper boat soccer, water gun bat- Bay, Byodo-In Temple, Waimea Bay, and tle boats, kayaking, paddle boats, and pineapple and sugarcane fields. Cost: $41 more. Barbecue lunch is included. Cost: adult, $19 child (does not include lunch; limit 100 people). $59 adult, no children (limit 50 people).

10.1/Adult, 10.2/child. 9 AM to 1 PM. Deluxe Little Circle Island Tour. This 60-mile tour shows many moods of 3.1/Adult, 3.2/child. 9 AM to 3:45 Hawaii—tranquil coves, rolling surf, PM. Stars and Stripes Tour. Visit breakers crashing against the rocky cliffs, where World War II began and ended for and lush tropical forests. Stops will inthe U.S. Board the Mighty MO for a special clude Diamond Head, Pali Lookout, and guided tour. Leave Pearl Harbor and drive Makapuu Lookout. Cost: $23 adult, $20 into historic Honolulu to Punchbowl. After child (limit 100 people). 2.0/Adult 11:50 AM to 6 PM. Hawaiian Ocean Thrills. (See 1.0 for details.)

OCTOBER 2,2000 C&EN 6 3

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program

ll.l/Adult, 11.2/child. 1 to 6 PM. Deluxe little Circle Island Tour. (See 10.1 for details.)

18.1/Adult, 18.2/child. 8:45 to 12:45 AM. Arizona Memorial Excursion. (See 6.1 for details.)

12.1/Adult, 12.2/child. 11:50 AM to 10:30 PM. Polynesian Cultural Center. (See 4.1 for details.)

19.1/Adult, 19.2/child. 10 AM to 2 PM. Arizona Memorial Excursion. (See 6.1 for details.)

Saturday, Dec. 16

20.0/Adult 8:15 AM to 2 PM. Hawaiian Ocean Thrills. (See 1.0 for details.)

13.1/Adult, 13.2/child. 4:45 AM to 8:30 PM. Hawaii—Grand Circle Island Tour. An island of wonder and diversity, see everything from the volcano to black-sand beaches and tropical rain forests. Stops made will be Rainbow Falls, Kilauea Iki Crater, Thurston Lava Tube, Hawaiian Volcano Observatory, Jagger Museum, Volcano House, Place of Refuge, Punaluu Black Sand Beach, an orchid garden, and Big Island Candies. Cost: $168 adult, $161 child (does not include lunch; includes round-trip transfer in Honolulu, airfare, and admission into national parks; limit 50 people). 14.1/Adult, 14.2/child. 4:45 AM to 6:30 PM. Hawaii—One-Day Volcano Tour. Experience the Hawaii Volcanoes National Park adventure tour where participants will be taken as close to the lava from the current eruptions as Civil Defense will allow. Stops will include a macadamia nut factory, Hawaii Volcanoes National Park, Jagger Museum, Volcano House, Kalapana, an orchid garden, and Rainbow Falls. Cost $168 adult; $161 child (does not include lunch; includes roundtrip transfer in Honolulu, airfare, and admission into Hawaii Volcanoes National Park; limit 50 people). 15.1/Adult, 15.2/child. 5:30 AM to 7:30 PM. Maui—The Valley Isle Tour. From natural wonders to luxurious resorts, participants will fly to Kahului and drive to the top of the Haleakala Crater—10,000 feet above sea level. The tour will continue to Iao Valley and Old Lahaina Town, once the capital of Hawaii's kingdom. Cost: $168 adult, $161 child (does not include lunch; includes round-trip transfer in Honolulu, airfare, and admission into Haleakala National Park; limit 50 people). 16.1/Adult, 16.2/child. 5:30 AM to 7 PM. Kauai—The Garden Isle Tour. The island of enchantment! Visit spectacular Waimea Canyon. Cruise up the Wailua River to the romantic Fern Grotto in addition to enjoying many other stunning scenic attractions. Cost: $168 adult, $161 child (does not include lunch; includes round-trip transfer in Honolulu, airfare, and admission for the Wailua River Boat Cruise; limit 50 people). 17.1/Adult, 17.2/child. 6:30 to 10:30 AM. Arizona Memorial Excursion. (See 6.1 for details.) 64 OCTOBER 2,2000 C&EN

21.0/Adult 11:50 AM to 6 PM. Hawaiian Ocean Thrills. (See 1.0 for details.) 22.1/Adult, 22.2/child. 8:30 AM to 11:25 PM. Waikild Trolley Tours. Your all-day/evening pass includes boarding and reboarding privileges at popular attractions and shopping destinations throughout Oahu. Thirty-seven great stops including Hilo Hattie, Kahala Mall, Ala Moana Shopping Center, Bishop Museum, Sea Life Park, Maui Divers, and more. Cost: $18 adult, $8.00 child (no limit).

6:30 PM. Hawaii—One-Day Volcano Tour. (See 14.1 for details.) 33.1/Adult, 33.2/child. 5:30 AM to 7:30 PM. Maui—The Valley Isle Tour. (See 15.1 for details.) 34.1/Adult, 34.2/child. 5:30 AM to 7 PM. Kauai—The Garden Isle Tour. (See 16.1 for details.) 35.1/Adult, 3 5 . 2 / c h i l d . 6:30 to 10:30 AM. Arizona Memorial Excursion. (See 6.1 for details.) 36.1/Adult, 3 6 . 2 / c h i l d . 8:45 to 12:45 AM. Arizona Memorial Excursion. (See 6.1 for details.) 37.1/Adult, 37.2/child. 10 AM to 2 PM. Arizona Memorial Excursion. (See 6.1 for details.)

Sunday, Dec. 17

38.1/Adult, 38.2/child. 11:50 AM to 10:30 PM. Polynesian Cultural Center. (See 4.1 for details.)

23.1/Adult, 23.2/child. 4:45 AM to 8:30 PM. Hawaii—Grand Circle Island Tour. (See 13.1 for details.)

39.1/Adult, 39.2/child. 9 AM to 3:45 PM. Stars and Stripes Tour. (See 3.1 for details.)

24.1/Adult, 24.2/child. 4:45 AM to 6:30 PM. Hawaii—One-Day Volcano Tour. (See 14.1 for details.)

40.1/Adult, 40.2/child. 8:30 AM to 11:25 PM. Waikiki Trolley Tours. (See 22.1 for details.)

25.1/Adult, 25.2/child. 5:30 AM to 7:30 PM. Maui—The Valley Isle Tour. (See 15.1 for details.)

41.1/Adult, 41.2/child. 4:20 to 9:30 PM. Ali'i Kai Catamaran—Dinner & Dance. (See 30.1 for details.)

26.1/Adult, 26.2/child. 5:30 AM to 7 PM. Kauai—The Garden Isle Tour. (See 16.1 for details.)

Tuesday, Dec. 19

27.1/Adult, 27.2/child. 9 AM to 1 PM. Deluxe Litde Circle Island Tour. (See 10.1 for details.) 28.1/Adult, 28.2/child. 1 to 6 PM. Deluxe Litde Circle Island Tour. (See 10.1 for details.) 29.1/Adult, 29.2/child. 8:30 AM to 11:25 PM. Waikiki Trolley Tours. (See 22.1 for details.) 30.1/Adult, 30.2/child. 4:20 to 9:30 PM. Ali'i Kai Catamaran—Dinner & Dance. Take a sunset dinner cruise off the shores of Waikiki. Savor cocktails as the sun sets in the west and dine on a bountiful buffet, then enjoy the Polynesian show and live music and dancing. Cost: $49 adult, $29 child (limit 100 people). Monday, Dec. 18 31.1/Adult, 31.2/child. 4:45 AM to 8:30 PM. Hawaii—Grand Circle Island Tour. (See 13.1 for details) 32.1/Adult, 32.2/child. 4:45 AM to

42.1/Adult, 42.2/child. 11:50 AM to 10:30 PM. Polynesian Cultural Center. (See 4.1 for details.) 43.1/Adult, 43.2/child. 8:30 AM to 11:25 PM. Waikiki Trolley Tours. (See 22.1 for details.) Wednesday, Dec. 20 44.1/Adult, 44.2/child. 4:45 AM to 8:30 PM. Hawaii—Grand Circle Island Tour. (See 13.1 for details.) 45.1/Adult, 45.2/child. 4:45 AM to 6:30 PM. Hawaii—One-Day Volcano Tour. (See 14.1 for details.) 46.1/Adult, 46.2/child. 5:30 AM to 7:30 PM. Maui—The Valley Isle Tour. (See 15.1 for details.) 47.1/Adult, 47.2/child. 5:30 AM to 7 PM. Kauai—The Garden Isle Tour. (See 16.1 for details.) 48.1/Adult, 48.2/child. 8:30 AM to 11:25 PM. Waikiki Trolley Tours. (See 22.1 for details.)

ADVANCE

REGISTRATION POLY MILLENNIAL 2000 DEADLINE/REFUND POLICIES:

PACIFICHEM 2000 DEADLINE/REFUND POLICIES:

Advance Registration Deadline: Deadline for full refund: Deadline for partial refund: No refund* after

Advance Registration Deadline: Written cancellation of registration after October 15,2000 will cost an additional $50.00

November 10,2000 November 17. 2000 November 24.2000 November 24. 2000

The 2000 International Chemical Congress of Pacific Basin Societies Sheraton Waikiki, Honolulu, Hawaii, December 14-19, 2000

October 15. 2000

POLY Millennial 2000 Hilton Waikoloa Villages, Hawaii, December 9-13, 2000

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OCTOBER 2,2000 C&EN 6 5

AGRO/TECHNICAL PROGRAM

This technical program contains the most up-to-date information that was available at C&EN press time. However, the program likely will change in the 10 weeks before the start of the meeting, so please check the online program at http://www.acs.org/ meetings/pacific2000A

AGRO

10:05—19. Molecular design of fine chemicals from lignin. S. Hirose, H. Hyoe 10:35—20. Model studies on the bioconversion of com fiber to xylitol. F. Agblevor, T. Walther, P. Hensirisak 11:05—21. Possible application of watersoluble cellulose derivatives. T. Hatakeyama, K. Nakamura

THURSDAY AFTERNOON

AREA 01-AGROCHEMISTRY

Hilton Hawaiian Village lolani Suite lll/IV, 2nd Floor, Tapa Conference Center

THURSDAY MORNING

Functional Food Ingredients: Trends and Prospects (111)

Hilton Hawaiian Village lolani Suite lll/IV, 2nd Floor, Tapa Conference Center Functional Food Ingredients: Trends and Prospects (111)

F. Shahidi, Presiding 8:05—1. Functional food ingredients: The parts of the sum. I. Benzie 8:25—2. Development of novel hybrid purification and separation processes to purify and concentrate nutraceuticals and functional food. E. Ponnampaiam 8:45—3. Sources of novel ingredients for nutritional industry. P. Kolodziejczyk 9:05—4. Rapid analytical methods for food ingredients using MALDI-MS. P. Sporns 9:25—5. Membrane/supercritical fluid technology for production of functional lecithin products. S. Koseoglu, L. Teberikler, A. Akgerman 9:45—6. Modulation of intestinal nutrient transporters by food factors. M. Shimizu, Y. Miyamoto 10:05—7. Milk and egg proteins as functional food ingredients: Trends and prospects. E. Li-Chan 10:25—8. Enzymatic synthesis of DHAcontaining structured lipids. C. C. Akoh, V. Yankah 10:45—9. Docosahexaenoic acid (DHA) as a new functional food ingredient. D. Kyle, J. Hoffman, C. Becker 11:05—10. Wasabi as functional food: An overview. H. Masuda Hilton Hawaiian Village Coral Ballroom V-VI Chemical Ecology and Biochemistry of Plant Resistance to Diseases and Nematodes (165)

G. Basarab, Presiding 8:05—11. Essential oil components: More than flavors and perfumes. R. Tsao, T. Zhou 8:45—12. Search for biologically active substances of plants by using the electrophysiological method with excitatory plant cells of Mimosa pudica. S. Nakajima, C. Sogawa, M. Matsumoto, K. Takemoto, M. Okamoto, K. Tokumura, N. Baba 9:25—14. Altemaria blackspot phytotoxins: Detoxification as a disease resistance marker. M. Pedras, I. Zaharia, Y. Zhou Hilton Hawaiian Village lolani Suite l/lI, 2nd Floor, Tapa Conference Center Fuels and Chemicals from Biomass (221)

J. Meister, Presiding 8:05—16. Liquid crystals, engineering plastics, and biodegradable polymers from biomass. H. Hatakeyama 9:05—17. Oligosaccharides from chitin and chitosan obtained by enzymatic hydrolysis. S. Alba, H. Zhu, E. Muraki 9:35—18. Possible applications of hybrids of marine polysaccharides. S. Tokura, H. Tamura

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OCTOBER 2, 2000 C&EN

T. Osawa, Presiding 1:05—22. Tocopherols and tocotrienols: A new perspective on vitamin E. A. Papas 1:25—23. Protective role of sesame lignins in oxidative stress. T. Osawa 1:45—24. Anticarcinogenic activity of flavones and flavonols at the dietary levels. K. Kanazawa 2:05—25. Physiological activity of cacao polyphenols. N. Osakabe, S. Baba, M. Yamagishi, T. Takizawa, J. Terao, T. Osawa 2:25—26. Evidence for antioxidant activity from a standardized North American ginseng (Panax quinquefolius) root extract. D. Kitts, C. Hu 2:45—27. Phytochemicals in soybeans: Antinutritional factors or nutraceuticals? C. Wang 3:05—28. Effect of processing on the nutraceutical quality of firm tofu. T-C. Huang, H-Y. Fu, C-T. Ho 3:25—29. Barley p-glucan as a functional ingredient. F. Temelli 3:45—30. Functional components in noni fruits {Morinda citrifolia). C-T. Ho, M. Wang 4:05—31. Compositional variations of dietary supplements containing Hypericum perforatum. C. Ang, F. Liu Hilton Hawaiian Village Coral Ballroom V-VI Chemical Ecology and Biochemistry of Plant Resistance to Diseases and Nematodes (165)

R. Tsao, Presiding 1:05—32. Natural product nematocides of microbial origin: A review. H. G. Cutler, S. J. Cutler 1:45—33. Multichemical defense of Olea europacca against microbial attack. I. Kubo 2:25—35. Antifungal compounds produced by ginseng root quality-improving fungus KGPF 305. L. Ten, M-J. Lee, M-K. Lee, L. Larina, J. H. Yoon 3:05—36. Peptide mimic of pectin fragments: Universal elicitor of HR? V. Matt, K. Sharrock, T. Reglinski Hilton Hawaiian Village lolani Suite l/l I, 2nd Floor, Tapa Conference Center Fuels and Chemicals from Biomass (221)

J. Saddler, Presiding 1:05—37. Synergies for production of ethanol and chemical coproducts from biomass. C. Wyman 1:35—38. Fuel ethanol from softwoodprocess development using a PDU. G. Zacchi, M. Galbe, K. Stenberg, J. Soderstrom 2:05—39. Conversion of cotton gin waste to ethanol by E. coli K011. F. Agblevor, T. Jeoh 2:35—40. Ethanol production from rice straw hydrolysate by immobilized recombinant Zymomonas mobilis in a fluidized-bed reactor. N. Nghiem, M. Fatigati, B. Davison, T. Cofer, D. Planas

3:05—41. A comparison between hot liquid water and steam pretreatment of biomass. S. Allen, D. Schulman, J. Lichwa, M. Antal Jr., M. Laser, L. Lynd 3:35—42. Metabolic engineering technologies for improved production of ethanol and lactic acid. R. Bothast, B. Dien, N. Nichols, C. Skory

61. Relationship between the structure and antioxidant activity of phospholipids. H. Saito Hilton Hawaiian Village Coral Ballroom V-VI Chemical Ecology and Biochemistry of Plant Resistance to Diseases and Nematodes (165)

FRIDAY MORNING

R. Hill, Presiding


8:05—62. Stress metabolites and phytoalexins of woody and herbaceous wild plants. F. Hanawa 8:45—63. Understanding plant chemical defenses: Reactions of important fungal pathogens to cruciferous phytoalexins. M. Pedras, P. Ahiahonu, F. Okanga 9:25—64. Synthesis and characterization of toxic compounds in biological control. R. Boulanger, D. McNally, K. Wurms, T. Avis, R. Belanger 10:05—65. Induced synthesis of fungitoxic terpenoids in cotton roots by seed treatment with the biocontrol agent Trichoderma virens. C. Howell, L. Hanson, R. Stipanovic, L. Puckhaber 10:45—66. Increasing resistance to plant pathogens in cotton utilizing biotechnology. R. Stipanovic, A. Bell, J. Liu, C. Benedict, L. Puckhaber, C. Magill, K. Rathore, F. Dayan

Functional Food Ingredients: Trends and Prospects (111)

T. Shibamoto, Presiding 8:05—43. Promising food phytochemicals for cancer prevention. H. Ohigashi, A. Murakami, Y. Nakamura, K. Koshimizu 8:25—44. Levels and effects of orange juice phytochemicals. A. A. Franke, R. V. Cooney, S. M. Henning, L. A. Okinaka, L J. Custer 8:45—45. Chemopreventive and chemotherapeutic potential of capsaicin, a major pungent ingredient of hot chili pepper. Y-J. Surh 9:05—46. Suppressive effects of citrus auraptene on pnorboi ester- and endotoxininduced inflammatory responses. A. Murakami, Y. Nakamura, T. Tanaka, K. Koshimizu, H. Ohigashi 9:25—47. Inhibitory effect of flavonoids isolated from Japanese radish leaves on diabetic cataract formation. Y. Morimitsu, M. Tamura, E. Hashizume, T. Kamrya, T. Osawa 9:45—48. Grapeseed extract: In vitro and in vivo antioxidant studies and effect after human supplementation. J. Vinson, J. Proch, P. Bose 10:05—49. Combined effects of sesamin and tocopherol on the prevention of MCAinitiated transformation of 10T1/2 cells. Y. Tanaka, R. V. Cooney 10:25—50. Biological activities of phytoestrogens. L. Plhak 10:45—51. Properties and applications of yellow mustard mucilage and synergistic effects with galactomannans in foods. M. Eskin, S. Cui 11:05—52. Phytosterols as functional food ingredients. J. Zawistowski

Hilton Hawaiian Village lolani Suite l/l I, 2nd Floor, Tapa Conference Center Fuels and Chemicals from Biomass (221)

H. Hatakeyama, Presiding

Hilton Hawaiian Village Coral Ballroom III, 6th Floor, Mid-Pacific Conference

8:05—67. Novel reactor concept based on very dilute sulfuric acid hydrolysis of hardwood for the improved production of fuels and chemicals. R. Torget, N. Nagle, R. Elander 9:05—68. Purification of acetic acid produced by anaerobic fermentation of glucose. M. Cheryan, S. Katikaneni 9:35—69. Bioconversion of sucrose into cellobiose. M. Kltaoka, K. Hayashi 10:05—70. Control of thermodynamic properties of akjinic acid/water systems. M. Takahashi, Y. Kawasaki, K. Komiya 10:35—71. Quality of edible oils. F. Shahidi 11:05—72. Reaction between woody waste materials and titanium in self-propagating high-temperature synthesis to afford TiC ceramics. T. Ashitani, R. Tomoshige, K. Sakai

Quality of Fresh and Processed Food (139)

FRIDAY AFTERNOON

Poster Session 9:00-11:00 53. Effect of barrel temperature and feed moisture content on volatile formation in extruded soy flour. C-T. Ho, R. Lundy 54. Evaluation of water washes for removal of organophosphorous pesticides from Maine wild blueberries. B. Perkins, R. Hazen, R. Bushway, A. Bushway 55. Development of heat transfer and color/ texture models for surimi seafood during thermal pasteurization. J. Park, J. Jaczynski 56. Antioxidatjve peptides in porcine myofibrillar protein hydrolysate by protease treatment. A. Saiga, T. Nishimura 57. Characterization of glycans in bovine lactoferrin isoform, lactoferrin-A. Z. Wei, T. Nishimura 58. Studies on microscopic observation of rice cakes. M. Onodera, M. Kusakabe, T. Takeuchi, T. Suzuki, S. Takesono, K. Toda, H. Kataoka 59. Studies on the flavor of vinegar, especially on its volatile components. S. Furukawa, R. Kuramitsu 60. Fingerprinting of enzyme-modified cheese flavors and peptides by GC/MS and LC/MS. B. Lee, S. Haileselassie, B. Stewart, V. A. Yaylayan

The Organizing Committee requests that there be no smoking in meeting rooms or committee meetings

Hilton Hawaiian Village lolani Suite lll/IV, 2nd Floor, Tapa Conference Center Quality of Fresh and Processed Food (139)

A. Spanier, Presiding 1:05—73. Importance and use of descriptive sensory analysis in quality assessment. E. Chambers, D. Chambers 1:25—74. Gas chromatography sniffing port analysis and its importance in food quality control. J. Roozen, S. Van Ruth 1:45—75. Screening for sensory quality in foods using solid-phase microextraction tandem mass spectrometry. C. Grimm, S. Lloyd, T. Braggins 2:05—76. Quality of microwave processed and prepared foods. S. Risch 2:25—77. Irradiation of apple cider: Impact on flavor quality. T. Boylston, H. Wang, C. Reitmeier, B. Glatz 2:45—78. Quality modification of food by extrusion processing. T-C. Lee, C. Gregson, D. Zasypkin 3:05—79. Stability of aseptic flavored milk beverages. R. Kadan 3:25—80. Quality assessment of a low-salt soy sauce made of a salty peptide or its related compounds. R. Kuramitsu 3:45—81. Sensory and peptides characteristics of soy sauce fractions obtained by ultrafiltration. A. Apriyantono, D. Setyaningsih, P. Hariyadi, L. Nuraida

Hilton Hawaiian Village Coral Ballroom V-VI Industrial Enzymes (145)

S. Utsumi, Presiding 1:05—82. Industrial enzymes from aquatic organisms. N. Haard 1:35—83. Cold-active enzymes from coldadapted microorganisms. T. Kurihara, L. Kulakova, A. Galkin, D-W. Choo, Y-L. Wei, T. Suzuki, N. Esaki 2:05—84. Industrial enzymes for oily substrates. C. Hou 2:35—85. Prospects for potato tuber lipolytic acyl hydrolase (LAH) as an industrial enzyme. K. Parkin, P. Pinsirodom, C. Anderson 3:05—87. Roles of Ca and sulfhydryl reductant in polymerization of soybean glycinin catalyzed by mammalian and microbial transglutaminases. G-Y. Zhang, S. Matsumoto, Y. Hayashi, Y. Matsumura, T. Mori 3:35—90. Production of a-amylase and xylanase by solid substrate fermentation. G. Szakacs, B. Bogar, J. Szendefy, L. Christov, R. Tengerdy Hilton Hawaiian Village lolani Suite l/lI, 2nd Floor, Tapa Conference Center Fuels and Chemicals from Biomass (221)

D. Gregg, Presiding 1:05—91. Fermentation of sugar beet pulp for enzyme production. L. Olsson, E. Palmqvist, K. Hansen, T. Christensen 1:35—92. Production of substrate-specific enzyme complexes by solid substrate fermentation for hydrolysis of cellulose- and hemicellulose-containing materials. G. Szakacs, R. Tengerdy 2:35—93. Novel chromogenic substrates for glycosidase-coupled assays of ot-glucuronidase and feruloylesterase. P. Biely, J. Hirsch, M. Mastihubova, D. La Grange, W. Van Zyl, B. Prior 3:05—94. Continuous conversion of phenolic compounds with immobilized fungal laccases. G. Guebitz, E. Abadulla, A. CavacoPaulo, K-H. Robra 3:35—95. Influence of carbon catabolite repression and redox balance in xylose fermenting Saccharomyces cerevisiae strains. C. Roca, J. Nielsen, L. Olson 4:00—96. Production of lactic acid from biomass hydrolysate by a coculture of lactic acid bacteria. M. Taniguchi, T. Tokunaga, T. Tanaka

FRIDAY EVENING Hilton Hawaiian Village lolani Suite 11 l/l V, 2nd Floor, Tapa Conference Center Functional Food Ingredients: Trends and Prospects (111)

F. Shahidi, Presiding 7:05—97. Antioxidative defense: Mechanisms and interaction between nonnutrient and nutrient antioxidants. L. Skibsted 7:25—98. Antioxidant activity of aroma chemicals formed in brewed coffee. T. Shibamoto, M. Fuster, A. Mitchell, H. Ochi 7:45—99. Effect of antioxidants to thermal deterioration of citral. T. Ueno, H. Masuda, S. Muranishi, S. Irisawa, O. Nishimura, K. Adachi, C-T. Ho 8:05—100. Potential cardioprotective properties of chocolate procyanidins in humans. C. Keen, D. Schramm, C. Fragal, J. Wang, H. Schmitz 8:25—101. Antioxidant activity of quercetin metabolites present in blood plasma. J-H. Moon, T. Tsushida, K. Nakahara, J. Terao 8:45—102. Bioactivity of thiosulfinates from alliums. K. Parkin, C. Shen, H. Xiao, S. Rajan, A. Verma, W. Briggs, I. Goldman 9:05—103. Importance of anthocyanins as an antioxidant under oxidative stress in rats. T. Tsuda, F. Horio, T. Osawa 9:25—104. Bioactive peptides derived from food proteins. M. Yoshikawa

Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters

The technical program is organized into 10 subject areas, which are listed here followed by their acronyms. The area coordinators for each of the main sponsors of Pacifichem 2000 are listed as welL Agrochemistry (AGRO) Sara J. Risch (ACS), Jack Saddler (CSC), Hajime Iwamura (CSJ), Ivan Kennedy (RACI) Analytical Chemistry (ANYL) Fred Hawkridge (ACS), Michael Blades (CSC), Yoshio Umezawa (CSJ), Bob Cattrall (RACI) Bioscience & Technology (BIOS) Fred Heineken (ACS), John Vederas (CSC), Masuo Aizawa (CSJ), Graham Johnston (RACI) Chemistry & the Community (COMM) Thomas R. Wildeman (ACS), Josef Takats (CSC), Haruo Hosoya (CSJ), Naoya Yoda (CSJ), Dennis Hogan (NZIC), Charles Fogliani (RACI) Environmental Chemistry (ENVR) V. Dean Adams (ACS), Elisabeth Dixon (CSC), Masatoshi Morita (CSJ) Inorganic Chemistry (INOR) Robert H. Crabtree (ACS), Michael Fryzuk (CSC), Kazuyuki Tatsumi (CSJ), Warren Roper FRS (NZIC), Richard Keene (RACI) Macromolecular Chemistry (MACR) Alan D. English (ACS), Almeria Natansohn (CSC), Seiichi Nakahama (CSJ), Brian Halton (NZIC), Tom Davis (RACI) Medicinal Chemistry (MEDI) Annette M. Doherty (ACS), Robert Young (CSC), Masakatsu Shibasaki (CSJ), W. (Bill) Denny (NZIC), Margaret Wong (RACI) Organic Chemistry (ORGN) Amos Smith (ACS), Mark Lautens (CSC), Shinji Murai (CSJ), Hiizu Iwamura (CSJ), Brian Halton (NZIC), Roy Jackson (RACI) Physical & Theoretical Chemistry (PHYS) Marsha I. Lester (ACS), Adam Hitchcock (CSC), Okitsugu Kajimoto (CSJ), Brian Halton (NZIC), Brian Yates (RACI)

Organization Key American Chemical Society (ACS) Canadian Society for Chemistry (CSC) Canadian Society for Chemical Engineering (CSChE) Centre for Applications of Isotopes & Radiation, Indonesia (CAIR-BATAN) Chemical Society of Japan (CSJ) Chemical Society, Taipei (CST) Chemical Society of the South Pacific (CSSP) Chemical Society of Thailand (CST) Chemical Society of Vietnam (CSV) Chinese Chemical Society (CCS) Colegio Panameno de Quimicos (CPQ) Hong Kong Chemical Society (HKCS) Institiut Kimia Malaysia (KM) Institute of Chemistry, Papua New Guinea (ICPNG) Integrated Chemists of the Philippines (ICP) Korean Chemical Society (KCS) New Zealand Institute of Chemistry (NZIC) Polymer Society of Taiwan (PST) Royal Australian Chemical Institute (RACI) Russian Mendeleev Chemical Society (RMCS) Singapore National Institute of Chemistry (SNIC) Society of Chemical Engineers, Japan (SChEJ) Sociedad Chilena de Quimica (SCQ) Sociedad Quimica de Mexico (SQM) Sociedad Quimica del Peru (SQP)

OCTOBER 2, 2000 C&EN 6 7

AGRCVTECHNICAL PROGRAM

9:45—105. Antioxidative and antiatherosclerotic properties of rosmarinic acid, a functional ingredient of rosemary. Y. Narto, J. Ochiai, N. Matsumoto, N. Fujita, H. Manabe, M. Uemura, N. Yoshida, S. Oka, T. Miyoshi, T. Yoshikawa Hilton Hawaiian Village lolani Suite l/lI, 2nd Floor, Tapa Conference Center Fuels and Chemicals from Biomass (221)

J. Meister, Presiding 7:05—106. Biodiesel fuel from vegetable oil wastes by supercritical methanol. S. Saka, D. Kusdiana 7:35—107. HPLC and GC/MS comparative analyses of phenolic compounds and flavonoids in maple products. S. Kermasha, I. Deslauriers, J. Oumont 8:35—108. New approach to agricultural biomass: Preparation and mechanical properties of regenerated cellulose fibers from rice straw. T-W. Son, S-K. Lim, B-K. Park, M-J. Kim 9:05—109. Reduced-risk pesticides based on plant essential oils for integrated fruit crop management. D. McArthur, E. Gelok, A. Wan, A. Boss, M. Isman 10:05—111. Environmental fate of lignosulfonates. R. Northey, J. Nelson

SATURDAY MORNING Hilton Hawaiian Village lolani Suite 11 l/l V, 2nd Floor, Tapa Conference Center Quality of Fresh and Processed Food (139)

T. J. Braggins, Presiding 8:05—112. Multiquality enhancement of muscle food. A. Spanier, B. Berry, R. Roma nowski, J. Eastridge, E. Paroczay, M. Solomon 8:25—113. Effect of animal production on meat quality. M. Solomon 8:45—114. Quality aspects of pork meat and its nutritional impact. F. Toldra, M. Rubio, J. Navarro, L. Cabrerizo 9:05—115. Effect of extended chilled storage on the odor and flavor of sheep meat. T. Braggins, M. Agnew, D. Frost, C. Podmore, T. Cummings 9:25—116. Interaction of disulfide flavor compounds with proteins in model systems and in food products. D. Mottram, R. Adams, J. Parker 9:45—117. Chemistry of quality enhancement in low-value fish. N. Howell 10:05—118. Polyol blends for cryoprotection of surimi and natural actomyosin from ling cod (Ophiodon elongatus) during frozen storage. E. Li-Chan, Y. Sultanbawa 10:25—119. Enzymatic hydrolysis of lipids in muscle of fish and shellfish during cold storage. M. Kaneniwa, M. Yokoyama, Y. Murata, R. Kuwahara 10:45—120. Influence of endopeptidases and aminopeptidases on the production of taste peptides and free amino acids in muscle foods. T. Nishimura Hilton Hawaiian Village Coral Ballroom V-VI Industrial Enzymes (145)

S. Utsumi, Presiding 8:05—121. Strategies to increase the functionality of food-related enzymes. R. Yada, B. Bryksa, K. G. Payie, M. Yoshimasu, T. Tanaka 8:35—122. Engineering new functionalities into an enzyme scaffold: Generation of a cyclomaltodextrin-glucano-transferase-like enzyme from a maltogenic ct-amylase, and a phospholipase A1-type enzyme from a triacylglycerol lipase. A. Svendsen 9:05—123. The Cetus process revisited: Pyranose oxidase for the production of carbohydrate-based food ingredients. D. Haltrich, C. Leitner, B. Nidetzky, K. Kulbe, J. Vole 9:35—124. Hydrolysis of casein-derived bitter peptides by peptidases. J. Steele 10:05—125. Structural comparison of soybean, barley, and Bacillus cereus p-amylases. B. Mikami, N. Yoshigi, H-J. Yoon, M. Adachi, E. Sarikaya, A. Sekine, S. Utsumi

68


10:35—126. X-ray crystallographic analysis of Bacillus cereus p-amylase and its C-terminal starch binding domain. H-J. Yoon, M. Adachi, A. Hirata, T. Kage, E. Sarikaya, S. Utsumi, B. Mikami 11:05—127. Deletion and insertion of a 200residue peptide at or near the active-site domain of p-galactosidases. T. Nakayama, S. Hasegawa, S. Iguchi, M. InoharaOchiai, Y. Goto, T. Ashikari, Y. Shibano, T. Nishino Hilton Hawaiian Village Honolulu II, 2nd Floor, Tapa Conference Center Chemical Modification, Properties, and Usage of Ugnin (152)

T. Hu, Presiding 8:05—128. Transforming alkylated and acylated Kraft lignins into thermoplastics. S. Sarkanen, Y. Li 8:45—129. Thermoplastic and rubber compounds based upon lignins and reactive processing technology. R. Mulhaupt, J. Nitz, H. Semke 9:15—130. Melt spun fibers of lignin/ synthetic polymer blends. J. Kadla, R. Venditti, R. Gilbert 9:45—131. Synthesis of poly[(lignin-o-(1chloroethylene)] under a partial factorial, experimental design. V. Shah, J. Meister 10:15—132. Lignin structure and wood properties of a loblolly pine that is heterozygous for the cad-n1 mutation. J. Scott, D. O'Malley, J. Kadla

SATURDAY AFTERNOON Hilton Hawaiian Village Tapa Ballroom III, 2nd Floor, Tapa Conference Center Functional Food Ingredients: Trends and Prospects (111) Poster Session 1:00-3:00 133. Biochemical characterization of rosmarinic acid as an effective inhibitor for hyaluronidase. K. Ippoushi, H. Itou, K. Azuma, H. Higashio 134. Interaction between dietary lipid peroxide and pantethine on the drugmetabolizing system and morphological state in rat liver cell. N. Hiramatsu, A. Ohara, M. Natake 135. Maillard reaction-based glycosylation of lysozyme: Effect on antimicrobial properties. C. Seaman, A. Yousif, S. Nakai 136. Minor components of edible oils serve as nutraceuticals. F. Shahidi 137. Antioxidant and prooxidant activity of a bamboo leaf extract. C. Hu, Y. Zhang, D. Kitts 138. Application of electron-beam irradiation and dietary vitamin E in ground beef quality preservation. P. Peon, P. Dubeski, D. Kitts 139. Quantification of soluble tannins in canola/rapeseed hulls by UV spectroscopy. M. Naczk, J. Pink, R. Amarowicz, D. Pink, F. Shahidi 140. Suppressive effects of lemon flavonoid on oxidative stress in exercise-induced rats. Y. Miyake, K. Yamamoto, Y. Kato, Y. Shimomura, T. Osawa 141. Antimutagenicity of anthocyanins. A. Ohara, K. Mori, K. Hosokawa, T. Matsuhisa 142. Effects of fermented tumeric intake on oxidative stress in the elderly. N. Inafuku, K. Megumi, K. Yasuhiro, I. Aki. Y. Kawashima, H. Fujiya, T. Osawa, O. Choken 143. Effects of heating and freezing on radical-scavenging activity of vegetables. T. Yamaguchi, M. Murakami, J. Terao, H. Takamura, T. Matoba 144. Protective effects of chlorogenic acid on oxidative stress in large intestinal mucosa of rats. K. Azuma, K. Ippoushi, H. Ito, H. Higashio, J. Terao 145. Marine oils and omega-3 fatty acids as nutraceutjcal ingredients. F. Shahidi 146. Polyphenols compounds and their superoxide-radicai-scavenging activity of Korean moru-ju. K-H. Koh, H-J. Choi, S. Han

Hilton Hawaiian Village lolani Suite lll/IV, 2nd Floor, Tapa Conference Center Quality of Fresh and Processed Food (139)

A. Shihidi, Presiding 1:05—147. Quality of fresh-cut produce. E. Garrett 1:25—148. Quality of fresh citrus fruit. R. Baker, R. Hagenmaier 1:45—149. Textural quality assessment in fresh fruits and vegetables. J. Abbott 2:05—150. Application of fruit and vegetable films to fresh-cut produce. T. McHugh, E. Senesi, C. Olsen 2:25—151. Effect of ozone on food quality. B. Hampson 2:45—152. New monocomponent enzymes for processing of plant food material. L. Kofod, G. Budotfsen, K. Clausen 3:05—153. Quality of edible oils. F. Shahidi 3:25—154. Raw and white sugar quality in food maufacture. L. Edye 3:45—155. Health and nutritional quality of pregerminated brown rice. H. Kayahara, K. Tsukahara, T. Tatai Hilton Hawaiian Village Coral Ballroom V-VI Industrial Enzymes (145)

S. Utsumi, Presiding 1:05—156. Mutation and X-ray crystallographic analysis of soybean p-amylase. M. Adachi, B. Mikami, S. Utsumi 1:35—157. Loop engineering of D-amino acid aminotransferase. Y. Fuchikaml, T. Yoshimura, K. Soda, N. Esaki 2:05—158. New thermo-alkali-stable catalase-peroxidases for the treatment of cellulose fibers bleaching effluents. G. Guebitz, M. Gudelj, A. Paar, K. Robra, A. Cavaco-Paulo 2:35—160. Mechanism of laccase-catalyzed oxidation of /V-hydroxy compounds. F. Xu, H-J. Deussen, K. Li, J. Kulys 3:05—159. Improvement of the reaction at a high temperature for Rhizopus niveus lipase. M. Kohno, W. Kugimiya 3:35—88. New substrates to elucidate the mechanism of action of acetylxylan esterases. P. Biely, M. Mastihubova, G. L. Cote, R. V. Greene Hilton Hawaiian Village Honolulu II, 2nd Floor, Tapa Conference Center Chemical Modification, Properties, and Usage of Ugnin (152)

B. Cole, Presiding 1:05—161. Pulping catalysts from lignin. D. Dimmef, J. Bozell 1:45—162. Catalytic modifications and photostabilization of lignin functional groups. T. Hu, G. Cairns, B. James 2:15—163. Tetrazole ethers from lignin model phenols: Synthesis, crystal structures, and photostability. B. James, A. Lu, T. Hu, D. Osmond 2:45—164. Change in erythro/threo ratio of (J-O-4 structure in stepwisely delignified wood. Y. Matsumoto, T. Sugimoto, G. Meshitsuka 3:15—165. Provenience of lignin reactivity in extended oxygen delignrfication. L. Lucia, A. Ragauskas, R. Yang 3:45—166. Use of potassium octacyanomolybdate as a laccase mediator for lignin oxidation. D. Rochefort R. Bourbonnais, D. Leech, M. Paice Hilton Hawaiian Village Tapa Ballroom III, 2nd Floor, Tapa Conference Center Fuels and Chemicals from Biomass (221) Poster Session 4:00-6:00 167. Application of alginate and phoshorylchitin blend beads for controlled release of drug. Y. Tsuruta, H. Tamura, S. Tokura


168. Preparation of chitosan fiber with acetic acid salt form to bind organic material on the surface. M. Sawada, Y. Tsuruta, H. Tamura, S. Tokura 169. Saccharification of cellulose using a hotcompressed-water flow-type reactor. T. Sakaki, M. Shibata, T. Sumi, S. Yasuda 170. Effects of acid pretreatment and inorganic salt addition on the hydrothermal decomposition of chitin. K. Sakanishi, T. Sakaki, M. Shibata, K. Mukae 171. Preparation of /V-acetylglucosamine from chitin by enzymatic hydrolysis. S. Aiba, H. Zhu, S. Miyaoka, E. Muraki 172. Fractionation and gasification of hemicellulose in kenaf and chinquapin using hot compressed water. N. Hayashi, S. Kumagai, T. Sakaki, M. Nakada, M. Shibata 173. Cellulase enzyme production. Z. Szengyel, K. Reczey, G. Zacchi 174. Production of ginkgolides by callus and cell suspension cultures of icho, Ginkgo biloba. S. Tachibana, K. Itoh, T. Ohta, T. Aruga 175. Recovery of organic substances from tobiko by supercritical isopropanol. J-l. Ozaki, K. Kurita, H. Komata, S. Takigami, A. Oya 176. Production of lactobionic acid by enzyme technology. D. Haltrich, R. Ludwig, C. Galhaup, U. Baminger, B. Nidetzky 177. Screening for novel cellulase-producing fungi on pretreated spruce and willow. G. Szakacs, G. Zacchi 178. Component fractionation of bamboo with hot compressed water heated in three steps. H. Ando, T. Sakaki, Y. Kamino, M. Shibata, Y. Uemura, Y. Hatate 179. Highly efficient degradation of cellulose catalyzed by lanthanide(lll) ions in water under mild conditions. K-l. Seri, H. Ishida, Y. Inoue, T. Sakaki, M. Shibata 180. Rapid microwave pyrolysis of wood. M. Miura, K. Ando, K. Takahashi, S. Tanaka, H. Kaga 181. Thermal and mechanical properties of polyurethane composites containing coffee grounds. D. Kamakura, H. Hatakeyama 182. Thermal and mechanical properties of flexible polyurethane foams having saccharide structure. Y. Asano, H. Hatakeyama 183. Thermal properties of cellulose-based polycaprolactone derivatives. H. Katsurada, H. Hatakeyama 184. Change of viscoelasticity of hyaluronic acid hydrosol by annealing. M. Takahashi, I. Takahiro 185. Effect of oxygen delignification on cellulase adsorption and hydrolysis of lignocellulosic material. S. Duff, C. Kurniawan, W. Cruickshank, K. Draude, P. Thomas 328. Parallel solution phase synthesis on automated platform. K. Machida, A. MacDonald, J. Labadie

SUNDAY MORNING Hilton Hawaiian Village Coral Ballroom V-VI Immunochemical Biomonitoring for Environment Chemicals (5)

I. Kennedy, Presiding 8:05—269. Immunoassays to measure biomarkers of human exposure to toxins. S. J. Gee, B. D. Hammock 8:35—263. Use of fluorescence microbead immunosorbent assays (FMIAs) for pesticide biomonitoring. R. Biagini, C. Striley, D. Murphy, B. Mackenzie, S. Roberston 9:05—267. Saliva biomonitoring of pesticide exposure among applicators using ELISA. C. Lu, L Denovan, C. Hines, R. Fenske 9:30—276. Analysis of urinary phenolic glucuronides by liquid chromatographyimmunoassay and liquid chromatographyelectrospray ionization-tandem mass spectrometry. N. Staimer, G. Zurek, S. Gee, B. Hammock 9:55—272. Immunoassay human exposure studies. J. M. Van Emon, A. W. Reed. J. C. Chuang 10:25—262. Standardization of immunoassays for environmental analysis. B. Hock



Food and Beverage Antioxidants in Health and Disease (202)

Food and Beverage Antioxidants in Health and Disease (202)

J. Vinson, Presiding

E. Niki,

8:05—192. Food antioxidants, biomarkers, and health management. O. Aruoma 8:35—193. Recommendations for ideal vitamin C intake. M. Levine 9:05—194. Lycopene. H. Sies, W. Stahl 9:35—195. Measurement of dietary polyphenols in humans for epidemiologic studies. A. Franke, L. Le Marchand, G. Maskarinec, L. Custer 10:05—196. Flavonoids and phenolic acids in foods and their contribution to the average dietary intake in Finland. J. Kumpulainen, P. Mattila, J. Astoia, M. Ovaskainen 10:35—197. Factors influencing the absorption of flavonoids across the small intestine. C. Rice-Evans 11:05—198. Does oxidative stress increase vitamin E requirements? M. Traber

1:05—238. Vitamin E supplementation and cardiovascular disease risk factors in diabetic patients. S. Jain 1:35—239. Antioxidants and the eye. J. Trevithick, M. Hirst, J. Wahlman 1:55—240. Antioxidative polyphenols of Theobroma cacao. N. Osakabe, M. Natsume, A. Yasuda, T. Takizawa, T. Hatano, T. Yoshida, K. Kondo, T. Osawa 2:15—241. Cancer chemopreventive effects of selected dietary antioxidants. Y-J. Surh 2:45—242. Brain oxidative damage and antioxidants: Posttraumatic brain disorders and their management. A. Mori 3:15—243. Health effects of wine antioxidants. A. Water-house 3:45—244. Potential for a novel IH636 grapeseed proanthocyanidin antioxidant in functional food and beverage formulations. D. Bagchi, S. Ray, M. Bagchi, E. Hickey 4:15—245. Green and black tea and heart disease. J . Vinson, N. Wu, Y. Dabbagh, J. Proch

Hilton Hawaiian Village Rainbow III, Lower Level, Rainbow Tower Agrochemistry General (01G-O) D. Klein,

Presiding

8:05—199. Development of an enzymelinked immunosorbent Assay for the insecticide imidacloprid. H. J. Kim, S. Liu, Q. X. U 8:25—200. Genome wide expression monitoring of metabolically engineered strains of S. cerevisiae with improved ethanol yield. J. Nielsen, C. Bro, B. Regenberg, C. Roca, L. Olsson 8:45—201. Supercritical fluid extraction and accelerated solvent extraction methods for spinosad in soil. J. A. Licudine, Q. X. Li 9:05—226. Improving peroxide bleaching by minimizing the Mn-induced peroxide decomposition. Y. Ni 9:25—202. GC-MS-MS for analysis of environmental samples. D. M. Klein, P. Hamlett 9:45—227. Analysis of carbohydrates in cigarette papers using ion chromatography and capillary electrophoresis with amperometric detection. A. Zemann, W. Gutleben, T. Kappes, P. Hauser, B. Galliker 10:05—228. Glucan-containing oligomers in the "glue matrix" of cotton fibers, cotton fabric, paper, and wood. A. K. Murray 10:25—229. Stable fixation of lipids in a curd by proteins. T. Ono, C. Tsukamoto 10:45—230. Electrolyzed chlorine solutions: Utilization of reactive oxygen species for management of food wholesomeness and soundness. T. Suzuki, K. Miyashita, M. Watanabe, Y. Okamoto, T. Fujihira 11:05—223. Effect of humic acid on the degradation of pentachlorophenol by the photo-Fenton reaction. M. Fukushima, K. Tatsumi 11:30—34. Differences of alkaloid concentrations among endophyte-infected perennial ryegrass clones and artificially disinfected clones derived from them. H. Araya, S. Tadayuki, F. Akiyama, K. Sugawara

SUNDAY AFTERNOON Hilton Hawaiian Village Rainbow III, Lower Level, Rainbow Tower Ugnocellulosics Science and Technology: From Laboratory to Market (153) D. Hon,

Presiding

1:05—231. From dream to reality: A challenge to scientists. D. Hon 1:30—232. Elements of successful technology commercialization. F. Rogers 2:00—233. Technology transfer today: Beginning and graduate-level options. C. D. Brand, J. Fredette 2:30—234. Lignocellulosic fibrous raw materials and their potential applications. R. Kozlowski 3:00—235. Back to nature: The use of plant fibers in polymer composites. D. Plackett 3:30—236. Oil palm {Elacis guaineensis, Jacq.) fiber-polypropylene. J. Harun, M. D. Zaman, G. A. Manarpaac 4:00—237. Mallee eucalypt wood residues for use in cement-bonded panels. K. Sample, R. Cunningham, P. Evans

Presiding

Hilton Hawaiian Village Coral Ballroom V-VI Immunochemical Biomonrtoring for Environment Chemicals (5) I. Kennedy,

Presiding

1:05—281. Monitoring mycotoxins and pesticides in grain and food production systems for risk management in Vietnam and Australia. N. Lee, R. Allan, A. Hill, B-V. Thin, V-T. Hau, T-V. An, L-V. To 1:35—279. Development of immunoassays for pesticide residue analysis. S. Ito, T. Imai, T. Kaneko, M. Nanjo, S. Kanai, Y. Yuasa, H. Ohkawa 2:05—260. Development of class and compound-specific immunoassays for the detection of pyrethroids. T. Watanabe, D. W. Stoutamire, S. J. Gee, B. D. Hammock 2:25—261. Detection of herbicides and herbicide metabolites using cross reactivity of enzyme immunoassays. E. M. Thurman 2:45—278. On-site detection of agrochemical residues and fungal contaminants for the wine industry. A. Hill, P. Kooij, V. Taylor, S. Bell, J. Skerritt 3:05—280. Assessment of the distribution of pesticides on particle fractions in irrigation run-off using centrifugal SPLITT fractionation and ELISA. A. Crossan, N-A. Lee, R. Sharma, R. Beckett, I. R. Kennedy 3:25—277. Analysis of transgenic plants using immunochemical methods. D. Grothaus, C. Alarcon, T. Davis

MONDAY MORNING Hilton Hawaiian Village lolani Suite lll/IV, 2nd Floor, Tapa Conference Center Molecular Designs of Food Proteins for Industrial Applications (6)

A. Kato, Presiding 8:35—247. Preparation, characterization, and bioavailability of milk micellar calcium phosphate-phosphopeptide complex. T. Aoki 8:55—248. Functional properties of fish myofibrillar protein conjugated with carbohydrates. H. Saeki 9:20—249. Reduced immunogenicity of p-lactoglobulin by conjugation with carboxymethyl dextran of different molecular weight. M. Hattori, K. Kobayashi, A. Hirano, A. Ohta, T. Yoshida, K. Takahashi 9:45—250. Processing and modification of rice proteins. F. Shih 10:10—251. Formation of stable emulsion by wheat gluten. M. Shimizu, K. Takeda 10:35—252. Molecular mechanism of excellent emulsifying properties of chicken egg yolk phosvitin. M. Khan, A. Kato, H. Azakami Hilton Hawaiian Village lolani Suite l/lI, 2nd Floor, Tapa Conference Center

1:05—300. New process for the continuous acetyration of lignocellulosic fiber. R. Rowell, R. Simonson 1:30—301. The indurite wood hardening process: From laboratory bench to market. R. Franich, P. McArthur 2:00—302. Comparisons of the lightfastness of chemically modified wood. S-T. Chang, H-T. Chang 2:30—303. Synthesis and potential application of phosphoramides as commercial wood preservatives for decay and fire protection. G. C. Chen 3:00—304. Laccase-lignin oxidative chemistry. A. Ragauskas, L. Allison, F. Chakar 3:30—305. Parsing laccase's effect on modifying lignin. R. Chandra, A. Ragauskas 4:00—306. Use of new oxidizing agents in the deinking process of old papers: Activated peroxide, perborate—efficiency, and impact on environment. C. Leduc, A-M. Launois, C. Daneault

MONDAY EVENING

N. Shiraishi,

Immunochemical Biomonrtoring for Environment Chemicals (5) Poster Session

Presiding

8:05—253. Cellulose synthesis and structure of cotton fiber. Y-L Hsieh 8:30—254. Diversity of molecular properties of cellulose from different origins. T. Matsumoto, D. Tatsumi, N. Tamai, T. Takaki 9:00—255. Cellulose esters: Highperformance biopolymers. B. Seller, C. Buchanan, K. Edgar 9:30—256. Graft polymerization of cyclic esters on cellulose acetate. M. Yoshloka, N. Shiraishi 10:00—257. Lignosulfonate chemicals at Georgia-Pacific: 2000 and beyond. C. Cornman, B-W. Chun, L Fiske, S. Baker 10:30—258. Sulfur-free lignins: Achievements and setbacks along the road to commercialization. J. Lora 11:00—259. Thermoplasticization and liquefaction of biomass and their application. N. Shiraishi, M. Yoshioka

MONDAY AFTERNOON Hilton Hawaiian Village lolani Suite lll/IV, 2nd Floor, Tapa Conference Center Molecular Designs of Food Proteins for Industrial Applications (6)

A. Kato, Presiding 1:05—282. Molecular design of hen egg white lysozyme for transgenic plants having a strong bactericidal action. A. Kato, M. Kato 1:30—295. Enhancement of antimicrobial activities of lysozyme by the reduction of intramolecular disulfide bonds. S. Hayakawa, K. Saitoh 1:55—296. Peptides from peptic digestion of bovine lactoferrin for industrial application as antimicrobial or surface-active agents. E. Li-Chan, A. Liceaga-Gesualdo, B. Skura 2:20—297. Molecular design of food allergen to reduce its allergenicity-ovomucoid. Y. Mine, E. Sasaki 2:45—298. Characterization of IgY having multiserotype specificity to Mutans streptococci and its practical use to prevent dental caries. H. Hatta, M. Hirasawa, S. Otake 3:10—299. Structure and sweetness of sweet proteins. N. Kltabatake

H. Ohkawa, Presiding

R. Rowell, Presiding

Hilton Hawaiian Village Coral Ballroom III, 6th Floor, Mid-Pacific Conference

Hilton Hawaiian Village Coral Ballroom V-VI

7:05—187. Immunoaffinity purification of complex matrices for the quantification of pesticides, toxins, and allergens in food. S. Ben-Rejeb, C. Cleroux, M. Abbott, D. Davies, F-L. Goffic 7:35—188. Preparation and characterization of sol-gel based immunoadsorbents using anti-polycyclic aromatic hydrocarbon antibodies and low-angle X-ray scattering. D. Knopp, M. Schedl, T. Schamweber, W. Doster, H. Leyser, R. Niessner 7:55—189. Engineering of monoclonal antibodies specific to the insecticide malathion. H. Ohkawa, K. Nishi, Y. Imajuku, M. Nakata 8:25—190. Antibody farming: A discussion and case study. J. C. Hall, N. Vettakkorumakankav 8:55—191. Antibody chips for microelectrochemical detection. R. Matsue

Ugnocellulosics Science and Technology: From Laboratory to Market (153)

Lignocellulosics Science and Technology: From Laboratory to Market (153)

SUNDAY EVENING

Immunochemical Biomonrtoring for Environment Chemicals (5)

Hilton Hawaiian Village lolani Suite l/l I, 2nd Floor, Tapa Conference Center


7:30-9:30 186. Saliva biomonrtoring for pesticide exposure using ELISA: A feasibility study in animals. C. Lu, L. Anderson, M. Morgan, R. Fenske 264. Sol-gel-based immunochemical monitoring of environmental chemicals. M. Altstein, A. Bronshtein, N. Aharonson 265. Trends in the application of immunoassay and biosensors technology to the analysis of environmental objects. V. V. Zyrianov, M. D. Goktfein 266. Optimal detection of steroid hormone with a flow-based fluorescence immunoassay using microspheres. Y. TsuMdate, H. Shinozaki, H. Saiki, N. Ohmura 268. Rapid enzyme immunoassays for pesticides detection with the use of bacillary a-amylase as label. B. Dzantiev, A. Zherdev 270. Rapid on-site immunoassays for persistent chemical contaminants in grains. S. Wang, A. Hill, I. Kennedy 271. Development of enzyme-linked immunosorbent assays for fenthion. Y. Lee, Y-J. Kim, Y-A. Cho. H-S. Lee, S. Gee, B. Hammock 273. Preparation of polyclonal and monoclonal antibodies for DDT test kit development. T. Prapamontol, R. Tiamjan, C. Hirunpetcharat 274. Effects of different hapten-enzyme conjugates on the sensitivity and specificity of cyclodiene immunoassays. N. Lee, I. Kennedy 275. Validation of ELISAs for pesticides residue analysis in fruits and vegetables. A. Hayashl, H. Iwabuchi, S. Watanabe, Y. Kagawa, S. Miyake, Y. Yuasa, M. Sonoda Hilton Hawaiian Village Coral Ballroom III, 6th Floor, Mid-Pacific Conference Agrochemistry (01G-P) Poster Session 7:30-9:30 13. Relationship of 2-furancarboxaldehyde and afiatoxin contamination in genetically linked cotton varieties. H. Zeringue Jr. 34. Differences of alkaloid concentrations among endophyte infected perennial ryegrass clones and artifically disinfected clones derived from them. H. Araya, S. Tadayuki, F. Akiyama, K. Sugawara 110. Surfacing sizing with emulsion rosin sizes: Two-dimensional XPS analysis of rosin distribution in paper. T. Kitaoka, H. Yamamoto, R. Nishino, H. Tanaka 203. Production and characterization of a monoclonal antibody against the p-adrenergic agonist ractopamine. W. Shelver, D. J. Smith, E. S. Berry


AGRO/ANYL/TECHNICAL PROGRAM

204. Protein-enriched spaghetti fortified with com gluten meal. Y. V. Wu, G. Hareland, K. Warner 205. Chemical forms of phosphorus in virgin and cultivated soils in Chile. M. Escudey, M. Brice, G. Galindo, J. Forster, A. Chang 206. Surdity reduction in a Kraft process by adding methanol and/or anthraquinone. C. Deneault, J-N. Destine, C. Leduc 207. Isolation and structure determination of a novel lipophilic protein from the shell of the pink shrimp, Pandalus borealis. K. Suzuki, M. Okamori, H. Katsuzaki, T. Komiya, O. Yamashita, K. Imai 208. Screening recombinant amylase enzymes using a bacterial expression system. C. Lee, D. Wong, G. Robertson 209. Importance of particle size and soil mineralogy on porosity and specific surface area of Chilean volcanic soils. M. Antilen, S. Del Confetto, E. Rodier, O. Fudym, A. Venezia, G. Deganello, J. E. Forster, M. Escudey 210. Environmentally benign chemistry for dewaxing cotton textiles. E. Boylston, B. Ingber, A. Lambert, 2 . Hruska, V. Yachmenev 211. Decomposition of cellulose with Fenton's reagent at temperatures higher than 100 °C. S. Inoue, T. Ogi 212. Phenolic acid of groundnut root cell walls. C. Nonaka, Y. Chounan, N. Ae, Y. Kato 213. Structure of Gramineae xylogucan. S. Ito, Y. Mitsuishi, K. Suzuki, T. Itoh, Y. Kato 214. Effect of inorganic additives on the aromatic hydrocarbon formation from plant materials. D. Kellogg, B. Waymack, M. Hajaligoi 215. Structure and biological activities of lacquer polysaccharides in Asia. R. Lu, T. Yoshida 216. Analysis of the physical degradation and chemical modification of pulp and textile fibers during bleaching by hydrogen peroxide. D. Mancosky, L. Lucia 217. In situ derivatization and Na 4 EDTAassisted pressurized fluid extraction of polar herbicides in soil. S. Campbell, Q. Li 218. Dipstick enzyme immunoassay for the detection of fenthion. H-S. Lee, Y-A. Cho, Y-J. Kim, Y. T. Lee 219. Degradation of phytate in brown rice with giant embryo during soaking in water. T. Inagakl, T. Horino, Y. Nakamura, K. Tsukahara, H. Kayahara 220. Formats for the homogeneous fluoroimmunoassay for a pesticide metabolite. E. Matveeva, W. Costandi, I. Kennedy, G. Shan, S. Gee, B. Hammock 221. Withdrawn. 222. Arsenic content in seafood products available in Singapore. N. P. Cheah, B. C. Bloodworth, S. H. Chan, A. Lime 224. Synthesis and fungicidal activities of 2-aryl-2-(1 H-1,2,4-triazole-1 -yl) methyloxetane derivatives. H. Kajino, H. Itoh, K. Sato, J. Tobitsuka, H. Takeshiba, S. Oida, H. Ohta, Y. Takahi 225. Mechanical and structural properties of cross-linked milk protein edible films. M. Lacroix 327. Biosynthetic studies on lovastatin: Enzyme-catalyzed Diels-Alder reaction. K. Auclair, J. C. Vederas, J. Kennedy, A. Sutherland, D. J. Witter, J. P. Van Den Heever, C. R. Hutchinson Hilton Hawaiian Village Coral Ballroom III, 6th Floor, Mid-Pacific Conference Lignocellulosics Science and Technology: From Laboratory to Market (153) Poster Session

7:30-9:30 307. Characterization of noncrystalline domains in cellulose using FTIR deuteration monitoring analysis. Y. Hishikawa, E. Togawa, Y. Katoka, T. Kondo 308. Novel structure of cellulose named nematic ordered cellulose. T. Kondo, E. Towaga, M. Brown Jr. 309. Facile crystallization of nematic ordered cellulose obtained from drawing of cellulose. E. Togawa, T. Kondo 310. Xylan-degrading enzymes with transxylosyl activity of fungi isolated from healthy leaves and their application. H. Shlnoyama, T. Fujii

70


311. Analysis of intramolecular hydrogen bonds in cellulosic solution. M. Nojiri, T. Kondo 312. Adsorptivity of metal ions and some dyes onto cellulosic materials and heated products from kenaf (hibiscus cannabininus) L plants. N. Miyata, T. Koga

TUESDAY MORNING

Hilton Hawaiian Village lolani Suite 11 l/l V, 2nd Floor, Tapa Conference Center

A. Kato, Presiding

Food and Beverage Antioxidants in Health and Disease (202) Poster Session 7:30-9:30 313. Superoxide anion radical oxidizes bovine serum albumin to its radical. K. Nishimura, J. Mano 314. Suppressive effect of antioxidant on cadmium chloride-induced cytotoxicity in Euglena gracilis. M. Watanabe, Y. Kawamura, T. Suzuki 315. Which brewing ingredients contribute the antioxidant components of beer responsible for cataract and atherosclerosis risk reduction? C. Trevithick, S. Hong, L. Bocksch, T. Dzialoszynski, M. Hirst, J. Trevithick 316. Green and black tea: Rich sources of polyphenolic antioxidants which inhibit atherosclerosis by three mechanisms. J. Vinson, Y. Dabbagh, N. Wu, K. Teufel 317. Prooxidative activity of tea catechin in the presence of copper(ll) ion under aerobic conditions. T. Kimura, F. Hayakawa, N. Hoshino, A. Yamaji, T. Ando 318. Beers: In vitro antioxidants and in vivo effect on an animal model of atherosclerosis. J. Vinson, M. Mandarano, D. Shuta 319. The French paradox revisted using an animal model of atherosclerosis. J. Vinson, K. Teufel, N. Wu 320. Antioxidants of allspice (Pimenta dioica). H. Kikuzaki, M. Hisamoto, N. Nakatani Hilton Hawaiian Village Coral Ballroom III, 6th Floor, Mid-Pacific Conference Molecular Designs of Food Proteins for Industrial Applications (6) Poster Session 7:30-9:30 283. Molecular design of bactericidal actionswitching lysozymes. S-T. Liu, S. Saito, H. Azakami, A. Kato 284. Stable mutant fysozyme (S91T) enhances the secretion in yeast. Y. Song, J. Sakai, H. Azakami, A. Kato 285. Wild-type ct-lactalbumin is glycosylated in the methylotrophic yeast Pichia pastoris. S. Saito, A. Kato 286. Structural element on the chaperonelike activity of ovalbumin. N. Matsudomi 287. Improved functional properties of carp myofibrillar protein by conjugation with alginate oligosaccharide. R. Sato, T. Sawabe, S. Nakamura, H. Saeki 288. Improved solubility of scallop myofibrillar protein in low ionic strength medium by glycolsylation with monosaccharides. S. Katayama, J. Shima, H. Saeki 289. Molecular design of cystatin by genetic glycosylation for food ingredient. S. Nakamura, J. Hata, M. Ogawa, M. Saito, H. Saeki, S. Nakai 290. Importance of multiple positive charges for elicitation of sweetness in sweet protein thaumatin I. R. Kaneko 291. Stable fixation of lipids in a curd by proteins. T. Ono, C. Thukamoto 292. Recombinant VP8* subunit protein offers new vaccination strategies for the prevention of human rotavirus infection. J. Kovacs-Nolan, E. Sasaki, Y. Mine, D. Yoo 293. Thermostability improvement of human cystatin c using site-directed mutagenesis directed by random-centroid optimization for genetics. M. Ogawa, S. Nakamura, C. Seaman, S. Nakai 294. Alteration of functional properties of soybean globulins by chimerization. R. Satoh, M. Adachi, N. Maruyama, S. Utsumi 323. Whether or not the sweet activity in hen egg lysozyme is in relation to its enzymatic activity. T. Masuda

Hilton Hawaiian Village lolani Suite lll/IV, 2nd Floor, Tapa Conference Center Molecular Designs of Food Proteins for Industrial Applications (6) 8:05—321. Molecular approach to understand structure-function relationships of aspartic proteinases. R. Yada, T. Tanaka, M. Okoniewska, C. Richter 8:30—322. Computer-aided strategy for structure-function relation study of food proteins. S. Nakai 8:55—324. Recombinant enzymes for preparation of bioreactors for design of protein functionality. H. Swaisgood 9:20—325. Genetic control of browning due to polyphenol oxidase activity in grapes. J. Whttaker, V. Virador, A. Moreno 9:45—326. Oligogrycosylation of lysozyme by chemical and genetic modifications. S. Nakamura, S. Miyasaka, M. Saito, T. Goto, H. Saeki, M. Ogawa, A. Kato

ANYL AREA 02-ANALYTICAL CHEMISTRY THURSDAY MORNING Renaissance llikai Melbourne Ballroom, Lobby Level Frontiers of Spectroscopic Analysis of the Brain (75)

H. Koizumi, Presiding 8:35—9. Importance of spectroscopic analysis of the brain. H. Koizumi 8:50—10. Sonic spray ionization for mass spectroscopic analysis of neurotransmitters. A. Hirabayashi 9:25—11. Quantification of brain regional metabolic changes with hr-MAS proton MR spectroscopy for Alzheimer's disease. K. Colson, W. Maas, L. L. Cheng 10:05—12. Electron microprobe analysis of mineral deposition in the brain. A. Muehlenbachs, I. Campbell, K. Muehlenbachs, H. Powell, H. Vinters 10:30—13. Voltammetric analysis of neurotransmitters in the brain. M. Wightman 11:05—14. Neurochemical basis of functional imaging and neuronal activity. R. Shulman Renaissance llikai Wellington Ballroom, Lobby Level Chemical and Biochemical Microsensors, Nanoparticles, and Probes (154)

R. Kopelman, Presiding 8:35—34. Dynamic imaging of single mammalian ceils. E. S. Yeung, Z. Wang, J. Gruenhagen, P. G. Haydon, M. Randic 9:10—35. Fluorescence study on the local environment of a core-shell-type microsphere. S. Yamada, S. Machida, S. Takahashi, K. Horie, H. Kawaguchi 9:45—36. Detection of single-cell events with micro- and nanoelectrodes. A. Ewing, T. Colliver, K. Krylova, J. Esson 10:20—37. Assaying neurotransmitters in and around cells. J. Sweedler 10:55—38. DNA-functionalized microspheres. H. Kawaguchi


11:10—39. Monitoring cell activities within small-volume sample by scanning electrochemical microscopy. H. Shiku, T. Shiraishi, H. Ohya, T. Matsue, H. Abe, H. Hoshi, M. Kobayashi 11:25—40. Design of integrated enzyme sensors and chemical cross talks. M. Suzuki, H. Akaguma, Y. Yamamoto, S. Kawauchi Renaissance llikai Auckland Ballroom, Lobby Level Analytical Chemistry General (02G-O)

K. Froese, Presiding 8:35—41. Rapid trace analysis of polar organic compounds at sub-ppb levels in drinking water using ESI-FAIMS-MS. K. Froese, B. Ells, S. Hrudey, D. Bamett, R. Guevremont, R. Purves 8:55—42. Determination of trace elements in natural waters by inductively coupled plasma-mass spectrometry with solidphase collection and concentration. K-H. Lee, D. Hikata, M. Oshima, S. Motomizu 9:15—43. Using solution-phase H/D exchange to determine the specificity of noncovalent complexes observed with ESIFTMS. S. Lorenz, T. Wood, Q. Li 9:35—44. Investigation of polymerization pathways of silsesquioxanes by graphite plate laser desorption/ionization time-offlight mass spectrometry. H-J. Kim, S-J. Park, D-Y. Yoo, J-K. Lee, H. Ro, D-Y. Yoon 9:55—45. Accelerator mass spectrometry for the determination of ^ C l in soil from Semipalatinsk nuclear test site. S. T o l machyov, S. Mitarai, N. Momoshima, M. Yamamoto, Y. Maeda 10:15—46. Chromatographic separation of hydrogen ion. W. Hu 10:35—47. An approach for comparing the stability of crown ether complexes formed with metals and amines in aqueous solutions. L Manege, T. Takayanagi, M. Oshima, S. Motomizu 10:55—48. Visual determination of urinary protein using color change of ternary associate on membrane filter. K. Yoshlmoto, E. Kaneko, T. Yotsuyanagi 11:15—49. Analysis of hydrogen supersaturation in an electrolyzed water of 'alkaliion water electrolyzer". K. Kikuchi, T. Okaya, B. Rabolt, Z. Ogumi, Y. Saihara

Renaissance llikai Pago Pago Ballroom, Lobby Level Ultrasensitive Chemical Measurement and Characterization (113)

E. Yeung, Presiding 8:05—15. Luminescent quantum dots and SERS-active nanoparticles for ultrasensitive biological detection. S. Nle, W. Chan, D. Maxwell, J. Taylor, S. Emory 8:35—29. Single-molecule and femtosecond quasi-thermal lens microscopy and observation of restricted molecular behavior in liquid microspace fabricated on chip. T. Krtamori 9:10—30. Single-molecule imaging and spectroscopy of fluorescent derivatives of nucleic acid bases. M. Ishikawa 9:45—31. Single-molecule enzymology. N. Dovichi, R. Polakowski, D. Craig, A. Skelley 10:20—32. Single-molecule NSOM studies of membrane structure. R. Dunn, C. Hollars, S. Vickery 10:55—33. Dynamic imaging of single molecules. E. S. Yeung, X. Xu, M. Shortreed, Y. Ma, H. Li, S. H. Kang Renaissance llikai Moorea Ballroom, Lobby Level Liquid-Liquid Interfaces in Analytical Sciences (26)

H. Watarai, Presiding 8:05—1. Computer simulation studies of ion transport across a liquid-liquid interface. L. X. Dang 8:30—2. Molecular dynamics simulation of the transfer of a small and a large ion across the nitrobenzene/water interface. M. Yamamoto, I. Benjamin, T. Kakiuchi 8:55—3. Computer simulations on liquidliquid assisted ion extraction: Importance of interfacial phenomena. G. Wipff

9:20—4. Observation of positive/negative bands in polarized external reflection visspectrum and the orientation of absorbed species at liquid-liquid interface. N. Ogawa, Y. Moriya, R. Amano, K. Hayashi, S-l. Nakata 9:45—5. Effect of the interfacial properties on the reaction rate of nickel ion extraction by LIX 84. G. Stevens, F. Grieser, J. Perera, D. Warren 10:10—6. Kinetics of complex formation at liquid-liquid interface in ion-association extraction by total reflection induced thermal lens. H. Kawazumi, N. Maeda 10:35—7. New approaches for measurements of interfacial complexation. H. Watarai 11:00—8. Electrochemical liquid-liquid extraction of metal ions assisted by organic ligands and its application to trace analysis. H. Katano, M. Senda

THURSDAY AFTERNOON Renaissance llikai Moorea Ballroom, Lobby Level Liquid-Liquid Interfaces in Analytical Sciences (26)

H. Watarai, Presiding 1:05—51. Vibrational sum frequency spectroscopy of liquid-liquid interfaces: Hydrogen bonding and solvation. L. F. Scatena, G. L. Richmond 1:30—52. Second harmonic generation spectroscopy of molecules at liquid-liquid interfaces. N. Teramae 1:55—53. Single-molecule probing of lateral transport at chemical interfaces. M. J. Wlrth, D. J. Swinton, M. D. Ludes 2:20—54. Ion partitioning in small liquidliquid two-phase systems. T. Kakiuchi 2:45—55. Spectroscopic studies of calcium ion uptake and transport in ultrathin polypeptide films. R. M. Corn, Y. Cheng, S. Barreira, M. Wanat, T. Grimsrud 3:10—56. Ion sensing based on two-phase ion transfer and on molecular recognition at monolayer surfaces. Y. Umezawa 3:35—57. Microamperometric ion-selective electrodes. H. Girault, H. J. Lee 4:00—58. Biomimetic membrane reactions of various types observed with artificial membranes. S. Kihara, H. Ohde, N. Kurauchi, Y. Yoshida, K. Maeda, O. Shirai 4:25—59. Orientation of crown ether complexes at liquid interfaces. J. Frey, A. Timson Renaissance llikai Melbourne Ballroom, Lobby Level Frontiers of Spectroscopic Analysis of the Brain (75) H. Koizumi, Presiding 1:05—60. Energy yield via glucose oxidation in the functioning brain detected by in vivo NMR. F. Hyder, D. Rothman 1:40—61. Functional MRI and optical topography for mapping brain function. R. Kennan 2:25—62. Optical imaging from the monkey inferotemporal cortex: A combination rule for object image representation. M. Tanifuji 3:15—63. Optical imaging of visual processing in primate visual cortex. A. Roe, B. Ramsden, C. Hung 3:50—64. Fast optical imaging of neuronal activities. H. Miyakawa

Renaissance llikai Auckland Ballroom, Lobby Level Analytical Chemistry General (02G-O)

P. Chen, Presiding 1:05—76. Multiplex nonlinear Raman probe. P. Chen, C. Joyner, K. Benton, S. Patrick 1:25—77. Classification of cultivation area of ginseng by near-IR spectroscopy and ICPAES. Y. A. Woo, C. H. Cho, H. J. Kim, J. Cho 1:45—78. Determination of M0O3 maximum monolayer dispersion amount on r-AI203 surface. G. Chu 2:05—79. A method of X-ray diffraction quantitative phase analysis by wholespectrum intensity matching. Q. Wu, G. Chu, X. Chu 2:25—80. Electrothermal atomic absorption spectrometric determination of cadmium after preconcentration onto zeolite. H. Minamlsawa, R. Okunugi, M. Minamisawa, A. Uzawa, N. Arai, T. Okutani 2:45—81. Evaluation of DNA-binding antitumor and antiviral agent by electroluminescent measurement—I. T. Kuwabara, T. Noda, M. Nanasawa, S. Toyama, Y. Ikariyama 3:05—82. Evaluation of DNA-binding antitumor and antiviral agent by electrochemiluminescent measurement—II. H. Ohtake, S. Toyama, T. lida, Y. Ikariyama 3:25—83. Split green fluorescent protein (GFP) as a new optical probe for proteinprotein interaction in vivo: The interaction produces GFP fluorophore by protein splicing. T. Ozawa, Y. Umezawa 3:45—84. Highly sensitive assay of ATP using enhancement of firefly bioluminescence with DEAE-dextran in the presence of ATP extractants. A. Ishida, T. Nakazawa, T. Kamidate 4:05—85. Atomic force microscope and quartz-crystal microbalance studies of DNA molecules immobilized on gold surfaces. M. Satjapipat, R. Sanedrin, E. Huang, F. Zhou Renaissance llikai Wellington Ballroom, Lobby Level Chemical and Biochemical Microsensors, Nanoparticles, and Probes (154)

R. Kopelman, Presiding 1:05—70. Optical nanosensors for chemical analysis and imaging outside and inside single living cells. R. Kopelman, M. Philbert 1:40—71. Molecular beacon: DNA/RNA/ protein analysis. W. Tan 2:15—72. Digital fluorescence imaging and sensing of the cellular response to liposomal drug delivery in single cells. Z. Rosenzweig, J. Lu, J. Ji 2:50—73. Characterization of microparticles suspended in an electrodynamic trap. M. Kotani 3:15—74. Fabrication of microarray biochip by hydrophobicity interaction. Y-S. Choi, A. Yamamura, Y. Murakami, K. Yokoyama, Y-S. Kwon, E. Tamiya 3:30—75. Stabilization of enzymeincorporated carbon paste-based biosensor. S. Toyama, O. Nakane, M. Hirano, Y. Ikariyama

FRIDAY MORNING Renaissance llikai Moorea Ballroom, Lobby Level

Renaissance llikai Pago Pago Ballroom, Lobby Level

Liquid-Liquid Interfaces in Analytical Sciences (26)

Ultrasensitive Chemical Measurement and Characterization (113)

H. Watarai, Presiding

E. Yeung, Presiding 1:05—65. Trace analysis of dioxins by supersonic jet/multiphoton ionization/mass spectrometry. T. Imasaka 1:35—66. Characterizing aerosol particles one by one: New insights into the roles of aerosols in affecting pollution and global climate change. K. Prather, S. Guazzotti, D. Suess, S. Pastor, K. Coffee 2:10—67. Molecule-specific imaging of biomaterials with mass spectrometry. N. Winograd 2:45—68. Molecular detection and cell dynamism at single-cellular level. T. Masujima 3:20—69. Assaying single cells to single organelles using mass spectrometry. J. Sweedler

8:05—89. Capillary electrophoretic separation of isomeric aromatic anions based on ion association and distribution to nonionic surfactant micelle. T. Takayanagi, K. Fushimi, S. Motomizu 8:30—90. Interfacial transport rate of some tris(p-diketonato) iron(lll) in triton X-100 micellar system and its effect on the whole extraction mechanism. K. Inaba 8:55—91. Interfacial metal ion recognition. S. Muralidharan 9:20—92. Chirality recognition of amino acids by surface molecular imprinting technique. M. Goto, M Yoshida, K. Uezu, S. Furusaki 9:45—93. Structure and dynamics of photosensitizers at the liquid-micelle interface. J. Zhang, M. Brelle, S. Gerhardt, M. Vermathen, U. Simonis

10:10—86. Developments in solvation dynamics at liquid interfaces. N. E. Levinger, E. Corbeil, D. M. Willard 10:35—87. Dynamic behaviors of molecules at liquid-liquid interfaces using the timeresolved quasi-elastic laser-scattering method. T. Sawada 11:00—88. Surface SHG of metal nanoparticles at liquid-liquid interfaces. P. F. Brevet P. Galletto, R. Anotine, M. Broyer, D. J. Schiffrin, C. Gomez-Diaz, J. P. Abid, H. H. Girault Renaissance llikai Melbourne Ballroom, Lobby Level Frontiers of Spectroscopic Analysis of the Brain (75)

H. Koizumi, Presiding 8:35—94. Dynamic spectroscopic analysis of cognitive functions of human brain. A. Maki, Y. Yamashita, T. Yamamoto, H. Koizumi 9:05—95. Spatio-temporal imaging of human brain activity by functional near-IR spectroscopy. Y. Hoshi 9:55 96. Measurement of optical properties of brain in vivo. Y. Yamada, A. Sassaroli, Y. Tanikawa, F. Martelli, R. Araki, K. Tanaka 10:30—97. Real-time optical imaging of the human brain. S. Fantini, V. Toronov, M. Wolf, A. Michaios, E. Gratton, M. A. Franceschini 11:05—98. Future trends in cognitive imaging with near-IR systems. B. Chance, S. Nioka, Y. Chen, H. Y. Ma Renaissance llikai Pago Pago Ballroom, Lobby Level Ultrasensitive Chemical Measurement and Characterization (113)

E. Yeung, Presiding 8:05—99. Analytical chemistry in small volumes at low concentration. M. Ramsey 8:35—100. Molecular transport using a liquid-liquid interface in a microchip. M. Takeshi, T. Minagawa, T. Kitamori 9:10—101. Liquid-phase microchemical reaction in microchip: Reaction time of diazo-coupling reaction. H. Hisamoto, M. Tokeshi, A. Hibara, T. Kitamori 9:45—102. Novel linear imaging UV detector for microchip electrophoresis. A. Arai, H. Tanaka, H. Abe, S. Maruyama, T. Ueda 10:20—103. Polymeric microchannel chips as disposable devices. N. Kitamura, K. Ueno, H-B. Kim, F. Kitagawa, C. Iwasaki, Y. Hosoda 10:55—104. Microfluidic protein processing for mass spectrometry of the proteome. D. J. Harrison, P. Thibault, C. Wang, A. Belay-Jemare, R. Oleschuk Renaissance llikai Auckland Ballroom, Lobby Level Raman Spectroscopy: Coming of Age in the New Millennium (171)

S. Asher, Presiding 8:35—111. ot-Helix peptide folding and unfolding activation barriers: A nanosecond UV resonance Raman study. S. Asher, I. Lednev, A. Kamoup, M. Sparrow 9:00—112. Femtosecond coherence spectroscopy of biomolecules. P. Champion, F. Rosea, W. Wang, A. Kumar, X. Ye, D. lonascu, W. Cao, T. Sjodin, A. Demidov 9:25—113. Structural study of the distal histidine of heme peroxidase by UV resonance Raman spectroscopy. S. Hashimoto, H. Takeuchi 9:50—114. Oxygen activation and reduction in cytochrome oxidase and prostaglandin H synthase. G. T. Babcock, D. Proshlyakov, S. Seibold, J. Cerda, B. Schmidt 10:15—115. Catalytic mechanism of cytochrome oxidase. D. Rousseau 10:40—116. Cytochrome c folding and unfolding: A biphasic mechanism. S-R. Yeh, S. Zhong, D. Rousseau


11:05—117. Raman microscopic imaging of bone tissue biomechanics. M. D. Morris 11:30—118. A 1064-nm excited near-IR Raman spectrometer for cancer diagnosis. S. Kaminaka, H. Yamazaki, T. Ito, E. Kohda, H. Hamaguchi Renaissance llikai Lobby Room, Lobby Level Analytical Chemistry General (02G-O) Poster Session 9:00-11:00 50. Optically gated sample introduction on a chip for monitoring cellular release. J . Lapos, A. Ewing 119. Molecular design and characterization of multidentate ligand. T. Odashima, K. Kohata, T. Sasaki, K. Yoshida, K. Takagi 120. Pretreatment for the determination of total mercury using peroxodisulfate-UV irradiation. K. Kurihara, K. Nagashima, M. Kamaya, H. Yamada 121. Development of a simple determination method for lecithin. M. Kamaya, K. Nagashima 122. Development of a monitoring tape for hydrogen cyanide in air using Cu(U) and DPD. M. Tamura, S. Hirayama, K. Nagashima, M. Kamaya, N. Nakano 123. Simple determination of peroxidase using pH change in sulfite/hydrogen peroxide system and its application to immunoassay. A. Manaka, S. Igarashi 124. Studies on energy transfer into capsuled chemiluminescence reactor. D. Kase, M. Ishii 125. Dry chemical sensor. A. Makise, S. Tabata, A. Izumiyama, N. Nakano, N. Kawashima 126. A better way to perform correlation principal component regression. J . Kalivas 127. Determination of ions using a quartzcrystal microbalance. T. Enda, T. Akagawa, T. Saito 128. Thermal desorption and adsorption of gases with marine ferromanganese crust materials gathered from the Pacific basin. G. Andermann, N. Pandya, S. Bailey, P. Gu, G. Kawamoto 129. Anomalous Si solubility in a select ferromanganese crust. G. Andermann, M. Sipin, A. Hee, D. Navas 130. Polymeric light-emitting materials based on the control of conjugated/nonconjugated main chain. J. Shen, Z. Ruifeng Renaissance llikai Wellington Ballroom, Lobby Level Chemical and Biochemical Microsensors, Nanoparticles, and Probes (154)

H. Masuhara, Presiding 8:35—105. Photon-pressure controlled assembling of nm polymer chains and micelles in solution. H. Masuhara, A. Kubota, J-l. Hotta, K. Sasaki 9:10—106. Single-molecule spectroscopy of dendritic structures. F. De Schryver 9:45—107. Spectroscopic and electrochemical characterization of single microdroplets in water. N. Kitamura 10:20—108. Chemical binding of nanoparticles and characteristics. Y. Nosaka, Y. Aota, M. Sasagawa, J. Nishino 10:55—109. Smell-seeing: A colorimetric artificial nose. K. S. Suslick, N. A. Rakow 11:20—110. Recent advances in photonic functions of organic microcrystals. H. Nakanishi

FRIDAY AFTERNOON Renaissance llikai Melbourne Ballroom, Lobby Level Frontiers of Spectroscopic Analysis of the Brain (75)

H. Koizumi, Presiding 1:15—131. Clinical applications of NIRS in neurosurgery. E. Watanabe, H. Koizumi 1:50—135. Spectroscopic analysis of hemodynamics in human infants. G. Taga, Y. Konishi, A. Maki, T. Tachibana, M. Fujiwara, H. Koizumi 2:25—132. Temporal cortex activation during sentence processing: Optical topography and fMRI study. K. L. Sakal 3:00—133. Observation of emergence of language in infants by near-IR imaging. J.


71

ANYL/TECHNICAL PROGRAM

3:15—134. Imaging human intracerebral connectivity by near-IR spectroscopic mapping during transcranial magnetic stimulation. N. Iwata, Y. Ugawa, E. Watanabe, Y. Yamashita, H. Koizumi, I. Kanazawa Renaissance llikai Pago Pago Ballroom, Lobby Level Ultrasensitive Chemical Measurement and Characterization (113)

E. Yeung, Presiding 1:00—136. Ultrasmall, ultrasensitive intraorganelle sensors in single living cells. R. Kopelman 1:35—137. Micromachining and nanomachining for ultrasensitive chemical measurement. M. Esashl, O. Takahito, A. Takashi 2:10—138. Two-photon excited fluorescence detection in capillaries. F. Lytle, S. Zugel 2:45—139. Absorption-based surface plasmon resonance sensors. K. Kurihara, K. Nakamura, E. Fujii, H. Hashimoto, D. Citterio, K. Suzuki 3:20—140. Ultrafast photothermal spectroscopy and its application. T. Sawada Renaissance llikai Moorea Ballroom, Lobby Level Separation Science: Trends for the New Century (117)

S. Alexandratos, Presiding 1:05—141. Recent progress with macro- and supramolecular systems in liquid-phase retention separation. K. E. Geckeler 1:35—142. Separation behavior of hydroxybenzene derivatives and naphthalenesulfonate isomers on macrocyclic polyamineimmobilized polymer resin. T. Imato, K. Takahashi, T. Mukuno, K. Otsuka 2:05—143. Efficient separation of isomeric organic anions by preferential anion exchange intercalation. D. O'Hare, R. Walton, L. Lixu, R. Millange, B. Lotsch 2:35—144. New chelating polymers for heavy and noble metal ion sorption. R. A. Bartsch, G. G. Talanova, L Zhong, O. V. Kravchenko, K. B. Yatsimirskii 3:05—145. Zirconium-loaded phosphoric acid resin as a selective adsorbent for arsenic. X. Zhu, A. Jyo 3:35—146. Research with polymersupported ionic complexants. S. Alexandratos Renaissance llikai Auckland Ballroom, Lobby Level Raman Spectroscopy: Coming of Age in the New Millennium (171)

R. Turner, Presiding 1:05—153. From Raman excitation profiles to dynamics. S-Y. Lee 1:30—154. Raman noncoincidence effect, band broadening, and ultrafast dynamics for delocalized vibrational modes in liquids. H. Torii 1:55—155. Excited-state dynamics observed through picosecond-femtosecond timeresolved vibrational spectroscopy. T. Tahara 2:20—156. Nonresonant femtosecond spectrograms: Looking inside ultrafast response pulses. L. Ziegler, J. Gardecki, S. Constantine, Y. Zhou 2:45—157. Raman spectroscopic characterization of structure and dynamics in supercritical fluids. S. Wailen, P. Raveendran 3:10—158. Coherent anti-Stokes Raman scattering microscopy. S. Xie, A. Volkmer, J-X. Cheng 3:35—159. Separation of Raman spectra from fluorescence background by principal component analysis. T. Hasegawa, J. Nishijo, J. Umemura 4:00—160. Raman spectroscopy at the crossing of centuries in China. S-L Zhang Renaissance llikai Lobby Room, Lobby Level Analytical Chemistry General (02G-P) Poster Session 1:00-3:00 161. Chemiluminescent flow-through sensor for hydrogen peroxide with transition-metal complex immobilized resin as catalysis. S. Hanaoka, J-M. Un, M. Yamada 162. Chemiluminescence behavior of tris(2,2'-bipyridine) ruthenium(ll) immobilized on a cationic ion-exchange resin. J-M. Un, M. Yamada

72


163. Cross-linked M,N-dimethylaminopropylacrylamide adsorbent for removal of DNA from protein solution. M. Sakata, T. Kamada, M. Kunitake, C. Hirayama 164. Design of cationic polymer adsorbents for removal of endotoxin from serum protein. M. Todokoro, M. Sakata, T. Ida, M. Kunitake, C. Hirayama 165. Extraction properties of aqueous twophase system of tetrabutylammonium bromide and (NH 4 ) 2 S0 4 mixture. Y. Akama, M. Ito, S. Tanaka 166. Simple determination of nonionic surfactant by adsorption method. M. Kakinuma, M. Kamaya, K. Nagashima 167. Chemiluminescent detection and imaging of reactive oxygen species in live hairless animal skin exposed to UVA. H. Yasui, H. Sakurai 168. Chemiluminescence detection of epinephrine by FIA on a microchip. T. Kaide, H. Tani, T. Shibata, E. Makino, T. Kamidate 169. Novel determination method of nonionic surfactants. Y. Gao, M. Kobayashi, S. Motomizu 170. Direct monitoring of chemiluminescence reactions in a microfluidic channel using a CCD camera. H. Tani, T. Kaide, T. Shibata, E. Makino, T. Kamidate 171. Investigation on the adsorption behavior of dioctadecyl rhodamine B at the liquidliquid interface with a confocal fluorescence microscope. X. Zheng, A. Harata 172. Chemiluminescence detection for immunoassays capillary electrophoresis. Z-L. Wang, Z-L. Gong, Y. Zhang 173. Pressurized fluid extraction for quantitative recovery of chloroacetanilide and nitrogen heterocyclic herbicides in soils. Y. Zhu, F. Guo, K. Yanagihara, Q. Li Renaissance llikai Lobby Room, Lobby Level Analytical Chemistry General Session Poster Session (02G-P)

187. Application of thermal desorption mass spectrometry for sinter processing of diamond fine particles. T. Tsugoshi, S. Kume, S. Hosomi, M. Mayuzumi 188. Optical sensing using metal complexes. M. ZakJr, H. Szmacinski 189. Analytical solution chemiluminescence for boron-subphthalocyanine. Y. Akahori, M. Ishii, D. Leznoff Renaissance llikai Wellington Ballroom, Lobby Level Chemical and Biochemical Microsensors, Nanoparticles, and Probes (154)

N. Dovichi, Presiding 1:05—147. The single cell proteome project. N. J. Dovichi, Z. Zhang, S. Krylov 1:40—148. Analysis of individual organelles by capillary electrophoresis with laserinduced fluorescence detection. E. Arriaga, C. Duffy, K. Fuller, N. Gunasekera, A. Anderson, M. Wokjamot 2:15—149. Synthesis, spectroscopic characterization, and imaging of lanthanide chelates for disease detection. D. Bornhop, J. Griffin, T. Goebel, S. Roberts, G. E. Kiefer, D. Morgan, B. Bell, M. Motamedi 2:50—150. Whole-cell microbial assay for chlorinated biphenyls. A. Mulchandani, J. K. Troxel, F. Bruhlmann, W. Chen 3:15—151. Fiber-optic ultraviolet resonance Raman spectrometry as a biophysical probe. M. Blades, C. Barbosa, R. Turner, G. Schulz, C. Haynes 3:50—152. Analytical approaches to measure events associated with exocytosis at single cells. M. Wightman, B. Bath, K. Troyer, H. Fries

FRIDAY EVENING Renaissance llikai Bora Bora Ballroom, Lobby Level New Wave of Analytical Reagents for Symbiotic Human Life with Nature (74)

4:00-6:00

Poster Session

174. Laser trapping: Picosecond fluorescence spectroscopy of single microdroplets under high pressure. F. Kttagawa, H-B. Kim, N. Kitamura 175. Multicomponent analysis of urinary metabolities by 1 H NMR for slimming diet stress and exercise stress. M. Suzuki, S. Okouchi, Y. Ishihara, S. Nagao, A. Sasaki, H. Hiraoka 176. Simultaneous determination of iron(V) and aluminum in their mixture using spectrophotometric method with chromazural S. Y. Matsui, H. Fujinuma 177. Determination of folic acid by matrixassisted laser desorption/ionization timeof-flight mass spectrometry. S-W. Cha, H-J. Kim 178. Interactions of phosphatidylinositol 3-kinase SH 3 domain with its ligand peptide studied by absorption, circular dichroism, and UV resonance Raman spectroscopies. N. Okishio, M. Nagai, S. Nagatomo, T. Kitagawa 179. Kinetic-catalytic determination of molybdenum by bromate oxidative coupling of 1,1-diphenylhydrazine with chromotropic acid. S. Nakano, Y. Fukumoto, M. Hayashi 180. Changes of tryptophan and tyrosine residues upon the RT transition of hemoglobin: Studies with near-UV CD and UV resonance Raman spectroscopy. M. Nagai, R. Li, Y. Nagai, S. Nagatomo, T. Kitagawa 181. Measurements of solvation dynamics at liquid-liquid interfaces by time-resolved total internal reflection fluorescence spectroscopy. T. Yamashita, T. Uchida, N. Teramae 182. Chemiluminescence detection of single molecule in capillary electrophoresis. J-K. Cheng, E-B. Uu, Y-M. Uu 183. Gas-phase nonlinear Raman spectroscopy using OPOs. P. Chen, C. Joyner, S. Patrick, K. Benton 184. Soft X-ray spectroscopy: Carbon content of ferromanganese crusts. G. Andermann, F. Fujiwara, G. Kawamoto, P. Wong 185. Nondestructive monitoring of wood decay process using FT-Raman technique. M. Kihara, H. Wariishi, H. Tanaka, M. Kuwahara, R. Watanabe, T. Hirano 186. Anion sensing by thiourea-based chromoionophores via hydrogen bonding and its application to food analysis. R. Kato, S. Nishizawa, T. Hayashita, N. Teramae

7:30-9:30 195. Chemiluminescence detection for microchip capillary electrophoresis. K. Tsukagoshi, M. Hashimoto, R. Nakajima, A. Arai 196. Electrochemical SNP analysis. K. Yamashita, M. Takagi, H. Kondo, S. Takenaka 197. Threading intercalator can stabilize the hetero duplex. S. Shinobu, K. Yanashita, M. Takagi, S. Takenaka 198. Selective fluorescence detection of carbohydrates by boronic acid fluorophore/ cydodextrin complex sensor. T. Hayashita, A. Tong, A. Yamauchi, N. Teramae, Z-Y. Zhang, B. D. Smith 199. Chiral amine recognition by lipophilic peptides in nonpolar solvent. T. Kuboyama, B. Mathew, S. Nakamura, M. Takagi 200. Affinity capillary electrophoresis for gene mutation assay using ODN-polyacrylamide conjugate as pseudoimmobilized phase. T. Anada, Y. Katayama, T. Arisawa, M. Maeda 201. A new fluorescent substrate for monitoring of protein kinase A activity. Y-Y. Ohuchl, Y. Katayama, M. Maeda Renaissance llikai Bora Bora Ballroom, Lobby Level Ultrasensitive Chemical Measurement and Characterization (113) Poster Session 7:30-9:30 16. Chemical state determination of vacancyimpurity complex defects in semiconductors by positron annihilation spectroscopy. M. Fujinami, K. Ohnishi, T. Sawada. T. Akahane 17. Single-molecule assays indicate that p-galactosidase is heterogeneous with respect to stabilization by magnesium. D. Craig, T. Hall, D. Goltz


18. Highly sensitive detection of transient absorption in ultrathin polymer films by the Ti0 2 /K + composite optical waveguide method. T. Nagamura, T. Adachi, K Sasaki, T. Matsuura, X-M. Chen. K. Itoh, M. Murabayashi 19. Ultratrace determination of chromium(lll) in seawater by chemiluminescence detection and the application to the speciation of chromium(lll) in seawater. K. Isshiki 20. Dissolving processes of amphiphilic molecules from air-liquid interface by laser two-photon ionization technique. I. Matsuo, H. Kawazumi 21. Submicro-RamarvHuorescence spectroscopy and imaging using a confocal optical microscope. S. Abe, T. Uchida, N. Teramae, Y. Xu, H-B. Sun, H. Misawa 22. On-chip integration of ion-pair extraction system employing lipophilic pH indicator dye and neutral ionophore. T. Horiuchi, H. Hisamoto, M. Tokeshi, T. Kitamori 23. Molecular transport by spontaneous behavior and integration of valveless chemical reaction and extraction system for environmental analysis. T. Minagawa, M. Tokeshi, T. Kitamori 24. Interface-chip between capillary electrophoresis and thermal lens microscopy for highly sensitive absorption detection. K. Uchiyama, K. Sato, M. Tokeshi. T. Kitamori 25. Electrochemical potential dependence of the ultrafast responses at Au electrode/ solution interfaces. T. Sugiyama, T. Ishio, ka, A. Harata 26. Enhancement of photothermal tensing signal by transient absorption of molecules in liquid solutions. A. Harata, Y. Naonori 27. Adsorption behavior of water-soluble dyes at the water surface studied by photoionization and surface tension measurements. K. Seno, T. Ishioka, A. Harata 28. Determination of dissolved trace elements in fresh water by high-resolution inductively coupled plasma mass spectrometry. S. Mito, H. Hasegawa, Y. Sohrin, K. Norisue, M. Matsui, M. Kawashima Renaissance llikai Auckland Ballroom. Lobby Level Separation Science: Trends for the New Century (117)

A. Jyo, Presiding 7:05—212. Proton-ionizable polyethers and their polymers for use in selective heavymetal ion separation. T. Hayashita, K. Hiratani. R. A. Bartsch 7:35—213. Thermally stable anion-exchange resin. K. Kudo, H. Kubota 8:05—214. Enhanced molecular-shape selectivity through highly oriented organic phase on silica. H. Ihara 8:35—215. A noble interpretation on the high complexability of anionic complexes in strong basic anion exchange resin. T. Miyajlma, H. Kodama, S-l. Ishiguro, J. Marinsky 9:05—216. Chromatographic separation of rare earth elements by the chelating resin having a spacer arm: Importance of steric flexibility of the functional group. T. Suzuki, T. Yokoyama, H. Kumagai 9:35—217. Phosphoric acid fiber having extremely high adsorption rate for heavymetal ions. A. Jyo, S. Aoki, K. Saito, T. Sugo Renaissance llikai Melbourne Ballroom, Lobby Level Liquid-Liquid Interfaces in Analytical Sciences (26)

R. Corn, Presiding 7:05—190. Liquid-liquid extraction of soft metal ions by polythioether derivatives as selective reagents. K. Chayama, K. Adachi, T. Mori, H. Tsuji 7:25—191. Solvent extraction of metal ions with 4-acyl-5-pyrazolone-substituted crown ethers. S. Umetani, S. Yamazaki, K. Ogura 7:50—192. Effect of hydrogen bonding on the liquid-liquid partition coefficient of tris(8-quinolinolato) metals(lll). H. Imura, T. Ozawa, K. Ohashi 8:15—193. Solar energy conversion at liquidliquid interfaces. A. Volkov 9:10—194. General isotherm of adsorption of amphiphilic molecules at liquid-liquid interfaces. V. Markin, A. Volkov

Renaissance llikai Lobby Room, Lobby Level Mterootoanarytteal Chemistry: Separations and Manipulations of Micron-Size Domains (137) Poster Session

7:30-9:30 218. Lab-on-a-chip device for fluorimetric nitrogen dioxide determination. T. Korenaga, T. Odake, L. Rong, M. Tabuchi, T. Iwata, T. Sato, H. SusaW, Y. Fujiyama, H. Nakanishi 219. Can Fourier transform infrared microscopy be used as a clinical tool? K. Yano, S. Ohoshima, T. Moriguchi, H. Katayama, K. Kumaido 220. Migration behavior of alkyl phenols by electrokinetic chromatography using sulfated cyctodextrin. M. Mori, H. Naraoka, S. Tanaka 221. Investigation of analytical enzymecatalyzed reactions in a microchip by thermal lens microscopy. M. Slyadnev, Y. Tanaka, M. Tokeshi, T. Kitamori 222. Reproducibility of quantitative analysis in capillary zone electrophoresis. N. Ikuta, T. Yoshiyama, T. Hirokawa 223. Standardization of CZE electropherograms obtained by using a field-enhanced sample stacking technique. T. Hirokawa, N. Ikuta, T. Yoshiyama, H. Okamoto 224. Microchip-based cellular analyses with a thermal lens microscope. E. TamaM, K. Sato, M. Tokeshi, M. Aihara, T. Kitamori 225. Rapid switching of chemical reaction on a chip by laser temperature control system. Y. Tanaka, M. Slyadnev, A. Hibara, M. Tokeshi, T. Kitamori 226. A rapid and sensitive immunoassay system integrated on a microchip. K. Sato, M. Tokeshi, H. Kimura, T. Kitamori 227. Anomalous laser photophoretic behavior of photo-absorbing organic droplets in water. H. Monjushiro, K. Takeuchi, H. Watarai 229. Aqueous phase system for the continuous separation of macromolecules and particulates in a microchannel. M. SeM, Y. KaWgi, J. W. Hong, T. Fujii, I. Endo Renaissance llikai Wellington Ballroom, Lobby Level Chemical and Biochemical Microsensors, Nanoparticles, and Probes (154) W. Tan,

Presiding

7:05—230. Detection of trace impurities in ultrapure chemicals using a silicon-based potentiometric sensor. O. Chyan, J-J. Chen, T. Ponnuswamy, R. Chan 7:20—231. Fiber-optic-based chemical sensor for the selective detection of uranium(VI). G. Collins 7:35—232. Supramolecular redox assembly sensors for the detection of biological pathogens. Q. Cheng, S. Zhu, R. C. Stevens 7:50—233. Stability of NASICON-based CO2 sensor under humid conditions at low temperature. T. Kkta, K. Shimanoe, N. Miura, N. Yamazoe 8:05—234. Performance characteristics of an amperometric acid sensor for wine. K. Takamura, F. Kusu, S. Ohtsuki, K. Arai, T. Nishida, T. Kusakabe 8:20—235. Characterization of multifunctional biosensor chip using random selfassembly of micropartides by magnetic force. A. Yamamura, M. Yuji, Y. Kenji, T. Eiichi 8:35—236. AFM observation of ultrathin films of silk fibroin on mica substrates. K. Yamada, Y. Tsuboi, A. Itaya

SATURDAY MORNING Renaissance llikai Wellington Ballroom, Lobby Level New Wave of Analytical Reagents for Symbiotic Human Life with Nature (74) M. Maeda,

Presiding

8:05—246. Novel fluorescence probes for hydroxyl radical, singlet oxygen, and nitric oxide-MO calculation-assisted development of new functional fluorescence probes. Y. Urano, K-l. Setsukinai, K. Tanaka, T. Miura, N. Umezawa, H. Kojima, T. Nagano

8:45—247. A novel molecular system developed for nitric oxide detection using spinexchange concept. N. Son, Y. Katayama, M. Maeda 9:05—248. Ferrocenylnaphthalene diimide: New reagent for electrochemical DNA detection. S. Takenaka 9:45—249. Binding of lipophilic peptides with amines in organic media. S. Nakamura, T. Kuboyama, B. Mathew, M. Takagi 10:05—237. Cinchona alkaloid-selective fluorescence-shift reagents prepared by molecular imprinting. H. Kubo, J. Matsui, T. Mukawa, T. Takeuchi 10:25—238. Ionic liquids as novel solvents for the solvent extraction of metal salts. R. A. Bartsch, S. Dzyuba, S. Chun Renaissance llikai Moorea Ballroom, Lobby Level Separation Science: Trends for the New Century (117)

M. Zaworotko, Presiding 8:05—253. Highly selective binding in metalorganic porous frameworks. O. Yaghi, M. Eddaoudi, T. Reineke, H. Li 8:35—254. New mesoporous molecular materials. J. Hupp 9:05—255. Composite materials by design. M. Zaworotko, A. Mondal, B. Moulton 9:35—256. Porous ordered materials constructed by the strategy of molecular tectonics: Applications in separation science. J. D. Wuest 10:05—250. Active materials based on mesocomposite protein/salt systems. A. Coleman, W. Peguet, C. Annarelli, K. Shigeta, K. Taniwaki 10:35—251. Porous materials through selfassembly of polyacids. S. Valiyaveettil, L. Rong, J. J. VittaJ 10:55—252. Toward a green organic chemistry in the solid state using linear molecular templates. L. R. MacGillivray, J. L. RekJ, J. A. Ripmeester Renaissance llikai Melbourne Ballroom, Lobby Level Novel Measurements of Gas-Phase Ions (121)

J. Traeger, Presiding 8:05—257. Recent developments in ionization methods for mass spectrometry: An overview and prospects. G. Van Berkel 8:45—260. Effects of running buffer, sheath liquid, ionization constant, micelle-forming agent, and analyte concentration on the sensitivities of synthetic drugs in MEKC/ ESI-MS analysis. G-R. Her, J-L. Chung, S. C. Hsiao 9:15—261. Sonic spray ionization: Novel atmospheric-pressure ionization for mass spectrometry. Y. Hirabayashi, A. Hirabayashi, M. Sakairi, H. Koizumi 9:45—262. Fundamental aspects of the laser spray LC-MS interface. K. Hiraoka 10:15—258. Nonpolar, charge-transfer matrices for matrix-assisted laser desorption/ ionization mass spectrometry. P. Limbach, S. Macha 10:45—259. Spray diagnostics in DC and modulated electrosprays. A. Vertes, M. GaJicia, J. Gauntt Renaissance llikai Pago Pago Ballroom, Lobby Level Microbioanalytical Chemistry: Separations and Manipulations of Micron-Size Domains (137) J . M. Ramsey,

Presiding

8:05—263. Microfabricated intrachannel connections for controlling material transport. S. C. Jacobson, C. T. Culbertson, J. Khandurina, R. S. Ramsey, J. M. Ramsey 8:45—264. Chromatographic and flow injection microsystems for biochemical analyses. J . P. Kutter, W. Rong, A. M. Jorgensen, K. B. Mogensen, N. J. Petersen, O. Geschke, P. Telleman 9:25—265. Biomimetic molecular environment in microfabricated devices: Immunoassay chip and cellular release experimental chip. T. Kitamori 10:05—266. High-performance capillary LC using a monolithic silica column. N. Tanaka, H. Kobayashi, T. Ikegami, K. Hosoya, N. Ishizuka, H. Minakuchi, K. Nakanishi, T. Ikegami

10:45—267. Uniformed-sized molecularly imprinted polymers selectively modified with hydrophilic external layer Application to biomedical analysis. J. Haginaka Renaissance llikai Auckland Ballroom, Lobby Level Raman Spectroscopy: Coming of Age in the New Millennium (171)

R. Turner, Presiding 8:35—268. Surface-enhanced Raman scattering from mass-selected silver clusters: A latter-day note on the mechanism of SERS. M. Moskovits, K. Bosnick, T. Haslett, H. Wang 9:00—269. Interpretation of surface-enhanced Raman spectra. R. Aroca, B. Skadchenko, I. Hung 9:25—270. Linear and nonlinear surfaceenhanced Raman scattering at the singlemolecule level. K. Kneipp, H. Kneipp, I. Itzkan, R. Dasari, M. Feld 9:50—271. Application of surface-enhanced Raman scattering to complex biomolecules: Low-density lipoproteins and photosynthetic reaction centers. G. Chumanov, L. Quaroni, W. White 10:15—272. In situ Raman spectroscopy of lubricated sliding contacts. P. Stair, A. Cheong 10:40—273. Characterization of microstructure of graphites by Raman spectroscopy. G. Katagiri 11:05—274. Raman spectroscopy of conjugated polymers and oligomers. Y. Furukawa 11:30—275. Resonance Raman examination of polyhalomethane photodissociation and photoisomerization reactions. D. L. Phillips, X. Zheng

SATURDAY AFTERNOON Renaissance llikai Moorea Ballroom, Lobby Level Separation Science: Trends for the New Century (117) R. Rogers,

Presiding

1:05—278. Building a better mousetrap: Ligand design with molecular mechanics. B. P. Hay 1:35—279. Liquid-liquid separation of NaOH using fluorinated alcohols and phenols. B. A. Mover, P. V. Bonnesen, C. K. Chambliss, T. J. Haveriock 2:05—276. Chip-based integrated optics. F. Lytle, B. Splawn 2:35—277. Molecular and superanion capsules: Isolation of fullerenes and potynudear metal cationic clusters. C. Raston, A. Drijaca, M. Hardie, C. Sandoval 3:35—281. Chemical and physical characteristics of room temperature ionic liquids (and solid-state analogs): Implications for their use as solvent alternatives. R. D. Rogers, A. E. Visser, R. P. Swatloski, W. M. Reichert Renaissance llikai Melbourne Ballroom, Lobby Level Novel Measurements of Gas-Phase Ions (121) J . Traeger,

Presiding

1:05—282. Miniaturized TOF mass spectrometers for biological research and bioagent detection. R. Cotter, S. Kovtoun, M. Prieto, V. Laiko 1:45—283. Development of the ion trap mass spectrometer for analyzing individual airborne particles and their interactions with the environment. P. T. A. Reilly, R. P. Rodgers, W. B. Whitten, J. M. Ramsey 2:10—284. Quadruple mass filtered external ion accumulation for FTICR mass spectrometry. C. L. Hendrickson, J. P. Quinn, M. R. Emmett, A. G. Marshall 2:35—285. Liquid microjet mass spectrometry. M. Burrtine


3:00—286. Desorption/ionization of porous silicon (DIOS): A multidimensional technique for small-molecule analysis. J. J. Thomas, Z. Shen, M. G. Finn, K. Broo, C. Averbuj, J. Wei, G. Siuzdak 3:25—287. Poryaniline coatings for durable emitters in nanospray mass spectrometry. T.Wood 3:50—288. Development of enabling mass spectrometry methods for proteome analysis. L. Li Renaissance llikai Pago Pago Ballroom, Lobby Level Microbioanalytical Chemistry: Separations and Manipulations of Micron-Size Domains (137)

J. M. Ramsey, Presiding 1:05—289. Strategies for the design of multiplexed microsystems for biochemical and biological assays on a chip. D. J. Harrison, S. B. Cheng, C. Skinner, R. Smith, R. Szarka, V. Ferdui 1:45—290. A PDMS (polydimethylsiloxane)glass hybrid microchip for gene amplification. J. W. Hong, T. Fujii, M. Seki, T. Yamamoto, I. Endo 2:25—291. Highly multiplexed capillary electrophoresis. E. S. Yeung, X. Gong, G. Xue, L Ma, S. H. Kang, Y. Zhang, H. M. Pang 3:05—292. Nanochip technology for human genome analysis and single DNA molecule analysis. Y. Baba 3:45—293. Integrated separation and electrochemical detection of DNA in microfluidic devices. W. Kuhr, S. Brazill, C. B. Davis, B. Roy Renaissance llikai Auckland Ballroom, Lobby Level Raman Spectroscopy: Coming of Age In the New Millennium (171)

T. Kitagawa, Presiding 1:05—294. New instrumentation for UV resonance Raman spectroscopy of giant proteins and its successful applications. T. Kitagawa, M. Aki, T. Ogura 1:30—295. Raman spectroscopy as a new discovery tool in carbohydrate chemistry. G. R. Loppnow, P. Arboleda 1:55—296. ATR-Raman spectroscopy beyond sensitivity and diffraction limitation. M. Futamata 2:20—297.2-D vibrational spectroscopies for selective Raman spectroscopy. J. Wright 2:45—298. In situ and stand-off Raman imaging using fiber-optic image guides and dimension reduction fiber arrays. M. Angel, C. Carter, M. Myrick, S. Sharma 3:10—299. A miniature deep-UV Raman microscope with fluorescence imaging. W. Hug, R. Reid, R. Bhartia, M. StorrieLombardi 3:35—300. Rapid-mix the slow way: Raman characterization of functional intermediates by encapsulation of proteins in porous sol-gels. J. M. Friedman 4:00—301. Fiber-optic-linked UV resonance Raman spectroscopy for bioanalytical and biophysical investigations. R. Turner, C. Barbosa, M. Blades, S. Greek, C. Haynes, G. Schulze Renaissance llikai Wellington Ballroom, Lobby Level New Wave of Analytical Reagents for Symbiotic Human Life wfth Nature (74) T. Lewis,

Presiding

1:05—239. Use of liquid core waveguides in environmental analysis: Light up your lab with liquid-filled optical fibers! R. Dasgupta 1:45—240. Microchip capillary electrophoresis with on-line chemiluminescence detection. K. Tsukagoshi, M. Hashimoto, R. Nakajima, A. Arai 2:05—241. DNA sensing through the aggregation of oligonucleotide-modified nanoparticles. T. Ihara, K. Kurohara, Y. Chikaura, A. Jyo 2:25—242. Sequence and chain-length discrimination of oligonucleotides using DNAcontaining synthetic polymer micelles for gene diagnosis. T. Mori, M. Maeda 2:45—243. Novel immunodiagnostic system by core-shell-type polymeric micelle. Y. Nagasaki, M. Akiyama, Y. Yamamoto, K. Kataoka


ANYL/TECHNICAL PROGRAM

3:05—244. Direct electrochemistry of cytochrome c and glucose oxidase covaleintly immobilized on oo-functjonalized alkanethiol monolayer electrode and biosensor applications. K. Nakano, T. Yoshrtake, K. Doi, Y. Yamashita 3:25—245. Electrochemical sensors for nitric oxide and nitrite analysis. I. Taniguchl, A. Kubo, K. Inada

10:40—335. Freeze concentration based on rapid phase transformation phenomena. R. Hartel, B. Liang, Y. Shi 11:05—338. Preparation of metal oxides powder from water-CTAB-hexanol microemulsion. C. Y. Tai, Y-C. Wu, P-Y. Hsiao

Renaissance llikai Lobby Room, Lobby Level

Novel Measurements of Gas-Phase Ions (121)

Analytical Chemistry General (02G-P) Poster Session 1:00-3:00 302. Detection of hypericin and its derivatives in Saint-John's-wort by HPLC. C. Fogliani 303. Separation of aldehydes and alcohols by HPLC-refractive index. S. Board 304. Differences in the hydroxyl groupsolvent and carbonyl group-solvent specific interactions monitored by HPLC between the methanol/water and acetonitrile/ water solvent systems. W. J. Cheong, Y. I. Kum 305. Determination of sulfonated azo dyes in food by ion-pair liquid chromatography with photodiode array detection. M-R. Fun, K-J. Chia 306. Chromatographic separation of hydroxide ion. W. Hu 307. Chiral separation of derivatized D,Lserine by Y-cydodextrin HPLC. T-Y. Kim, hW. Kim 308. Preparation of porous polymer resins by copolymerization of monomers in template silica gel and their application to column packings. K. KHahara, M. Tamura, I. Yoshihama, T. Masuda, K. Nagashima, S. Aral, J. Yamashita 309. Studies on trigonelline and nicotinic acid in green and roasted coffees. M. Mlnamtsawa, S. Nakajima, H. Minamisawa, S. YoshkJa, N. Takai 310. High-performance liquid-chromatographic separation of carbohydrates on a stationary phase prepared from polystyrene-based resins and novel tertiary diamines. T. Masuda, K. Kitahara, S. Arai 311. Paper electrophoresis of the phosphonium and ammonium salts: Comparison with the HPLC methods. J. Koketsu, K. Makita, T. Okuyama, F. Ando 312. Ion-pair extraction of EDTA and its complexes with tetraalkylammonium ion. K. Satoh 313. High-performance liquid chromatographic determination of endocrine disruptive alkyl and chlorophenolic compounds as dansyl and ferrocenyl derivatives. Y. Kato, Y. Esaka, M. Goto, B. Uno 314. High-periormance liquid-chromatographic determination of cocaine using postcolumn trisphenylenebenzobisoxazole) and poly(pphenylenebenzobisthiazole). Y. Takahashi

Royal Hawaiian Regency Room 3, Lobby Level Self-Ordering Phenomena in Polymeric Systems: From Microscopic to Mesoscopic Scales (056) E. J . Amis,

Presiding

1:05—510. Phase separation and gelation of polymer-dispersed liquid crystals. T. Ohta 1:50—511. Polymerization kinetics and structure retention of lyotropic liquidcrystalline systems. A. Guymon, C. Lester, C. Colson, S. Smith 2:15—512. Scaling of rheological properties in polyelectrolytes and mixed polyelectrolyte systems in aqueous solutions. M. Tsianou, K. Thuresson 2:40—513. Numerical study of phase separation under temperature gradient. T. Araki, H. Tanaka 3:05—514. High-throughput studies confined dewetting on gradient-patterned surfaces. A. Karim, A. Sehgal, E. Amis 3:30—515. Alcohol cluster formation on silicon oxide surfaces from cyclohexanealcohol binary liquids. M. Mizukami, K. Kurihara 3:55—516. Periodic bursting of microbeads induced by laser. N. Magome, S-l. Nomura, M. Ichikawa, K. Yoshikawa Royal Hawaiian Regency Room 1, Lobby Level

1:05—589. Chemical amplification resists for excimer laser lithography: Progress and evolution from 248 to 157 nm. H. Ito 1:45—590. Development of subpicosecond pulse radiolysis system for investigation of reaction mechanisms in resist materials for electron-beam and X-ray lithography. T. Kozawa, A. Saeki, S. Tsuji, Y. Yoshida, S. Tagawa 2:05—591. Radiation chemistry for microfabrication of conjugated polymers and carbon nanotubes. L. Dai 2:25—592. Raman spectral mapping of UVirradiated polypropylene. G. Graeme, I. Blakey 2:55—593. New photosensitive polyimide resin based on photooxidation-induced polycondensation (POP) mechanism. Y. Tajima, Y. Shigemitsu, E. Takeuchi, K. Takeuchi 3:15—594. UV excimer laser irradiation of polystyrene. H. Griesser, M. Browne 3:35—595. Fundamental studies of dissolution inhibition in a poly(norbomene-a/fmaleic anhydride) based. F. Houlihan, G. Dabbagh, I. Rushkin, R. Hutton, D. Osei, K. Bolan, O. Nalamasu, E. Reichmanis, A. Reiser, Z. Yan, J. Sousa 3:55—596. Plasma oxidation of selfassembled monolayers: Radiation effects during XPS analysis. P. Moulds, G. George, F. Elms 4:15—597. Effect of solvents on grafting and curing reactions with charge-transfer complexes. L-T. Ng, J. Garnett, D. Nguyen, E. Zilic

New Methodologies in Polymer Synthesis (149)

Royal Hawaiian Regency Room 2, Lobby Level

Structures and Properties of Polymer Alloys (055)

High-Performance Polymers (050)

M. Dadmum, K. J. Kim, Presiding

M-A. Kakimoto, Presiding 1:05—456. Synthesis and properties of wholly aromatic poly(thioether-ketone)s bearing naphthalene unit. S. Matsumura, N. Kihara, T. Takata 1:25—457. Synthesis of soluble polyimides from unsymmetrical diamines containing trifluoromethyl groups. S. Kim, I. Chung, I. In 1:55—458. Synthesis and properties of hyperbranched aromatic polyamides prepared from diamines and trimesic acid. M. Jikei

B. Hsieh, Presiding 1:05—581. Soluble and solid-phase polymers for combinatorial organic chemistry. K. D. Janda 1:35—582. Dendrimerization leads to combinatorial constructs. G. R. Newkome 2:05—583. A chemically diverse, conducting polymer composite-based "electronic nose." N. Lewis, S. Briglin, M. Fruend, E. Severin 2:25—584. Polymerization of monosubstituted acetylenes with a liquid crystalline moiety by methathesis catalysts. C-S. Hsu, C-H. Ting 2:45—585. New synthesis methods for the polymer synthesis. C. Yang, D. Zhang 3:05—586. One-step syntheses of trisubstituted amines from urea and their conversion to trifunctional crosslinking agents. N. D. Sachinvala, D. L. Winsor, T. L. Vigo, N. R. Bertoniere 3:25—587. Selective synthesis of 7t-conjugated functional oligomers by crossmetathesis. T. Yasuda, J. Abe, T. lyoda, T. Kawai 3:45—588. "Radical-controlled" oxidative polymerization of phenols. H. Higashimura, K. Fujisawa, Y. Moro-Oka, S. Namekawa, M. Kubota, A. Shiga, H. Uyama, S. Kobayashi Sheraton Moana Surfrider Ballroom

1:05—937. Self-Assembly of poly(ferrocene) block copolymers: A route to organometallic cylinders and nanotubes. I. Manners


1:40—939. Crystallization and microdomain morphology of polyethylene-atactic polypropylene block coploymers. K. Sakurai, S. Shinkai, W. Kacknight, D. Lohse, S. Sakurai, M. Ueda, S. Nomura 2:05—945. Phase transformations in nanoconfined environments. S. Cheng, L. Zhu, Q. Ge, R. Quirk, E. Thomas, B. Hsiao, F. Yeh, B. Lotz 2:30—963. Novel multiple interwoven mesostructures and mikto-arm copolymer melts. S. Hyde 2:55—951. Lamellar ordering by uniaxial stretching of cross-linked SBS triblock coploymers. S. Sakurai, S. Aida, S. Nomura 3:20—959. Macroscopic phase decomposition in styrene-butadiene block copolmers driven by thermo-oxidative reaction. T. Kyu, S. Fan 3:45—967. Diblock and triblock thin films with nanochannels. G. Liu

SUNDAY EVENING Sheraton Moana Surfrider Ballroom High-Performance Polymers (050) Poster Session

7:30-9:30 463. Metal patterning on organopolysilanecoated films by electroless deposition. E. Tabei, M. Fukushima, M. Aramata, Y. Hamada, S. Mori 464. n-Conjugated aromatic ladder polymer bridged by sulfonio groups. K. Oyaizu, A. Hay, F. Mitsuhashi, E. Tsuchida, K. Miyatake 465. New sulfonic acid-containing polymer. K. Miyatake, A. Hay, E. Tsuchida 466. Degradability and morphology for films and fibers of polylactic acid blended with polycaprolactone or polybutylenesuccinate. N. Kuriyama, S. Takahashi, H. Okamoto, H. Hyodo, Y. Nishimura, K. Kato, T. Kasemura 467. Preparation and properties of linear and hyperbranched polyamide copolymers from AB and AB 2 monomers. K. Fujii, M. Jikei, M-A. Kakimoto 468. Toughening tetrafunctional epoxy resins using modified polyetherimide. Y. Gao, K. Siow 469. Preparation and properties of hyperbranched aromatic polyimides via polyamic acid methyl ester precursors. K. Yamanaka, M. Jikei, M-A. Kakimoto 470. AB-type semicrystalline polyimides based on hydroquinone, resorcinol, and catechol. X-Q. Liu, M. Jikei, M-A. Kakimoto 471. Synthesis and properties of macromonomers having phospholipid polar groups. H. Yamasaki, K. Onimura, H. Tsutsumi, T. Oishi 472. Lamella thickening in nascent poly(acrylonitrile) upon annealing. D. Sawai, T. Kanamoto, M. Miyamoto 473. Uniaxial drawing of poly(i_-lactic acid) melt-crystallized films. T. Imamura, D. Sawai, M. Itou, T. Kanamoto, S-H. Hyon 474. Structure and properties of extrusiondrawn poly(vinylidene fluoride). K. Nakamura, T. Kanamoto, Y. Takahashi, T. Furukawa 475. Two-stage drawing of a blend of ultrahigh molecular weight polyethylene and poly(tetrafluoroethylene) reactor powders. T. Yamanoue, T. Kanamoto, M. Ito, D. Sawai 476. Effect of bond defects on the structure of drawn poly(vinylidene fluoride). Y. Watanabe, K. Nakamura, T. Kanamoto, M. Ito 477. Dynamic mechanical relaxation behavior of polysulfone-polycarbonate copolymers. J. Lee, K. Lee, S. Hwang, J. Jho 478. Lithium ion-conducting gel polymer electrolytes based on a new host polymer. Y. Oyama, M. Mehta, T. Fujinami 479. Synthesis and characterization of lithium ion-conducting polymer electrolytes based on new copolymers. T. Mitani, M. Mehta, T. Fujinami 480. Structural defects generated upon solidstate extrusion drawing of ultrahigh molecular weight polyethylene reactor powder. J. Enta, D. Sawai, T. Kanamoto 481. Synthesis and properties of acrylatesulfobetaine zwitterionomers. M. Gauthier, T. Carrozzella, K. Nielsen, A. Penlidis 482. Crystalline poly(2,5-dimethyl-1,4phenylene oxide). S. Namekawa, H. Higashimura, M. Kubota, A. Shiga, K. Fujisawa, Y. Moro-Oka, H. Uyama, S. Kobayashi

483. Selective synthesis of novel cyclic phenylazomethine monomers. M. Higuchi, A. Kimoto, S. Shiki, K. Yamamoto 484. Lithiu»i ion conductivity of aluminophosphonate polymers. Y. Buzojima, T. Fujinami, M. Mehta 485. Preparation and proton conductivity of organic-inorganic hybrid polyelectrolyte systems. Y. Yoshida, M. Nakamichi, M. Mehta, T. Fujinami 486. Proton-conducting organic-inorganic hybrid borosiloxane networks. Y. Yang, R. Harada, Y. Yoshida, M. Mehta, T. Fujinami 487. Preparation and properties of porous polyimide films. K. Arimatsu, T. Takeichi 488. Polybenzoxazine-based composites: Studies on using polyurethane as modifier. Y. Guo, T. Agag, T. Takeichi 489. Synthesis and characterization of poly{[1-0-[2-(methacryloyloxy)ethyl]2,3,4,6-0-(tetracyanoethyl) glucopyranoside}]. R. Nishida, S. Saito, T. Ishikawa 490. Preparation and electrochemical characterization of a borosiloxane solid electrolyte containing oligoether chains. R. Kurono, M. Mehta, T. Fujinami 491. Correlation between craze and/or neck structure and chain entanglement of polyester films. A. Takeno, M. Miwa, T. Yokoi 492. Studies on preparation and properties of novel poly(urethane-amide)s. K. Suefuji, T. Takeichi, K. Inoue 493. New positive-type photosensitive poly(amic acid tert-butyldimethylsilylester) with diazonaphthoquinone. Y. Watanabe, Y. Sakai, T. Hayakawa, S. Yuji, M. Ueda 494. Characterization and processing of TLCP blend with PEI: Effect of surface functionalization. Y. Seo 495. Nonisothermal crystallization of PEEK. Y. Seo 496. Polybenzoxazine/layered silicate hybrids as novel high-performance nanocomposites. R. Zeidam, T. Agag, T. Takeichi 497. Novel separation procedure for biopolymers by using UCST polymer-coated magnetite particles. H. Furukawa, N. Onishi, K. Kataoka, K. Ueno 498. Palladium-catalyzed polycondensations of aromatic dichlorides with bisacrylamides or diamines and carbon monoxide. M. Yoneyama, H. Takakusaki, S. Ishibe 499. Preparation of (1,6)-3,4-di-0-alkyl-2,5anhydro-D-glucitol as a stationary phase and its resolving ability for metal cations and amino acid derivatives in HPLC. S. Umeda, T. Satoh, T. Kakuchi, K. Yokota 500. Application of polysilane-polyaniline composite film to electric material. T. Ohtaki, K. Kabeta, M. Watanabe 501. Preparation of pitch-based thermosetting polymers and adhesive properties. M. Ota, Y. Aoyagi, S. Miyazaki, M. Shibasaki 502. Liquid crystalline epoxies. E. Douglas, E. Robinson, J. Mecholsky, Jr., J. Feng 503. Novel polyarylene/polymides as high-K, low-loss dielectrics. G. Jamison, D. Wheeler, B. Turtle 504. Intercalation of unentangled polymer melts in layered nanostructures: A coarsegrained molecular dynamics simulation study. R. K. Bharadwaj, R. A. Vaia, B. L. Farmer 505. Molecular dynamics simulations of norbornene-POSS polymers. B. L. Farmer, R. K. Bharadwaj, R. J. Berry 506. Utilization of khaya seed oil in the stabilization of PVC against thermal degradation. F. Okieimen, C. O. Eromosele 507. Direct synthesis of aromatic polycarbonate by oxidative carbonylation of bisphenol-A using precisely designed Pd catalyst system. H. Ishii, M. Goyal, M. Ueda, K. Takeuchi, M. Asai 508. Molecular modeling of the deformation of polymer chains. R. Pachter, B. Farmer, W. Sivak, W. Adams, R. J. Young 509. Elastic properties of soft polycarbonate resin. H. Tamura, M. Hironobu, S. Shuji Hilton Hawaiian Village Coral Ballroom IV, Mid-Pacific Conference Center Precision Polymerizations and Controlled Supramolecular Architectures (057) Poster Session 7:30-9:30 518. Synthetic peptide/biocompatible polymer macromolecular complexes with tertiary organization: A step toward preparation of synthetic biofunctional materials. I. Khan, K. Pemawansa

519. Helix induction and induced CD of poly((4-dihydroxyborophenyl)acetylene) with nucleic acid analogs. H. Kawamura, K. Maeda, E. Yashima, Y. Okamoto 520. Regioselectivity control for synthesis of functional polyesters by lipase catalyst. H. Uyama, S. Kobayashi 521. Vines-twining polymerization: A new method for synthesis of polymer-polymer inclusion complexes. J-l. Kadokawa, Y. Kaneko, H. Tagaya 522. Producing nanopatterns of proteins using particles lithography. J. Garno, K. Wadu-Mesthrige, B. Stackpoole, G-Y. Liu 523. Rigid 1,3,5-phenylene-based dendritic porphyrins and phthalocyanines. M. Kimura, K. Hanabusa, H. Shirai, N. Kobayashi 524. Precise copolymerization of methacrylates with 1,3-dioxolane. T. Matsumoto, T. Endo 525. Formation of inclusion complexes between amylose and various polyethers by vines-twining polymerization. S-l. Nagase, J-l. Kadokawa, Y. Kaneko, H. Tagaya 526. Triblock nanotubes and hollow nanospheres. G. Liu, S. Stewart 527. Self-organization of a dipeptide-core dendrimer to form a micrometer-scale fibrous assembly with a helical superstructure. W-D. Jang, D-L. Jiang, T. Aida 528. Steroid cyclophanes at the air-water interface: Dynamic cavity conversion and its consequence in piezoluminescence behavior. J-l. Kikuchi, K. Ariga, Y. Terasaka, H. Tsuji 529. Living radical polymerization of acrylate, methacrylate, and styrene with halfmetallocene-type ruthenium complexes. T. Ando, Y. Watanabe, M. Kamigaito, M. Sawamoto 530. Stereocontrol by Lewis acid catalysts in radical polymerization of a-(alkoxymethyl) acrylates. S. Habaue, H. Baraki, Y. Okamoto 531. Coordination polymer of porphyrins. Y. Kobuke, K. Ogawa, N. Nagata 532. Synthesis of all acrylic ABA-type triblock copolymers by transition-metal-mediated living radical polymerization. T. Ohtake, M. Kamigaito, M. Sawamoto 533. Living radical polymerization and copolymerization of styrene with iron(lll) dithiocarbamate/AIBN systems. M. Nishimura, M. Kamigaito, M. Sawamoto 534. Controlled radical polymerization of vinyl monomers mediated by stable ruthenium-carbene complexes bearing /V-heterocyclic carbene ligands. F. Simal, A. Demonceau, A. Noels 535. Structural control in enzymatic oxidative polymerization of phenols. N. Mita, S-l. Tawaki, H. Uyama, S. Kobayashi 536. Polymerization of vinyl chloride in the presence of Lewis acids. Y. Oki, Y. Okamoto 537. Synthesis of aromatic polyethers with low polydispersities by chain-growth polycondensation. Y. Suzuki, S. Hiraoko, T. Yokozawa 538. Optically active binaphthyl metallosalen hybrid polymer: A rational design of helical molecules. T. Takeuchi, Y. Furusho, T. Takata 539. Chain-growth polycondensation for welldefined polymides study of bases. R. Sugi, S. Hiraoka, T. Yokozawa 540. Asymmetric polymerization of A/-substituted maleimide with chiral bisoxazoline derivative/organometal complexes. K. Onimura, H. Tsutsumi, T. Oishi 541. Preparation of DNA catenanes and direct observation of their structures by atomic force microscopy. H. Yamaguchi, K. Kubota, A. Harada 542. Radical polymerization of chiral methacrylate bearing urethane bonds and 1,1'binaphthalene moieties. Y-K. Lee, K. Onimura, H. Tsutsumi, T. Oishi 543. Asymmetric anionic polymerization of /V-1-anthrylmaleimide with diethylzincchiral ligand complexes. Y. Isobe, K. Onimura, H. Tsutsumi, T. Oishi 544. Preparation and properties of monoclonal antibodies for viologens. H. Yamaguchi, A. Harada 545. Synthesis of amylose-polyester inclusion complex by vines-twining polymerization. Y. Kaneko, J-l. Kadokawa, A. Nakaya, H. Tagaya 546. Catalysis via complementary hydrogenbonding interactions: Catalysis of a nucleobase via multiple hydrogen-bonding interactions. K. Konishi, M. Tominaga, T. Aida

547. Catalysis via complementary hydrogenbonding interactions: A new approach toward supramolecular catalysis. K. Oosaki, K. Konishi, T. Aida 548. Polymerization of ethylene and lactones catalyzed by 2,2'-tellurobis(aryloxo)titanium complexes. Y. Nakayama, K. Watanabe, N. Ueyama, A. Nakamura, A. Harada 549. Effects of charges on the mobility of cyclodextrin onto the thread. Y. Kawaguchi, A. Harada 550. Synthesis of head-to-tail ordered polyurethanes from p-isocyanatobenzyl isocyanate and ethylene glycol. T. Hikita, M. Ueda, K. Takeuchi, M. Asai 551. Asymmetric anionic polymerizations of chiral (fl)-(+)- and (S)-(-)-/V-a-methylbenzylmaleimides with chiral ligandorganometal complex. T. Oishi, H. Zhou, K. Onimura, H. Tsutsumi 552. Inclusion complex formation between cyclodextrins and inorganic polymers containing silicon. H. Okumura, Y. Kawaguchi, M. Okada, A. Harada 553. Characterization of individual block sizes of poly(styrene-Wocfc-isoprene) series using liquid chromatography at the chromatographic critical condition (LCCC). W. Lee, T. Chang 554. Principle of topochemical polymerization of 1,3-diene monomers in the crystalline state. A. Matsumoto, T. Tsubouchi, S. Nagahama 555. Synthesis of liquid-crystalline polyketones by asymmetric copolymerization. Y. Kawashima, K. Nozaki, T. Hiyama 556. Space size effect of host channels in inclusion polymerization. T. Tanaka, M. Chikada, K. Sada, M. Miyata, A. Kajiwara, M. Kamachi 557. Crystal structures and solid-state polymerization of alkylammonium sorbates. K. Inoue, K. Sada, M. Miyata, S. Nagahama, A. Matsumoto 558. Living cationic polymerization of cyclopentadiene with SnCI4 and related Lewis acids. M. Ouchi, M. Kamigaito, M. Sawamoto 559. Controlled synthesis of side-chain-type polyrotaxanes. H. Kawasaki, N. Kihara, T. Hasegawa, T. Takata 560. Molecular paneling via coordination: Guest-controlled assembly of open cone and tetrahedron structures from eight metals and four ligands. K. Umemoto, K. Yamaguchi, M. Fujita 561. Inclusion complexes between microporous molybdenum(ll) dicarboxylates and organic polyethers. S. Takamizawa, M. Furihata, S. Takeda, K. Yamaguchi, W. Mori 562. Shape-persistent and shape-adaptive polymers based on restricted rotation. K. Shimizu, D-S. Choi, Y. Chong, J. Berch, C. Degenhardt 563. Thermal polymerization of 1,2-dithiane and characterization of the polymer. G. Kojima, K. Endo 564. Synthesis of ladder polymer by topochemical polymerization of alkylendiammonium disorbates in the crystal state. S. Nagahama, A. Matsumoto 565. Polymerizations of vinyl monomer by manganese complex-halogen compound. A. Yachi, E. Kiyoshi 566. Cylindrical, dendritic nanoobjects: Synthesis, behavior at interfaces, and individual manipulation. L. Shu 567. Toward dendrimers with polarity gradient. C. Modrakowski 517. Helical and higher structurally ordered poly(3-methyl-4-vinylpyridine): Facile preparation of helical motifs for synthetic proteins. I. Khan, L. Ortiz, B. Sannigrahi, K. Gordon


Sheraton Moana Surfrider Ballroom II Radiation Chemistry of Polymers (209)

H. Griesser, Presiding 7:05—608. Limits to resolution in NMR spectra of radiation cross-linked rubbers. A. Whittaker 7:25—599. Radiation cross-linking of polyblend system: Radiation degradative and cross-linking-type polymers. J. Sun 7:35—598. High-resolution 19F solid-state NMR of radiation-modified fluoropolymers. U. Scheler, B. Fuchs, T. Miyoshi 8:15—878. Interpenetrating polymer networks using radiation methods. R. Burford, B. Shirodkar 8:35—869. High energy radiation chemistry of some polyimides. D. J. T. Hill, M. M. Alexander, S. Devasahayam, J. W. Connell 9:05—600. Oxidation degradation over long term in high-density polyethylene irradiated with ion beam. Y. Hama, T. Oka, F. Yatagai Sheraton Moana Surfrider Ballroom Structures and Properties of Polymer Alloys (055) Poster Session

7:30-9:30 929. Dynamics of morphological transitions in mesophases. M. Nonomura, T. Ohta 930. Some features of dynamic mechanical behaviour of thermoplastic elastomer. T. I. Medintseva, N. A. Erina, E. V. Prut 935. Mode selection in phase separation of polymer mixtures under temporal and spatial modulations. T. Ito, K. Ejiri, Q. TranCong 941. Growth of gyroid grain in the mixture of a diblock copolymer and a homopolymer. H. Hasegawa, N. Eiji, H. Takeji 942. Introduction of metal nanoparticles into the nanoporous films prepared from the bicontinuous structure of block copolymer. M. Adachi, A. Okumura, T. Hashimoto 943. Microdomain morphology of polyisoprene-block-poly (vinyl methyether) triblock copolymers. Y. Kazuhiro, H. Hasegawa, T. Hashimoto 944. Solid-state structures of graft copolymers having crystalline side chains. K. Inomata, Y. Sakane, T. Nose 948. Synthesis of new Chitosan derivatives for the electroless plating. M. Nishiyama, M. Morimoto, H. Saimoto, Y. Shigemasa, Y. Omura 950. Investigation of rapid structural changes in heat setting of oriented polymer blends. M. Cakmak, S. Bicakci, J. Choi, T. Serhatkulu 955. Dynamic infrared spectroscopic studies on segmented polyurethaneureas. S. Nomura, S-l. Sakurai, K. Kaede, S. Shutoh 965. Reaction mixing of polypropylene and polyisoprene elastomer. O. P. Kuznetsova, L. M. Tchepel, A. N. Zelenetskiy, E. V. Prut

MONDAY MORNING Royal Hawaiian Regency Room 2, Lobby Level High-Performance Polymers (050)

M-A. Kakimoto, Presiding 8:05—609. Synthesis and property of eletrochromic polyimides. W. Wang, H. Zheng, L. Dinescu, P. Desjardins, L. Kuang 8:35—610. Aromatic polyamides with low polydispersities from chain-growth polycondensation. T. Yokozawa 9:05—611. Functional polymers derived from a biphenol containing a naphthalic anhydride moiety. A. Hay, Y. Meng, A. Hlil, J. Lu 9:35—612. Aramides prepared from macrocyclic monomers and in the presence of crown ethers. H. Gibson, D. Nagvekar, S. Bhattacharjee, H. Lefebvre 10:05—613. Preparation of polyimide with very low birefringence for thermoforming grooves of core pattern of optical waveguide. H. Ashitaka 10:25—614. Synthesis and properties of polyimide-g-nylon 6 and nylon 6-fcpolyimide-b-nylon 6 copolymers. F. Harris, Y. Pae, S. Cheng 10:55—615. Preparation and phase behavior of novel amphiphilic block copolymers. M. Hillmyer


117

MACR/TECHNICAL PROGRAM

Sheraton Moana Surfrider Parlor Self-Ordering Phenomena in Polymeric Systems: From Microscopic to Mesoscopic Scales (056)

K. Yoshikawa, Presiding 8:05—616. Single-molecule dynamics in biological systems. T. Yanagida 8:50—617. Self-assembled structures in biological polyelectrolytes. C. Safinya 9:35—618. Effects of multivalent counterions on macroionic systems. I. Rouzina, V. A. Bloomfield, B. Shklovskii 10:20—619. Stepwise assembly of stereoregular poly(methyl methacrylate)s with a double-stranded nanostructure. K-l. Hamada, T. Serizawa, M. Akashi, T. Kitayama, K-l. Katsukawa, K. Hatada 10:45—620. DNA condensation by multivalent cations. V. Bloomfield, I. Rouzina, C. Baumann, S. He 11:10—621. Switching in the higher-order structure of DNA. K. Yoshikawa Sheraton Moana Surfrider Ballroom Photophysics and Photochemistry of Polymeric Materials (068)

K. Sugita, Presiding 8:05—622. Studies of multiphoton processes in synthetic polymer antennas. J. Guillet, R. Murphy 8:35—623. Energy transfer and dynamics in dendrimers and polyelectrolytes. K. Ghiggino 9:05—624. Fluorescence studies on mesogen interaction in polymer liquid crystals. K. Horie 9:35—625. Nanosphere and hollow nanosphere characterization by fluorescence techniques. G. Liu 9:55—626. Fluorescence polarization measurements of the dynamic behavior of polymers. T. Smith, L. Bajada, D. Dunstan 10:15—627. Dynamics of glassy polymers studied by chiral optical methods. M. Green, J-W. Park, M. Ediger 10:40—628. Probing microscopic heterogeneity in polymer systems using singlemolecule fluorescence techniques. J. Quirin, J. Torkelson 11:00—629. Local motion of polystyrene chain end studied by the fluorescence depolarization method. M. Yamamoto, J-l. Horinaka, S. Ito, T. Matsuda Royal Hawaiian Regency Room 1, Lobby Level New Methodologies in Polymer Synthesis (149)

B. Hsieh, Presiding 8:05—630. Development of high activity, supported ansa-metallocene catalysts. S. Collins, J. Tian, Y-S. Ko, Y. Feng 8:35—631. Olefin polymerization catalyzed by (cyclopentadienyl)(aryloxy)titanium complexes-cocatalyst system. K. Nomura 9:05—632. Structure-thermochemistryreactivity relationships in single site olefin polymerization catalysts. T. Marks 9:35—633. Block copolymerizations of olefins with polar monomers initiated by rare earth metal complexes. H. Yasuda 10:00—634. Living polymerization of methyl methacrylate by methyl methacrylate complexes of tantalum. K. Mashima, Y. Matsuo, K. Tani 10:25—635. Olefin polymerizations catalyzed by Ni(ll)- and Pd(ll) complexes. M. Brookhart, D. Gates, F. A. Hicks, R. L. Huff, L K. Johnson, C. M. Killian, M. D. Leatherman, S. A. Svejda, D. J. Tempel 10:50—636. Branched polymer structures by tandem catalysis. G. Bazan, Z. Komon, B. Lee Sheraton Moana Surfrider Ballroom II Radiation Chemistry of Polymers (209)

D. Hill, Presiding 8:05—877. Time- and space-resolved spectroscopic studies on polymer. S. Tagawa 8:35—455. Radiation target analyses of a protein containing a stable free radical. E. Kempner, G. Bolger, M. Liuzzi 8:55—601. Influence of processing conditions on the EB curing kinetic of an epoxy resin for composites. B. Defoort, L. T. Drzal

1 1 8 OCTOBER 2, 2000 C&EN

9:15—602. Two main radicals formed in deuterated L-alanine by heavy ion beam irradiation: Influence of irradiation temperature to radical formation. A. Minegishi, H. Isao, T. Shinji, A. Chikara, M. Takeshi, K. Tatsuaki, F. Yoshiya 9:55—603. Investigation of geminate ion recombination in liquid alkane and polymer solution using subpicosecond pulse radiolysis and computer simulation. A. Saeki, T. Kozawa, Y. Yoshida, K. Ushida, S. Tagawa 10:15—604. Ion beam pulse radiolysis study on polystyrene excimer. Y. Yoshida 10:35—605. Study on solvent effects of polystyrene dimer cation radical by using pulse radiolysis. K. Okamoto, T. Kozawa, Y. Yoshida, S. Tagawa 10:55—606. Effect of the degree of hydrolysis on the radiation chemistry of polyvinyl alcohol) and polyvinyl acetate). K. J. Thomas, M. Biscoglio, B. H. Milosavljevic 11:15—607. A fast, thin-film scintillator for radioactive material assay. A. Hoyt, J-M. Gosau, L. Harrah, N. Coons

MONDAY AFTERNOON Sheraton Exhibit Pavilion Advanced NMR Characterization of Polymers: Precise Structural Analyses and Molecular Interpretation of Macroscopic Properties (003) Poster Session 1:00-3:00 637. Relationship between the phase and chain structures of semicrystalline copolymers as studied by high-resolution solidstate 13C NMR spectroscopy. Q. Chen, Q. Zhang, W. Lin, G. Yang 638. 1 7 0 NMR chemical shifts and quadruple coupling constants in solid peptides and polypeptides as determined by using highspeed MAS techniques. S. Kuroki, K. Yamauchi, I. Ando, A. Shoji, T. Ozaki 639. Structural analysis of B4C and h-BN using 2-D 11B-MQMAS NMR. K. Kanehashi, K. Saito, H. Sugisawa 640. Diffusional behavior of n-alkanes in polypeptide gel system with highly oriented chains as studied by pulsed fieldgradient spin-echo 1 H NMR method. C. Zhao, S. Kuroki, I. Ando 641. NMR study on the structure and the structural change of silk fibroins from wild silkworms. Y. Nakazawa, T. Asakura 642. Heterogeneous structure of Bombyx mori silk fiber studied with solid-state NMR. K. Ohgo, T. Kameda, Y. Juming, T. Asakura 643. Solid-state NMR analyses of the structure and molecular motion for the chain ends in the different a.oo-alkanediol crystals. K. Kuwabara, F. Horii, Y. Ogawa 644. Structural and dynamic study of (ethylene-vinyl alcohol) copolymer gels by ^H pulse NMR and solid-state 13C NMR. M. Kanekiyo, M. Kobayashi, I. Ando, H. Kurosu, S. Amiya 645. Solid-state NMR analyses of the hydrogen bonding and conformation of polyvinyl alcohol) in the hydrated state. K. Masuda, H. Kaji, F. Horii 646. Structural changes in biopolymer gel systems studied by pulsed NMR. S. Matsukawa, K. Abe, M. Abe, T. Watanabe 647. Dynamics of water molecule in pullulan aqueous solution by NMR method. R. Okada, R. Kuniya, S. Matsukawa, T. Watanabe 648. Study on Cu(ll)-bridged structure between polysaccharide chains in gellan and welan solution. S. Kanesaka, S. Matsukawa, T. Watanabe 649. Characterization of uniaxially drawn poly(ethylene terephthalate). Y. Miwa, Y. Takahashi, Y. Kitano, H. Hashimoto, K. Gen 650. Structural analysis of nylon-6 crystals by WAXD and NMR. R. Konishi, I. Masayoshi 651. Solid-state NMR studies of structure of polyether crystallized from the different liquid-crystalline states. M. Murakami, M. Miyazaki, H. Ishida, F. Horii 652. Synthesis and dynamics of polyethylene glycol) rotaxanated with a-cyclodextrin. T. Girardeau, J. Leisen, H. Beckham 653. NMR nonequivalence of the methylene protons neighboring on asymmetric S atoms in sulfilimines. Y. Nakamura, N. Utatsu, K. Ikeda, M. Otsuji, T. Yamamoto

Royal Hawaiian Regency Room 2, Lobby Level High-Performance Polymers (050)

M-A. Kakimoto, Presiding 1:05—654. Synthesis and properties of polybenzoxazine-based composites. T. Takeichi, T. Agag, Y. Guo, R. Zeidam 1:35—655. Multifunctional orthogonal initiators and triflate catalysts for the synthesis of polyesters with complex architectures. J. Hedrick, M. Moller, R. Kange, A. Wursch 2:05—656. Synthesis of aromatic polymers containing triazine units. Y. Oishi 2:35—657. High-temperature transfer molding resins-ll. J. Conned, J. Smith, P. Hergenrother 3:05—658. Thermally stable and photosensitive polymer. M. Ueda 3:35—659. Investigations of novel methods to extend the use-temperatures of polymers. W. W. Adams, T. J. Bunning, B. L. Farmer, R. A. Vaia, K. M. Kearns, T. Banerjee, H. G. Jeon 3:55—660. Combinatorial polymer chemistry. G. Klaerner, D. Benoit, M. Petro, C. Hawker Royal Hawaiian Regency Room 1, Lobby Level Reactive Polymer Processing (102)

W. Baker, Presiding 1:05—681. Reactive extrusion processes developed at the CRC for polymers: (1) chain extention and branching of PP and PET; (2) controlled degradation of HDPE. M. O'Shea, G. Moad, E. Rizzardo, G. Peeters, R. Tozer, T. Bray, A. Postma 2:25—683. Reactive processing of polyolefin nanocomposites based on organoclay. R. Mulhaupt, J. Nitz, P. Reichert 2:55—684. On-line monitoring of reactive processing of polyolefin in a model twin screw extruder. K. Min 3:25—685. Innovative process for mixing and compatibilizing blends: Solid-state shear pulverization. J. Torkelson, N. Furgiuele, K. Khait, A. Davydov, A. Lebovitz Royal Hawaiian Regency Room 3, Lobby Level Associations in Solutions: Amphiphiles, Macromolecules, and Colloids (203)

S. Khan, Presiding 1:05—686. Model alkali-soluble associative polymers and ionic surfactant interactions. R. Jenkins, W. P. Seng, K. C. Tarn, D. Bassett 1:20—687. Hydrophobe association in aqueous solutions of a HASE associative polymer. Y. Rharbi, E. Araujo, R. Jenkins, M. Winnik 1:35—688. Shear effects on temperatureinduced sponge-to-lamellar transition in membrane systems. M. Isobe, H. Tanaka 1:50—689. Associative polymers bearing n-alkyl hydrophobes: Solution or microgel? S. Khan, R. English, S. Raghavan, R. Jenkins 2:05—690. Investigation of associated structures in solution with combined rheomechnical and rheo-optical measurements. W-M. Kulicke, C. Clasen 2:20—691. Friction of gels: Effects of charges, substrates, and velocity. G. Kagata, T. Kurokawa, J. Gong, Y. Osada 2:35—692. Interaction between inorganic nanofiber network gel and amphiphiles with phosphonate groups. A. Takahara, K. Yamamoto, T. Kajiyama, S. Wada 2:50—693. Self-assembled nanofibers from home-and heteroditopic 1,co-nucleobase bolaamphiphiles. T. Shimizu, R. Iwaura, M. Masuda, Y. Okada, K. Yase 3:05—694. Erasable shape memory gels: Molecular mechanism and applications. T. Miyazaki, A. Matsuda, T. Kaneko, J-P. Gong, Y. Osada 3:20—695. Structure and rheology of diblock polyelectrolyte gels. S. Bhatia, R. Prud'Homme, A. Mourchid


3:45—696. Preparation of amphoteric functional colloids and their bioapplications. S-J. Fang, H. Kawaguchi 4:00—697. Preparation of carbohydrate surface-accumulated core-corona polystyrene nanospheres and their interaction with lectin. T. Uchida, S. Yasunaga, T. Serizawa, M. Akashi 4:15—698. Hybrids of polystyrene-6/oc/cpoly(ethylene oxide) micelles with cationic and anionic surfactants in aqueous solutions: Interaction with metal ions and metal nanoparticle formation. L. Bronstein, D. Chernyshov, G. Timofeeva, L. Dubrovina, P. Valetsky, S. Kazakov, A. Khokhlov Sheraton Moana Surfrider Ballroom Photophysics and Photochemistry of Polymeric Materials (068)

K. Sugita, Presiding 1:05—673. Influence of structure on the photodegradation of aromatic-containing polymers. C. Hoyle 1:35—674. Steric and heavy atom effects on the luminescence of conjugated polythiophenes. S. Holdcroft, C. Yang, G. Vamvounis 1:35—675. Microstructure formation of a composite of carbon black and elastomer by laser ablation. A. Yabe, H. Niino, Y. Sato, S. Ono 1:55—676. Photochemistry of stilbenecontaining liquid-crystalline polymers. D. Creed, A. Somlai, C. Hoyle 2:15—677. Photophysics of electroluminescent conjugated polymers: Single chains, thin films, and self-assembled mesostructures. S. Jenekhe 2:35—678. Photodegradable toners for electrophotography: Photodegradation and cross-linking mechanism of matrix resin by deep UV-exposure. K. Sugita, T. Ishizawa, H. Tateno, M. Kushida, K. Harada, K. Saito, N. Namatame, N. Mogi, T. Hosoda 2:55—679. Image formation with trithiocyanuric acid. K. Yamada, H. Tabe, H. Hamano 3:15—680. Aqueous solubilization of photosensitive membrane for space science applications. J. Scaiano, A. Szymanskal, M. J. Regimbald-Kmell, A. Berinstain, R. Sinta Sheraton Moana Surfrider Ballroom II Macromolecular Chemistry General Session (07G-02)

D. Choi, Presiding 1:05—699. Photoinduced anisotropy and diffraction grating of the thin films of polymers containing a p-nitroazobenzene. D. H. Choi, J. H. Kim, H. T. Hong, K. J. Cho, J. Y. Lee 1:25—700. Photochemically induced holographic gratings in polymer azobenzene liquid crystals. T. Ikeda, O. Tsutsumi, A. Kanazawa 1:45—701. Light-guided displacement of liquids on azobenzene monolayers. S-K. Oh, M. Nakagawa, K. Ichimura 2:05—702. Photoreorientation of azobenzenes induced by sunshine. K. Ichimura, M. Han 2:25—703. Photoinduced surface modification of azobenzene polyesters. P. S. Ramanujam, S. Hvilsted, M. Helgert, D. Bublitz, B. Fleck, L. Wenke 2:45—704. Methacrylate copolymers incorporating diacetylenes as thermally curable, high-stability materials in electrooptic modulators. D. Spells, C. Zhang, L. Dalton 3:05—705. Salt permselectivity in chargemosaic membranes prepared from laminated structure. M. Higa, E. Kobayashi, D. Masuda, T. Hashiguchi, K. Matsusaki 3:25—706. Assembly and characterization of polymer-supported lipid bilayers on solid support. W. Shen, W. Knoll, C. Frank 3:45—707. New phenylated bisphthalic and bisnaphthalic anhydrides and organosoluble polyheteroarylenes therefrom. A. L. Rusanov, M. L. Keshtov, F. W. Harris

Sheraton Exhibit Pavilion Macromolecular Chemistry General Session (07G-P2) Poster Session 1:00-3:00 708. Novel triarylamine-containing polyquinoline for single-layer LED device. L. Wang, 710. Withdrawn. 711. Precise structural analyses of phenolformaldehyde polymers. Q. Zheng, A. Easteal, D. Siew, N. Edmonds, Q. Rawlinson 712. Organic thin-film membrane based on dendrimers for facilitated olefin transport. J. Won, B. J. Cha, Y. S. Park, Y. S. Kang 714. Rheological-optical characterization of modified ethyl cellulose polymeric liquid crystals. Q. Zheng, A. Easteal, D. Siew 722. Supramolecular structure of selfassembled synthetic zinc chlorins possessing a primary, secondary, or tertiary alcoholic hydroxyl group. S. Yagai, T. Miyatake, H. Tamiaki 723. Fabrication and applicability of photopatterned monolayers formed by di- and tetracationic adsorbates bearing bis(pyridinioethylene) moieties in aqueous systems. M. Nakagawa, S. Saida, S. K. Oh, K. Ichimura 724. Fibrous self-organization formed by azopyridine carboxylic acids: Morphological alternation of molecular assemblages by light. K-l. Aoki, M. Nakagawa, K. Ichimura 725. Supramolecular assemblies of proteins at the galleries of a-zirconium phosphonates. A. Chaudhari, C. V. Kumar 728. Synthesis and characterization of poly(oxyethylene)s containing phenylalkysulfonyl or aklylphenylsulfonyl side groups. J-C. Lee, J. Y. Jho, J-W. Kim, T-H. Kim 729. Charge-carrier transport properties of double-layer organic photoconductor containing liquid crystal. B. Lee, S-Y. Jung, J-K. Kim 735. Synthesis and characterization of polyurethanes having tricyanocyclopropyl group for piezoelectric applications. J-Y. Lee, E-J. Park, M-K. Jin 737. Dosage form design using intelligent polymers: Thermally reversible xyloglucan gels as vehicles for oral drug delivery. S. Miyazaki 738. Synthesis and evaluation of lithium ionconducting polymers containing cationic PEO. T. Morita, M. Rikukawa, K. Sanui 739. Complexation of polyacryloylalanine with divalent metal ions. K. Suzuki, S. Masuda, K. Minagawa, M. Tanaka 741. Proton-conducting polymer electrolytes derived from poly(4-phenoxybenzoyl-1,4phenylene). T. Yamamoto, M. Rikukawa, K. Sanui 742. Thermosensitive properties of poly(methyl A/-acetylaminoacrylate). T. Maruyama, S. Masuda, K. Minagawa, M. Tanaka 745. Interpenetrating polymer networks of poly(4-vinyl pyridine) and poly(2,6dimethyl-1,4-phenylene oxide): Synthesis and characterization. G. Phelan, S. Maaref, S. Sharma, H. Frisch 748. Octacyanophthalocyanines as cathodeactive materials for secondary lithium battery. Y. Asai, S. Miyata, K. Onishi, M. Matsumoto, K. Shigehara 749. Lithium/polymer electrolyte/octacyanophthalocyanine battery without halides and hazardous transition metal. K. Onishi, S. Miyata, Y. Asai, M. Matsumoto, K. Shigehara 755. Insights into the dynamics of DMSO in phosphatidylcholine bilayers. H. H. Chang 756. Spectroscopic investigations of surfactant "flip-flop" in catanionic vesicles. K. K. Karukstis, N. S. Joshi, C. L. Giddings 758. Mesoscopic pattern formation from liquid-crystalline polymers. H. Yabu, S-l. Nishimura, O. Karthaus, M. Shimomura, K. Akagi 761. Synthesis and characterization of polyimide for monolithic photorefractive system measuring two-beam coupling. Y. Sakai, T. Fukuda, M. Ueda 762. Fundamental material recycle of unsaturated polyester resin. T. Yokoi, M. Miwa, A. Takeno 765. Effect of electric field on physical aging of poly(ethylene-2,6-naphthalate). M. Yamato, T. Kimura, Y. Shinagawa, K. Hashimoto 766. Formation of chiral porphyrin microfibers in organic solvents. T. Sagawa, T. Hashimoto, S. Fukugawa, H. Ihara

768. Surface diffusion of Au fine particles deposited on pretreated glass substrates with 3-mercaptopropyltrimethoxysilane. H. Kasahara 769. Elution of significant metals on amidoxime adsorbent with organic solvent. N. Seko, M. Tamada, A. Katakai, S. Hasegawa, N. Kasai, T. Sugo 773. Temperature dependence of gel structure of polysaccharide, Curdlan, studied by AFM and NMR. S-l. Hotta, Y. Yamashita, S. Matsukawa, T. Watanabe 774. Melt drawing of high-molecular-weight nylon-6. E. Uga, M. Ito, T. Kanamoto 775. Release-controlled stimuli-responsive gel-silica composite particles. T. Yumura, K. Suzuki, Y. Tanaka, M. Akashi 777. Electro-optical response of hybrid twisted nematic liquid-crystal displays. A. Kubono, Y. Kyokane, K. Tanaka, R. Akiyama 779. NMR, XRD, PALS, and DTA investigation of polydimethylphosphazene (PDMP) and the catalyst-Ru-doped PDMP. T. Bastow, A. Hill, M. Hoang, P. Pertici, G. Vitalli 780. Photofabrication of micro relief images on azobenzene polymer films using a computer-generated hologram. T. Fukuda, T. Kimura, K. Sumaru, T. Yamanaka, H. Matsuda 783. Red-light-emitting polymer containing dicyanopyrone moiety. H-K. Shim 788. Linear extrapolated method to predict long-term mechanical behavior and lifetime for PS. L. Hu 790. Coloring behavior of animal fiber using tryptophan color reactions. K. Donowaki 791. Withdrawn. 797. Effect of surfactants on the swelling behavior of ionic acrylamide gels. Y. Inoue, T. Sato, N. Ohtani 798. Effects of magnetic field on undoping process in polypyrrole. H. Morioka, T. Kimura, R. Aogaki 799. Dielectic studies of dynamics in miscible blends of polystyrene and polyvinyl methyl ether). H. Takeno, M. Kobayashi, Y. Kiya, M. Naoki 801. Novel vapor deposition system for preparation of organic films under high magnetic field and UV excitation. R. Ye, K. Ohta, M. Baba, K. Nishidate, Y. Oishi, K. Mori 802. Theoretical study of magnetic interaction for metal oxides. T. Onishi 803. Thermotropic smectic liquid crystal in helical polysilane. H. Kamee, J. Watanabe, M. Fujiki 811. Transport vector control of ions across a thermo-sensitive charged membrane. M. Higa, S. Emori, T. Yamakawa, S. Ishida 825. A his (i)/trp (i+4) zipper in prion protein sequence and a his (i)/tyr (i+4) zipper in beta-amyloid peptide sequence: Unique sequence similarity supports a common putative free-radical molecular mechanism. C. M. Yang 826. Self-assembling two-directional arborol gels. P. S. Russo, K. Yu 827. Thermoplastic elastomer toughening of syndiotactic polystyrene (SPS)/poly(2,6dimethyl-1,4-phenylene oxide) (PPO) blends by reactive extrusion. S. M. Hong, S. S. Hwang, K. U. Kim, S. P. Hong 828. Flocculation and rheological characteristics of carboxymethyl cellulose-g polyacrylamide. F. E. Okieimen, K. I. Idehan 829. Relationship between superstructure and mechanical properties in filled rubber system—I. N. Suzuki, Y. Fumito, I. Masayoshi 830. Polyblends of poly(phenylene ether) with styrene-ethylene-butylene-styrene. R. Deanin, J. Knox 833. Relationship between superstructure and mechanical properties in filled rubber system—II. F. Yatsuyanagi, N. Suzuki, M. Ito 835. Properties of photocross-linkable polyvinyl alcohols) with pendant styrylpyridinium groups. Y. Shindo, H. Masatoshi, A. Daisaku, I. Kazuo Sheraton Exhibit Pavilion Macromolecular Chemistry General Session (07G-P1) Poster Session 4:00-6:00 709. Preparation of dendrimer-encapsulated copper nanoparticles. Y. Niu, L. Sun, R. M. Crooks

713. Synthesis and applications of chargetransporting poly(organophosphazene). L. M. Leung, M. Lay, C. K. Wong 715. Preparation of organofunctionalized polysilsesquioxane through tributylstannylated derivative. O. Moriya, T. Sugizaki 716. Polyaddition of bis(cyclic thiocarbonate) with diamines: Novel efficient synthetic method of polyhydroxythiourethanes. H. Tomita, T. Endo 717. Grafting of polyamidoamine dendrimer onto ultrafine silica surface in dry system. S. Sato, M. Murota, N. Tsubokawa 718. Functionalization of terminal amino groups of polyamidoamine dendrimergrafted ultrafine silica. K. Kotama, M. Karino, E. Saito, N. Tsubokawa 719. Immobilization of zwitterion moieties onto silica gel surface and application to stationary phase for liquid chromatographic separation of ions. H. Arasawa, C. Odawara, N. Tsubokawa 720. Synthesis of polyurea dendrimer via Crutius rearrangement. M. Okaniwa, M. Ueda, K. Takeuchi, M. Asai 721. Synthesis and polymerization behavior of spiro-ketals. I. Fukuchi, F. Sanda, T. Endo 726. Dendritic MRI contrast agent: Design and synthesis of dendrimer-metal chelate. M. Takahashi, Y. Hara, T. Oshikawa, M. Yamashita 727. Synthesis and properties of star polyimides using hyperbranched polyimides as the central core. J. Fang, H. Kita, K-l. Okamoto 730. Hyperbranched carbosilanes: Controlled synthesis, functionalization, and application. C. Schlenk, T. Pusel, H. Frey 731. Synthesis, characterization, and morphologies of hyperbranched aliphatic and aromatic copolyesters. A. Moeck, R. Hanselmann, H. Frey 732. Novel synthetic route to highly crosslinked polyvinyl ethers) by free-radical polymerization. J-Y. Lee, M-K. Jin, E-J. Park 733. Synthesis of hyperbranched polymers by proton-transfer polymerization of acrylate monomers. K. Ikuma, J-l. Kadokawa, Y. Kaneko, H. Tagaya 734. Synthesis of functional polymers having an allyl alcohol moiety by Pd(0)-catalyzed polyaddition of bifunctional vinyloxiranes with nucleophiles. T. Koizumi, J. Sakamoto, Y. Gondo, T. Endo 740. Synthesis and evaluation of novel proton-conducting polymer electrolytes containing phosphoric acid. D. Inagaki, M. Rikukawa, K. Sanui 743. Synthesis and characterization of polyimides derived from alicyclic tetracarboxylic dianhydride. K. Ogasawara, Y. Oishi, H. Hirahara, K. Mori 744. Preparation and characterization of polymer electrolytes containing triazine rings. Y. Saito, Y. Oishi, H. Hirahara, K. Mori, K. Kurosaki 746. Synthesis of the polyene includes heterocycle in main chain. Y. Sato, T. Kikuchi 750. Specific binding of amino acids by helical peptide-modified dendrimer. N. Higashi, T. Koga, M. Niwa 751. Degradation of waste plastics to useful fuels over acidic solid catalysts. T. Kuroki, T. Marusaki, Y. Yoshida, T. Hosojima, T. Matsuda 752. Conformational study of oligopeptide assembled onto dendrimer template. N. Higashi, T. Koga, N. Niwa, M. Niwa 753. Copolymerization of hexafluoropropylene oxide and cyclic ethers. M. Shinohara, T. Hagiwara, Y. Yoshida 754. Novel rotaxane dendrimers. J. W. Lee, K. Kim 757. Effect of magnetic field on photopolymerization of vapor-deposited thin films of the triazinedithiol derivatives. K. Suzuki, K. Mori, H. Hirahara, N. Yoshimoto 759. Molecular design of functionalized thermosensitive hydrogel. K. Yamashita, T. Nishimura, O. Hashimoto, M. Nango 760. Synthesis and the enzymatic polymerization of 4-alkenylcatechols. T. Kimura, T. Miyakoshi 763. Cationic ring-opening polymerization of six-membered cyclic thiocarbonate. N. Nemoto, F. Sanda, T. Endo 764. Copolymerization of carbon dioxide and propylene oxide with the diethylzinc/ fullerol/carbon dioxide catalyst system. S-l. Aikawa, M. Zhou, H. Noguchi, S. Ishii, Y. Yoshida

770. Novel dendritic macromolecule consisting of nucleobases: Synthesis and applications of dendritic polyuracils with multiple sugar units. K. Sugama, M. Tominaga, K. Konishi, T. Aida 771. PAMAM dendrimers having photolabile (caged) groups at their periphery. S. Watanabe, M. Sato, M. Iwamura 772. Synthesis of oligo(5-butyl-1,3adamantane). H. Tajima, T. Ishizone, S. Nakahama 776. Design, synthesis, and biological evaluation of carbosilane dendrimers uniformly functionalized with bioactive saccharide sequence. K. Matsuoka, O. Hiroyuki, T. Takaki, K. Nishikawa, Y. Natori, Y. Esumi, D. Teranuma, H. Kuzuhara 781. Pilot plant synthesis of pharmaceuticalgrade polyanhydrides. J. Hufnagel, A. Bhatia, K. Drengler, D. Obradovich, B. Ellington, T. Rehm, J. Marek, R. Lorenzini, L. Scaggs, G. Robinson 782. Chemoselective polyesterification. M. Okazaki, T. Morishita, T. Hayakawa, Y. Shibasaki, M. Ueda, K. Takeuchi, M. Asai 784. Polymerization of 1,4-bis(trimethylsilylethynylbenzene) with copper and silver catalysts. F. Tomohisa, H. Tokio, Y. Yasuhiko 785. Asymmetric reduction of enantiomerically pure poly((S)-1-oxo-2-methylpropylene). N. Kosaka, K. Nokazi, T. Hiyama 786. Cationic ring-opening polymerization of novel bicyclic monomers prepared from hydantoins. M. Miyamoto, H. Yamamoto, Y. Kimura 787. Synthesis and characterization of dendrimer containing dichalcogenide bond as the core. Y. Takaguchi, S. Suzuki, T. Tajima, J. Motoyoshiya, H. Aoyama 789. Phosophonium-diene-based mesogens: Synthesis, liquid-crystalline behavior, and in-phase polymerization. B. Pindzola, D. Markevitch, B. Hoag, D. Gin 792. Synthesis and characterization of polyimides derived from alicyclic tetracarboxylic dianhydride. Y. Oishi, K. Ogasawara, H. Hirahara, K. Mori 793. Synthesis and properties of aromatic polycyanurates from triazinedichlorides with phenyl or phenoxy substituents. R. Takahashi, Y. Oishi, H. Hirahara, K. Mori 794. Preparation and characterization of polymer electrolytes containing triazine rings. Y. Saitou, Y. Oishi, H. Hirahara, K. Mori 795. Synthesis and properties of aromatic polycyanurates by solution polycondensation of triazinedichloride and bisphenols. R. Takayama, Y. Oishi, H. Hirahara, K. Mori 796. Controlled synthesis of cucurbit[n]urils. R. Blanch, A. Arnold, A. Day, T. White, A. Sleeman 804. Anionic polymerization of A/-(psubstituted phenyl)itaconimides. T. Fujii, S. Kawata, T. Hagiwara, Y. Yoshida 805. Plasma polymerization of metal porphyrins. S. Suzuki, M. Watanabe, K. Nakamura, H. Noguchi 806. Synthesis and characterization of novel dendritic skeletons having caged compounds at periphery. Y. Hirayama, R. Sakuragi 807. Modification of chitosans with acyl chlorides: Synthesis and characterization. A. Nakayama, I. Arvanitoyannis, S. Aiba 808. Oxidative coupling polymerization of bis(2-naphthol) compounds using copper/ chiral amine/oxygen system. O. Haba, A. Nagai 809. Synthesis of chitin- and chitosan-oraftaliphatic polyester and their characteristics. H. Okada, M. Fujioka, T. Ueno, M. Zhou, S. Ishii, H. Noguchi, Y. Yoshida 810. Chemistry of thiophene and dibenzothiophene-S-oxides. K. Arima, T. Thiemann, K. Kumazoe, D. Ohira, T. Sawada, S. Mataka 812. Synthesis of fluorescent dendrimers having a reactive core for tandem claisen rearrangement. H. Tokuhisa, E. Koyama, Y. Nagawa, K. Hiratani 813. pH Memory effects in pH-sensitive charged membranes. M. Higa, M. Motonaga, J. Sonoda, T. Watabe 814. Polymerization of 1-methylethenyl methoxymethyl ether prepared from acetone and methoxymethyltriethylammonium chloride. T. Hara, H. Noguchi, Y. Yoshida


119

MACR/MEDI/TECHNICAL PROGRAM

815. Synthesis of bis(phenol) A-imprinted polymer and adsorptive characteristic of bis(phenol) A. Y. Matsuta, H. Kajitani, T. Miyoshi, T. Saito 818. Tetrahydroxydiisopropyamine BDI: A perfect AB4 monomer to produce watersoluble dendrimers? Not quite: You need a more nucleophilic nitrogen. G. Fleet 819. Synthesis and characterization of poly(propyleneimine) dendrimers. K. Okuyama, K. Yonetake, O. Haba 820. Ring-opening polymerization of y-butyrolactone under high pressure. A. Oishl, Y. Taguchi, K. Fujita, Y. Ikeda, T. Masuda 821. Solving the "dilution problem" associated with the synthesis of "cored" dendrimers. L. Schultz, S. Zimmerman 822. Solid-phase synthesis of dendrimers via orthogonal method. Y. Osanai, O. Haba 823. Covalent capture of dendritic metalloporphyrin complexes. Y. Kim, E-l. Kim, S. Zimmerman 824. Hydrogen-bond-mediated self-assembly of dendrimers. Y. Ma, S. V. Kolotuchin, S. C. Zimmerman 831. Synthesis and free-radical polymerization of 1-(2-methylene-3-butenoyl) piperidine. T. Yaegashi, T. Hiroki, T. Katsuhiko, S. Tomoo 832. Dendritic hyperbranched LnF3 containing host-guest systems on a base of tris (pentafluorophenyl) germane. M. Bochkarev, M. Katkova, I. Brezhneva, G. Maximov, J. Guschina 834. Polymers bearing norbornadiene (NBD) moieties and their solar energy storage property [xxxv]: Synthesis of polystyrenes containing pendant carbamoyl-substituted D-A type NBD moieties and their photochemical property. N. Kawashima, A. Kameyama, T. Nishikubo 836. Synthesis and ring-opening polymerization of macrocyclic thiocarbonates containing bis(phenol A) structure. T. Kouketsu, A. Kameyama, N. Tadatomi 837. Synthesis and photoinitiated cationic polymerization of polyimides containing pendant epoxy groups. N. Kazuyuki, K. Atsushi, N. Tadatomi 838. Controlled ring-opening alternating copolymerization of oxiranes with cyclic dicarboxylic anhydrides using quaternary onium salts. T. Toshiyuki, K. Atsushi, N. Tadatomi 839. Synthesis and characterization of copoly[poly(ethylene terephthalate)/copoly(succinic anhydride/ethylene oxide)] by transreaction. Y. Maeda, T. Maeda, K. Yamaguchi, S. Kubota, A. Nakayama, N. Kawasaki, N. Yamamoto, S. Aiba 896. Genetically engineered syntheses of tandem repetitive polypeptides consisting of glycine-rich sequence of spider dragline silk. Y. Fukishima

MONDAY EVENING Sheraton Moana Surfrider Ballroom Self-Ordering Phenomena in Polymeric Systems: From Microscopic to Mesoscopic Scales (056) Poster Session 7:30-9:30 661. Diffusely layered structure of "not-sohairy" rods. S-H. Chen, A-C. Su, W. Huang, S-A. Chen 662. Surface wave studies of a thin gel by surface wave spectroscopy. M. Kim, A. Keunho, H. Kyung 663. Preparation of ordered assembly of cyclodextrins for the recognition of large guest molecules. T. Hishiya, T. Akiyama, H. Asanuma, M. Komiyama 664. Anomalous structural organization from a mixture of the core-shell nanoparticles of poly(L-lactide)-b/oc/c-poly(oxyethylene) and poly(D-lactide)-Z?/oc/c-poly(oxyethylene). T. Fujiwara, M. Miyamoto, Y. Kimura 665. Effect of polyimide layer on fluorescence properties of a liquid crystal containing imide groups. S. Machida, Y. Uchida, K. Horie, T. Kaneko, J. Watanabe 666. Thermo-sensitive property of an optically active polymer. M. Muramatsu, T. Aoki, K. Sanui 667. 2-D Pattern formation of nanoparticles. M. Nonomura, T. Sawadaishi, M. Shimomura, T. Yanagita, R. Kobayashi, Y. Nishiura

120


668. Colloidal dispersions confined in voids of polymer gel matrix. J. Yamanaka, H. Hiroma, K. Yamada, M. Yonese 669. Calcium carbonate thin film crystals formed by organic/inorganic interactions: Control of morphology by organic matrices. N. Hosoda, T. Kato 670. Light-scattering and small-angle neutron-scattering studies of shearinduced structures in semi-dilute polymer solution. S. Saito, T. Hashimoto, D. Pine 671. Liquid crystalline texture and electrooptic response for straight and oncebroken rods of PBLG. Y. Uematsu, K. Monzen, M. Date, H. Suzuki 672. Supramolecular assemblies of tape-like pseudopolymer chains formed by interbase hydrogen bonds between alkylsilylated nucleoside derivatives. R. Takasawa, T. Sato, I. Yoshikawa, K. Araki Sheraton Moana Surfrider Ballroom Photophysics and Photochemistry of Polymeric Materials (068)

K. Sugita, Presiding 7:05—840. Modeling and experimental characterization of the dependence of polymerization rate on photoinitiation rate. C. Bowman, L. Lovell, K. Berchtold, B. Hacioglu, J. Nie 7:35—841. Novel curing systems by the use of photobase generators. M. Tsunooka, H. Tachi, M. Shirai 8:05—842. Photoinitiated polymerization involving /V-substituted maleimides. S. Jonsson, C. Hoyle 8:25—843. Synthesis of new functional vinyl ether monomers and their photoinitiated cationic polymerization. A. Kameyama, N. Tadatomi 8:45—844. Kinetic study of the photocuring of photooxidation-induced polycondensation (POP) resin. H. Aral, Y. Tajima, K. Takeuchi 9:05—845. Two-photon photoinitiated polymerization and microfabrication. K. D. Belfield, X. Ren, J. Liu, E. W. Van Stryland, D. I. Hagan, V. Dubikovsky 9:25—846. Fiber-optic-based, intrinsic fluorescence sensors: Monitoring of inprocess polymer resin cure and postprocessing physical aging. J. Torkelson, J. Quirin, H. Cao, N. Maercklein Sheraton Moana Surfrider Ballroom Associations in Solutions: Amphiphiles, Macromolecules, and Colloids (203) Poster Session

7:30-9:30 847. Synthesis and applications of novel phosphine substituted block copolymers. H. Borner, W. Heitz, M. Antonietti, M. Roth, D. Chernyshov 848. Pyrene solubilization in C n E 7 surfactant micelles with fluorescence spectroscopy. C. Honda, M. Itagaki, K. Endo 849. Synthesis of fluoroalkyl end-capped oligomers containing 8-hydroxyquinolyl segments and application of oligomercatalyzed solvolysis reactions. H. Sawada, S. Hata, T. Kawase, K. Fujimori 850. Immobilization of cytochrome c by the self-assembled aggregates of fluoroalkyl end-capped A/-(1,1-dimethyl-3-oxobutyl) acrylamide oligomers. H. Sawada, Y. Hirata, T. Kawase, K. Fujimori 851. Synthesis and antibacterial activity of fluoroalkyl end-capped oligomers containing dimethyl(octyl)ammonium segments. H. Sawada, K. Yanagida, Y. Inaba, M. Sugiya, T. Kawase 852. Hydrolysis of sodium laurate at the interface between two liquids. T. Yamashita, M. Yamasaki 853. Low-molecular-weight chiral gelator for organic solvents and their helical aggregation. K. Hanabusa, M. Yamada, M. Kimura, A. Kakehi, H. Shirai 854. Synthesis and functions of thermosensitive and water-soluble copolymers containing phosphinic acid groups. T. Nonaka, T. Watanabe, Y. Hanada, H. Shigemoto, S. Kurihara 855. Poly(alkyl-alkoxyphenylsilane) aggregates with chiral recognition ability. H. Nakashima, M. Fujiki, M. Motonaga, J. Koe 856. Diarylpolysilane aggregate chirality: Solvent dependence. J. R. Koe, M. Fujiki, M. Motonaga, H. Nakashima

857. Novel organic-inorganic hybrid "cerasome"-bilayer vesicle with silicate surface. K. Katagiri, K. Ariga, J. Kikuchi 858. Characteristics of hydrogen-bonding modes in petide lipid membranes. S. Kawanami, T. Kosaka, K. Ariga, J-l. Kikuchi 859. Withdrawn. 860. Oligomer-protected Au nanoparticles and their immobilization on metal oxide surface. S. Deki, K. Akamatsu, T. Fujit, K. Sayo, M. Mizuhata, A. Kajinami 861. Photocontrol of self-association of a permethylated p-cyclodextrin connected to an azobenzene. T. Fujimoto, Y. Sakata, T. Kaneda 862. Electrochemical behavior of indigo in a presence of iron(lll)-triethanolamine complex and calix[4]resorcinarene derivatives. S. Okubayashi, F. Kobayashi, H. Shosenji 863. Solution properties of poly(ethylene oxide)-b/oc/t-poly(L-lactide) in water. H. Lee, T. Chang, D. Lee 864. Characteristics of hydrogen-bonding modes in peptide lipid membranes. S. I. Kawanami, T. Kosaka, K. Ariga, J. I. Kikuchi 865. Hydrolase model of bis-quaternary ammonium salts' effect of connecting chain on hydrolytic activity. A. Nishimura, Y. Ohkatsu, T. Takezawa 866. Aggregation behavior of graft copolymer in selective solvent. M. Itakura, K. Inomata, T. Nose 867. Cloud point behavior and lightscattering studies of poly(tert-butyl methacrylate)-d/oc/f-poly(1,1-dihydroperfluorooctyl methacrylate) in supercritical C0 2 . E. Yoshida, S. L. Wells, J. M. Desimone Sheraton Moana Surfrider Ballroom Radiation Chemistry of Polymers (209) Poster Session

7:30-9:30 868. Assessment of the radiation resistance of some aromatic polyesters. D. J. T. Hill, E-J. Choi, K-Y. Kim 870. Radiation behavior of poly(tetrafluoroethylene-co-hexafluoropropylene). S. Mohajerani, D. J. T. Hill, P. J. Pomery, A. K. Whittaker 871. Radiation grafting of styrene onto polyethylene. Y. Izumi, H. Nagaike, S. Tabuse, Y. Yoshida, S. Tagawa 872. Radiation protection effects by addition of aromatic compounds to n-dodecane. S. Tabuse, Y. Izumi, T. Kojima, Y. Yoshida, M. Miki, S. Tagawa, T. Kozawa 873. A new radiochromic dosimetry formulation. A. Hoyt, L. Harrah, N. Coons 874. Refractive index control of polymers by electron beam reaction. T. Yamashita, Y. Maekawa, Y. Muroya, K. Yoshii, M. Uesaka, Y. Katsumura, K. Saigo 875. Effects of pulsed irradiation on EB curing kinetics of an acrylate formulation. B. Defoort, X. Coqueret, G. Larnac 876. Novel lens array fabrication utilizing the UV-photodecomposition of polysilane. Y. Sakurai, S. Okuda, N. Nagayama, M. Yokoyama

TUESDAY MORNING Royal Hawaiian Regency Room 1, Lobby Level Reactive Polymer Processing (102)

W. Baker, Presiding 8:05—879. Effect of end functionality of reactive polymers on reaction kinetics and interfacial adhesion. K. Char, Y. Yang 8:25—880. Novel reactive processing approach to functionalization and compatibilization of polymers. S. Al-Malaika 8:45—881. Nonlinear phenomena in freeradical polymerization. M. Cioffi, A. Hoffmann, L. Janssen 9:05—882. Rheological investigation of reactive blends of SAN and epoxy systems. S. Jana, A. Chandra

The Organizinq Committee requests that there be no smoking in meeting rooms or committee meetings

9:25—883. Monodisperse polymer microspheres with the epoxy group as carriers for biomedically functional substances. S. Hosaka, S. Miebori Royal Hawaiian Regency Room 3, Lobby Level Associations in Solutions: Amphiphiles, Macromolecules, and Colloids (203)

S. Khan, Presiding 8:05—884. Macromolecular association at solid-liquid interfaces. K. Kato, T. Nishino 8:20—885. Glass formation in microemulsion droplets. G. Warr, P. Harrowell, A. Widmer-Cooper, P. Butler 8:35—886. A study of self-assembling behavior of hydrogenated polybutadiene. O. Matsuda, T. Shoji 8:50—887. Diffusion of macromolecules in enzymatically modified biopolymer solutions and hydrogels: A laser-scanning confocal microscopy study. M. Burke, J. Park, M. Srinivasarao, S. Khan 9:05—888. Preparation of antigenresponsive hydrogels using antigenantibody binding process. T. Miyata, N. Asami, T. Uragami 9:20—889. Structure direction in the synthesis of organosilsesquioxane resins. J. Harreld, G. Stucky, K. Su, D. Katsoulis 9:35—890. Synthesis and properties of heptadecafluorodecahydro-1-naphthyl end-capped oligomers. H. Sawada, M. Kurachi, K. Takishita, T. Tanedani, T. Kawase, N. Terasawa, Y. Haykawa 9:50—891. Sugar-integrated gelators of organic solvents: The relationship between absolute configuration and gelation ability. O. Gronwald, K. Sakurai, S. Shinkai 10:05—892. Primer abilities of chlorinated isotactic polypropylene. A. Teruaki, T. Funasaka, S. Ohno, K. Nakamae 10:20—893. Stimuli-responsibility of primary amine-containing functional polymers prepared by hydrolysis of poly(/Vvinylformamide-co-AAvinylisobutyramide). K. Yamamoto, T. Serizawa, M. Akashi 10:35—894. Effect of boron, aluminum, and tetracholoromethane on the polymerization of silicic acid as studied by means of FT-IRAS. K. Yaguchi, M. Muroya, K. Nakamae 10:50—895. Helix formation of an organogelator bearing a nucleic base group and the effects of addition of nucleosidederivatives. E. Snip, S. Shinkai Royal Hawaiian Regency Room 2, Lobby Level Macromolecular Chemistry General Session (07G-01)

J. Puskas, Presiding 8:05—898. New method for producing polyamide from polyester. S. Nakano, K. Jadaya 8:25—900. Role of radical transfer reactions in determining the strength of the gel effect in free radical polymerization. B. P. Chekal, J. M. Torkelson 8:45—903. Free-radical polymerization of 2-triethoxymethyl-1,3-butadiene. K. Takenaka, H. Toshiya, H. Kayoko, S. Tomoo 9:05—906. Synthesis of carboxylate and amido complexes of Ni(ll) and their reactivity to the ethylene with activator (C6F5)3B. B. Lee, G. Barzan 9:25—908. Enzymatic synthesis of polyphenol derivatives from natural resources. T. Yoshida, Z. Xia 9:45—912. Synthesis and characterization of novel functional biodegradable polyester prepared from D,L-lactic acid and hydroxycinnamic acid. M. Matsusaki, A. Kishida, M. Akashi 10:05—914. Effect of anionic starburst dendrimers on the crystallization of calcium carbonate in aqueous solution. K. Naka, T. Tanaka, Y. Chujo 10:25—917. Preparation and characterization of light-focusing plastic rods with high acceptance angles. J. Liu, H. Wang 10:45—920. Preparation of nanoparticles from submicron-sized carboxylated polymer emulsion by the particle dissolution method. M. Okubo, N. Fukami, R. Shinohara 11:05—921. Synthesis and characterization of hyperbranched polyisobutylenes. J. Puskas, C. Paulo 11:25—925. Amphiphilic networks: Synthesis and characterization of polyacrylamide1-polytetrahydrofuran. Y. X. Peng, Y. Guan

THURSDAY AFTERNOON

Sheraton Moana Surfrider Ballroom II Macromolecular Chemistry General Session (07G-04)

MEDI

Hilton Hawaiian Village South Pacific Ballroom III, Mid-Pacific Conference Center

U. Scheler, Presiding

Chemistry and Signal Transduction (011)

8:35—901. Detection of size and charge of polyelectrolytes using electrophoresisNMR. U. Scheler, S. Wong 8:55—904. Comparative discussion of the 2-D NMR characteristics of cellulose ethers and their derivatives. N. Sachinvala, D. L. Winsor, W. Niemczura, K. Maskos, N. Bertoniere 9:15—907. Improving barrier properties by use of polymer nanocomposites. M. Krook, M. Hedenqvist 9:35—910. Fluorinated amphiphiles can generate nanocompartmentalized systems. M. P. Krafft, L. Schieldknecht, F. Giulieri, M. Schmutz, M. Goldmann, P. Fontaine 9:55—913. Ordering of nanostructure in thin films of isotropic/liquid-crystalline block copolymers. R. Spontak, P. Figueiredo, S. Geppert, W. Gronski, G. Brandsch, G. Bar, D. Samlenski 10:15—916. Compatibilization and toughening of polycarbonate/polyamide blends. C. Liao, A. Easteal 10:35—918. Small-angle neutron scattering and flow birefringence from viscoelastic polymer-clay solutions. G. Schmidt, A. Nakatani, P. Butler, A. Karim, C. Han 10:55—800. Elongational flow-induced deformation behavior of triblock copolymer melt with cylindrical microdomains. Y. Kobira, Y. K. Kwon, M. Okamoto, T. Kotaka 11:05—923. Elongational flow-induced lamellar rotation observed in diblock copolymer melt. Y. K. Kwon, M. Okamoto, T. Kotaka 11:15—924. Shear flow behavior of sidechain liquid-crystalline polymers. C. Schmidt, I. Quijada-Garrido, H. Siebert, P. Becker 11:35—927. Development of phaseseparated structure in poly(styrene-coacrylonitrile)/poly(methyl methacrylate) blend under elongational flow. Y. H. Kim, M. Okamoto, T. Kotaka 11:55—928. Morphologies of benzyl-ether dendrimer-d-polystyrene diblock copolymer. J. S. H. Huang, C. J. Hawker, C. A. Klug

T. Wandless, Presiding

Sheraton Moana Surfrider Ballroom Macromolecular Chemistry General Session (07G-03)

F. Cardona, Presiding 8:05—897. Is elastic modulus of spider silks high? S. Osaki 8:25—899. Polymer fractionation modeling. P. N. Kaloni 8:45—902. Radiation-induced damage and amorphotization in crystalline polyethylene. B. Jiang 9:05—905. Crystallization of poly(ethylene naphthalate) by infrared spectroscopy. N. Vasanthan, D. Salem 9:25—909. Characterization of poly-L-lactic acid and gelatin conjugate. M. S. Huda, M. Yasui, T. Fujimura, Y. Kimura 9:45—911. Structural analysis of regenerated cellulose hydrogels by small-angle and ultra-small-angle X-ray scattering. T. Konishi, H. Ando 10:05—915. Characterization and properties of the copolymers obtained by the radiation grafting of polystyrene onto poly(tetrafluoroethylene-perfluoroethylene-perfluoropropylvinylether)substrates. F. Cardona, D. Hill, G. George, F. Rasoul, J. Maeji 10:25—919. Characterization of the surface density of end-tethered polymers from the mushroom to the brush limits. M. Pepin, M. Whitmore 10:45—922. Discharge property influenced by surface chemical structure. A. Makabe, M. Narita, F. Hamada 11:05—926. Electrostatic properties of carboxyl-terminated dendrimers. P. Dubin

ARIA 08-MEDICINAL CHEMISTRY THURSDAY MORNING Hilton Hawaiian Village South Pacific Ballroom I, Mid-Pacific Conference Center Molecular Recognition Using Nucleic Acids and Their Related Substances (045) In honor of Professor Robert L. Letsinger

A. Matsuda, Presiding 8:05—1. Mimicking the structures and functions of DNA. E. Kool 8:45—2. Synthesis and physicochemical properties of a novel class of peptide nucleic acids. Y. Tsantrizos, L. D. Fader 9:00—3. Peptide ribonucleic acids (PRNA): A novel strategy for active control of DNA recognition through borate ester formation. T. Wada, H. Sato, T. Uetsuhara, N. Minamimoto, Y. Inoue 9:25—4. Structure and function of nucleic acid analogs. M. Egli 10:05—5. Photoregulation of DNA duplex and triplex formation by using modified oligonucleotides carrying azobenzene. X. Liang, T. Yoshida, H. Asanuma, M. Komiyama Hilton Hawaiian Village Coral Ballroom II, Mid-Pacific Conference Center New Strategies in Novel Protease Inhibitor Design (132)

P. Lam, Presiding 8:05—6. Design of macrocyclic serine protease inhibitors using a screen based on enzymatic cyclization. K. K. Haman, P. A. Bartlett 8:45—7. Peptidomimetic HIV protease inhibitors and prodrug forms. Y. Kiso 9:25—8. New development in the inhibition of zinc-containing proteases with hydroxamates. D. H. Kim 10:05—9. Structure-directed design of subnanomolar urokinase inhibitors that access novel binding subsites. V. Nienaber, D. Davidson, R. Edalji, A. Geyer, V. Giranda, J. Henkin, V. Klinghofer, R. Mantei, W. McClellan, T. Rockway, J. Severin, R. Smith, K. Stewart, K. Walter, J. Wang, M. Wendt, M. Weitzberg, X. Zhao 10:45—10. Novel proteasome inhibitor development. C. Crews, J. Myung, K. B. Kim Hilton Hawaiian Village South Pacific Ballroom II, Mid-Pacific Conference Center Novel Mechanisms for the Treatment of Pain (219)

M. Rafferty, Presiding 8:05—11. Drug design for pathological states of pain and opioid tolerance. F. Porreca, J. Lai, R. Agnes, V. J. Hruby 8:45—12. Potent and exceptionally selective, nonpeptidic 6-opioid receptor agonists as candidate drugs for pain. C. Walpole, N. Plobeck, Z-Y. Wei, D. Delorme, W. Brown, E. Roberts 9:25—13. Rational drug design and synthesis of selective opioid 8 and K agonists. H. Nagase 10:05—14. Antinociceptive effect of nonpeptide 6-opioid receptor agonist, TAN-67, in diabetic mice. J. Kamei, H. Nagase 10:45—15. Pharmacological profile of TRK820, a novel k-opioid receptor agonist. T. Suzuki, M. Tsuji, M. Narita, T. Endoh, H. Nagase

1:05—17. Conditional activation and inactivation of genes using induced proximity with chemical inducers of dimerization. G. Crabtree 1:55—18. Cellular targets of glycopeptide antibiotics. D. Kahne 2:45—19. Designed prostaglandin probes in brain research. M. Suzuki 3:35—20. Reverse chemical genetics: A global view of the response of cells to nutrients. S. Schreiber Hilton Hawaiian Village South Pacific Ballroom I, Mid-Pacific Conference Center Molecular Recognition Using Nucleic Acids and Their Related Substances (045)

A. Matsuda, Presiding 1:05—21. Synthesis and antitumor activities of phosmidosine and related compound/ species. M. Sekine, T. Moriguchi, N. Asai, T. Wada, K. Seio, T. Sasaki 1:45—22. An unnatural base pair: Enzymatic incorporation of a pyridin-2-one nucleoside triphosphate pairing with 2-amino-6-(thien2-yl) purine nucleosides into DNA and RNA. I. Hirao, T. Fujiwara, T. Mitsui, T. Okuni, T. Ohtsuki, H. Sugiyama, M. Kimoto, S. Yokoyama 2:05—23. Antitumor molecular switch indenoquinolines toward DNA. K. Ishida, T. Asao, L. G. Marzilli, M. Shionoya 2:25—24. Antitumor mechanisms and metabolism of the novel antitumor nucleoside a n a l o g , 1 -(3-C-ethynyl-p-(D)-r/7?opentofuranosyl)cytosine (ECyd). Y. Wataya, T. Sasaki, A. Matsuda 3:05—25. Crystal structures of DNAs damaged by methoxylation, and pyrimidineand purine-transition mutagenesis. A. Takenaka, M. T. Hossain, T. Chatake, T. Hikima, A. Ono, Y. Ueno, A. Matsuda Hilton Hawaiian Village Coral Ballroom II, Mid-Pacific Conference Center New Strategies in Novel Protease Inhibitor Design (132)

P. Lam, Presiding 1:05—26. Design, synthesis, and biological activity of NAALADase inhibitors. P. F. Jackson, K. L. Tays, K. M. Maclin, W. Li, D. Vitharana, Y-S. Ko, T. Tsukamoto, X-C. Lu, K. Wozniak, B. Slusher 1:45—27. Novel serine protease inhibition motif involving a multicentered short hydrogen bonding network at the active site. B. Katz 2:25—28. Design, synthesis, and evaluation of bicyclic pyridones as thrombin inhibitors. J. Vacca 3:05—29. Design and synthesis of highly potent, selective, and orally bioavailable factor Xa inhibitors. R. Wexler, D. Pinto, M. Orwat, J. Fevig, M. Quan, Q. Han, R. Galemmo, J. Pruitt, R. Alexander, B. Aungst, K. Rossi, M. Wright, S. Bai, P. Wong, R. Knabb, P. Lam 3:45—30. Use of structure-based drug design in the development of novel, potent, and highly selective factor Xa inhibitors. S. Young, L. Brady, S. Jones, J. Liebeschuetz, J. Mahler, H. Martin, P. Morgan, C. Murray, A. Rimmer, J. Roscoe, B. Waszkowycz, P. Welsh, K. Wilkinson, W. Wylie

Hilton Hawaiian Village South Pacific Ballroom II, Mid-Pacific Conference Center Novel Mechanisms for the Treatment of Pain (219)

E. Roberts, Presiding 1:05—31. Endocannabinoid proteins as novel targets in drug discovery. A. Makriyanis 1:45—32. Discovery of a novel class of highly potent and orally active nonpeptide bradykinin B2 antagonists and their application for the treatment of pain. S. Satoh, H. Kayakiri, Y. Abe, T. Inoue, Y. Sawada, K. Imai, M. Asano, N. Inamura, C. Hatori, H. Sawai, T. Oku, H. Tanaka 2:25—33. Synthesis and biological evaluation of 1-(2-nitrophenyl)thiosemicarbazide derivatives as novel bradykinin B2 receptor antagonists. E. Dziadulewicz, T. Ritchie, A. Hallett, C. Snell, S. Ko, J. Davies, R. Wrigglesworth, G. Burgess, M. Brown, P. Mclntyre, M. Perkins, E. Campbell, L. Urban, H. Rang, A. Dunstan, G. Bloomfield, G. Drake, G. Hughes, W. Lee, C. Davis, M. Yaqoob, S. Phagoo, E. Phillips, A. Davis 3:05—34. Antagonists of the EP1 receptor as potent analgesics. A. J. Barker, G. Breault, E. Griffen, P. Warner, H. Tucker, J. Shaw, C. Heapy, C. Berent, D. Jones 3:45—35. Novel gabapentinoids having antihyperalgesic properties. D. Wustrow, J. Bryans, C. Kneen, T. Capiris, T. Belliotti, C. Burgos-Lepley, L. Singh, C. Taylor

FRIDAY MORNING Hilton Hawaiian Village South Pacific Ballroom I, Mid-Pacific Conference Center Molecular Recognition Using Nucleic Acids and Their Related Substances (045)

M. Damha, Presiding 8:05—40. Importance of molecular recognition in antisense olignucleotide technology. M. Manoharan 8:45—41. Isopoly (S-carboxymethyl-Lcysteine) derivatives of nucleic acid bases as antisense compound. Y. Inaki, S. Kitaoka, H. Maruoka, M. Miyata, N. Tohnai 9:05—42. Comb-type cationic copolymer expedites DNA strand exchange while stabilizing DNA duplex. A. Maruyama, W. J. Kim, T. Ishihara, T. Akaike 9:25—43. DNA and RNA mimetics: Oligonucleotide N3-P5 phosphoramidates. S. Gryaznov 9:50—44. Properties and applications of oligonucleotide-nanoparticle assemblies generated in solution and on solid surfaces. R. L. Letsinger Hilton Hawaiian Village Coral Ballroom II, Mid-Pacific Conference Center Cysteine Proteases (160)

P. Prasit, Presiding 8:05—45. Structure-based drug design of HMR3480/VX740, an orally active inhibitor of the interleukin-1 p converting enzyme. J. Golec 8:45—46. Development of potent and selective caspase-3 inhibitors. R. Zamboni, R. Aspiotis, C. Black, C. Bayly, J. Becker, E. Grimm, E. Isabel, M. Janes, D. McKay, D. Nicholson, E. Peterson, D. Rasper, J. Renaud, J. Rotonda, S. Roy, J. Tarn, P. Tawa, N. Thornberry, J. Vaillancourt, S. Xanthoudakis 9:25—47. Evolution of design of novel cathepsin K inhibitors. D. S. Yamashita 10:05—48. Design and synthesis of cathepsin K inhibitors targeting osteoporosis. J. Palmer 10:45—49. Role of cathepsin S in antigen presentation and inhibitors to modulate its activity. J. Link Hilton Hawaiian Village South Pacific Ballroom II, Mid-Pacific Conference Center Advances in Radiopharmaceutical Chemistry (172)

H. VanBrocklin, Presiding Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters

8:05—64. Imaging of gene expression following gene transfer. D. J. Buchsbaum, B. E. Rogers, W. E. Grizzle, D. T. Curiel, V. N. Krasnykh, K. R. Chaudhuri, K. R. Zinn


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MEDI/TECHNICAL PROGRAM

8:30—65. Novel gallium(lll) complexes as potential PET imaging agents for probing multidrug resistance (MDR1) P-glycoprotein (Pgp) transport activity: Effect of MDR reversal agents. V. Sharma, J. Dahlheimer, C. Pica, D. Piwnica-Worms 8:45—66. Synthesis and characterization of carrier-free M C u diiminedioxime complexes: Potential PET radiopharmaceuticals for evaluating multidrug resistance. A. Packard, S. Kiani, E. Guice 9:00—67. New concept for the design of radiolabeling agents for proteins and peptides. Y. Arano 9:25—68. Targeting GC-C receptors on colon cancer cells with an ln-111-DOTA-ST conjugate. W. Volkert, H. Gali, T. Hoffman, G. Sieckman, L. Forte, D. Chin, N. Owen 9:40—69. Characterization of 676a 3 * complex with cis, c/'s-1,3,5-triaminocyclohexane-/V,A/',/V''-triacetic acid. E. Dadachova, C. Park, H. Luo, N. Eberly, R. Rogers, C. Paik, M. Brechbiel 9:55—70. Production and applications of bromine-76, bromine-77, and iodine-124. T. McCarthy, R. Laforest, B. Hughey, A-R. Lo, M. Welch 10:10—71. Investigating of novel antibody conjugates for use in pretargeting of radionuclides to cancer. D. S. Wilbur, D. Hamlin, B. Liang, M-K. Chyan, K. Buhler, R. Vessella 10:35—72. Atypical in vivo metabolism of a 18 F-labeled arylfluoride radiotracer. S. Snyder, P. Sherman, K. Kuszpit, M. Kilboum, E. Butch 10:50—73. Fluorine-18 labeled 4 - ( 4 ' fluoroanilino)-6,7-dialkoxy-quinazolines: Synthesis and evaluation of new breast cancer receptor imaging agents. H. VanBocklin, A. Gibbs, J. Lim, D. Riese II 11:05—74. 3'-Deoxy-3'-([F-18]fluorothymidine): A PET metabolic tracer for the noninvasive monitoring of thymidine kinase-1 (TK-1) expression in vivo. J. Grierson Hilton Hawaiian Village South Pacific Ballroom III, Mid-Pacific Conference Center Chemistry and Signal Transduction (011)

S. Michnick, Presiding 8:05—36. Structural development of retinoids and thalidomide, and their activity expansion. Y. Hashimoto 8:55—37. Improving protein-ligand interactions. T. Wandless 9:45—38. Novel Bcl2-like low-molecularweight inhibitors of cell death. M. Sodeoka, R. Asakai, Y. Aoyama, M. Katoh, M. Fujita, T. Fujimoto, Y. Kamei 10:35—39. Reverse chemical genetic studies of protein kinases. K. Shokat

FRIDAY AFTERNOON Hilton Hawaiian Village South Pacific Ballroom III, Mid-Pacific Conference Center Chemistry and Signal Transduction (011)

M. Sodeoka, Presiding 1:05—75. Sulfation and extracellular signaling. C. Bertozzi 1:55—76. Bioprobes, tryprostatin A and pironetin, for the investigation of tubulinpolymerization and apoptosis in mammalian cells. H. Osada 2:45—77. Quantitative mapping of protein interactions in living cells: New strategies in molecular ontogeny. S. Michnick 3:35—78. Peptide morphing. G. Verdine, T. Gierasch, B. Harrison, M. Chytil, M. Didiuk, R. Roers Hilton Hawaiian Village South Pacific Ballroom II, Mid-Pacific Conference Center Advances in Radiopharmaceutical Chemistry (172)

Y. Fujibashya, Presiding 1:05—100. PET studies of CNS substance-P (NK-1) receptors. R. Gibson, H. Burns, M. Goldberg, M. Kramer, R. Hargreaves, D. Sciberras, J. Hietala, J. Bergman, A. Laakso, M. Haaparanta, T. Gronroos, O. Eskola, S. Aalto, O. Solin, M. Bergstrom, M. Ogren, B. Langstrom, D. Brooks, S. Luthra, N. Turjanski 1:30—101. Withdrawn.

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1:30—102. Radiolabeled 5-ferf-butyl-2phenyldithiane oxides: Ligands for imaging GABAA-gated chloride ion channels. M. Kilbourn, J. Blair, S. Snyder 2:10—103. PE2I: A cocaine derivative for scintigraphic exploration of the dopamine transporter in Parkinson's disease. P. Emond, S. Chalon, C. Prunier, L. Garreau, J. C. Besnard, D. Guilloteau 2:25—104. Fluorine-18 labeled 2p-carbomethoxy-3p-(4' -(2-f luoroisopropenyl)phenyl)nortropane (fippnt): Synthesis, characterization and tissue distribution of a potential radioligand for mapping serotonin transporter sites by PET. M. Goodman, P. Chen, C. Kilts, T. Ely, V. Camp, E. Malveaux, J Votaw, M Davis, M Owen 2:40—105. Synthesis and biological evaluation of 18F-labeled piperidyl benzilates: In vivo probes for measuring changes in endogenous levels of acetylcholine. M. Skaddan, M. Kilbourn, S. Snyder, P. Sherman, T. Desmond 2:55—106. PET measurements of H1 receptor occupancy in human brains after the administration of sedating and nonsedating antihistamines: A relationship between H1 receptor occupancy and impaired cognition. K. Yanai 3:10—107. Radiosynthesis and evaluation of [11CH3]methyl-PVC, a novel PET ligand for the nicotinic acetylcholine receptor. L. Brown, S. Chefer, A. Mukhin, O. Pavlova, A. Koren, M. Stratton, A. Kimes, A. K. Horti 3:35—108. Radiolabeling of [11C]t-PA stop: A potent serine protease inhibitor. L. Barre, F. Simeon, F. Gourand, D. Vivien, A. Buisson 3:50—109. Genetics and the development of novel enzyme targets for diagnostic imaging. L. Wiebe 4:05—110. Labeling, dopamine transporter affinity, and brain uptake of the first cyclopentadienyl-tricarbonyl-[99m technetiumj-tropane conjugate. G. Tamagnan, R. Cesati III, S. Zoghbi, A. Varrone, M. Al-Tikriti, N. Kula, R. Baldessarini, J. Seibyl, J. Katzenellenbogen, R. Innis, R. Baldwin Hilton Hawaiian Village Coral Ballroom II, Mid-Pacific Conference Center Viral Serine Proteases (156)

D. Liotta, Presiding 1:05—556. Molecular pathogenesis of influenza A virus and sendai virus infection: Proteolytic activation of viral infectivity and natural protease inhibitors as defensive compounds. H. Kido, T. Towatari, M. Murakami, B. Yang 1:35—557. Design and synthesis of novel inhibitors of the Hepatitis C virus NS3 protease. Y. Tsantrizos 2:05—558. Design of HCMV serine protease inhibitors. K-Y. Byun, N. Nevins, M. Hager, J. Snyder 2:35—561. Inhibitors of HCMV protease. M. A. Abreo, C. S. Agree, J. Meng 3:05—562. Structure and inhibition of HCMV protease. L. Tong, R. Khayat, R. Batra

FRIDAY EVENING Hilton Hawaiian Village South Pacific Ballroom III, Mid-Pacific Conference Center Mathematical and Computational Aspects of Molecular Design (140)

D. Winkler, Presiding 7:05—113. Evolving roles for combichem and diversity software. R. S. Pearlman, K. M. Smith, H. Zhu, M-Y. K. Brusniak 7:35—131. An information-theoretic approach to cell-based mappings of chemistry spaces. G. Maggiora, V. Shanmugasundaram 8:05—132. Multidimensional scaling of massive molecular similarity tables. D. Agrafiotis, V. Lobanov, D. Rassokhin 8:35—133. Use of pharmacore analysis in mining biological data at the National Cancer Institute. R. Gussio, C. F. McGrath, D. W. Zaharevitz 9:05—134. ChemGPS: A chemical space navigation tool. J. Gottfries, P. Svensson, T. Oprea

9:35—135. R-group feature vector representation and its application in the rapid lead optimization of the glucagon antagonists. S. Shi, A. Kuki, A. Ling, M. Plewe, J. Gonzalez 10:05—136. Characteristic-monomial method for enumeration of isomers: Comparison with unit-subduced-cycle-index methods. S. Fujita

Hilton Hawaiian Village Coral Ballroom III, Mid-Pacific Conference Center

Hilton Hawaiian Village Coral Ballroom III, Mid-Pacific Conference Center

137. Targeted tumor radiotherapy with radioiododeoxyuridine in lipiodol. H. E. Wang, R. S. Liu, F. D. Chen, H. M. Yu, K. H. Chi, K. L. Huang, A. R. Lou, G. Ting 138. Study of Re-188 lipiodol for radiotherapy of hepatoma. S-J. Wang, W-Y. Lin, M-N. Chen, B-T. Hsieh, L-H. Shen, T-W. Lee, H-T. Huang, G. Ting 139. Rhenium-188 microsphere as a radiation synovectomy agent. W-Y. Lin, B-T. Hsieh, M-N. Chen, H-T. Huang, S-J. Wang, G. Ting 140. Evaluation of Re-188 species for intravascular radiation therapy. B-T. Hsieh, T-W. Lee, W-Y. Lin, G. Ting, S-J. Wang 141. Re-188 labeling of monoclonal antibody map Cx-99 and growth inhibition of cancer cell lines in vitro. T-W. Lee, L-C. Tsai, C-C. Yuan, B-T. Hsieh, C-H. Chang, G. Ting 143. Imaging of infection/inflammation with a novel synthetic peptide analog of platelet factor 4 (PF4). R. Manchanda, B. Moyer, M. Guaraldi, C. Nelson, D. Pearson, J. Lister-James, R. Dean 144. The need for and availability of radioisotopes and radiopharmaceutical manufacturing facilities. C. Seidel 145. Melanoma cells show high cellular uptake of radioiodinated methylene blue: Prospects for melanoma scintigraphy. G. Sobal, M. Rodrigues, H. Sinzinger

Advances in Radiopharmaceutical Chemistry (172) Poster Session 7:30-9:30 50. Evidence that cycloheximide, an inhibitor of protein synthesis, does not influence the brain trapping of a-[14c]methyl-Ltryptophan a-[14c] MTrp. M. Diksic, Y. Tohyama, M. FirkeMerid 51. oM-t^Fjfluorobenzylguanine ([ 18 F] FBG) and C ^ H 1 3 1 Ijiodobenzylguanine ([131I]IBG): Potential tracers for the noninvasive mapping of O^-alkylguanine-DNA alkyl transferase (AGT). G. Vaidyanathan, D. J. Affleck, C. M. Cavazos, S. P. Johnson, S. Shankar, H. S. Friedman, M. O. Colvin, M. R. Zalutsky 52. Radiotracers for p-cell imaging. C-Y. Shiue, R. Schirrmacher, A. Alavi 53. F-18 labeled 2-deoxy-2-fluoro-£>-dglycosyl fluoride derivatives as potential imaging probes for glucocerebrosidase. M. Adam, A. Wong, S. Withers 54. Synthesis of tropane and nortropane analogs with phenyl substitutions as serotonin transporter ligand. P. Emond, J. Helfenbein, Y. Frangin, S. Chalon, L. Garreau, J. C. Besnard, D. Guilloteau 55. Novel 67 Cu complexes with pyridinecontaining ligands as potential radiopharmaceuticals. E. Dadachova, H. Bryant, R. Planalp, M. Brechbiel 56. Synthesis and evaluation of a new 18 Flabeled nitroimidazole derivative with low LUMO energy as brain hypoxia marker. F. Yamamoto, M. Aoki, Y. Furusawa, K. Ando, Y. Kuwabara, K. Masuda, S. Sasaki, M. Maeda 58. Synthesis and evaluation of 99mTc and 123 l-labeled antimicrobial peptide. O. Seung Jun, R. Jin Sook, H. Hyun-Joon, M. Dae Hyuk, C. Jun Hong, L. Hee Kyung 59. ln-111 and Y-90 labeled GRP analogs: A structure-activity relationship. W. A. Volkert, H. Gali, T. J. Hoffman, N. K. Owen, G. L. Sieckman, C. J. Smith 60. Tc-99m-labeled substance-P (SP) for imaging inflammatory disease. K. Ozker 61. High-affinity ligands for the imaging of serotonin transporter: 4-Halo-6-nitroquipazine derivatives. D. Y. Chi, B. S. Lee, K. C. Lee, K-H. Chung, Y. S. Choe, C. Jin 62. Metabolism study of [18F]fluoroalkyl derivatives. D. Y. Chi, K. C. Lee, Y. S. Choe 63. Metallated angiotensin II receptor antagonist: New imaging modality for fibrosis in heart. R. Pandurangi, D. Papagiannopoulou, L. Kurti, M. Papadopoulos, I. Pirmettis, A. Terzis, E. Chiotellis, M. Harmata, R. Kuntz 111. Synthesis and monoamine transporter binding affinities of 2j3-carbomethoxy-3p(4-aromatic substituted phenyl) tropanes. G. Tamagnan, X. Fu, R. Baldwin, N. Kula, R. Baldessarini, R. Innis 112. Reliable regiospecific synthesis of the benzamide neuroleptic [123I]IBZM. G. Tamagnan, R. Baldwin, X. Fu, L. Amici, S. S. Zoghbi, T. Depaulis, R. Innis 563. Potential PET biomarkers for epidermal growth factor receptor tyrosine kinase. E. Mishani, T. A. Bonasera, G. Ortu, Y. Rozen, R. Krais, N. M. T. Freedman, R. Chisin, A. Gazit, A. Levitzki

The Organizinq Committee requests that there be no smoking in meeting rooms or committee meetings

Radionuclides for Therapeutic Oncology (174) Poster Session 7:30-9:30

SATURDAY MORNING Hilton Hawaiian Village South Pacific Ballroom III, Mid-Pacific Conference Center Mathematical and Computational Aspects of Molecular Design (140)

D. Winkler, Presiding 8:05—147. A simple continuous chirality measure. G. Crippen 8:35—148. A widely applicable set of molecular descriptors. P. Labute 9:05—149. SAR using Gaussian processes. F. Burden, D. Winkler 9:35—150. A novel 3-D QSAR procedure: Voronoi field. H. Chuman 10:05—151. Robust QSAR using automatic relevance detection and Bayesian neural nets. D. Winkler, F. Burden 10:35—152. SAR discovery using the cascade model. T. Okada 11:05—153. Quantum holography as a computational tool for molecular design. P. G. Mezey Hilton Hawaiian Village South Pacific Ballroom I, Mid-Pacific Conference Center Frontiers in Antibiotics: Synthesis, Design, and Mode of Action (181)

J. Vederas, Presiding 8:05—154. The need for new antibiotics. J. Davies 8:45—155. Design, syntheses, and studies of new antimicrobial agents. M. Miller 9:25—156. Design and development of practical syntheses of novel anti-MRS carbapenems. G. Humphrey 9:45—157. Studies in peptidoglycan biosynthesis: The transglycosylation reaction. L. Blaszczak, A. Kraft, M. Van Nieuwenhze, M. Zia-Ebrahimi, S. Mauldin, W. Hornback, S. Saha, E. Dingess-Hammond, B. Winger, D. Peake, R. Boyer 10:25—158. Chemlnformatics3: Converting HTS hits into medicinal chemistry leads. J. M. Finn 10:45—159. Total synthesis and development of useful antibiotics. K. Tatsuta

Hilton Hawaiian Village South Pacific Ballroom II, Mid-Pacific Conference Center Chemical Perspectives on Human Cancer (199)

L. Peterson, Presiding 8:05—160. Human carcinogen uptake and metabolism: Relation to cancer risk. S. Hecht 8:45—161. Metabolic activation and carcinogenesis of food-derived heterocyclic amines. E. Snyderwine 9:25—162. Environmental mutagens and carcinogens in Thailand. W. Kusamran, T. Kusamran 10:05—163. Identification of mutagens/ carcinogens in cooked food. K. Wakabayashi 10:45—164. Biomarkers of etiology and prevention in liver cancer. J. Groopman, T. Kensler Hilton Hawaiian Village Coral Ballroom II, Mid-Pacific Conference Center MMP Inhibitors (217)

B. De, Presiding 8:05—165. MMP inhibitors: A brief overview of key interactions leading to the design and synthesis of potent and selective inhibitors. B. De, S. Pikul, M. Natchus, N. Almstead, M. Cheng, G. Mieling, F. Gu, Y. Taiwo 8:15—166. Design, synthesis, and biological evaluation of potent thiazepine-based MMP inhibitors. N. Almstead, R. Bradley, S. Pikul, B. De, M. Natchus, Y. Taiwo, M. Janusz, F. Gu 8:50—167. The search for matrix metalloprotease inhibitors as therapeutic agents. L. Reiter, P. Mitchell 9:25—168. Anthranilic acid and benzodiazepine sulfonamides as novel MMP inhibitors. J. Skotnicki, J. D. Albright, J. Chen, R. Cowling, E. Delos Santos, J. DiJoseph, M. Du, X. Du, G. Ellestad, J. Ellingboe, Y. Gu, G. Jin, L. Killar, J. Levin, F. Moy, F. Nelson, R. Powers, M. Sharr, A. Sung, A. Venkatesan, T. Walter, Z. Xu, A. Zask 10:00—169. Substituted /V-hydroxyl-aphenyl sulfonylacetamides: Orally active MMP inhibitors. V. Aranapakam, G. Grosu, J. Davis, J. Baker, B. Hu, J. Ellingboe, A. Zask, V. Sandanayaka, J. Levin, J. Skotnicki, L. Killar, A. Sung, M. Sharr, J. DiJoseph, T. Walter, R. Cowling, J. Guixian 10:35—170. Design and synthesis of enzyme inhibitors: Lessons learned from modeling and X-ray crystallography. S. Hanessian, N. Moitessier, B. Mackay, S. Wilmouth

SATURDAY AFTERNOON Hilton Hawaiian Village Coral Ballroom IV, Mid-Pacific Conference Center Chemistry and Signal Transduction (011) Poster Session 4:00-6:00 171. Molecular recognition at the protein kinase C isozyme receptors: Identification of the residues in the protein kinase C C1 domains that play an important role in phorbol ester binding. M. Shindo, K. Irie, A. Nakahara, H. Ohigashi, P. Wender 172. Induction of apoptosis in rat thymocytes by shorter-chain prenyl compounds. Y. Kodaira, H. Sagami 173. Comparative studies on the cellular response to chemical stresses in strains of Euglena gracilis Z and SMZ. M. Ohta, T. Suzuki 174. Design and synthesis of compounds aimed at manipulation of the apoptotic signaling. K. Yonemura, M. Otsuka, T. Yamasaki, J-l. Inoue 175. Analysis of geranylgeranyl diphosphate synthase in rat. Y. Matsumura, T. Kuzuguchi, H. Sagami 176. An azido-functionalized dantrolene derivative as an efficient probe for photoaffinity labeling in the study of molecular mechanism of excitation-contraction coupling in the skeletal muscle. T. Hosoya, H. Aoyama, T. Ikemoto, Y. Kihara, M. Endo, M. Suzuki

177. Split green fluorescent protein as a probe for protein-protein interaction in vivo: The interaction produces matured green fluorescent protein based on protein splicing. T. Ozawa, Y. Umezawa 178. Molecular design and cellular antidiabetic activity of protein-tyrosine phosphatase inhibitors. T. Watanabe, T. Suzuki, A. Hiroki, Y. Umezawa, T. Takeuchi, K. Umezawa 179. Reactivity of novel organic nitrates, and NO/cGMP signaling as a therapeutic target. S. Smith, G. Thatcher 180. Designed prostaglandins exerting nerve protective effects: Promotion of neurite outgrowth. K. Tomokiyo, K. Furuta, T. Satoh, Y. Watanabe, M. Suzuki 181. Designed prostaglandins exerting nerve protective effects: Prevention of neuronal cell death. K. Furuta, K. Tomokiyo, T. Satoh, Y. Watanabe, M. Suzuki 182. Ligand specificity of ErbB receptors. K. Saito, J-H. Kim, M. Yamanaka, S. Yokoyama 183. Macrocyclic peptidomimetics as conformationally constrained Grb2 SH2 domain inhibitors. T. Burke Jr., J. Voigt, J. Kelley, D. Yang, Y. Gao 184. New human lingual G-protein-coupled receptors. T. Haertle, J-C. Gaudin, L. Breuils 185. Identification of C-terminal residues in Neuregulin2a and Neuregulin2P responsible for differential binding and activation of the ErbB4 receptor. R. P. Hammer, E. M. Cameron, E. N. Blommel, D. J. Riese II 186. Fingerprinting the protein kinase C isozyme binding selectivity of therapeutic leads: The binding affinities of phorbol ester, diacylglycerol, and bryostatins to the C1 domains of all protein kinase C isozymes. K. Irie, A. Nakahara, H. Ohigashi, M. Shindo, H. Fukuda, P. A. Wender, B. Lippa 187. Polymer-bound A/-hydroxysuccinimide esters: A column-free fluorescent-labeling method. M. Katoh, M. Sodeoka 188. Synthesis and evaluation of coumermycin analogs as mediators of signal transduction. S. H. Olson, M. A. Farrar, L. H. Slossberg, R. M. Perlmutter 189. The C4 hydroxyl group of phorbol esters may not be necessary for protein kinase C binding. M. Tanaka, K. Irie, Y. Nakagawa, H. Ohigashi, P. A. Wender 190. Design and synthesis of new phorboltelocidin agonists with conformational restriction of cyclic amide structure. Y. Endo 191. Structure-based design of Ser/Thr protein phosphatase 2B(PP2B) selective inhibitors. B. Yoshiyasy, M. Sodeoka, T. Naoto, H. Nozomu Hilton Hawaiian Village South Pacific Ballroom III, Mid-Pacific Conference Center Mathematical and Computational Aspects of Molecular Design (140)

D. Winkler, Presiding 1:05—192. Rapid structure generation, shape classification, docking and scoring. A. Nicholls, M. Stahl, A. Grant, M. McGann 1:35—193. Representation of hydrophobic profile of chemical compounds based on the TFS method. Y. Takahashi, T. Kanahata 2:05—194. Empirical free energy scoring of biological interactions: Understanding the effects of site-directed mutations on protein-protein associations. G. Kellogg, J. Burnett, D. Abraham 2:35—195. a-Helix folding in isolated s-peptide of mase A by Monte Carlo simulated annealing. T. Nakazawa, Y. Okamoto, S. Ban, Y. Okuda, A. Mitsutake 3:05—196. Design and synthesis of novel peptidyl prolyl isomerase (PPIase) inhibitors. P. Karuso, J-M. Poudrel, D. Moran 3:35—197. Molecular docking using a genetic algorithm approach based on graphs of critical points of electron density. D. P. Vercauteren, A. Becue, N. Meurice 4:05—198. Simultaneous superimposition of several rigid and flexible benzodiazepinelike ligands using a specific genetic algorithm strategy. N. Meurice, D. Vercauteren

Hilton Hawaiian Village Coral Ballroom II, Mid-Pacific Conference Center MMP Inhibitors (217)

B. De, Presiding 1:05—209. SAR of hydroxamate-based MMP inhibitors and new aspects for clinical application. M. Yamamoto 1:40—210. Design and development of hydroxyproline-derived MMP inhibitors as antiarthritic agents. M. Natchus, R. Bookland, S. Pikul, B. De, N. Almstead, Y. Taiwo, M. Jansuz, F. Gu 2:15—211. Matrix metalloprotease inhibitors for arthritis and cancer treatment. R. Andrews, M. Andersen, R. Austin, E. Beaudet, D. Becherer, D. Bubacz, M. Bickett, G. Boncek, J. Chan, J. Conway, D. Cowan, C. Crumrine, S. Dickerson, M. Gaul, K. Glennon, Y. Guo, B. Han, K. Hedeen, B. Keith, M. Lambert, T. Leesnitzer, P. Lin, M. Luzzio, D. McDougald, J. Mitchell, M. Moss, R. Mullin, D. Musso, H. Pink, M. Rabinowitz, M. Rizzolio, P. Scates, L. Schaller, T. Seaton, J. Selph, J. Stanford, S. Stimpson, T. Tippin, J. Triantafillou, J. Warner, G. Whitesell, R. Wiethe 2:50—212. Rational design of peptidomimetic inhibitors of TNF-a processing aggrecanase. C. Decicco 3:25—213. Discovery and development of potent, long-lived, nonpeptidic retrohydroxamates as MMP inhibitors. M. Michaelides, M. Curtin, Y. Dai, H. Heyman, R. Garland, Y. Guo, J. Holms, J. Stacey, D. Steinman, C. Wada, D. Albert, T. Magoc, P. Marcotte, K. Glaser, D. Morgan, S. Davidsen 4:00—214. Oxophosphonates: A new class of potent matrix metalloproteinase inhibitors. E. Breuer, R. Reich, C. Salomon, Y. Katz, W. Chen, A. Goldblum Hilton Hawaiian Village Coral Ballroom IV, Mid-Pacific Conference Center Molecular Recognition Using Nucleic Acids and Their Related Substances (045) Poster Session 4:00-6:00 79. Controlling the higher order structure of DNA-histone H1 complex by laser manipulation. Y. Yoshikawa, S-l. M. Nomura 80. Retrovirus-specific random mutagenesis by a hydrogen bond ambivalent nucleoside 5A*-triphosphate analog. K. Moriyama, D. Loakes, K. Negishi 81. New method for scanning of singlenucleotide polymorphisms: Recognition of guanine-guanine mismatches by dimeric naphthyridines. S. Sando, K. Nakatani, I. Saito 82. Binding of a quinacrine-netropsin conjugate to DNA studied by NMR spectroscopy. Y. Kubota, S. Tani, S. Kawamura 83. Triplex formation of oligonucleotide derivatives containing bicyclic nucleosides with a fixed N-form sugar puckering: Selective recognition of a CYG base pair interruption. Y. Hari, S. Obika, M. Sekiguchi, T. Imanishi 84. Specific cross-linking reaction to duplex DNA mediated by triple helix formation. F. Nagatsugi, D. Usui, T. Kawasaki, M. Maeda, S. Sasaki 85. New DNA binding ligands with bistetrahydrofuran and bisfuran skeleton bearing diamine and long alkyl chains. S. Sasaki, T. Shibata, H. Torigoe, Y. Shibata, M. Maeda 86. Mutagenic specificity of an abasic site studied by yeast oligonucleotide transformation assay. C. Otsuka, Y. Hata, D. Loakes, K. Negishi 87. RNA aptamers selected against the Rasbinding domain of Raf-1 inhibit Rasdependent Raf-1 activation. M. Kimoto, M. Shirouzu, S. Mizutani, H. Koide, Y. Kaziro, I. Hirao, S. Yokoyama

88. Reversible DNA photopadlocking via 5-vinyldeoxycytidine. S. Matsuda, K. Fujimoto, I. Saito 89. Fluorescent probe and permeability to cells of antisense compound: Isopoly (Scarboxymethyl-L-cysteine) derivative of nucleic acid bases. S. Kitaoka, N. Tohnai, Y. Inaki, M. Miyata, T. Hatae, T. Tanabe 90. Antisense inhibition of PSD-95 protein by isopoly(S-carboxymethyl-L-cysteine) derivatives of nucleic acid bases. H. Maruoka, N. Tohnai, Y. Inaki, M. Miyata 91. Oxidative condition that produces imidazolone from guanine. K. Kino, H. Sugiyama 92. Comb-type cationic copolymeroligonucleotide conjugate for DNA triplex stabilization. A. Maruyama, M. Ueda, M. Saito, T. Ishihara, T. Akaike 93. Synthesis of 2 ' , 5'-isoDNA mimic chiral peptide nucleic acids. T. Yamasaki, M. Osman, Y. Okamoto, T. Okawara, M. Otsuka 94. Synthesis of nucleosides possessing recombinant SAH hydrolase inhibitory activities. Y. Kitade, A. Kozaki, M. Nakanishi, C. Yatome 95. lsoindolin-1-one homo-n-nucleoside derivatives for recognition of CG base pairs. E. Mertz, S. Zimmerman 96. Synthesis and biological evaluation of multisubstrate analog inhibitors for purine nucleoside phosphorylas. T. Yomoaatsu, Y. Hayakawa, S. Shibuya, T. Kihara, S. Soeda, H. Shimeno 97. In vital selection of RNA aptamers that respond to a small RNA-binding ligand. M. Hagihara, M. Takashi, M. Keisuke 98. DNA binding of a basic leucine-zipper protein with novel folding domain. S-l. Sato, M. Takashi, M. Keisuke 99. N 2 -nitro-2 1 -deoxyguanosine, a novel DNA lesion from 2-deoxyguanosine treated with NO/0 2 . M. Yamada, S. Toshinori, K. Kenji, T. Kunihiko, M. Takashi, M. Keisuke Hilton Hawaiian Village South Pacific Ballroom I, Mid-Pacific Conference Center Frontiers in Antibiotics: Synthesis, Design, and Mode of Action (181)

R. Williams, Presiding 1:05—199. Vancomycin, teicoplanin, and ramoplanin: Synthetic and mechanistic studies. D. Boger 1:45—200. Constrained lactams as mimics of the venerable carbapenems. S. Hanessian, R. Buckle 2:25—201. Asymmetric total synthesis of antitumor antibiotic, fredericamycin A. Y. Kita 3:05—202. Synthetic studies on optically active FR-900482. T. Fukuyama, M. Kambe, M. Suzuki, H. Tokuyama 4:05—203. 3-Heteroarylthio cephalosporin antibiotics effective against resistant grampositive bacteria. S. J. Hecker Hilton Hawaiian Village South Pacific Ballroom II, Mid-Pacific Conference Center Chemical Perspectives on Human Cancer (199)

D. Josephy, Presiding 1:05—204. Site-specific mutagenesis by O6substituted guanines and O4methylthymine in E. coli and human cells. R. Moschel 1:45—205. Mutagenesis induced by endogenous DNA adducts in human cells. M. Moriya, R. Levine, l-Y. Yang, S. Khullar, F. Johnson, A. Grollman 2:25—206. Molecular analysis of in vivo mutations using transgenic mice GPT5. T. Nohmi 3:05—207. Examining tissue-specific bioactivation in vitro: Cytochrome P450 1B1 and other extrahepatic forms in the metabolism of carcinogens. E. Gillam, L. Notely, K. Crewe, F. P. Guengerich, T. Shimada, M. Lennard 3:45—208. Bacterial mutagenicity assays with recombinant human enzymes: A new tool for studying the biochemistry of carcinogen bioactivation. P. D. Josephy



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MEDI/TECHNICAL PROGRAM

SUNDAY MORNING Hilton Hawaiian Village South Pacific Ballroom III, Mid-Pacific Conference Center Neurochemistry of Excitatory Amino Acids (036)

Y. Ohfune, Presiding 8:05—215. Chemical and pharmacological studies of dysiherbaine, a marine-derived excitatory amino acid. R. Sakai, G. Swanson, A. Contractor, A. Ghetti, S. Hienemann, K. Shimamoto, M. Sasaki, T. Koike, M. Takahiro, K. Tachibana, C. Oiwa, H. Kamiya 8:25—216. Synthesis of dysiherbaine, a new marine neuroexcitatory amino acid, and its analogs. S. Hatakeyama 8:45—217. Structurally novel AMPA potentiators: New opportunities for drug development. P. Ornstein 9:05—218. Isolation and structure determination of AMPA and NMDA antagonist of microbial origin, kaitocephalin. K. Shin-Ya 9:25—219. Design, synthesis, and biological activity of (1 S,2fl)-1 -phenyl-2-[(S)-1 -aminoalkyl]-/V,AAdiethylcyclopropanecarboxamide, a new class of NMDA receptor antagonists. S. Shuto 9:45—220. Glutamate NMDA receptor NR1 subunit splice variants in Alzheimer's disease. P. Dodd, M. Hynd, H. Scott 10:05—221. Long-term consolidation of NMDA signals in hippocampal dentate gyrus. Y. Yoneda, T. Kitayama, E. Hinoi, N. Nakamichi 10:25—222. Synthesis and biological evaluation of novel mGluR modulators. D. Ma 10:45—223. Novel mGluR ligands acting as glutamate carboxypeptidase II inhibitors: Role as neuroprotective and antiangiogenic agents. A. Kozikowski, F. Nan, P. Conti 11:10—224. Synthesis and pharmacological characterization of the potent and selective mGlu8 receptor agonist UBP1109. D. Jane, N. Thomas, R. Wright, P. Howson, A. Kingston, D. Schoepp 11:35—225. Pharmacology of systemically active ligands for metabotropic glutamate receptors. D. D. Schoepp, J. A. Monn, P. L. Ornstein Hilton Hawaiian Village Coral Ballroom II, Mid-Pacific Conference Center Next Generation Therapeutics (189)

J. Kozarich, Presiding 8:05—232. Merging mature and modern modes of antibacterial discovery. D. Pompliano 8:45—233. Cleavage of mRNA in cells by novel sliding ribozymes is independent of the folding of the target mRNA. M. Warashina, H. Kawasaki, T. Kuwabara, K. Taira 9:20—236. Role of protein tyrosine phosphatase- 1B in diabetes and obesity. B. Kennedy 10:00—237. Novel opioid receptor antagonist in pain regulation: Discovery and pharmacological profiles of nociceptin(orphanin FQ) antagonist J-113397. Y. Iwasawa 10:40—238. Photoactivated, active sitedirected y-secretase inhibitors covalently label presenilin. J. Shafer, M. Xu, M-T. Lai, Q. Huang, J. Castro, J. DimuzioMower, T. Harrison, C. Lellis, A. Nadin, J. Neduvelil, R. B. Register, M. Sardana, M. Shearman, A. Smith, X-P. Shi, K-C. Yin, S. Gardell, Y-M. Li Hilton Hawaiian Village South Pacific Ballroom I, Mid-Pacific Conference Center Frontiers in Antibiotics: Synthesis, Design, and Mode of Action (181)

J. Vederas, Presiding 8:05—226. How bacteria cross-link their cell walls: Target for antibiotics. S. Mobashery, W. Lee, M. McDonough, L. Kotra, 2-H. Li, Y. Takeda, J. Kelly 8:45—227. Antibiotics from Merck's natural products drug discovery program. S. J. Gould 9:05—228. Synthetic studies on marine polycyclic ethers. T. Nakata

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9:45—229. Exploring structure-activity relationships of peptide antibiotics with azabicycloalkane amino acids as dipeptide surrogates. W. D. Lubell, S. Roy, H-G. Lombart 10:05—230. Synthetic studies on pradimicinbenanomicin class antibiotics. K. Suzuki 10:45—231. Synthesis and antimicrobial evaluation of TAN-1057A/B analogs. R. Williams, C. Yuan Hilton Hawaiian Village South Pacific Ballroom II, Mid-Pacific Conference Center Chemical Perspectives on Human Cancer (199)

L. Peterson, Presiding 8:05—239. DNA adducts: Markers of exposure and predictors of risk. R. Santella 9:25—240. DNA damage induced by hydroxyestrogens and the mutagenic potential. I. Yoshizawa, S. Itoh, K. Wakabayashi, S. Shibutani 9:45—241. DNA damage by nitric oxide. K. Makino 10:05—242. Structure and function of sitespecific PAH-diol epoxide oligonucleotide adducts. N. Geacintov 10:45—243. Interactions of carcinogenmodified DNA with polymerases. F. P. Guengerich, H. Einolf, A. Mican, D. Keller, K. Williams, L. Furge

SUNDAY AFTERNOON Hilton Hawaiian Village South Pacific Ballroom III, Mid-Pacific Conference Center Neurochemistry of Excitatory Amino Acids (036)

G. Johnston, Presiding 1:05—244. Neuronal glutamate transport and Alzheimer's disease pathogenesis. H. Scott, P. Dodd 1:30—245. Excitatory amino acid transporters (EAATs): Keeping up with glutamate. S. Amara, C. Cheng, S. S. Das, W. Fairman, B. H. Leighton, K. Poth, R. P. Seal, Y. Shigeri, S. D. Watts 1:55—246. Inhibition of glutamate transporters by conformationally restricted analogs of glutamate: 1 S-amino-5S-methylcyclopent-3-ene-1,3-dicarboxylate. G. Johnston, A. Mitrovic, R. Vandernberg, S. Pyne 2:20—247. New (3-hydroxyaspartate derivatives as glutamate transporter blockers. K. Shimamoto, Y. Shigeri, Y. YasudaKamatani, B. Lebrun, N. Yumoto, T. Nakajima 2:45—248. The glutamate vesicular transporter: Pharmacophore development. C. Thompson, C. Carrigan, R. Bridges, S. Esslinger, K. Cybulski, P. Tongcharoensirikul 3:10—249. Conformationally constrained analogs as probes of uptake and efflux through CISIS glutamate transporters. R. Bridges 3:35—250. Regulation of vesicular glutamate quantal size. T. Ueda Hilton Hawaiian Village South Pacific Ballroom I, Mid-Pacific Conference Center Frontiers in Antibiotics: Synthesis, Design, and Mode of Action (181)

T. Fukuyama, Presiding 1:05—257. Stereoselective synthesis of remarkably bioactive heterocycles, FR901464 and kaitocephalin. T. Kitahara 1:45—258. Exploitation of new reagents and their application to the synthesis of biologically interesting natural products. T. Shioiri, A. Toyohiko, Y. Fumiaki 2:25—259. Some multidrug transporters in bacteria can pump out a very wide range of drugs and are related to human disease proteins. H. Nikaido 3:05—260. Synthetic strategies and energy capture in the biosynthesis of p-lactam antibiotics. C. Townsend 3:45—261. Assembly line enzymology for nonribosomal peptide and siderophore biosynthesis. C. Walsh

Hilton Hawaiian Village Coral Ballroom II, Mid-Pacific Conference Center Next Generation Therapeutics (189)

J. Kozarich, Presiding 1:05—266. Photodynamic therapy. D. Dolphin 1:45—267. Synthesis of amphiphilic derivatives of rose bengal for cancer treatments using ultrasound. N. Sugita, K-l. Kawabata, K. Sasaki, S-l. Umemura, I. Sakata 2:25—268. Therapeutic potential of flavonoid-based redox regulators for oxidative stress. G. Miller, S. Flaim, B. Wang 3:05—269. Fluorocarbon-based blood substitutes: An update. J. Riess 3:45—270. A new class of anti-inflammatory and antipyretic drugs: Discovery of Vioxx, a Cox-2 selective inhibitor. Z. Wang, S. Boyce, C. Brideau, C. Chan, S. Charleson, W. Cromlish, N. Chauret, D. Ethier, J. F. Evans, A. Ford-Hutchinson, M. Forrest, J. Y. Gauthier, R. Gordon, M. Gresser, J. Guay, S. Kargman, B. Kennedy, Y. Leblanc, S. Leger, J. Mancini, G. O'Neill, M. Ouellet, D. Percival, D. Patrick, H. Perrier, P. Prasit, D. Riendeau, I. Rodger, P. N. Rupniak, P. Tagari, M. Therien, P. Vickers, D. Visco, E. Wong, L. J. Xu, R. N. Young, R. Zamboni 4:00—271. Hydroxymethyl nitrofurazone, a potential antichagasic prodrug with decreased mutagenic activity related to nitrofurazone. M. C. Chung, M. Silva, R. V. C. Guido, E. A. Varavda, E. I. Ferreira Hilton Hawaiian Village South Pacific Ballroom II, Mid-Pacific Conference Center Chemical Perspectives on Human Cancer (199)

J. Essigmann, Presiding 1:05—272. Cellular responses to DNA damage. J. Essigmann 1:45—273. 2-Hydroxy-dATP formation by oxidative dA damage, mutagenic effect, and hydrolysis human MTHI protein. H. Kasai 2:25—274. Complex cellular responses to alkylating agents. L. Samson 3:05—275. Mutagenesis in synthetic c-Haras genes by damaged bases. E. Ohtsuka, H. Kamiya 3:45—276. Creating human DNA alkyltransferases for the protection of bone marrow hematopoietic precursor cells. L. Loeb, B. Davis, S. Gerson, L. Encell Hilton Hawaiian Village Coral Ballroom IV, Mid-Pacific Conference Center Medicinal Chemistry General (08G-P) Poster Session

1:00-3:00 303. An investigational work into the potency demonstrated by oxime-based MMP inhibitors. M. Cheng, B. De, M. Natchus, N. Almstead, S. Pikul, M. Dowty, C. Dietsch, M. Dunaway, F. Gu, L Hsieh, M. Janusz, Y. Taiwo 304. Synthesis and morphological reversion activity on src*sNRK cells of pyrimidinylpropanamide antibiotics, sparsomycin, sparoxomycins A1 and A2, and their analogs. N. Nakajima, M. Ubukata 305. Selective mechanism-based inhibition of matrix metalloproteinases. S. Brown, M. Bernardo, Z-H. Li, L. Kotra, Y. Tanaka, R. Fridman, S. Mobashery 306. Biochemical characterization of the OXA-10 p-lactamase. D. Golemi, S. Vakulenko, A. Ishiwata, S. Mobashery 307. Preparation of topostatin-like derivatives and their inhibitory activity of topoisomerase l/lI. T. Okawara, K. Kaneko, K. Suzuki, M. Otsuka 308. Targeting pharmacologic delivery of nitric oxide (NO). L. Keefer, N. Anadu, E. Arnold, C. Bonifant, M. Citro, A. Fitzhugh, J. Hrabie, J. Saavedra, A. Shanklin


309. Computational studies on the mechanism of activation of matrix metalloproteases. S. Mobashery, L. P. Kotra, J. Cross, H. B. Schlegel 310. Ester and hydroxamate analogs of methionyl and isoleucyl adenylate as inhibitors of E. coli methionyl and isoleucyltRNA synthetase. J. Lee, S. U. Kang, Y. J. Jo, S. Kim 311. Inhibitory effect on testosterone-5areductase activity by strong acid electrolytic hot spring water. N. Kato, A. Ohno, K. Kasai, H. Koyama, T. Yamadera, T. Araki 312. Selective inhibition of E-selectin expression in human umbilical vein endothelial cells by 2-aryl-4-carboxyquinolines. K. Condroski, D. Stout, J. Freeman, N. Mort, S. Boyd, D. Arendsen, D. Fry, B. Cool, E. Reilly, L. Kifle, P. Tobin Jr., G. Okasinski, K. Marsh, A. Kempf-Grote, P. Kilgannon, W. Wisdom, M. Gallatin 313. Regiospecific synthesis of folate conjugates: Ligands for Gd complexes with potential for tumor imaging. K. Ramalingam, R. Ranganathan, T. Arunachalam, R. Pillai 314. Experimental receptor mapping for the sugar binding site of concanavalin A with a surface plasmon resonance sensor. S. Goto, K. Masuda, H. Chuman, H. Terada 315. Novel synthetic oleanane and ursane triterpenoids with enone functionalities in rings A and C: A series of highly active inhibitors of nitric oxide production in mouse macrophages. T. Honda, G. Gribble, B. Rounds, N. Suh, H. Finlay, L. Bore, F. Favaloro Jr., Y. Wang, M. Sporn 316. Synthesis and structure-activity relationships (SAR) of a novel class of potent selective orally active vasopressin V2 receptor agonists. A. Failli, J. Dusza, T. Caggiano, M. Ashwell, J. Shumsky, R. Steffan, A. Molinari, E. Trybulski, R. Dushin, J. Bagli, E. Hodgkin, D. Williams, J. D. Albright, E. G. Delos Santos, X. Du, P. Chan, C. Park 317. Structure and antitumoral activity of lichenic metabolite and its copper complex. R. Sartori, S. Diez, R. Sariego, E. Navarrete, W. Quilhot, M. Hidalgo, S. Moya 318. Studies on some chelates derived from anti ulcer vitamin. J. J. Vora, D. R. Patel, D. G. Patel, M. Brahmbhatt, A. Patel, S. Sharma, J. Joshi 319. Synergistic effects of azole group antifungal agents and cyclic peptide antibiotics with a terminal guanidino side chain. J. Kuroda, T. Fukai, M. Konishi, J. Uno, K. Kurusu, T. Otani, T. Nomura 320. Synthesis of peptides mimicking chemokine receptor CCR5 and their inhibitory effects against HIV-1 infection. K. Ikeda, K. Konishi, K. Achiwa, H. Hishino, K. Tanaka 321. Cyclotron T1-201 production G. Casale, J. Lago Fernandez, G. Maslat 322. Irreversible inhibition of IMP-1 metallop-lactamase by 4-nitrophenyl 3-mercaptopropionate and its derivatives and activity modulation by site-specific modification of ASP near the active site. M. Goto, K. Soga, T. Kuroki, K. Hata, A. Kawanami, H. Mori, H. Kurosaki 323. Long-range interstrand cross-links formed by polynuclear platinum complexes. Y. Qu, J. Malina, V. Brabec, J. Cox, N. Farrell 324. Parallel synthesis of inhibitors of NAD synthetase as new antibacterial agents. W. Brouillette, S. Velu, C. Brouillette, C-H. Luan, L. Delucas 325. Kinetic and structural studies on NAD synthetase: A new antibacterial target. D. Muccio, B. Pybus, Y-C. Lee, P. Jackson, S. Harville, M. Jablonsky, L. Delucas 326. Synthesis of nonnucleoside pyrimidine analogs and their antiviral activity. G. Vargas-Hernandez, B. Gordillo 327. Synthesis of methylated homocysteine to methionine by 5-methyltetrahydrofolate. H. Green, D. Ross, J. Mitnick 328. Novel specific inhibitors of puromycinsensitive aminopeptidase with a cyclic imide skeleton. H. Takahashi, M. Komoda, H. Takayama, Y. Hashimoto 329. Self-organization of liver constitutive cells mediated by synthetic polymer. M. Kamihira 330. Synthesis of novel beterocyclic serine protease inhibitors. D. Martyn, A. Abell 331. Biodegradable polymers for biomedical applications. W. Busby, N. Cameron 559. Substituted quinoline-2,4-dicarboxylic acids: Inhibitors of the glutamate vesicular transporter. C. Thompson, C. N. Carrigan, R. J. Bridges, K. Cybulski, C. S. Esslinger, P. Tongcharoensirikul

SUNDAY EVENING Hilton Hawaiian Village Coral Ballroom III, Mid-Pacific Conference Center Neurochemistry of Excitatory Amino Acids (036) Poster Session 7:30-9:30 251. Characterization of novel amino acids containing squaryl group to glutamate receptors. Y. Shigeri, T. Shinada, K. Shimamoto, N. Yumoto, Y. Ohfune 252. Atropisomerism within series of noncompetitive AMPA antagonists. W. Welch, J. Huang, F. Ewing, F. Menniti, M. Pagnozzi, M. Banker, K. Devries 253. The synthesis of tritated homoquinolinic acid as a NR2B selective NMDA receptor radioligand. D. Jane, H. W. Tse, D. A. Skitter, V. J. Andaloro, J. C. Brown, M. C. Kemp, D. T. Monaghan 254. Effects of dl-threo-p-benzyloxyaspartate (dl-TBOA) on excitatory amino acid transporters (EAAT4 and EAAT5). Y. Shigeri, Y. Shimamoto, K. Yasuda-Kamatani, R. Seal, N. Yumoto, T. Nakajima, S. Amara 255. Efficient synthesis of a novel glutamate analog possessing 4-hydroxy-2,3dioxocyclobut-1-enyl group. T. Shinada, K-l. Hayashi, Y. Ohfune 256. Structure characterization of neurotoxic spider toxins. H. Naoki, K. Murata, T. Fujita, K. Konno, M. S. Palma, M. Andriantsiferana, Y. Ohfune, T. Nakajima Hilton Hawaiian Village Coral Ballroom III, Mid-Pacific Conference Center Next Generation Therapeutics (189) Poster Session 7:30-9:30 234. Hybrid liposomes as a drug carrier for the oral administration of insulin in rat model of diabetes. K. Nakashima, M. Miyagi, Y. Matsumoto, R. Ueoka 235. Potent, orally active Cox-2 inhibitors with improved half-life. P. Roy, S. Boyce, C. Brideau, C. C. Chan, S. Charleson, N. Chauret, D. Claveau, D. Ethier, A. FordHutchinson, R. Gordon, M. Gresser, E. Grimm, J. Guay, Y. Leblanc, C-S. Li, D. Nicoll-Griffith, D. Riendeau, D. Visco, Z. Wang, J. Webb, L-J. Xu. R. Young, R. Zamboni, P. Prasit Hilton Hawaiian Village Coral Ballroom I, Mid-Pacific Conference Center Combinatorial and Parallel Synthesis: Applications to Medicinal Chemistry (218) Poster Session

7:30-9:30 350. Design and parallel synthesis of novel small molecules for drug discovery. D. S. Dhanoa 352. Small molecule approaches to sulfotransferase inhibition. J. Armstrong, C. Bertozzi 353. Efficient synthesis of 4-boronophenylanine, a boron-carrier for boron neutron capture theory. K. Park, K. Yoshino, H. Tomiyasu Hilton Hawaiian Village South Pacific Ballroom II, Mid-Pacific Conference Center Radionuclides for Therapeutic Oncology (174)

S. C. Srivastava, Presiding 7:05—333. Prospects for developments in medical uses of radioisotopes. A. McEwan 7:30—334. Progress is targeted radiotherapy: Improving the therapeutic index. R. Dean 7:55—335. Status and prospects of radiopharmaceutical research for targeted radiotherapy in Taiwan. G. Ting, S-J. Wang 8:20—336. Intratumoral radionuclide therapy. M. Thakur, D. Leeper, R. Howell, P. Wachsberger, S. Goonewerdene, G. Ilakis, F. Waterman, P. Rao, D. VassilevaBelnikolovska, A. Dicker 8:40—337. Development of Lu-177 for targeted radiotherapy. J-L. Vanderheyden, D. Pipes, J. Brodack

Hilton Hawaiian Village Coral Ballroom III, Mid-Pacific Conference Center Chemical Perspectives on Human Cancer (199) Poster Session 7:30-9:30 277. Design and synthesis of transferable farnesyl pyrophosphate analogs to Ras by protein Farnesyltransferase. H. Spielmann, K. Chehade, D. Andres, R. Isaacs, E. Micali 278. ER-68203-00, a structurally novel sulfonamide as a potential, orally active anti cancer agent by inhibiting tumor angiogenesis. T. Haneda, T. Wakabayashi, A. Tsuruoka, J. Kamata, S. Hamaoka, K. Takahashi, N. Ueda, Y. Funahasi, T. Semba, N. Sugi, H. Ymamoto 279. Effects of cadmium on benzo(a) pyreneDNA adduct formation and repair in the mammary glands of Sprague-Dawley rats. A. Prakash, C. Dameron, C. Peng 280. Specific inhibitory effects of hybrid liposomes on the growth of various tumor cells. K. Nakano, W. Takata, Y. Matsumoto, R. Ueoka 281. Induction of apoptosis by hybrid liposomes through activation of caspase-3. M. Yamamoto, Y. Iwamoto, Y. Yano, Y. Matsumoto, R. Ueoka 282. Farnesyl transferase inhibitors: In vitro and in vivo activity in specific cell lines. B-Y. Kwon, K-H. Son, M-Y. Han, H-M. Kim, S-H. Lee, H-W. Jeong, H-K. Kim 283. On the modification of calf thymus DNA by 6-hydroxyestrone 6-sulfates. S. Itoh, S. Watanabe, K. Takanashi, Y. Itoh, I. Yoshizawa 284. Identification of mutagens in the Waka River in Wakayama, Japan. T. EnyaTakamura, A. Tada, T. Sugimura, K. Wakabayashi, T. Watanabe, T. Hirayama 285. Detection of 1,n2-cyclic-propanodeoxyguanosine adducts in vitro and in rats liver by 32p-postlabeling methods. B. Budiawan, E. Eder 286. Metabolism of the tobacco-specific nitrosamine A/'-nitrosonornicotine in the Patas monkey. P. Upadhyaya, S. Hecht 287. DNA damage and mutation by highvalent chromium. K. Sugden, B. Martin 288. Molecular dynamics of a damaged DNA by FMM and MTS method. H. ishida 289. Novel DNA-DNA cross-linking agent with heterobifunctional group. Q. Zhou, W. Duan, D. Simmons, O. Fedoroff, L. Hurley 290. Synthesis and evaluation of 5'-fluoro-1(2'-oxoalkyl)uracils as a new class of radiation-activating antitumor prodrugs. T. Mori, M. Mori, L. Zhou, H. Hatta, S-l. Nishimoto 291. A [1H,15N] NMR study of aquation kinetics and the stepwise formation of a 1,4interstrand GG cross-link of the new platinum anticancer drug BBR 3464 [{transPtCI(NH3)2}2{m-frans-Pt(NH3)2(NH2(CH2) 6NH2)2}](NO3)4(1,0,1/t,t,t(n = 6)). A. Hegmans, S. Berners-Price, J. Cox, M. Davies, Z. Guo, N. Farrell, D. Thomas 292. Reaction and mechanism of phosphoglycolaldehyde with DNA. M. Awada, P. Dedon 293. Reactivity studies on frans-planar amine platinum compounds (TPAs). W. Bates, A. Quiroga, N. Farrell 294. Generation of a reactive coumarin metabolite by rat esophogeal microsomes (REM) and its role a the inhibition of A/-nitrosobenzylmethylamine (NBzMA) metabolism. S. Murphy, L. Von Weyman 295. Reaction of c/s-2-butene 1,4-dial with deoxynucleosides. L. Gingipalli, P. Dedon 296. Biochemical evidence for base flipping in positively supercoiled DNA. M. Barth, W. Lamarr, S. Ciftan, P. Dedon 297. Role of tamoxifen and 9-c/s retinoic acid and their interactive combinations in the chemoprevention of human breast cancer. M. Haghpanah, E. Branca, J. Mitnick 298. Importance of DNA repair in 4-(methylnitrosamino)-1 -(3-pyridyl)-1 butanone(NNK)-induced lung tumorigenesis. L. Peterson, N. Thomson, D. Crankshaw, P. Kenney 299. /V-Nitrosotolazoline: Mechanism of decomposition and guanine adduction. R. Loeppky, S. Jianzheng

300. Radiolabeled C-7 substituted estra1,3,5(10),6-tetraenes as potential diagnostics for estrogen-positive breast cancer. T. Thiemann, E. Inohae, K. Umeno, S. Mataka, M. Melo, M. C. Silva, L. Patricio, I. Santos, F. Marujo-Marquez, C. Santos 301. Drugs for treating diseases of the prostate. P. Weintraub, J. Burkhart, C. Gates, R. Resvick, R. Vaz, D. Friedrich, M. Angelastro, P. Bey, N. Peet 302. Lipid hydroperoxide-induced cell death in a leukemia cell line u937. N. Baba, T. Morimoto, T. Motoyama, M. Nagamura, C. Zhu, K. Takahata Hilton Hawaiian Village Coral Ballroom III, Mid-Pacific Conference Center Mathematical and Computational Aspects of Molecular Design (140) Poster Session

7:30-9:30 114. Recent developments in pharmacophore perception in drug design. O. Guner, C. Freeman, J. Sutter, O. Clement 115. OSPPREYS: An oriented substituent pharmacophore PRopErtY space. E. Martin, T. Hoeffel 116. Modeling with molecular pseudoconnectivity descriptors. L. Pogliani 117. GA approaches for successful QSAR modeling. M. Embrechts, C. Breneman, K. Bennett, S. Nagumani 118. Relationships between the structural/ electronic properties and odor activities of pyrazine derivatives. K. Shimazaki, N. Higashi, H. Komatsu, H. Shikata, K. Sakakibara 119. New computer-aided drug design methodologies. R. Griffith, J. Bremner, P. Keller, T. Luu 120. CROMRsel-s: Efficient algorithms for the selection of most important variables in the QSAR/QSPR modeling. N. Trinajstic, B. Lucie 121. 3-D QSAR analysis of inhibition of murine-soluble epoxide hydrolase (MsEH) by benzoyl ureas, aryl ureas, and their analogs. C. Wheelock, Y. Nakagawa, C. Morisseau, M. Goodrow, B. Hammock 122. An approach to automated identification of 3-D protein motifs. H. Kato, Y. Takahashi, H. Abe 123. Toward an optimal procedure for variable selection and QSAR model building. A. Yasri, R. Czerminski, B. Wythoff, D. Hartsough 124. Combinatorial library design: An integrated approach based on interactive visualization, property, and structure-based selection of reagents and products. P. Svensson, J. Gottfries, S. Volker 125. Computational approaches for structure-based rational design of HIV-1 protease inhibitors: 2-D and 3-D molecular modeling. X. Wang, W. Welsh 126. Informative library design as an efficient tool for lead generation and optimization: Method and applications. E. Bradley, J. Miller, E. Saiah, M. Ramirez-Weinhouse, M. Wayland, L. Robinson, P. Grootenhuis 127. Finding guaranteed global energy minima for conformationally flexible molecules. M. Vargyas, Z. Szabo 128. New methodology to classify active and inactive organic molecules using quantum mechanical descriptors. D. Galvao, R. Braga, R. Vandrame, P. Barone 129. Electronic indices methodology (EIM) applied to the study of taxol and derivatives. D. Galvao, S. Braga 130. On the electronic structure of antitumor drugs ellipticines. P. M. V. B. Barone, S. F. Braga, S. D. O. Dantas, D. S. Galvo Hilton Hawaiian Village Coral Ballroom III, Mid-Pacific Conference Center Frontiers in Antibiotics: Synthesis, Design, and Mode of Action (181) Poster Session 7:30-9:30 262. Synthesis and minimal inhibitory concentration determination of 5-nitro-2thiophylidene derivatives against MRSA. L. C. Tavares, P-A. Rezende, L. Prestes

263. Quinolone antibacterials: Design, synthesis, and biological activity of potent, novel, and safe nonfluoroquinolones (NFQs). J-l. Almstead, S. M. Flaim, C. P. Gallagher, J. L. Gray, E. X. Hu, N. K. kirn, B. Ledoussal, C. J. Taylor 264. Azalide 3,6-ketals: Synthesis and SAR of a novel class of macrolide antibiotics. K. Lundy, M. Minch, B. Jaynes, S. Hayashi, B. Kamicker, C. Bertsche, H. Cheng, D. George, B. Morton, B. Pratt, R. Rafka, S. Santoro, A. Silvia 265. Azalide 3,6-ketals: SAR in an aromatic analog series with potent gram-positive and gram-negative activity. H. Cheng, P. Bertinato, C. Bertsche, K. Daniel, J. Dutra, D. George, S. Hayashi, B. Kamicker, K. Lundy, N. Minich, B. Morton, R. Rafka, S. Sakya, S. Santoro, M. Suarez-Contreras, N. Vamvkides, C. Zeigler

MONDAY MORNING Hilton Hawaiian Village South Pacific Ballroom II, Mid-Pacific Conference Center Radionuclides for Therapeutic Oncology (174)

G. Ting, Presiding 8:35—338. DOTA-Bombesin complexes with Sm-153 and NCA Pm-149. S. Jurisson, C. Cutler, F. Hu, T. Hoffman, W. Volkert 8:55—339. Strategies for systemic cancer treatment with radionuclides. J. Buscombe 9:15—340. Development of electron-emitting radioisotopes for therapeutic oncology. L. Mausner 9:35—341. 64 Cu-fc/s(thiosemicarbazone) complexes as agents for diagnosis and radiotherapy. J. Lewis, J. Connett, T. Buettner, Y. Fujibayashi, M. Welch 9:50—342. Radiolabeled SSTR-binding peptides for diagnosis and therapy of lung cancer. R. Manchanda, D. Pearson, D. Wilson, B. Moyer, C. Nelson, J. Cyr, M. DeRosch, W. Jones, Y. Baran, J. ListerJames, R. Dean 10:05—343. Current status of the production of radionuclides at the National Accelerator Centre (NAC). T. N. Van Der Walt, F. M. Nortier 10:20—344. DTPA-octreotide complexes with the NCA radiolanthanides (Pm-149, Ho-166, Lu-177). C. Cutler, S. Jurisson, W. Li, C. Smith, T. Hoffman, N. Owen 10:40—345. Modification to existing radiation-measuring systems required for specialized applications for radionuclide therapy. J. Bede, M. A. Dell 11:00—346. SarAr—A new ligand for radiolabeling with ^ C u : Its potential for therapy. S. Smith-Jones, N. DiBartolo, A. Sargeson, E. Hetherington 11:15—347. Preclinical evaluation of 111 In/ 90Y labeled J591, a radiolabeled antibody for clinical detection and treatment of prostate cancer. P. Jones-Smith, V. Navarro, C. Hunter, D. Bastidas, S. Goldsmith, N. Bander, S. Vallabhajosula 11:30—348. Bifunctional actinium chelate for human a particle therapy. D. Ma, G. Kiefer, M. Mcdevitt, G. Gulyas, L. Lai, V. Pellegrini, M. Curcio, P. Borchardt, K. Mcmillan, R. Frank, J. Simon, R. Finn, D. Scheinberg, D. Ma 11:45—349. New phage display peptide to endothelium of tumor vasculature. K. Kairemo Hilton Hawaiian Village Coral Ballroom II, Mid-Pacific Conference Center Combinatorial and Parallel Synthesis: Applications to Medicinal Chemistry (218)

A. Combs, Presiding 8:05—357. Toward a chemical genetics. S. Schreiber 8:55—355. From lead generation optimization using unbiased encoded libraries and targeted parallel libraries. B. Ruhland 9:35—358. Integrating combinatorial and medicinal chemistry for the discovery of synthetic antibacterial agents. D. Patel


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10:15—351. New methods for the solidsupported synthesis of biologically active molecules: Applications to drug discovery. J. Nuss 10:55—356. Interrogation of gene families with mixtures. K. Chapman Hilton Hawaiian Village South Pacific Ballroom III, Mid-Pacific Conference Center Alzheimer's Disease: Receptors and Small Molecule Therapies (173)

D. Weaver, Presiding 8:35—565. Modified peptide inhibitors of amyloid beta peptide polymerization. M. A. Findeis 9:00—567. Design and synthesis of potent and selective pre-synaptic M2 muscarinic receptor antagonists. Y. Wang, S. Chackalamannil, Z. Hu, J. Clader, W. Greenlee, W. Billard, H. Binch III, G. Crosby, V. Ruperto, R. Duffy, J. Lachowicz, V. Coffin, K. Cox, X. Zhang 9:25—568. A practical synthesis of potent Butyrylcholinesterase Inhibitor Bisnorcymserine. X. Zhu, Q. Yu 9:50—569. Methyl and dimethyl substituted phenserine: Synthesis and structure/ activity relationship. Q. Yu 10:15—570. Melatonin, N-acetylserotonin and their derivatives protect neurons against beta-amyloid induced neurotoxicity and improve memory in animal model of Alzheimer's disease. S. O. Bachurin, G. F. Oxenkrug, N. N. Lermontova, A. Z. Afanasiev, T. V. Mukhina, B. K. Beznosko, G. I. Van'Kin, N. S. Zefirov 10:40—571. Examining the molecular structure of Alzheimer's amyloid-pfibrils. P. Fraser, D-S. Yang, J. McLaurin, C. Yip 11:05—572. Alzheimer's amyloid p-peptide (1-42)-induced oxidative stress and neurotoxicity: Role of methionine residue 35 and prevention by vitamin E. A. Butterfield

MONDAY AFTERNOON Hilton Hawaiian Village Coral Ballroom II, Mid-Pacific Conference Center Combinatorial and Parallel Synthesis: Applications to Medicinal Chemistry (218)

A. Combs, Presiding 1:05—370. Small-molecule library strategies and tactics. J. Ellman 1:55—354. Parallel synthesis and optimization of pyrazole-based inhibitors of helicobacter pylori dihydroorotate dehydrogenase. T. Haque 2:35—371. Liquid-phase combinatorial synthesis of benzofused heterocycles. C-M. Sun 3:15—372. Method development and parallel synthesis of amino-imidazole-based libraries: Efforts on lead identification in the therapeutical area for treatment of congestive heart failure (CHF). S. Liu, M. RennelIs, B. Blass, M. Li, K. Ellis, D. Portlock, R. Kawamoto 3:55—373. Applications of automated synthesis to accelerated medicinal chemistry. M. Poss, Z-W. Cai, J. Stevenson, J. Lloyd, D. Ryono, R. M. Lawrence, O. Fryszman, S. Biller, E. Petrillo, H. Weller, M. Hermsmeier, M. Russo

2:20—363. Radioiodination of anilinemustard glucuronide, as an anticancer prodrug potential for combined chemoand radiotherapy of cancer. T. Unak, Z. Akgun 2:40—364. Development of PET-labeled agents for use in cancer treatment planning. G. Kabalka, T. Nichols, D. Lonford, S. Gary, L Miller 3:00—365. DAHA: New ligand for radiolabeling with ^ C u shows potential for faster imaging times. S. Smith, M. Ramli, N. DiBartolo, L. Lindoy 3:15—366. Toxicity and dosimetry of lutetium-177-DOTA-Y3-octreotate. C. Anderson, J. Lewis, M. Wang, F. Wang, A. Srinivasan, J. Erion 3:35—367. Optimization of biotin derivative structures to carry a-emitting radionuclides in pretargeting of cancer. S. Wilbur, D. Hamlin, M-K. Chyan, B. Kegley, K. Buhler, R. Vessella, M. Brechbiel 3:55—368. Development of suitable Afunctional chelating agents for therapeutic application with oc-emitters. M. Brechbiel, E. Dadachova, K. Garmistani, K. Deal, L. Chappell, I. Davis, S. Kennel, S. Mirzadeh, D. Milenic, Z. Yao, J. Carrasquillo 4:15—369. Pain palliation of 153Sm-EDTMPVienna protocol. S. Meghdadi, S. Granegger, M. Rodrigues, C. Kratzik, H. Sinzinger Hilton Hawaiian Village South Pacific Ballroom I, Mid-Pacific Conference Center Medicinal Chemistry General (08G-01)

S. Wang, Presiding 1:05—332. New developments of the enhanced CACTVS browser of the open NCI database. M. Nicklaus, F. Oellien, W-D. Ihlenfeldt 1:25—374. TAE/RECON method in large database mining, QSAR, and ADME: A progress report on the DDASSL project. N. Sukumar, C. Breneman, K. Bennett, M. Embrechts, M. Sundling, L. Lockwood 1:45—375. Harness the power of the computer in drug design for lead discovery and optimization. S. Wang 2:05—376. Site-directed drug discovery. D. Erlanson, A. Braisted, D. Raphael, M. Randal, R. Stroud, E. Gordon, J. Wells 2:25—377. Sequence-dependent chemistry of proteins: The fourth dimension in protein-function prediction? C-M. Yang 2:45—378. Impact of furanose ring pucker on the biological activity of nucleosides and nucleotides. J. Barchi, H. Ford, L Anderson, M. Nicklaus, V. Marquez 3:05—379. Proline-hydrazide-hydrazone loop mimics. G. Noronha, K. Nguyen 3:25—380. Structure-activity relationships of a potent and selective Ca 2+ receptor antagonist that stimulates bone formation. P. Bhatnagar, A. Lago, J. Callahan, W. Huffman, J. Gleason, M. Gowen, G. Stroup, R. Dodds, B. Smith, I. James, J. Lee, E. Nemeth, J. Fox, E. Delmar 3:45—381. Studies on some chelates derived from antiulcer vitamin. J. Vora, J. Joshi, S. Sharma, R. Patel, D. Patel, D. G. Patel, M. Brahmbhatt, A. Patel 4:05—382. Silanediols as transition-state analogs, nanomolar inhibitors of metallo and aspartic proteases. S. Sieburth, C-A. Chen, A. Glekas, G. Hewitt, J. Kim, M. Wa Mutahi, T. Nittoli

Hilton Hawaiian Village South Pacific Ballroom II, Mid-Pacific Conference Center

MONDAY EVENING

Radionuclides for Therapeutic Oncology (174)


R. Reid, Presiding 1:05—359. Radioimmunotherapy of nonHodgkin's lymphoma. R. Wahl, M. Kaminski 1:25—360. Targeted delivery of radioiodinated lUdR for radiotherapy of hepatic carcinoma. L. Wiebe, J. Diakur, P. Kumar, S. Singh 1:45—361. Radioimmunotherapy by affinity enhanced tumor targeting of human colon cancer xenografts in immune-suppressed sheep. J. Webb, R. G. F Giles, A. H. Rose, J-F. Gestin, A. Loussouarn, A. Faivre, J. Barbet, J-F. Chatal, J. H. Turner 2:05—146. Therapy of neoplastic meningitis with methotrexate and 5-[125/] odo-2'deoxyuridine. A. Kassis, S. J. Adelstein

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8:25—387. Isolated limb perfusion with Sn117m-bisphosphonate for treatment of bone tumors. R. Claessens, G. Rakhorst, Z. Kolar, J. Elstrodt, H. TerVeen, D. A. Piers, J. Van Horn 8:40—388. Tumor therapy with low-energy electron-emitting radionuclides. A. Kassis, S. J. Adelstein

TUESDAY MORNING Hilton Hawaiian Village Coral Ballroom II, Mid-Pacific Conference Center Combinatorial and Parallel Synthesis: Applications to Medicinal Chemistry (218)

A. Combs, Presiding 8:05—389. Exploiting molecular recognition in drug delivery. M. Gallop 8:35—392. Design and synthesis of cysteine protease inhibitors for the treatment of osteoporosis and parasitic infections. S. Thompson, T. Tomaszek Jr., D. Tew, P. Rosenthal, J. Mckerrow, D. Veber 8:45—390. Development of diversityoriented synthesis for chemical biology. M. Shair 9:25—555. Synthesis of biologically active compounds on solid support. P. M. S. Chauhan 10:05—391. Spirocyclic ketals as novel combinatorial targets for lead discovery libraries. R. P. Trump, P. A. Bartlett 10:55—564. Development and use of new combinatorial chemistry methods for lead generation and optimization. S. W. Kaldor Hilton Hawaiian Village South Pacific Ballroom I, Mid-Pacific Conference Center Medicinal Chemistry General (08G-02)

P. Goodenough, Presiding 8:35—393. Mutagenesis disproves the "electrostatic switch" hypothesis in Ananain. G. Peter, C. Carole 8:55—394. Capillary electrophoretic determination of HIV therapy drugs in human serum. A. Zemann, W. Gutleben, H. Stoiber, M. Dierich 9:35—395. Interaction of hepatitis-A virus proteinase 3C with substrates, RNA, and inhibitors, as studied by surface plasmon resonance. H. Peters, T. Peters, Y. Kusov, S. Hengst, V. Gauss-Mueller 9:55—396. Discovery of potent, orally active and nonemetic phosphodiesterase inhibitors. D. Guay, M. Blouin, N. Chauret, Y. Ducharmes, R. Frenette, R. Friesen, P. Hamel, Z. Huang, M. Girard, Y. Girard, T. Jones, F. Laliberte, C. Li, P. Masson, M. Mcauliffe, D. Nicoll-Griffith, J. Silva, J. Yergey, R. Young 10:15—397. ABT-963: An orally active selective cyclooxygenase-2 inhibitor. L. Black, R. Athalye, A. Basha, P. Bhatia, L. Cherneskey, J. Demattei, T. Gane, A. Hakeem, R. Harris, C. Henry, P. Jacobson, J. Ji, T. Kolasa, M. Kort, D. Larson, H. Liu, S. Majest, K. Marsh, C. Mccarty, M. Nuss, M. Patel, D. Pireh, M. Pliuschev, T. Rhoades, J. Rohde, R. Sciotti, S. Surapaneni, F. Wagenaar, M. Michaelides, A. Stewart, M. Coghlan, R. Bell, C. Brooks, G. Carter 10:35—398. Crystal structure of caspasecleaved P35 V71P mutant. W. de la Cruz 10:55—399. Preparation of ammonium polylipids and evaluation of their potential in drug delivery. M. Lizarzaburu, M. Kurth, M. Nantz 11:35—400. Synthesis and biological activity of new DNA alkylating antitumor agents based on the natural product CC-1065. L. Swan, D. Young, P. Parsons

A. Singh, Presiding 7:05—383. Radioisotope therapy for metastatic bone pain: A review of experience with amarium-153-EDTMP. A. Serafini 7:25—384. Rationale and reasoning for developing radionuclides for palliation of metastatic bone pain. K. Gerbail, S. Krishnamurthy 7:45—385. Sm-153 EDTMP for bone pain palliation and marrow ablation. D. Macfarlane 8:05—386. Sn-117m chelates for radionuclide therapy of cancer in bone. S. Srivastava


ORGN AREA09-ORGANIC CHEMISTRY THURSDAY MORNING Hilton Hawaiian Village lolani Suite V/VI, Tapa Conference Center re-Electronic Systems with Novel Structure (010)

Y. Tobe, Presiding 8:05—2. Complexation of fullerenes with cyclic[6]paraphenylacetylene. T. Kawase, K. Tanaka, M. Oda 8:40—3. Modular assembly and characterization of cross-conjugated macrocycles. R. Tykwinski 9:15—4. Synthesis and crystal structures of the first stable silacyclopropabenzene and bis(silacyclopropa)benzenes. N. Tokitoh 9:50—5. n-Conjugated helices and double helices. A. Rajca, H. Wang, S. Rajca, A. Safronov 10:25—6. (M)- and (P)-[N\ triangulanes: The q-analogs of the aromatic helicenes. A. De Meijere, A. F. Khlebnikov, R. R. Kostikov, S. I. Kozhushkov, P. R. Schreiner, A. Wittkopp, W-J. Hansen, W. Hug Hilton Hawaiian Village Honolulu Suite II, Tapa Conference Center Strategy for Molecular and Supramolecular Photochemistry (012)

H. Inoue, Presiding 8:05—7. In the footsteps of Pasteur: Asymmetric induction in the photochemistry of crystalline ammonium carboxylate salts. J. R. Scheffer 8:35—8. Asymmetric [2+2] photocycloadditions of enones with alkenes, in solution. J. P. Pete 9:05—9. Solid-state organic photochemistry in two-component system. H. Koshima 9:20—10. Photochemistry of some dopamine and tryptamine derivatives. Y. Ito, Y. Shindo, D. Ichikawa 9:50—11. Zeolites as reaction media for photochemical reactions. V. Ramamurthy 10:20—12. Supramolecular asymmetric photochemistry using cyclodextrin and bovine serum albumin as chiral hosts. Y. Inoue, A. Nakamura, K. Kimura, S. Goto, T. Wada 10:50—13. Supramolecular enantiodifferentiating photosensitization in zeolite supercages modified with chiral sensitizers. T. Wada, M. Shikimi, Y. Inoue, G. Lem, N. J. Turro 11:05—14. Photochemical properties of the related compounds to aequorin bioluminescence. T. Hirano, Y. Imai, S. Nakai, Y. Iga, S. Fujio, T. Sekiguchi, K. Yasui, S. Maki, H. Niwa, M. Ohashi Hilton Hawaiian Village Honolulu Suite III, Tapa Conference Center New Synthetic Methods in Organofluorine Chemistry (020)

T. Taguchi, Presiding 8:05—15. Stereospecific preparation of new fluorinated vinyl stannane synthons and their applications in the stereospecific synthesis of fluorinated olefin and diene derivatives. D. Burton 8:35—16. Organic synthesis with fluorinecontaining palladium complex: New efficient routes to the synthesis of fluorinated allene and furan derivatives. T. Konno, M. Tanikawa, T. Ishihara, H. Yamanaka 8:55—17. Synthesis of trifluoromethylated furans and pyrans. F. L. Qing 9:15—18. Bis-trifluoromethylated meldrum S acid and its direct fluoridation products: New synthons in organofluorine chemistry. J. S. Thrasher, A. Waterfeld 9:35—19. Discerning the stereoelectronic effect in the Baeyer-Villiger reaction with the help of fluorine. C. Crudden, A. Chen, L. Calhoun

9:55—20. Progress in the synthesis of fluoroorganic compounds using HF-base molten salts. N. Yoneda 10:15—21. Novel zwitterionic iodonium salts. D. Desmarteau, V. Montanari, B. Thomas 10:35—22. Highly regioselective anodic mono- and difluorination of propargyl sulfides. H. Ishii, S. Riyadh, T. Fuchigami 10:55—23. Synthesis of fluorinated heterocycles using molecular fluorine. M. Sato, Y. Suzuki, M. Mori, H. Ono 11:15—24. Research on synthesis of organofluorine compounds using xenon difluoride. M. Tamura, H-D. Quan, R-X. Gao, A. Sekiya Hilton Hawaiian Village Tapa Ballroom II, Tapa Conference Center New Developments in Organic Radical Chemistry (029)

I. Ryu, Presiding 8:35—25. Kinetics and mechanisms of p-phosphate radical reactions. M. Newcomb 9:15—26. New radical reactions with organotellurium compounds. S. Yamago, H. Miyazoe, R. Goto, T. Sawazaki, M. Hashidume, J-l. Yoshida 9:35—27. Tetraphenyldisilane as a novel strategic radical reagent. H. Togo, O. Yamazaki, S. Matsubayashi 9:55—28. Nonoxidative pathway to alkene radical cations: Mechanism, stereochemistry, and application. D. Crich 10:35—29. Shedding new light onto the tri-nbutylstannyl radical: A kinetic and thermodynamic spectroscopic investigation of bond strengths, hydrogen transfer, and self-termination. T. Autrey, W. Shaw, J. Franz 10:55—30. Enantioselective radical reaction through discrimination of an enantiotopic sulfonyl oxygen. Y. Watanabe, N. Mase, R. Furue, T. Toru 11:15—31. Synthesis of conformationally fixed nucleosides via radical cascade reaction. C. Chatgilialoglu 11:40—32. Effect of group 14 element compound in the radical substitution reaction. Y. Yokoyama, K. Hattori, T. Sugiyama, A. Sugimori, M. Kajitani Hilton Hawaiian Village lolani Suite VII, 2nd Floor, Tapa Conference Center Phase-Transfer Catalysis (060)

T. Nishikubo, Presiding 8:05—33. Asymmetric phase-transfer catalysis utilizing the quaternary ammonium salts derived from cinchona alkaloids. T. Shioiri, S. Arai 8:35—34. New results in applications and mechanism of phase-transfer catalysis. M. Makosza 9:05—35. Phase-transfer catalysis in supercritical fluids. C. L. Liotta, C. A. Eckert, K. Griffith, A. Dillow, D. Suleiman, K. Chandler, C. Culp, J. Brown, H. Lesutis, D. Bush, B. West, D. Lamb 9:35—36. Activation of aromatic C-CI and C-H bonds by Pd catalysts in the presence of phase-transfer agents. Y. Sasson, S. Mukhopadhyay, G. Rothenberg, D. Gitis 10:05—37. Synthesis of polymers containing pendant reactive chloromethyl groups by the polyaddition of bis(epoxides) with diacyl chlorides and their chemical modification using PTC. T. Nishikubo, A. Kameyama, U. Inagaki 10:35—38. PTC in the plastics industry. D. Brunelle, E. Boden, P. Phelps 11:05—39. Phase-transfer-catalyzed (PTC) reactions of some C-H acids with di- and trichlorethylene. A. Jonczyk Hilton Hawaiian Village Tapa Ballroom III, Tapa Conference Center Discovery and Development of Asymmetric Synthesis and Chiral Technology (065)

I. Shinkai, Presiding 8:35—40. Chiral phosphine catalysts for enantioselective acylation. E. Vedejs, O. Daugulis, E. Rozners, P. Aleman, J. Mackay 9:15—41. Eu(lll)-catalyzed asymmetric aldol reactions: Unique stereocontrol and use for polyol synthesis. T. Nakai 9:55—42. New enantioselective C-C bondforming reactions: Synthetic and mechanistic studies. M. Lautens

10:35—43. Asymmetric synthesis of alkaloids using 8-amino p-ketoesters. F. A. Davis, B. Chao, T. Fang, D. Burns 10:55—44. Asymmetric alkylation of aldehydes with chiral organomagnesium amides. M. Chong, K. Yong 11:15—45. Asymmetric reissert-type reaction promoted by bifunctional catalyst. M. Shibasaki Hilton Hawaiian Village Coral Ballroom I, Mid-Pacific Conference Center Organic Reactions in Aqueous Media (123)

10:15—67. Photoinduced synthesis of alkylzinc reagents: Scope and synthetic applications. A. Beauchemin, J-F. Marcoux, A. B. Charette 10:35—68. Synthesis of fluorine compounds using reactions of ethyl bromodifluoroacetate with copper powder. K. Sato, O. Masaaki, A. Ando, I. Kumadaki 10:55—69. Synthesis of WS9885B, a potent cytotoxic agent of novel structure. C. D. Vanderwal, D. A. Vosburg, E. J. Sorensen 11:15—70. Synthetic approaches to the marine alkaloid variolin B. J. C. Morris, R. Anderson, J. Galligan, M. Vigneswaran

T. H. Chan, Presiding

THURSDAY AFTERNOON

8:05—46. Biomimetic reactions in water solution. R. Breslow 8:50—47. Diels-Alder reactions in water: Lewis acid and micellar catalysts designed on the basis of an analysis of aqueous rate aqueous accelerations. J. B. F. N. Engberts 9:30—48. Broensted-acid-catalyzed Mannich-type reaction: Activation of aldimines in aqueous media. T. Akiyama, J. Takaya, H. Kagoshima 10:10—49. Effect of aquatic environments on solvolysis and pericyclic reactions. J. J. Gajewski

Hilton Hawaiian Village lolani Suite V/VI, Tapa Conference Center

Hilton Hawaiian Village Tapa Ballroom I, Tapa Conference Center Cycloaddition and Annulation Strategies (144)

R. Danheiser, Presiding 8:35—50. Lewis acid catalyst for selective organic synthesis. H. Yamamoto 9:05—51. Cycloaddition reactions of masked o-benzoquinones and their applications to the synthesis of natural products. C-C. Liao 9:40—52. Adventures in total synthesis using tandem cycloadditions of nitroalkenes. S. E. Denmark 10:15—53. Use of furan and benzo[c]furan in organic synthesis. H. N. C. Wong 10:50—54. Ring formations in the synthesis of semiochemicals. K. Mori 11:25—55. Highly enantioselective Lewisacid-catalyzed Diels-Alder reactions. V. Rawal Hilton Hawaiian Village Honolulu Suite I, Tapa Conference Center Bioorganic Reaction Mechanisms (163)

J. Richard, Presiding 8:05—56. Mechanistic adaptations to environment by dehydrogenases. R. L. Schowen 8:40—57. Mutagenesis of dienelactone hydrolase gives dienelactone isomerase. C. Easton, I. Walker, D. Ollis 9:10—58. Metal-ion-promoted methanolysis of some selected amide and phosphate ester substrates. S. Brown, A. Neverov, P. Montoya-Pelaez 9:45—59. Design of artificial molecules for switching protein/peptide activity. I. Hamachi 10:20—60. Symmetry of hydrogen bonds in solution. C. L. Perrin 10:55—61. Predicting the rates of organic reactions with no adjustable parameters. J. P. Guthrie Hilton Hawaiian Village South Pacific III, Mid-Pacific Conference Center Organic Chemistry General Session (09G-01)

J. Morris, Presiding 8:35—62. Polymeric light-emitting materials based on the control of conjugated/ nonconjugated main chain. J. Shen, R. Zhang 8:55—63. Palladium-catalyzed enantioselective alkylative ring opening. S. Hiebert, M. Lautens, J-L. Renaud 9:15—64. Aldol reactions in water and under solvent-free condition. L-C. Feng, T-P. Loh 9:35—65. Bis(isobenzofurans): Reactive linkers. P. Dibble 9:55—66. Synthesis of fluorovinylzinc reagents and their reaction with aryl iodides. A. Ando, K. Sato, M. Omote, I. Kumadaki

7t-Electronic Systems with Novel Structure (010)

Y. Tobe, Presiding 1:05—71. Highly unsaturated aromatic compounds on the way to fullerenes and their endohedral metal complexes. Y. Rubin 1:40—72. Macropolycyclic polyynes: Precursors to fullerenes. Y. Tobe 2:15—73. Rainbow switches: Multistate, multicolored photoswitches. R. H. Mitchell, T. Ward, Y. Wang, M. Sheepwash, C. Bohne 2:50—74. [1.1]Paracyclophane: Kinetic stabilization, structure, and property. T. Tsuji 3:25—75. New approaches to cubane. P. E. Eaton Hilton Hawaiian Village Honolulu II, Tapa Conference Center Strategy for Molecular and Supramolecular Photochemistry (012)

I. Ryu, Presiding 1:05—76. From molecular photochemistry to supramolecular photochemistry. N. Turro 1:35—77. Chemistry of meso-meso-coupled porphyrin arrays. A. Osuka 2:05—78. Building photoactive arrays. A. Harriman 2:35—79. Complexation dynamics of guests to cyclodextrin complexes containing two host molecules. C. Bohne, A. S. M. Dyck 3:05—80. Photoinduced charge-separation in retinyl-fullerene dyad. M. Yamazaki, M. Fujitsuka, O. Ito 3:20—81. Porphyrin-based light-harvesting arrays. J. Lindsey, D. Bocian, D. Holten, J. Li, L. Yu, A. Ambroise, J. Seth, J. Diers, S-l. Yang 3:50—82. Unusual photoisomerization behavior of stilbazole covalently bound to porphyrin. H. Sugimoto, K. Kuramoto, S. Inoue 4:05—83. Medium-controlled selectivity in organic photochemical reactions. C-H. Tung Hilton Hawaiian Village lolani Suite VII, 2nd Floor, Tapa Conference Center Phase-Transfer Catalysis (060)

T. Nishikubo, Presiding 1:05—101. Phase-transfer catalysis applications to organic industrial synthesis. D. Landini, D. Albanese, V. Lupi, A. Maia, M. Penso 1:35—102. Unnatural amino acid and peptide synthesis by PTC. M. J. O'Donnell, W. L. Scott 2:05—103. Epoxidation of 5-vinyl-2norbomene under phase-transfer catalysis conditions. M-L. Wang, T-H. Huang 2:35—104. Production of benzaldehyde: A case study in a possible industrial application of phase-transfer catalysis. L. K. Doraiswamy, J. Satrio 3:05—105. Recent advances on polymeric phase-transfer catalysts. M. Tomoi 3:35—106. Role of the solid surface and its influence on kinetics in solid-liquid phasetransfer catalysis: The study of nucleophilic substitution with solid halides. S. Yufit, S. Zinovyev 4:05—107. Alkane activation under phasetransfer catalysis. P. R. Schreiner, O. Lauenstein, A. A. Fokin

Hilton Hawaiian Village Tapa Ballroom III, Tapa Conference Center Discovery and Development of Asymmetric Synthesis and Chiral Technology (065)

I. Shinkai, Presiding 1:05—108. Catalytic asymmetric alkylation of imines catalyzed by copper-chiral phosphine complex. K. Tomioka 1:45—109. Boron-mediated asymmetric double aldol reaction. A. Abiko, M. Satoru 2:05—110. Trifluoroborate salts: Reagents for stereoselective C-C bond-forming reactions. R. Batey, A. Thadani, T. Quach, D. Smil 2:25—111. Diversity strategies for reaction development. M. Snapper 3:05—112. Enantioselective enolborination. D. Ward 3:25—113. Asymmetric reactions catalyzed by BINAP-silver(l) complexes. A. Yanagisawa 3:45—114. New strategies for the construction of chiral carbon centers from allylic alcohols. C. Spino, C. Beaulieu, J. Lafreniere, C. Godbout, M-C. Granger Hilton Hawaiian Village Coral Ballroom I, Mid-Pacific Conference Center Organic Reactions in Aqueous Media (123)

T. H. Chan, Presiding 1:05—115. C-C bond formation in water: Toward a new carbohydrate chemistry. A. Lubineau, Y. Canac 1:45—116. Chemo- and stereoselective protection of 1,2-diols and polyols catalyzed by organotin compound under aqueous conditions. Y. Matsumura 2:25—117. Synergy of metal, water, and C-C bonds. C. J. Li 3:05—118. New reactions of organoboronic acids. N. A. Petasis 3:45—119. Synthesis of new water-soluble phosphines and their application in aqueous-phase catalysis. B. E. Hanson, H. Gulyas, J. Bakos, A. Riisager, H. Klein, M. Beller 10:50—120. Lewis acid catalysis in aqueous media. S. Kobayashi Hilton Hawaiian Village Tapa Ballroom I, Tapa Conference Center Cycloaddition and Annulation Strategies (144)

R. Danheiser, Presiding 1:05—121. Ene cyclization classification and discovery. M. Koichi, O. Hirotumi, T. Masahiro 1:40—122. Tertiary phosphine catalyzed [3+2] cycloaddition reactions of allenoates or 2-alkynoates with electron-deficient alkenes or imines: A new three-carbon synthon from allenoates or 2-alkynoates. X. Lu, C. Chang, Z. Xu 2:15—123. Recent developments in natural product synthesis. P. A. Grieco 2:50—124. [3+2] and [5+2] Cycloaddition reactions using carbocation species. K. Tanino 3:25—125. Toward the ideal synthesis: The design and development of new transitionmetal-catalyzed cycloadditions. P. Wender Hilton Hawaiian Village Honolulu III, Tapa Conference Center New Synthetic Methods in Organofluorine Chemistry (020)

T. Taguchi, Presiding 1:05—84. New synthetic methods for fluorinated amino acids. K. Uneyama, H. Amii, H. Abe, S. Mae, J. Hao, H. Okura 1:35—85. Versatile trifluoromethylation and difluorocyclopropanation reagents derived from fluorosulfonyldifluoracetate esters. W. Dolbier Jr., J-X. Duan, Q-Y. Chen 2:05—86. Novel syntheitc methods for CF3substituted target molecules. T. Hiyama, Y. S. Kyoto 2:25—87. Stereoselective construction of CF3-containing quaternary carbon centers using glucose-based substrates. T. Yamazaki, S. Hiraoka, T. Kitazume 2:45—88. New aromatic fluorine compounds as ligands in asymmetric catalysis. A. K. Yudin


127

ORGN/TECHNICAL PROGRAM

3:15—89. Synthesis of novel axially dissymmetric ligands and their application to asymmetric reactions. M. Omote, T. Hasegawa, K. Sato, A. Ando, I. Kumadak 3:35—90. Catalytic asymmetric synthesis of a-trifluoromethyl alcohols and a.ccdifluoro-p-hydroxycarboxylates. K. Iseki 3:55—91. Asymmetric catalytic FriedelCrafts reactions with fluoroal. M. Koichi, A. Ishii 4:15—92. Reactions of 2-alkoxy-2,3,3,3tetrafluoropropanoic acid derivatives with nucleophiles. T. Kubota, H. Yoshida, N. Kanazawa, S-G. Nakaoka, M. Igari Hilton Hawaiian Village Honolulu Suite I, Tapa Conference Center Bioorganic Reaction Mechanisms (163)

J. Richard, Presiding 1:05—126. Asymmetric oxidation catalyzed by myoglobin mutants. Y. Watanabe 1:45—127. Transition-state stabilization in glycosidases and transglycosylases: Insights from substrate analogs, inhibitors, and mutants. S. Withers 2:25—128. Structure and mechanism of asparagine synthetase: Evolution of a complex enzyme. N. Richards, H. Holden, J. Thoden, S. Boehlein, T. Larsen, S. Schuster, I. Rayment 3:00—129. Method for the quantitative analysis of functional chimeras. J. F. Kirsch, T. Luong 3:35—130. Membrane transport of carbohydrates. P. Duggan 4:10—131. Mechanistic studies of y-glutamyl transpeptidase. J. Keillor, A. Menard, R. Castonguay, C. Lherbet Hilton Hawaiian Village Tapa II, Tapa Conference Center New Developments in Organic Radical Chemistry (029)

C. Easton, Presiding 1:05—93. Some biologically relevant radical reactions. K. U. Ingold, T. Paul 1:45—94. Radical rearrangements promoted by surface immobilization. A. C. Buchanan III, P. F. Britt 2:05—95. Estimating the activation energy for (3-scission reactions of hydrocarbon radicals by a combination of semiempirical calculation and family correlation. X. Ma, H. H. Schobert 2:25—96. Radical addition of tri-2furanylgermane to alkenes. K. Oshima 3:05—97. Intramolecular aromatic 1,5hydrogen transfer in the free radical reactions of aryl ethers, thioethers, sulfoxides, and sulfones. S. Karady, J. M. Cummins, P. Dorman, U. H. Dolling, B. Marcune, P. J. Reider 3:25—98. Density functional theory study of the competition between intramolecular aromatic 1,5-hydrogen transfer and ring closure free-radical reactions of aryl ethers, thioethers, sulfoxides, and sulfones. T. Brill, D. Miksa, N. Gunawardena 3:45—99. Sulfur-mediated free-radical reactions. M. Bachi, Y. Bilokin, E. Korshin 4:10—100. Extremely convenient cyclization of medium rings using Sml2. F. Matsuda

FRIDAY MORNING Hilton Hawaiian Village lolani Suite V/VI, Tapa Conference Center it-Electronic Systems with Novel Structure (010)

Y. Tobe, Presiding 8:05—132. Toward artificial molecular machinery. J. Perkins, J. F. Stoddart 8:40—133. Chemistry on a string: Or was that a tightrope? R. N. Warrener, M. Shang, M. R. Johnston, D. N. Butler 9:15—134. Molecular paneling via coordination. M. Fujita 9:50—135. Self-assembly of nanoscopic polyhedra and related 3-D species via the coordination paradigm. P. J. Stang 10:25—136. Organofullerene as artificial vector for gene transfer. E. Nakamura

128


Hilton Hawaiian Village Honolulu Suite II, Tapa Conference Center

11:40—161. Radical additions to C=0 and C=N bonds. S. Kim

Strategy for Molecular and Supramolecular Photochemistry (012)

Hilton Hawaiian Village lolani Suite VII, Tapa Conference Center

H. Inoue,

Presiding

8:05—137. Revisiting hula-twist: Is it a general mechanism for photoisomerization? Does it violate the NEER hypothesis? R. S. H. Liu, G. S. Hammond 8:35—138. Template photochemistry of retinals. K. Tsujimoto, Y. Yoshimura, T. Mizukami 8:50—139. Photoinduced electron-transfer MCP rearrangement: Stereochemistry and evidences for two types of intermediates. T. Miyashi, H. Ikeda 9:20—140. Photochemistry of conjugated polyalkynes with some olefins. S. C. Shim, B. D. Kim 9:50—141. Possible o(C-N) - 7i(Ph) orbital interactions in the cation-radical deazetation of 1-phenyl-2,3-diazabicyclo [2.2.2]oct-2-ene. H. Ikeda, T. Minegishi, M. Sato, T. Miyashi 10:05—142. Light harvest by retarding reverse flow of charge-balancing cations. K. B. Yoon, Y. S. Park, E. J. Lee, Y. S. Chun 10:35—143. Effect of alkali-metal ion on photoisomerization of stilbene and azobenzene in zeolite. M. Kojima, T. Takagi 10:50—144. Enhancement of one-electron oxidation of guanine by base-pairing with cytosine. T. Majima, K. Kawai, N. Ichinose Hilton Hawaiian Village Honolulu Suite III, Tapa Conference Center New Synthetic Methods in Organofluorine Chemistry (020)

T. Taguchi, Presiding 8:05—145. Driving the self-assembly of perfluorocarbon and hydrocarbon units. G. Resnati, M. T. Messina, P. Metrangolo 8:25—146. Dihaloperfluoroarene involvement in a 2-D supramolecular network. P. Metrangolo, M. T. Messina, G. Resnati, M. Parisi, T. Pilati, S. Pappalardo 8:45—147. Heterocycles galore. R. D. Chambers, P. Hoskins, G. Sandford 9:05—148. CFPA and CFTA: New fluorinecontaining chiral-derivatizing agents for determinations of both enantiomeric excess and absolute configuration of chiral molecules. Y. Takeuchi 9:35—149. Synthesis and characterization of fluorinated dihydrodipicolinate synthase inhibitors. J. T. Welch, I. H. Jeong, W. Chung 10:05—150. Asymmetric synthesis and biological properties of both enantiomers of various types of point-difluorinatedeldanolide. T. Itoh, K. Kazutoshi, T. Naoko, T. Fumie, P. Zagatti, M. Renou 10:25—151. 1,1 ,2,2-Tetrafluoroethyl-/V,/Vdimethylamine: A new selective fluorinating agent for polyfluoroalcohols. V. Petrov 10:45—152. Processes for manufacture of fluorinated propanes and propenes. M. Rao, A. Sievert, M. Nappa, W. Manogue 11:05—153. Synthetic method for fluorinated carbocycles from gem-difluoroalkenyl active methines. T. Taguchi, A. Saito, M. Okada Hilton Hawaiian Village Tapa Ballroom II, Tapa Conference Center New Developments in Organic Radical Chemistry (029)

I. Ryu, Presiding 8:35—154. Addition fragmentation chemistry for controlling free-radical polymerization. E. Rizzardo, J. Chiefari, R. Mayadunne, G. Moad, S. Thang 9:15—155. Highly selective thioselenation of isocyanides using a disulfide-diselenide binary system. A. Ogawa, Y. Tsuboi 9:35—156. Asymmetric radical addition to chiral /V-acylhydrazones. G. K. Friestad, J. Qin 9:55—157. Generation of radical species by one-electron transfer: Application to the construction of molecular skeletons. K. Narasaka 10:35—158. Radical cyclization of 1-(2fbromobenzyl) isoquinolines and related compounds. K. Orito, S. Uchiito, T. Tatsuzawa, Y. Satoh, H. Nishizawa, M. Tokuda 10:55—159. New asymmetric radical processes. M. Malacria 11:20—160. Hydrocarbon a-radical cations in the gas phase and solution. A. Forkin, P. Schreiner

Phase-Transfer Catalysis (060)

T. Nishikubo, Presiding 8:05—162. Mechanisms of s/l and l/l PTC in base-containing systems. F. Sirovski 8:35—163. Achieving effective separation of phase-transfer catalysts from products and minimizing aqueous waste. R. Grinstein, M. Halpern 9:05—164. Hydrogen peroxide oxidation of various organic compounds catalyzed by heteropolyoxometalates having phasetransfer function. Y. Ishii 9:35—165. Selectivity and kinetics of the catalytic multiphase hydrodehalogenation of halo-aromatics. P. Tundo, A. Perosa, S. Zinovyev 10:05—166. Design of a C2-symmetric chiral phase-transfer catalyst for practical cc-amino acid synthesis. K. Maruoka 10:35—167. Chain-growth polycondensation in solid-liquid phase with phase-transfer catalysts. T. Yokozawa 11:05—168. Phase-transfer alkylation of 2-arylalkanenitriles revisited. M. Fedorynski Hilton Hawaiian Village Tapa Ballroom III, Tapa Conference Center Discovery and Development of Asymmetric Synthesis and Chiral Technology (065)

I. Shinkai, Presiding 8:35—169. Crafting chiral space for molecular recognition in a catalytic synthetic reaction. B. M. Trost 9:15—170. Asymmetric catalysis of secondgeneration metallosalen complexes. T. Katsuki 10:35—171. Applications of carbenoidderived enols in synthesis. J. L. Wood, G. A. Moniz 10:55—172. Asymmetric synthesis using high-symmetry catalysts. H. M. Davies 11:15—173. Rhodium-catalyzed asymmetric carbon-carbon bond-forming reactions. T. Hayashi Hilton Hawaiian Village Coral Ballroom I, Mid-Pacific Conference Center Organic Reactions in Aqueous Media (123)

T. H. Chan, Presiding 8:05—174. Synthesis of complex molecules using organic reactions in aqueous media. T-P. Loh 8:40—175. Palladium-catalyzed organic reactions in water by use of PEG-PS resinsupported palladium-phosphine complexes. Y. Uozumi 9:10—176. Tropical chemistry and organometallic reactions. L. W. Bieber 9:55—177. Exploring the conformational properties of chiral, amphiphilic dendrimers in water. J. R. Parquette, M. J. Laufersweiler, S. Broxer, N. Paul, J. G. Weintraub Hilton Hawaiian Village Tapa Ballroom I, Tapa Conference Center Cycloaddition and Annulation Strategies (144)

R. Danheiser, Presiding 8:35—178. Total synthesis of natural products using cycloaddition and annulation. K. Tatsuta 9:05—179. Heterocyclic azadiene DielsAlder reactions: Scope and applications. D. L. Boger 9:40—180. Atropselective cyclization strategy for ansamacrolide enediynes synthesis. M. Hirama 1 0 : 1 5 — 1 8 1 . Cyclopentannelations of allenes. M. Titus 10:50—182. Annulation and intramolecular cycloaddition routes to members of the lamellarin class of marine natural products. M. G. Banwell, B. L. Flynn, R. W. Longmore 11:25—183. Complete stereochemical structure and asymmetric total synthesis of globomycin. H. Kogen

Hilton Hawaiian Village Honolulu Suite I, Tapa Conference Center Bioorganic Reaction Mechanisms (163)

J. Richard, Presiding 8:05—184. Is the 5'-deoxyadenosyl radical a discrete intermediate in enzymatic reactions? P. Frey, O. Magnusson 8:45—185. Molecular-imprinted cyclodextrins as tailor-made receptors for nanometer-scaled guests. M. Komiyama, T. Hishiya, H. Asanuma 9:20—186. Dual function proteins: How do copper amine oxidases make their own cofactor? J. Klinman 9:55—187. Temperature effects on the rate enhancement and transition-state affinity of cytidine deaminase, and the contribution of a substrate "anchor" to catalysis. R. V. Wolfenden, M. J. Snider 10:30—188. Least atomic motion in enzymatic catalysis: Nucleophilic displacement by electrophilic attack in A/-ribosyltransferases. V. L. Schramm, A. Federov, G. Kicska, W. Shi, P. C. Tyler, R. H. Furneaux, S. C. Almo 11:10—189. Mechanism of decarboxylation of orotic acid analogs. W. Wu Hilton Hawaiian Village Coral Ballroom III, Mid-Pacific Conference Center New Strategies to TransitionMetal-Catalyzed or Mediated Organic Synthesis (024) Poster Session 9:00-11:00 272. Immobilization of Grubbs ruthenium carbene complex on soluble polymer: A robust and reusable catalyst for ring-closing olefin metathesis. Q. Yao 273. Metal-catalyzed functionalization of methane. Y. Fujiwara, M. Asadullah, T. Kitamura 274. Sml2-induced ring expansion reactions of activated cyclopropyl ketone. P. Lee 275. Diastereoselective reduction and C-C bond formation of homochiral. H. Matuszawa, S. Fukuzawa, M. Miura 276. Aziridine synthesis from aldehydes, amines, and diazoacetates through the activation of imines catalyzed by iridium complex. S. Sakaguchi, T. Kubo, Y. Ishii 277. Stereoselective construction of contiguous stereogenic centers by using I m migration of an (diene)Fe(CO)3 group. T. Yoshiji, I. Kiyonori, H. Asani, O. Kazuya, I. Toshiro, T. Tetsuaki 278. Catalytic asymmetric allylation of prochiral nucleophiles catalyzed by BINAP-palladium complex. R. Kuwano, R. Nishio, Y. Ito 279. Unusual coupling pattern in the palladium-catalyzed cross-coupling reactions of [(2-pyridyldimethylsilyl)methyl]lithium with aryl halides. T. Kamei, K. Itami, J-l. Yoshida 280. Selective organometallic reactions using removable intramolecular ligand. T. Koike, K. Itami, J-l. Yoshida 281. Catalytic carbonylative alkyne-alkyne coupling reaction using iridium complex. K. Yamashita, T. Shibata, K. Takagi 283. Kinetic study of the ruthenium-catalyzed reaction of aromatic ketones with olefins. F. Kakiuchi, A. Suntivisut, N. Chatani, S. Murai 284. Formation of functionalized aryl acids and esters via activated copper reagents. G. W. Ebert, W. L. Juda, B. Ma, R. Kosakowski, L. Dong, K. Cummings, M. Phelps, A. Mostafa 285. Effective Wacker-type catalyst. T. Hosokawa, K. Koga, K. Minami 286. Cofactor approach to metallocatalytic antibodies. K. M. Nicholas, P. Wentworth, Jr, K. Janda 287. Nickel(0)-catalyzed bisrnetallative carbocyclization of (o-formyl-1,3-dienes. Y. Sato, N. Saito, M. Mori 288. Cyclization of 4-pentyn-1-ols mediated by a manganese(ll) salt. R. Sakuragi, M. Hojo, A. Hosomi, 289. Pd/C-amine: A novel catalytic system for the hydrodechlorination of aromatic chlorides. H. Sajiki, A. Kume, K. Hattori, H. Nagase, K. Hirota 290. Ruthenium-catalyzed intramolecular hydroamination of aminoalkynes. T. Okada, T. Suzuki, T. Kondo, T-A. Mitsudo

291. Mechanism of the ruthenium-catalyzed reaction of aromatic esters with olefins on the basis of 13C kinetic isotope effects. H. Ohtaki, F. Kakiuchi, N. Chatani, S. Murai 292. Synthesis and characterization of monoand dipalladium complexes containing pentadiynyl ligand. K. Tsutsumi, T. Ide, Y. Nakagai, T. Morimato, K. Kakiuchi 293. Palladium-catalyzed coupling of trimethylsilyl- or terminal alkynes by the activation of silver(l) oxide. A. Mori, M. Suguro, J. Kawashima, T. Shimada, K. Hirabayashi, Y. Nishihara 294. Transition-metal-catalyzed allylation of alkenes. T. Sato, S. Sugawara, N. Tsukada, Y. Inoue 295. Development of novel synthetic reaction using cationic cobaltadithiolene complex. S. Suzuki, Y. Yokoyama, T. Sugiyama, M. Kajitani 296. Benzannulation from alkynes and allyl tosylates via a rc-allylpalladium intermediate. N. Tsukada, S. Sugawara, Y. Inoue 297. Computation on the reaction mechanism of "radical-controlled" oxidative coupling. M. Kubota, H. Higashimura, A. Shiga, S. Namekawa, K. Fujisawa, Y. MoroOka, H. Uyama, S. Kobayashi 298. Palladium-catalyzed benzannulation of conjugated enynes substituted with electron withdrawing groups. T. Nogami, N. Tsuboya, T. Fukushi, Y. Yamada, Y. Chounan, S. Saito, Y. Yamamoto 299. Tandem cyclizations of Fischer aminocarbene complexes and polyalkynes. A. G. Meyer, B. L. Flynn 300. Intramolecular cyclization of vinyl sulfide and acetylene with Ti(ll) alkoxide: Its extension to a novel asymmetric cyclization. M. Narita, H. Urabe, F. Sato 301. Highly regio- and diastereoselective addition of olefinic and acetylenic estertitanium alkoxide complex to aldehydes. D. Suzuki, H. Urabe, F. Sato 302. Withdrawn. 304. Rhodium-catalyzed direct ortho arylation of 2-phenylpyridines with arylstannanes via c-h activation. S. Fukita, S. Oi, Y. Inoue 305. Realization of high coupling efficiency in the rapid Stille methylation for the synthesis of 11C-labled tolylisocarbacyclins toward the in vivo investigation of a IP2 receptor in a human brain. H. Doi, M. Suzuki, M. Bjorkman, B. Langstrom, Y. Watanabe, R. Noyori 306. Reductive dimerization reaction of imines with lanthanum metal. T. Nishino, Y. Nishiyama, N. Sonoda 307. Reduction of alkyl halides with lanthanum metal. T. Watanabe, T. Nishino, Y. Nishiyama, N. Sonoda 308. Syntheses, structures, and reactivities of novel low-valent ruthenium complexes based on Ru(1-6-ri-cyclooctatriene)(dimethyl fumarate)2. M. Shiotsuki, T. Suzuki, K. Wada, T. Kondo, T-A. Mitsudo 309. Reaction of Odihalogen substituted arene with diene in the presence of lanthanum metal. H. Kawabata, T. Nishino, Y. Nishiyama, N. Sonoda 310. Effect of the ligands on the addition reaction of B-Sn bonds across alkynes. S-Y. Onozawa, Y. Hatanaka, T. Fudakawa, M. Tanaka 311. Direct and selective reduction of alcohols to alkanes using a chlorodiphenylsilane-indium trichloride system. M. Yasuda, Y. Onishi, A. Baba 312. Diastereoselectivity in Rh- and Cocatalyzed hydroformylation of 4-f-butylmethylenecyclohexane. Y. Kawanami, K. Yamamoto 313. Chemo- and regioselective cyclotrimerization of enones and alkynes by a nickel and aluminum catalytic system. N. Mori, S-l. Ikeda 314. Palladium-catalyzed silylation of a, (J-unsaturated carbonyl compounds with HBF4 and (PhMe2Si)2. Y. Higuchi, S. Ogoshi, H. Kurosawa 315. Phosphinophenolate ligand for the palladium-catalyzed silylation or aryl halides. T. Kurahashi, E. Shirakawa, T. Hiyama 316. Syntheses of novel dithiolene complexes having polymerization activities. T. Osada, Y. Yokoyama, T. Sugiyama, H. Hiraike, M. Kajitani 317. Reaction of conjugate olefins with nitrogen monoxide catalyzed by salen complex. Y. H. Sohgawa, Y. Furusho, N. Kihara, T. Takata

318. Transition-metal-catalyzed reactions, including the insertion of unsaturated molecule into M-S (M=Pd, Pt) bonds. H. Kuniyasu, H. Kurosawa, N. Kambe 319. Cobalt complex-promoted reductive reaction by use of samarium diiodide. K. Ishida, Y. Yokoyama, J. Inanaga, M. Kajitani 320. Highly efficient synthesis of indoles from anilines and propargyl alcohols via ruthenium catalyzed intermolecular hydroamination. M. Tokunaga, M. Ota, M. A. Haga, Y. Wakatsuki 321. Synthesis of neutral rc-allylpalladium complexes having bisnitrogen ligands and palladium-catalyzed cyclopropanation of ketene silyl acetals with allylic acetates. A. Satake, H. Koshino, T. Nakata 322. Palladium-catalyzed reaction of a, p-unsaturated carbonyl compound with alkyl aluminum and alkyl zinc. M. Morita, T. Yoshida, S. Ogoshi, H. Kurosawa 323. Iridium hydride complex catalyzed addition of pronucleophiles to carbon-nitrogen triple bonds of nitriles. H. Takaya, S-l. Murahashi 324. Synthesis and interconversion of C- and N-bound isomers of cc-cyanocarbanion complexes of ruthenium. A. Tanna, T. Naota, S-l. Murahashi Hilton Hawaiian Village Coral Ballroom III, Mid-Pacific Conference Center New Strategies to TransitionMetal-Catalyzed or Mediated Organic Synthesis (024) Poster Session 9:00-11:00 325. Asymmetric synthesis of allenecarboxylates by palladium-catalyzed carbomylation of propargyl phosphates. Y. Imada, A. Kitamura, D. Fukushima, T. Teraoka, S-l. Murahanshi 326. Ni-catalyzed coupling reaction of conjugated dienes, carbonyl compounds, and organozinc. K. Shibata, M. Kimura, Y. Tamaru 327. Ni-catalyzed regio- and stereoselective homoallylation of carbonyl compounds with conjugated dienes by triethylborane. A. Ezoe, M. Kimura, Y. Tamaru 328. Asymmetric Michael addition of a a-cyanocarboncylates with (3-unsaturated carbonyl compounds catalyzed by bis(oxazolinyl)phenyl-derived chiral rhodium(l) complexes. Y. Motoyama, K. Kobayashi, H. Nishiyama 329. Vapor-phase asymmetric hydroformylation of olefins catalyzed by a polymer supported (R.S)-BINAPHOS-Rh complex. F. Shibahara, K. Nozaki, T. Hiyama 330. Development of a new Lewis acidpromoted tandem-acyl-Claisen rearrangement. V. Dong, D. Macmillan, T. Yoon 331. Zirconocene catalyzed silylation of olefins with chlorosilanes. N. Kambe, J. Terao, K. Hitoshi 332. Progress toward a concise asymmetric synthesis of Pacifigorgiol using a transition-metal-catalyzed intramolecular [4 + 2] cycloaddition. T. E. Smith, K. Belecki, C. A. Stickney, S. A. Snyder, M. Djang 333. Ligand design for asymmetric catalysis using 1,10-phenanthroline. E. Schoffers 334. Syn stereochemistry in Wacker-type cyclization catalyzed by a dicationic palladium(ll) complex. K. Yamasaki, M. Mimura, Y. Uozumi, T. Hayashi 335. New reaction for installation of aryl and alkenyl group onto cyclopentene-ring and its synthetic application. Y. Kobayashi 336. Ru(ll)-1 and Pt(ll)-catalyzed cycloisomerization of co-aryl-l-alkynes. H. Inoue, N. Chatani, T. Ikeda, S. Murai 337. Ruthenium-catalyzed silylation of 2-aryloxazolines with hydrosilanes. K. Igi, F. Kakiuchi, M. Matsumoto, N. Chatani, S. Murai 338. Novel silylation reaction of heteroaromatics with vinylsilanes using Ru3(CO)12 as the catalyst. M. Matsumoto, F. Kakiuchi, N. Chatani, S. Murai 339. Rhodium-catalyzed silyl-imination of alkynes. H. Motoyuki, Y. Fukumoto, N. Chatani, S. Murai 340. Palladium-catalyzed diastereoselective and enantiotopic cycloisomerization of 1,6enynes. K. Hiroi, A. Jiro, M. Toshinori, A. Ikuko

341. Activation of C-H bonds of imines by ruthenium complexes. D. Hirasawa, D. Masui, M. Yamaguchi, T. Yamagishi 342. Oxidative carbonylation of phenol to diphenyl carbonate using precisely designed Pd catalyst system tethered on support. H. Ishii, M. Goyal, M. Ueda, K. Takeuchi, M. Asai 343. Novel carbon-carbon bond formation promoted by titanium tetraiodide. R. Hayakawa, S. Makoto 344. Novel preparation of Mannich-type bases by using zinc triflate and water. K. Ishimaru, T. Kojima 345. Palladium catalysis in stereoselective carbohydrate synthesis. M. Hayashi, H. Kawabata, K. Yamada

FRIDAY AFTERNOON Hilton Hawaiian Village lolani Suite V/VI, Tapa Conference Center 7i-Electronic Systems with Novel Structure (010)

Y. Tobe, Presiding 1:05—190. Dilithiosilane, dilithiogermane, and cyclobutadiene dianion. A. Sekiguchi 1:40—191. Constructing a computer from molecular components. J. Tour 2:15—192. Stable cyclic and acyclic persilylated disilenes as novel silicon. M. Kira, T. Iwamoto, T. Makoto, C. Kabuto 2:50—193. Bulk and local magnetic properties of charged fullerenes. M. Rabinovitz, T. Sternfeld 3:25—194. Annulating geodesic polyarenes for the new millennium. L. T. Scott, D. V. Preda, R. B. Ansems, H. Reisch, H. Wegner, J. Amara Hilton Hawaiian Village Honolulu Suite II, Tapa Conference Center Strategy for Molecular and Supramolecular Photochemistry (012)

H. Inoue, Presiding 1:05—195. Interfacial photochemistry: Toward artificial photosynthesis. A. Fujishima 1:35—196. Two-electron sensitization: A new concept for silver halide photography. I. Gould, S. Farid, A. Muenter, J. Lenhard, S. Godleski 2:05—197. Photochromism of dithienylethene oligomers: Highly efficient photocoloration systems. M. Irie 2:35—198. Luminescent building blocks for metal-based materials and chemosensing. V. W-W. Yam 3:05—199. Photoelectrochemical processes in pyridinium-conjugated assemblies. T. lyoda, M. M. Matsushita, J. Abe 3:35—200. Excited state dynamics of selfassembled wire-type dendrimers by confocal and near-field fluorescence microspectroscopy. H. Masuhara, S. Masuo, H. Yoshikawa, T. Asahi, T. Sato, D-L. Jiang, T. Aida 4:05—201. Environmentally controlled fluorescence behavior of cyanobiphenyl mesogen in polymer-dispersed liquid-crystal films. C. Pac, S. Kato Hilton Hawaiian Village Tapa Ballroom II, Tapa Conference Center New Strategies to TransitionMetal-Catalyzed or Mediated Organic Synthesis (024)

H. Kurosawa, Presiding 1:05—218. There goes the neighborhood: The pharmaceutical industry has discovered the value of transition metals. P. Reider 1:25—219. Metal-catalyzed ring-forming and ring-cleaving reactions. M. Lautens 2:25—220. Development of asymmetric catalytic reactions with arrayed catalyst evaluation. J. P. Morken 2:45—221. New approaches to transitionmetal-mediated asymmetric catalysis. M. Reetz


3:05—222. Homogeneous catalysis with metallodendrimers and metallostars in organic synthesis. G. Van Koten Hilton Hawaiian Village Honolulu Suite III, Tapa Conference Center Organic and Combinatorial Chemistry on Solid Supports (052)

T. Takahashi, Presiding 1:05—223. Novel immobilized palladiumphosphine complexes for asymmetric catalysis in water: Identified and optimized from parallel synthetic libraries. Y. Uozumi 1:30—224. Synthetic transformations and resin-to-resin transfer reactions of solidsupported arylboronic acids. M. Gravel, C. Berube, J. Tailor, D. Hall 1:55—225. Metalation chemistry in solidphase synthesis. Y. Kondo 2:20—226. Microwave-enhanced solidphase organic synthesis: Does it work? C. Kappe, A. Stadler, G. Strohmeier 2:45—227. Multiple parallel solid-phase organic synthesis on grafted surfaces. A. Bray 3:10—1844. Peptide mimics of neutralizing sites on HIV-1 envelope. M. B. Zwick, A. Menendez, N. Van Houten, P. W. H. I. Parren, D. R. Burton, J. K. Scott Hilton Hawaiian Village Tapa Ballroom III, Tapa Conference Center Discovery and Development of Asymmetric Synthesis and Chiral Technology (065)

I. Shinkai, Presiding 1:05—228. New vistas in asymmetric catalysis with chiral Lewis bases. S. Denmark 1:45—229. Enantioselective transformations of cc-diazo carbonyl compounds catalyzed by dirhodium(ll) carboxylates incorporating /V-phthaloyl amino acids as chiral bridging ligands. S. Hashimoto 2:25—230. Asymmetric catalysis with "planar-chiral" heterocycles. G. Fu 3:05—231. New generation of asymmetric catalysts derived from polyfluorobinaphthol ligands. A. Yudin 3:25—232. Asymmetric hydroformylation of olefins with (f?,S)-binaphos-Rh and its derivatives. K. Nozaki, T. Hiyama 3:45—233. Chiral, bidentate Ti(IV) Lewis acids for catalytic asymmetric synthesis. K. Maruoka Hilton Hawaiian Village lolani Suite VII, 2nd Floor, Tapa Conference Center Molecular Oxygen and Organic Peroxides in Chemistry and Biology (122)

E. Clennan, Presiding 1:05—234. Recent advances in peroxide synthesis. P. Dussault 1:45—235. Synthesis and chemistry of new 1,2-dioxane and 1,2-dioxepane derivatives. K. McCullough 2:10—236. Total synthesis of natural and unnatural organic peroxides. J. Boukouvalas 2:35—237. New antimalarial organic peroxides: Chemistry and biology. G. Posner 3:15—238. Dissociative electron transfer of 0 - 0 bonds in peroxides and endoperoxides. M. Workentin, R. Donkers, D. Stringle, D. Magri 3:40—239. Qinghaosu: The misunderstood malarial drug? R. Haynes, H-W. Tsang, H-W. Chan 4:05—240. Interactions of quinghaosu (artemisinin) with biomolecules. Y-L. Wu, Y-K. Wu, W-M. Wu Hilton Hawaiian Village Coral Ballroom I, Mid-Pacific Conference Center Organic Reactions in Aqueous Media (123)

T. H. Chan, Presiding 1:05—241. Stability of hydrosoluble phosphine catalysts. E. G. Kuntz, O. Vittori 1:45—242. New developments in aqueous medium with transition-metal catalysis: Synthetic applications. J. Genet 3:05—243. Stitching with nitrogen in water. K. Sharpless


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Hilton Hawaiian Village Tapa Ballroom I, Tapa Conference Center Cycloaddition and Annulation Strategies (144)

K. Nomura, Presiding 1:05—254. New strategy for convergent synthesis of polyether natural products. M. Sasaki 1:35—255. New annulation strategies based on highly unsaturated conjugated molecules. R. Danheiser 2:10—256. Radical cyclizations of acylsilanes in organic synthesis. Y-M. Tsai 2:45—257. Constructing rings and quaternary carbon centers using organopalladium chemistry. L. Overman 3:20—258. Stereoselective oxacycle synthesis via radical cyclization. E. Lee 3:55—259. One-pot synthesis of substituted furans and pyrrole from propargylic dithioacetals. New annulation route to highly photoluminescent oligoaryls. T-Y. Luh, C-F. Lee, L-M. Yang Hilton Hawaiian Village Honolulu Suite I, Tapa Conference Center Bioorganic Reaction Mechanisms (163)

K. Nomura, Presiding 1:05—260. Tetrachlorohydroquinone dehalogenase: Elaboration of a glutathione S-transferase mechanism to allow reductive dehalogenation of an aromatic ring. S. Copley, K. Anandarajah, P. Kiefer Jr. 1:40—261. Interfacial enzymology of a phospholipase A2 reaction cycle. M. Gelb, S. Bezzine, A. Singer, J-H. Min, R. Nielsen, B. Robinson 2:20—262. Role of nonnatural amino acids and nonnatural nucleic acid analogs in biological reactions. M. Sisido 2:55—263. Enzyme mimics by RNA molecules. H. Suga 3:30—264. In vitro evolution of catalytic antibodies through optmizing the transitionstate stabilization. I. Fujii 4:10—265. Kinetic footprinting of RNA folding pathways. A. Macmillan

FRIDAY EVENING Hilton Hawaiian Village Coral Ballroom I, Mid-Pacific Conference Center Natural Products of Chemistry: Biological Activity and Synthesis (042)

D. Uemura, Presiding 7:05—373. Stereocontrolled total synthesis of p-phomoidride B (CP-263,114). T. Fukuyama, N. Waizumi, T. Itoh 7:40—374. Progress toward the synthesis of kedarcidin chromophore. A. Myers 8:15—375. Stereochemistry of a cruciferous phytoalexin, spirobrassinin and its analog: Absolute configurations, biological activities, and enantiomeric enrichment phenomena in an achiral HPLC system. K. Monde, N. Harada, M. Takasugi, H. Goto, P. Kutschy 8:30—376. Enediyne prodrugs: Synthesis and mechanism of action. W. Dai, W. Anxin 8:45—377. Synthetic study of ciguatoxins. T. Oishi, H. Oguri, M. Hirama 9:20—378. Biaryl coupling: Applications to peptide chemistry and natural products synthesis. D. Van Vranken Hilton Hawaiian Village Tapa Ballroom III, Tapa Conference Center Discovery and Development of Asymmetric Synthesis and Chiral Technology (065)

I. Shinkai, Presiding 7:05—379. Synthesis of new axially chiral 3,3'-diaryl BINOL and BINAP ligands. V. Snieckus, R. Milburn, R. Quinn 7:25—380. Asymmetric synthesis via cyclization with enantioenriched functionalized allylsilanes. M. Suginome, T. Iwanami, Y. Ito 7:45—381. Total syntheses of polyoxins B, D, J, and L. H. Akita, K. Keisuke 8:05—382. Development of new chiral systems based on salen complexes. X. R. Bu, M. Lebron, A. Gaquere Lepretre, S. Liang 8:25—383. Carbon monoxide-free hydrocarboxylation: A new asymmetric synthesis of ibuprofen and its analogs. C. Crudden, L. Ren, A. Chen

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8:45—384. First total synthesis of lipid II: The final monomeric intermediate in bacterial cell wall biosynthesis. M. Vannieuwenhze, S. Mauldin, M. Zia-Ebrahimi, B. Winger, W. Homback, S. Saha, L. Blaszczak 9:05—385. Mechanism of asymmetric hydrogenation catalyzed by Rh complexes of new P-chirogenic diphosphine ligands. I. Gridnev, N. Higashi, T. Imamoto 9:25—386. Asymmetric synthesis of small rings via boronic esters. D. S. Matteson, H-W. Man, W. C. Hiscox, D. Fernando 9:45—387. Rapid and highly stereoselective hydrogenation of simple ketones. T. Ohkuma, R. Noyori 10:05—388. Syntheses of NK-1 antagonists via highly efficient asymmetric transformations. J. Mcnamara Hilton Hawaiian Village Tapa Ballroom I, Tapa Conference Center Organic Photochemistry (141)

H. Zimmerman, Presiding 7:05—389. Preparation of a-carbonyl radical pairs in crystalline solids: Synthesis of a-cuparenone in a solvent-free crystalline phase reaction. M. Garcia-Garibay, Z. Yang, D. Ng 7:40—390. Template-directed reversible photoligation, photocircularization, and photobranching of DNA oligomers: A new photochemical gene manipulation. I. Saito, K. Fujimoto, S. Matsuda, N. Ogawa, M. Hayashi 8:15—391. Mechanism of single-crystalline photochromism of diarylethenes. M. Irie Hilton Hawaiian Village Honolulu Suite I, Tapa Conference Center Bioorganic Reaction Mechanisms (163)

J. Richard, Presiding 7:05—392. Chemistry of carcinogenic and mutagenic metabolites of heterocyclic aromatic amines. M. Novak, K. Toth, S. Rajagopal, S. Kazerani, L Xu, R. Wolf 7:35—393. Reaction mechanisms and reactive intermediates in the chemistry of toxicants, carcinogens, and anticarcinogens. J. Fishbein 8:05—394. A/-acyloxy-/v-alkoxyamides: Factors controlling reactivity, mutagenicity, and DNA damage. S. Glover, T. Banks, A. Bonin, G. Hammond, A. Prakash 8:40—395. Recent developments in enol chemistry: The effect of introducing p-oxygen and nitrogen substituents. A. J. Kresge 9:15—396. Rate-determining proton transfers in the fragmentation of thiaminaldehyde conjugates. R. Kluger, I. Moore 9:50—397. Determination of the pKas of weak carbon acids in aqueous solution: Substituent effects and Marcus intrinsic barriers. T. Amyes, A. Rios, G. Williams, J. Richard 10:10—398. Catalytic mechanism of scytalone dehydratase. G. S. Basarab, D. B. Jordan Hilton Hawaiian Village Honolulu Suite II, Tapa Conference Center Strategy for Molecular and Supramolecular Photochemistry (012)

K. Nomura, Presiding 7:05—266. Photochemistry in polyfluorinated microenvironment with anisotropy. H. Inoue 7:35—267. Metal-to-ligand charge-transfer states in ^-conjugated systems. K. Schanze 8:05—268. Photochemical regeneration of clay layer structure by an electron transfer. K. Takagi 8:35—269. Covalently linked metal complexaromatic hydrocarbon sensitizers. R. Schmehl 8:50—270. Synthesis of new photocatalysts [Re(X2bpy)(CO)2(PR3)2]+- O. Ishitani, J. Tanabe, K. Sakamoto, K. Koike 9:05—271. Supramolecular organization with inorganic layered materials: From protons to proteins. C. Kumar, A. Chaudhari

Hilton Hawaiian Village Coral Ballroom IV, Mid-Pacific Conference Center New Synthetic Methods in Organofluorine Chemistry (020) Poster Session 7:30-9:30 203. Asymmetric synthesis of fluorinated allylic alcohols: Mechanistic studies on [2,3]Wittig rearrangements of chiral fluoroallylic ethers. K. I. Kudo, I. Toshiyuki, T. Yumiko, K. Hiroshi 204. Synthesis of bis- and oligo-gemdifluorocyclopropanes using olefin metathesis reaction. N. Ishida, T. Itoh, Y. Sako, H. Sasaki 205. Synthesis of novel amino acids that contain gem-difluorocyclopropane moiety. Y. Sako, T. Itoh, N. Ishida, H. Sasaki 206. Friedel-Crafts reaction of A/-alkyl trifluoroacetaldehyde imine: Facile synthesis of 1 -aryl-2,2,2-trifluoroethylamines. Y-F. Gong, K. Kato, H. Kimoto 207. Diiodoperfluoroarene-driven siteselective synthesis of a supramolecular 1-D network. P. Metrangolo, E. Corradi, A. Manfredi, T. Messina, S. Meille, G. Resnati, S. Quid 208. Preparation of fluorinated cyclohexadienones by the electrochemical fluorination of phenols. T. Fukuhara, K. Miura, T. Tada, S. Hara, N. Yoneda 209. Stereo- and regioselective synthesis of fluoroalkenes from ( E ) - 2 - f l u o r o - 1 alkenyliodonium salts. D. Ohta, M. Yoshida, K-l. Yamamoto, S. Hara, T. Fukuhara, N. Yoneda 210. Synthesis of optically pure pentafluorophenyl-substituted chiral 1, 2-diols, aminoalcohols, and related compounds. H. Tanaka, S. Minami, T. Ema 211. Novel nonbonded interaction between fluoride and cyanide. K. Nishide, Y. Hagimoto, H. Hasegawa, M. Node 212. Development of novel cyanofluoromethylation using germyl anion species. T. Mural, Y. Yokoyama, K. Mochida, M. Kajitani 213. Development of syntheses of fluorinated carboxylic acid derivatives. T. Kobayashi, Y. Yokoyama, K. Mochida, M. Kajitani 214. Facile preparation of p-amino-ptrifluoromethyl carbonyl compounds. J. Takaya, H. Kagoshima, T. Akiyama 215. Effective synthesis of fluoroalkylated heterocyclic compounds. M. Ohkoshi, M. Yoshida, H. Matsuyama, M. lyoda 216. Synthesis of fluorine-containing cyclopentenones by intramolecular PausonKhand reaction. M. Ishizaki, D. Suzuki, O. Hoshino 217. Electrochemical oxidation of perfluoroalcohols and use of oxidation products in organic synthesis. K. Shirai, O. Onomura, T. Maki, T. Hamamoto, Y. Matsumura Hilton Hawaiian Village Coral Ballroom IV, Mid-Pacific Conference Center New Developments in Organic Radical Chemistry (029) Poster Session 7:30-9:30 346. Intramolecular radical cyclization initiated by the reaction of unsaturated hydroperoxides with iron(ll) sulfate. T. Sugawara, A. Masuyama, M. Nojima 347. Catalytic nitration of alkanes with nitrogen dioxide by /V-hydroxyphthalimide. S. Sakaguchi, Y. Nishiywaki, Y. Ishii 348. Synthesis of amino acids based on radical addition to oxime ethers. H. Miyabe, M. Ueda, K. Fujii, T. Naito 349. Imidoyl radicals as synthons of unstable acyl radicals. S-l. Fujiwara, T. Matsuya, H. Maeda, T. Shin-Ike, N. Kambe, N. Sonoda 350. Hypophosphite deoxygenation reactions in pharmaceutical process chemistry: An efficient alternative to tin hydride. A. Graham, S. Parekh, A. Thomas, R. Yang 351. Carbon-carbon bond formation using stannyl enolates as a radical transfer agent. N. Fujisawa, H. Saito, K. Miura, A. Hosomi 352. Vanadium-catalyzed stereoselective pinacol coupling reaction. Y. Imamoto, T. Hirao, A. Ogawa, B. Hatano 353. Catalytic pinacol coupling in the presence of an acylating reagent. H. Takeuchi, T. Hirao, A. Ogawa

354. New three-component coupling reactions using silyl tellurides. H. Miyazoe, S. Yamago, J-l. Yoshida 355. Radical-mediated synthesis of substituted quinones with organotellurium compounds. M. Hashidume, S. Yamago, J-l. Yoshida 356. Stereoselective pinacol coupling of aromatic ketones by use of rare earth metalchlorosilane systems. H. Takeuchi, A. Ogawa, T. Hirao 357. Magnesium-promoted carbon-acylation through electron transfer of aromatic carbonyl compounds. M. Sakai, I. Nishiguchi, H. Maekawa, T. Ohno 358. Stereoselective preparation of polysubstituted tetrahydrofurans. A. Kamimura, H. Mitsudera, Y. Omata 359. Catalytic dehalogenation reaction by indium trichloride-tributyltin hydride system. I. Shibata, K. Inoue, A. Baba 360. Hydrogen atom abstraction pathways to functionalized free radicals. R. K. Lush 361. Efficient synthesis of a,a-difluorolactam derivatives by transition-metal-catalyzed radical cyclization of /V-allylhalodifluoroacetamides. S-l. Iwamatsu, Y. Isono, H. Nagashima 362. Stannylcarbonylation of azaenynes: Novel synthesis of ^-lactams based on /V-philic 4-exo cyclization of acyl radicals. I. Ryu, H. Miyazato, H. Kuriyama, G-H. Yamamura, S. Minakata, M. Komatsu 363. Photoinduced addition of carbamotelluroates to acetylenes. Y. Shimizu, N. Kambe, S-l. Fujiwara, T. Shin-Ike 364. Cyclizative multiple carbonylation of 4-alkenyl halides using a hybrid metal/ radical reaction. S. Kreimerman, I. Ryu, F. Araki, S. Minakata, M. Komatsu 365. Stereoselectivity in the samarium(ll)promoted reductive dimerization of 3-substituted acrylic amides: Asymmetric synthesis of 3,4-disubstituted adipamides via radical process. T. Kikukawa, T. Hanamoto, J. Inanaga 366. Nitrate esters as precursors of amino acid-derived alkoxy radicals. C. Easton, A. Mortimer, M. Davies 367. Methane conversion using oxygen-rich plasmas. H. Naito, H. Kimuro, H. Sudoh, K. Onoe 368. Brown coal conversion by cold plasma. T. Horie, M. Kobayashi, K. Onoe, T. Yamaguchi 369. Element distribution of Yalloum coal into fuel products during microwave plasma reaction. M. Kobyashi, T. Horie, H. Onodera, K. Onoe, T. Yamaguchi 370. Stereoselection at the steady state in radical cyclizations of acyclic precursors. D. Curran, K. Stalinski 3 7 1 . New synthetic method to 1,2benzisothiazoline-3-one derivatives and related reactions via sulfonamidyl radicals. M. Katohgi, H. Togo, M. Yokoyama 372. Generation of a-keto radicals from ketones by Mn(ll)-0 2 system and the addition to aikenes. T. Iwahama, S. Satoshi, I. Yasutaka

SATURDAY MORNING Hilton Hawaiian Village lolani Suite V/VI, Tapa Conference Center Reactive Intermediates and Unusual Molecules (001)

H. Tomioka, Presiding 8:05—399. Supramolecular carbene chemistry. U. Brinker, D. Krois, M. Bobek, M. Rosenberg 8:30—400. Novel transformations of heteroaryl carbenes. R. S. Sheridan 9:00—401. Stable triplet species: Carbene or diradical? H. Tomioka 9:30—402. New intra- and intermolecular reactions of oxy- and dioxycarbenes. J. Warkentin 10:00—403. Carbenes fragmenting to carbocations. R. A. Moss 10:30—404. Reaction of carbenes with benzene: Evidence for the formation of charge-transfer complexes. M. Platz, S. Celebi, M-L. Tsao, D. Merrer, J. Toscano, Y. Wang

Hilton Hawaiian Village Coral Ballroom I, Mid-Pacific Conference Center Natural Products of Chemistry: Biological Activity and Synthesis (042)

D. Uemura, Presiding 8:05—547. Natural products and natural product libraries. J. Clardy 8:40—548. Diversity-oriented organic synthesis of natural product-like compounds. S. Schreiber 9:15—549. Quick screening of lipid A in Helicobacter pylori strains: Structural and functional variability. Y. Suda, T. Ogawa, K. Nagata, Y. M. Kim, Y. Hasegawa, K. Aoyama, T. Shimoyama, S. Kusumoto, T. Tamura 9:3fJ—550. Discovery of a new structural class of glucan synthesis inhibitors with antifungal activity. R. Schwartz, J. Onishi, M. Meinz, R. Giacobbe, A. Cabello, F. Vicente 9:45—551. Studies on the laboratory culture of the myxomycetes and their chemical constituents. M. Ishibashi, T. Iwasaki, S. Imai, M. Mitamura, A. Ito 10:00—552. Chemistry of natural and designer brassinosteroids. T. Back, D. Andersen, S. Nakajima, K. Minksztym, K. Michalak, G. Sung 10:15—553. Clinical applications of angiogenesis research. M. O'Reilly 10:50—554. Studies on imidazopyradinone bioluminescence: Syntheses and activities of the mechanism-based inhibitors. H. Nakamura

10:35—569. Asymmetric synthesis of heterocyclic natural products using palladium catalysts. S. Pyne, Z. Dong 11:15—570. Lewis acid catalysis in heterocyclic chemistry. S. Kobayashi Hilton Hawaiian Village lolani Suite VII, 2nd Floor, Tapa Conference Center Molecular Oxygen and Organic Peroxides in Chemistry and Biology (122)

E. Clennan, Presiding 8:05—571. Lipid peroxidation and its inhibition by antioxidant in low-density lipoprotein particles. E. Niki, Sr., N. Noguchi 8:45—572. Steady-state and time-resolved methods for elucidation of singlet and radical oxygenation mechanisms. C. Tanielian 9:05—573. On the role of charge-transfer interactions during oxygen quenching of excited singlet and triplet states. F. Wilkinson, A. Abdel-Shafi 9:25—574. Singlet oxygen and ultraviolet-A in cellular signalling. H. Sies, L. O. Klotz 10:05—575. Pro- and antioxidative processes involving dietary carotenoids: A fast reaction study. G. Truscott, D. McGarvey, R. Edge, M. Burke, E. Land 10:25—576. Active oxygen species generated from photoexcited fullerene in an aqueous media. N. Miyata 10:45—577. Design of carbon-centered radicals unreactive toward oxygen. J. C. Scaiano Hilton Hawaiian Village lolani Suite l/lI, Tapa Conference Center

Hilton Hawaiian Village Honolulu Suite III, Tapa Conference Center

Organic and Biological Electrochemistry: Fundamentals and Applications (133)

Organic and Combinatorial Chemistry on Solid Supports (052)

J. Lessard, Presiding

T. Takahashi,

Presiding

8:55—556. Real-time monitoring method using stained compound for the solid-phase reaction. T. Suenaga, C. Schutz, T. Nakata 9:45—557. Novel supports for combichem base on polymer grafted porous teflon materials. J. Thiele, A. Atuegbu, V. Antonenko 10:10—558. New methodologies for oligosaccharide synthesis, solid phase synthesis, and hybrid synthesis based on affinity separation (SAS). K. Fukase, K. Shoichi 10:35—559. Glycopeptide antibiotics. D. Kahne Hilton Hawaiian Village Tapa Ballroom III, Tapa Conference Center Discovery and Development of Asymmetric Synthesis and Chiral Technology (065)

I. Shinkai, Presiding 8:35—560. Enabling technologies for biology and medicine arising from endeavors in total synthesis. K. C. Nicolaou 9:15—561. Synthesis of optically active a,ccdisubstituted amino acids based on memory of chirality. K. Fuji, T. Kawabata, H. Suzuki, T. Nagae 9:35—562. Enantioselective construction of acyclic segments in natural products based on chiral oxazaborolidinonemediated aldol reaction under promoter (catalyst) control. S. I. Kiyooka 9:55—563. New methods of enantioselective synthesis of polycyclic natural products. L. Overman 10:35—564. Phorboxazoles A and B: Architecturally challenging synthetic targets. A. B. Smith, P. R. Verhoest, K. P. Minbiole, M. Schelhaas 11:15—565. Methods for the asymmetric synthesis of diverse natural products. G. Molander Hilton Hawaiian Village Tapa Ballroom I, Tapa Conference Center New Developments in Heterocyclic Chemistry (066)

M. Komatsu, Presiding 8:35—566. Synthesis of heterocycles from oximer derivatives. K. Narasaka 9:15—567. Intramolecular radical cyclizations onto hydrazone and related imine acceptors: Synthetic investigations and kinetic data. A. Fallis 9:55—568. Stereoselective synthesis of nitrogen heterocycles via intramolecular radical cyclizations. P. A. Evans

8:05—604. Electron-transfer reactions followed by bond cleavage: Reactions of some dianions. D. Evans, Z. R. Zheng 8:35—605. Competition between electron transfer (ET) and radical processes in distonic radical anions formed by the dissociative ET to endoperoxides. M. S. Workentin, R. L. Donkers, D. L. B. Stringle 9:00—690. Dithioacetal as a substrate for the electrochemical C-C bond formation. R. Uchiyama, S. Kim, Y. Kitano, M. Tada, K. Chiba 9:05—606. Intramolecular assistance of electron transfer from heteroatom compounds. M. Watanabe, S. Suga, T. Chow, J-l. Yoshida 9:25—607. Interfacial electron-transfer kinetics through n-alkyl monolayers formed on hydrogen-terminated n-Si(111). D. M. Wayner, H-Z. Yu 9:55—608. Carbon-bond formation through electron-transfer reaction of vinyl phosphonate derivatives. M. Kyoda, I. Nishiguchi, H. Maekawa, J-l. Yoshida 10:15—609. Efficient C-C bond formation using electrogenerated oxycarbenium ion pool. S. Suzuki, S. Suga, J-l. Yoshida 10:35—610. Direct oxidative C-C bond formation using cation flow method. S. Suga, K. Fujiwara, M. Okajima, J-l. Yoshida Hilton Hawaiian Village Tapa II, Tapa Conference Center Organic Photochemistry (141)

H. Zimmerman, Presiding 8:35—611. Intermolecular photochemistry in organized systems. S. A. Fleming, C. Mao, J. C. Cecil 9:10—612. Recent advances in the photochemistry of organic "super" photoacids. L. Tolbert 9:45—613. Theoretical study of reaction paths and nonadiabatic dynamics for photochemical processes. M. Robb, M. Bearpark, A. Sanchez-Galvez, P. Hunt, M. Garavelli, M. Olivucci, F. Jolibois 10:20—614. Recent studies on the reactions of triplet benzenes. P. Wagner 10:55—615. Photoinduced electron transfer in organic synthesis, cycloaddition, addition, and cyclization reactions. J. Mattay 11:30—616. Concentration effect of radical ion intermediates in photochemical redox reactions. Y. Sawaki, K. Ishiguro, H. Yokoi, S. Moriizumi

Hilton Hawaiian Village Coral Ballroom III, Mid-Pacific Conference Center n-Electronic Systems with Novel Structure (010) Poster Session 9:00-11:00 405. Dilithium salt of [4]radialene dianion stabilized by silyl groups: Evidence for a lithium walk on the 8C/10-electron system. T. Matsuo, A. Sekiguchi 406. Toward a rational synthesis of buckminsterfullerene. M. M. Boorum, L. T. Scott 407. Change in spin distribution in iron(lll) porphyrin complexes caused by the ring deformation. M. Nakamura, T. Ikeue, Y. Ohgo, H. Fujii 408. Synthesis and characterization of thio-pquinonoid compounds, monothio-pbenzoquinone, and p-thioquinonemethide derivatives with steric protection. R. Suzuki, K. Matsumoto, H. Kurata, M. Oda 409. Synthesis of bacteriochlorophyll-e/f derivatives. M. Omoda, Y. Saga, H. Tamiaki 410. Redox properties of silylated fullerenes. T. Wakahara, M. Ito, Y. Maeda, Y. Akasaka, G. Xiang, E. Van Caemelbecke, K. M. Kadish, K. Kobayashi, S. Nagase, M. Kako, Y. Nakadaira 411. Synthesis, structure, and photophysical properties of phenanthreneophanes. Y. Nakamura, Y. Fujii, J. Nishimura 412. Cyclic [6]-metaphenylacetylenes with six methoxy groups inside the cavity (the extended spherands with acetylenic bonds). Y. Hosokawa, T. Kawase, M. Oda 413. Design of reversible one-electron redox systems using 7-n electron framework containing chalcogen atoms. S. Ogawa, N. Nagahora, Y. Kawai, T. Kimura, R. Sato 414. Progress in the synthesis of large [n] phenacenes: A family of graphite ribbons. F. B. Mallory, K. E. Butler, A. Berube, E. D. Luzik, Jr., C. W. Mallory 415. Dithiole-containing cycloproparenes. C. S. Jones, B. Halton 416. Synthesis, properties, and redox behaviors of azulene-substituted carbocations. T. Kubo, S. Ito, N. Morita, T. Asao, K. Fujimori 417. Synthesis and characterization of 6-(cycloheptatrienylidene)-2,4-cycloheptadien1-one Fe(CO)3. N. Morita, M. Kinjo, K. Saito, S. Moriyama, S. Ito 418. Convenient synthetic method for the rc-conjugated systems with sevenmembered ring. R. Yokoyama, N. Morita, S. Ito, N. Harada, M. Watanabe 419. Syntheses of actylenic oligophenylene macrocycles based on a novel Dewar benzene building-block approach. M. Ohkita, K. Ando, T. Suzuki, T. Tsuji 420. Synthesis and properties of azulenesubstituted heterocumulenes. T. Okujima, S. Ito, C. Kabuto, N. Morita 421. Helicity coding: Programmed molecular self-organization of achiral nonbiological oligomers into multiturn helical superstructures. M. Ohkita, J-M. Lehn 422. Dynamic redox properties of ninemembered cyclic peroxides: Reversible extrusion and trapping of 0 2 . J. I. Nishida, T. Suzuki, M. Ohkita, T. Tsuji 423. Synthesis and structure of first isolable pentasilapiropentadiene. T. Iwamoto, M. Tamura, C. Kabuto, M. Kira 424. Ultrathin [60]fullerene layer constructed from [60]fullerene-homooxacalix[3]arene complex on a gold surface. T. Hatano, A. Ikeda, T. Akiyama, S. Yamada, M. Sano, Y. Kanekiyo, S. Shinkai 425. Synthesis and properties of [m.n.](3,9) carbazolophanes. K. Tani, K. Hori, Y. Tohda, H. Ohkita, S. Ito, M. Yamamoto 426. Synthesis and properties of terrylenedicarboximide derivatives. H. Iwawaki, Y. Nagao, K. Kozawa 427. A 3-D oriented rc-conjugated system: Synthesis and characterization of porphyrins bearing rc-conjugated pendant strands. K. Saito, T. Hirao 428. Helical dimer and tetramer of biphenylene-dimer tetraanion: Unusual anionic aggregates. R. Shenhar, M. Rabinovitz, I. Willner, H. Wang, N. Rajca, R. Beust 429. Reduced species of the curved C6o fragment d i i n d e n o [ 1 , 2 , 3 , 4 , - d e f g \ ] ' , 2',3',4'-mnop] chrysene: The blessed interplay between experiment and calculation. R. Shenhar, M. Rabionvitz, I. Willner, R. Beust, H. E. Bronstein, L. T. Scott

430. Revealing the cyclohexa(benzylanion). L. Eshdat, A. Ayalon, R. Beust, R. Shenhar, M. Rabinovitz 431. Synthesis and substituent effect on the properties of methyl cations stabilized by a substituted benzene and two 2Hcyclohepta[fc]furan-2-ones or 2Hcyclohepta[b]pyrrol-2-one derivatives. S-l. Naya, M. Nitta 432. Kinetic stabilization of [1.1] paracyclophane by structural modification of methylene bridges. H. Kawai, T. Tsuji 433. Porphyrin square: Synthesis of a square-shaped n-conjugated porphyrin tetramer connected by diacetylene linkages. Y. Fujimoto, K-l. Sugiura, Y. Sakata 434. Structural and stereodynamic studies of bianthrone derivatives. C-T. Chen, Y-H. Chen, C-H. Hong 435. Intramolecular movement of bisazo dyes, including a-cyclodextrin. T. Tanaka, T. Kawanabe, H. Shosenji 436. Opening the C 60 core: A surgical approach to endohedral metallofullerenes. T. Jarrosson, G-W. Wang, M. D. Bamberger, G. Schick, M. Saunders, K. N. Houk, Y. Rubin 437. New extended rc-electronic systems controlled with orientational dihexylbithiophenes. H. Higuchi, T. Ishikura, H. Sakai, K. Yamamoto 438. Intramolecular charge transfer in 5,6open azafulleroid bearing p-phenylenediamine donating groups. A. Comito, G. Schick, M. D. Bartberger, A. L Viado, Y. Rubin 439. Hydrogel formation of bolaamphiphilic cascade molecules with aromatic core. S. Arai, H. Takagi, H. Asano, K-l. Kitahara, I. Yoshihama, T. Takemura 440. Synthesis and light-harvesting properties of oligophenylene-substituted porphyrins having cross and sea urchin shapes. M. Saika, K-l. Sugiura, Y. Sakata 441. Role of the nonbonded rc-type S-Se interactions on the structure 1-(methylselanyl)-8-(arylselanyl)naphthalenes. W. Nakanishi, S. Hayashi 442. Inclusion phenomena of calix[4]arene with small organic guests in solid state. M. Hirakata, K. Nishimoto, K. Yoshimura, S. Usui, Y. Fukazawa 443. Mono- and bis[octaalkylporphyrinatorhodiumj-fullerene. M. Urahigashi, H. Kimura, S. Miki 444. Synthesis of a calix[5]arene capped porphyrin. H. Iwamoto, Y. Yukimasa, Y. Fukazawa 445. Conjugated [2]porphyracene dimers. S. Takara, K-l. Sugiura, Y. Sakata 446. Synthesis, structure, and properties of silicon-acetylene cyclic compounds. M. Unno, T. Saito, K. Negishi, H. Matsumoto 447. Solvent-dependent deformation of geometry of permethylated ^cyclodextrin systems containing pylene units at a 6-position. K. Asano, Y. Sakata, T. Kaneda 448. Mechanism of isomerization reactions of naphthalene and its homologues. M. Shimomasu, K. Fukunishi, S. Miki 449. Synthesis of calix[4]arene-based receptor for dicarboxylates. T. Haino, M. Nakamura, N. Kato, Y. Fukazawa 450. Exploration of new open-shell molecules: Synthetic study of 6-oxophenalenoxyl-based heterospin diradicals with a-nitronyl nitroxide. J. Kawai, Y. Morita, K. Fukui, K. Sato, D. Shiomi, T. Takui, K. Nakasuji 451. Synthesis of the first stable silicontellurium double-bond compound, silanetellone, by taking advantage of an overcrowded dilithiosilane. K. Hatano, N. Takeda, N. Tokitoh 452. Synthesis and properties of triphenyleno[1, 1 \2-bcdA,5-b'c'd: '8,96"c"cr"]trithiophene: The first bowl-shaped polycyclic heteroaromatic. Y. Aso, K. Imamura, K. Takano, K. Takimiya, T. Otsubo 453. Molecular assembling of multiporphyrin utilizing intermolecular interactions. H. Shinmori, A. Osuka 454. Synthesis and chemical properties of cyclohepta[b]thieno[3,4-d]pyrrole and related compounds. T. Takayasu, M. Nitta 455. Cavity-directed synthesis of otherwise labile siloxane oligomers within selfassembled coordination nanocages. M. Yoshizawa, T. Kusukawa, S. Sakamoto, K. Yamaguchi, M. Fujita 456. A porphyrin prism. N. Fujita, S. Sakamoto, K. Yamaguchi, M. Fujita 457. NH tautomerism of N-confused porphyrins. H. Furuta


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458. Preparation, conformation, and reactivities of metacyclophanes consisting of three aromatic rings. M. Inoue, A. Tsuge, T. Moriguchi 459. Triple fluorescence behavior of 1,8naphthalimide-arene-dimethylamine. S. Nakajima, Y. Kubo 460. Guideline for stable it-expanded wuruster-type redox system: Synthesis, properties, and electron-transfer complex of 13,13,14,14-tetracyano-1,6- and 1,8pyrenoquinodimethanes. S. Mikami, K-l. Sugiura, K. Iwasaki, S. Hino, J. Miller, Y. Sakata 461. Template effects on the macrocyclization of a bishydroxybenzaldehyde with diamines. H. Houjou, Y. Nagawa, K. Hiratani 462. Pseudo-rotaxanes formed between crownophanes and dibenzylamines. Y. Nagawa, H. Houjou, T. Ogihara, K. Hiratani 463. Preparation and kinetic stabilization of [1.1]naphthalenophane. M. Saito, H. Kawai, T. Tsuji 464. Substituent effects on planarity of 6rc eight-membered rings. N. Mizoguchi 465. Synthesis of expanded porphyrins by the condensation of two 2,2'-bipyrrole derivatives. S. Maeda, N. lizuna, J-l. Setsune 466. Synthesis of binaphthol derivatives having phenolic hydroxyl groups via stepwise Claisen rearrangement. H. Miura, Y. Nagawa, H. Tokuhisa, K. Hiratani, K. Watanabe 467. Supramolecular metal complex based on calix[5]arene for fullerenes. H. Araki, Y. Yamanaka, T. Haino, Y. Fukazawa 468. Photoredox behaviors of A/(21),/V(22)bridged porphyrins. S. Tanikawa, K. Kashihara, K-l. Wada, J-l. Setsune 469. Preparation and properties of novel quaterthiophenes. M. Kozaki, Y. Yonezawa, K. Okada 470. Synthesis and structure of extended silapericyclynes. K. Negishi, H. Matsumoto, M. Unno 471. Synthesis of novel macrocycles having plural amides and phenolic hydroxyl groups. M. Numata, S. Masubuchi, H. Houjou, K. Hiratani, S. Akabori 472. Synthesis and properties of benzooxazinophenoxazines and the sulfur analogs. T. Okamoto, M. Kozaki, D. Shiomi, K. Sato, T. Takui, Y. Yamashita, M. Uchida, G. Wang, H. Yokoi, K. Furukawa, K. Okada 473. Search for homoaromatic semibullvalenes: Theory and experimentconcert or conflict. R. V. Williams 474. Carbon networks based on dehydrobenzoannulenes: Synthesis of graphyne and graphidiyne substructures. M. Haley, B. Wan 475. Iridabenzenes and valence isomers: Synthesis and characterization of unusual metallo-aromatics. M. Haley, R. Gilbertson, T. Lau 476. Structure-property studies of crossconjugated oligo(enynes). R. Tykwinski, S. Ciulei, J. Cho, Y. Zhao 477. C64. B. Halton, M. Cooney 478. Preparation and properties of bicyclo[e] annelated dihydropyrenes. T. Sawada, R. Mitchell 479. Synthesis of dodecaaryl[6]radialene derivative, an extended [6]radialene system. M. Todaka, N. Nakamura, M. Yoshida, Y. Kuwatani, H. Matsuyama, M. lyoda 480. Synthesis and cheletropic fragmentation of diethynylmethylenebicyclo[4.3.1 jdecatriene: An alternative entry into all-carbon molecules. N. Iwasa, S. Motohiro, T. Yoshito 481. Synthesis and properties of 1,8naphthalenophane and 1,8-anthracenophane containing two biaryl bridges. K. Nakao, T. Kondo, M. Yoshida, H. Matsuyama, M. lyoda 482. Metal-lustrous crystals from 1-alkyl-2,5di(2-thienyl)pyrrole derivatives. H. Yanai, O. Katsuyukia, A. Motohiro, M. Shoji 483. Synthesis and functionalization of 1,3,5tri(1-azulenyl)benzene. S. Yamashiro, K. Imafuku 484. Reactions of fullerene dimer C12o- K. Fujiwara, K. Komatsu 485. Synthesis and properties of sulfurcontaining cyclic TL-systems annelated with rigid o- frameworks. A. Wakamiya, K. Komatsu 486. Synthesis and structural properties of the novel paracyclophane. S. Kuroda, O. Mitsunori, O. Yuji, N. Teruhiko, M. Ryuta, K. Mayumi, F. Shinji, K. Kimiko, K. Ryoko, T. Tokiko

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487. Synthesis and properties of cyclic T r conjugated systems annelated with bicyclo[2.1.1]hexene. A. Matsuura, K. Komatsu 488. Formation of polyyne-bridged [12.12] paracyclophanes and their transformation into C36 fullerene. R. Furukawa, S. Motohiro, T. Yoshito 489. Synthesis and self-association behavior of butadiyne-bridged [4.4.4.4] metacyclophaneoctayne derivative in polar sovlents. K. Adachi, S. Araki, S. Motohiro, H. Keiji, T. Yoshito 490. 1,3,5(o-Hydroxphenyl)benzene as a new fundamental structure of artificial host. T. Kuwashima, H. Keiji, J. Satoshi, T. Yoshito 491. Computational investigation of possible planar 3,3'-disubstitutedbithiophenes. M. Pomerantz 492. Chiral recognition of secondary amines by using macrocyclic polyethers. A. Fujiwara, H. Keiji, T. Yoshito 493. AII-Z-/n]benzo[4]annulenes and their metal complexes. Y. Kuwatani, Y. Tadahiro, K. Ayako, M. lyoda 494. Synthesis of hexaaryl[3]radialenes via dibromo [3] dendralenes. N. Nakamura, M. Todaka, S. Ohtsu, M. Yoshida, M. lyoda, M. Sugita, I. Haruo 495. Mesogenic properties of 5-cyanotropones with a dialkoxybenzoyloxy. M. Hashimoto, A. Mori, S. Ujiie 496. Molecular machine, a light-powered chiral molecular motor: Its chemisry and rotation mechanism. N. Harada, N. Koumura, R. Van Delden, R. Zijlstra, B. L. Feringa 497. Inclusion of [60]fullerene in a selfassembled homooxacalix[3]arene-based dimeric capsule constructed by a Pd"pyridine interaction. A. Ikeda, H. Udzu, S. Shinkai Hilton Hawaiian Village Coral Ballroom IV, Mid-Pacific Conference Center Strategy for Molecular and Supramolecular Photochemistry (012) Poster Session

9:00-11:00 498. Long-lived ionic radical pair generated by photoinduced charge separation in doped poly(/vWinylcarbazole) solid films. T. Ikoma, M. Nakai, K. Akiyama, S. TeroKubota 499. Synthesis and self-assembly of zinc methyl bacteriopheophorbide-f and its homolog. H. Tamiaki, M. Kubo, T. Oba 500. Ultrafast absorption changes in the visible and near-infrared regions due to radical and dimer radical cation formation upon excitation of ion-pair charge-transfer complexes of nitro- and dicyanovinylstyrylpyridinium tetraphenylborates. H. Kawai, T. Nagamura 501. Regulation of the efficiency for DNAmediated hole transport and hole trapping. C. Dohno, K. Nakatani, I. Saito 502. Role of the contact charge-transfer complexes between stilbenes and oxygen formed in Zeolite Y on direct photooxygenation. M. Nakajo, M. Kojima 503. Mechanism for phenothiazinesensitized degradation of sodium hyaluronate and relative estimation of phototoxicity. S. Nebashi, M. Kojima, K. Nakamura, T. Sunada 504. Syntheses and photocatalytic properties of Fe and Mn porphyrin Ru(bpy)3 conjugates and Fe- and Mn-containing heterometallic bis(porphyrin)s. J. Lintuluoto, V. Borovkov, Y. Inoue 505. Quinone imine dye formation via photocycloaddition between isocyanates and quinones. K. Wakamatsu 506. Thermokinetic study on light-induced lophyl radical from hexaarylbiimidazolyl derivative. H. Ito, M. M. Matsuhita, T. lyoda, J.Abe 507. Mechanism of [3+2]-photocycloaddition of dimethyl 1,4-naphthalenedicarboxylate and alkenes: Effect of addition of radical scavenger. Y. Kubo, K. Ito, T. Narukage, H. Shiratori 508. Latex photochemistry: Photoinduced electron transfer from serotonin to 1-pryenemethanol on the surface of polystyrene latex particles. D. Koide, Y-K. Gong, K. Nakashima

509. Rapid approach of photoaffinity labeling for the structural analysis of biosupramolecular systems. Y. Hatanaka, U. Kempin, J-J. Park 510. Synthesis and photochromic reaction of [n.2] metacyclophan-1-enes. M. Takeshita, M. Ogawa, T. Yamato 511. Development of fluorescent chemosensors from substituted phenols and hydroquinones. M. Iwamura, S. Yamada 512. Photolysis of 2-pentanone included within alkali metal ion-exchanged zeolite cavities and investigations of their processes by ab initio molecular orbital calculations. S. Takada, H. Yamashita, M. Nishimura, H. Bessho, T. Nakajima, H. Nakatsuji, M. Anpo, M. Hada 513. Amphiphilic lucigenin analogs as chemiluminescent sensors: Preparation and properties. S. Yamada, C. Takahashi, N. Kohsaka, M. Iwamura 514. Preparations of oligopyridine-metal complexes having diazo moieties and magnetic properties of their photoproducts. T. Itoh, N. Koga 515. Super high-spin molecules and ferromagnets consisting of carbenes and metal ions in frozen solutions. S. Karasawa, N. Koga 516. Molecular structures of terpyridinecopper complexes having diazo moieties and magnetic properties of their photoproducts. M. Suehiro, S. Karasawa, N. Koga 517. Magnetic properties of tetra(pyridinecarbene)copper(ll) complexes in frozen solutions. H. Morikawa, S. Karasawa, N. Koga 518. Magnetic properties of pyridine-metal complexes having high-spin polycarbenes. N. Yamamoto, S. Karasawa, N. Koga 519. Synthesis and photochemical properties of ruthenium bipyridyl-Schiff base complexes. N. Komatsuzaki, Y. Himeda, R. Katoh, H. Sugihara, H. Arakawa, K. Kasuga 520. Enantio- and diastereodifferentiating photoisomerization of 1- and 5,6substituted cyclooctenes. M. Kaneda, M. Kawasaki, K. Fujisawa, T. Wada, Y. Inoue 521. Enantiodifferentiating photocyclodimerization of 4-methoxystyrene sensitized by optically active naphthalene(di)carboxylates. S. Shiraishi, S. Asaoka, T. Wada, Y. Inoue 522. Solvolysis and photosolvolysis of phenacyl sulfonate. S. Usui, M. Okamura, Y. Umezawa, M. Okada 523. Supramolecular asymmetric photoisomerization of 1,2-diazacyclooctene in cyclodextrin cavity: First preparation and chiroptical properties of optically active (E)1,2-diazacyclooctene. K. Goto, A. Nishide, T. Wada, Y. Inoue 524. Magnetic field effects due to the Ag mechanism upon photochemical reactions under ultrahigh fields of up to 30 T. M. Wakasa, K. Nishizawa, H. Hayashi 525. Enantiodifferentiating photoisomerization reaction of cyclooctene in supercritical carbon dioxide. R. Saito, Y. Inoue 526. Supramolecular enantiodifferentiating photocyclodimerization of an anthracene derivative in the y^cyclodextrin cavity. A. Nakamura, Y. Inoue 527. Chiral intramolecular excimer formation of two naphthyls tethered to y-cyclodextrin: Sense of excimer chirality determined by circularly polarized fluorescence spectroscopy. A. Nakamura, Y. Inoue 528. Regioselective photocydoaddition of furan derivatives to cyanonaphthalene assisted by hydrogen bonding. K. Chiyonobu, K. Mizuno 529. Intercalation of polyfluorinated surfactant into clay layer: Structure, microenvironment, and characteristics. T. Yui, H. Inoue 530. Synthesis and properties of novel ruthenium(ll) complexes having pyridylpyrazoline derivatives as ligands. P. Wang, K. Kasuga, N. Komatsuzaki, R. Katoh, Y. Himeda, H. Sugihara, H. Arakawa


531. Photochemical epoxidation of alkene sensitized by Ru(ll) porphyrin. S. Funyu, S. Takagi, T. Shimada, H. Inoue 532. Photohydroxylation of alkyquinolinium ions in clay interlayers. H. Usami, M. Watanabe, H. Fujimatsu, T. lijima 533. Photocatalytic reduction of carbonyl compounds with rhodium complexes as a redox catalyst. Y. Himeda, N. Komatsuzaki, H-H. Sugihara, H. Arakawa, K. Kasuga 534. Cyclooctenones: Promising compounds for absolute asymmetric synthesis. M. Oelgemoeller, K. Fukui, Y. Naitoh, Y. Inoue 535. Photocatalytic and enantioselective degradation of cobalt complex by chiral ruthenium tris(bipyridine) derivatives. H. Ishida, D. Hesek, F. Aoki, Y. Inoue 536. Synthesis of macrocyclic bis(benzoxazole) derivatives via tandem Claisen rearrangement and their fluorescent properties. E. Koyama, G. Yang, S-K. Lee, Y. Nagawa, K. Hiratani 537. Changes in temperature during excimer laser ablation of conducting polymer films. K. Tsunoda, D. Kumaki, H. Yajima, T. Ishsii 538. Photochemically tunable supramolecular materials. O. Sato, Z-Z. Gu, S. Hayami, A. Fujishima 539. Absolute asymmetric synthesis of nonaromatic amino acids by circularly polarized synchrotron radiation. H. Nishino, Y. Inoue, A. Kosaka, H. Shitomi, H. Onuki 540. Diastereodifferentiating Z-E photoisomerizations of chiral benzoyloxycyclooctenes. K. Matsuyama, I. Toru, I. Yoshihisa 541. Curious oxygen effect on photosensitized electron-transfer isomerization of 1,1-diaryl-2-f-butylethene. T. Ishiduka, Y. Kawamura, M. Nishiuchi, M. Tsukayama Hilton Hawaiian Village Tapa Ballroom II, Tapa Conference Center New Strategies to TransitionMetal-Catalyzed or Mediated Organic Synthesis (024)

K. Nomura, Presiding 8:35—542. Recent advances in selective organic synthesis mediated by a Ti(0-APr)4/ 2PrMgX reagent. F. Sato 9:15—543. New pathways for the formation and cleavage of carbon-carbon bonds: Transition-metal-directed free-radical alkylation and electrophilic two-carbon ring expansion. J. Stryker, T. Dzwiniel, G. Greidanus, P. Tiege, J. Chen 10:15—544. Group 3- and lanthanide metallocenes as catalysts for carbocycle synthesis. G. A. Molander 10:55—545. Synthetic applications of tungsten-catalyzed alkynol cycloisomerizations. F. McDonald 11:15—546. Organic tungsten compounds in organic synthesis. R-S. Liu Hilton Hawaiian Village Coral Ballroom IV, Mid-Pacific Conference Center Organic Reactions in Aqueous Media

(123) Poster Session 9:00-11:00 578. Ketenimine formation from hydrothermolysis of an alkyl azide at high temperature and pressure. T. Brill, D. Miksa, N. Gunawardena 579. Synthesis of p.y-unsaturated ketones using aldehydes and methyl vinyl ketone in the presence of ln/lnCI3 in aqueous media. Y. Kim, S. B. Kang, S. Y. Hahn, G. Keum, T. S. Jang, S. Y. Kang 580. 2-Pyridyldimethylsilyl group as a removable hydrophilic group in aqueous organic reactions. K. Itami, T. Nokami, J-l. Yoshida 581. Selective decomposition of organics in aqueous solution using superheated steam oxidation. M. Satoh, Y. Ogo, T. Moriyoshi 582. New reductive method and its application to prepare deuterated compounds. K. Ishimoto, H. Suzuki, Y. Mitoma, M. Tashiro 583. Synthesis of macroheterocycles by intramolecular reductive coupling of dialdehydes or diimines in aqueous media. C. Simion, A. Simion, S. Nagashima, M. Tashiro 584. Palladium-promoted reduction using water as a hydrogen source. S. Nagashima, Y. Mitoma, C. Simion, A. Simion, Z. Li, M. Tashiro

585. Convenient reduction and reductive coupling of carbonyl and imine compounds by metallic calcium. Y. Mitoma, S. Nagashima, C. Simion, A. Simion, Z. Li, M. Tashiro 586. Cyclodextrin-rare earth metal perfluoroalkylsulfonylamide and -methide complexes as metalloenzyme models. J. Nishikido, M. Nanbo, H. Nakajima, K. Mikami, 587. CaCI2-promoted aldol reaction of dimethylsilyl enolates in aqueous media. T. Nakagawa, K. Miura, A. Hosomi 588. Development and utilization of new dehydrating condensing agents. M. Kunishima, C. Kawachi, K. Terao, K. Hioki, S. Tani 589. Coupling reaction of nitroarenes with aminoarenes and one-pot procedure for preparation of aminodiphenylamine derivatives. Z. Li, J. Ma, Y. Mitoma, M. Tashiro 590. Chemoselective ligation of azides and phosphines. E. Saxon, C. Bertozzi 591. Synthesis of new pyranose analogs by the reaction in aqueous media. H. Takada, S. Okabe, M. Morimoto, H. Saimoto, Y. Shigemasa 592. Mannich-type aminomethylation with various amines. Y. Taruno, Y. Irisa, Y. Ogo, M. Morimoto, H. Saimoto, Y. Shigemasa 593. Rhodium-catalyzed enantioselective hydrogenation in water using water-soluble chiral ligands derived from natural sugars. K. Ohe, K. Yonehara, K. Mori, K. Morioka, S. Uemura 594. Oxygen transfer reaction of 4-acetylazoxybenzenes in sulfuric acid. J. Yamamoto, K. Hamanaka 595. Reaction of 1,3-dihydroxyacetone with a,a-unsaturated aldehydes or ketones in aqueous media. M. Hironobu, S. Okabe, M. Morimoto, H. Sakamoto, Y. Shigemasa 596. Synthesis of new retinoids having phenolic moiety. Y. Irisa, Y. Taruno, M. Minoru, H. Saimoto, Y. Okamoto, S. Minami, Y. Shigemasa 597. Facile and clean oxidation of alcohols and sulfides in water using the polymersupported hypervalent iodine(lll) reagent. H. Tohma, S. Takizawa, T. Maegawa, Y. Kita 598. Radical substitution reaction of metalladithiolene complex in aqueous media. T. Harada, Y. Yokoyama, Y. Murata, T. Sugiyama, M. Kajitani 599. Allylation of aldimine with allylstannane promoted by Broensted acid in aqueous media. Y. Onuma, H. Kagoshima, T. Akiyama 600. Reduction and reductive coupling of substituted aromatic compounds in aqueous media. T. Tsukinoki, G. B. Liu, T. Kanda, Y. Mitoma, S. Nagashima, M. Tashiro 601. Lewis acid catalysis by titanium, vandium, and boron halides in water. Y. Matsumoto, M. Koichi 602. Surfactant-aided Lewis acid catalysis in water using colloidal dispersions as reaction media. K. Manabe, Y. Mori, S. Kobayashi 603. New developments in Raschig process: Elaboration of strongly concentrated chloramine solutions. C. Duriche, M. Elkhatib, L. Peyrot, H. Delalu

4:05—629. Screw-sense selective polymerization of 1,2-diisocyanobenzenes catalyzed by chiral organopalladium(ll) complexes: Synthesis of helical poly(quinoxaline)s. Y. Ito, M. Suginome

SATURDAY AFTERNOON

Discovery and Development of Asymmetric Synthesis and Chiral Technology (065)

Hilton Hawaiian Village Tapa Ballroom II, Tapa Conference Center New Strategies to TransitionMetal-Catalyzed or Mediated Organic Synthesis (024)

H. Kurosawa, Presiding 1:05—624. Recent advances in catalytic C-H/olefin coupling. S. Murai, F. Kakiuchi, N. Chatani 1:45—625. Catalytic asymmetric C-H activation in organic synthesis. H. D. Madoc 2:25—626. Lactone formation via rhodiumcatalyzed CA-C bond cleavage of cyclobutanone. M. Murakami, T. Tsuruta, Y. Ito 3:05—627. Activation and formation of C-C bonds. D. Milstein, Y. Ben-David, R. Cohen, M. Gandelman, A. Ohff, M. Ohff, B. Rybtchinski, M. Van der Boom, A. Vigalok, H. Weissman 3:45—628. Synthesis and utility of transitionmetal catalysts: A new class of N-substituted imidazolinylidene ligands. R. Batey, M. Shen

3:45—670. Efavirenz-practical asymmetric alkynylation reactions. R. Tillyer

Hilton Hawaiian Village Honolulu Suite I, Tapa Conference Center

Hilton Hawaiian Village Tapa Ballroom I, Tapa Conference Center

Organic Photochemistry (141)

Hilton Hawaiian Village Coral Ballroom I, Mid-Pacific Conference Center

New Developments in Heterocyclic Chemistry (066)

Natural Products of Chemistry: Biological Activity and Synthesis (042)

1:05—671. Thiopyran templates for stereoselective Diels-Alder and aldol reactions. D. Ward 1:45—672. Asymmetric synthesis based on Lewis acid/Lewis base cooperation. S. Kanemasa 2:25—673. New methods for the conversion of alkyl azides to heterocycles. J. Aube 3:05—674. The chemistry and biochemistry of ring-deactivated pyrroles. A. Abell 3:45—675. Nanomolecular architectures: Heteroaromatic self-assembly processes. G. Newkome, C. N. Moorefield

D. Uemura, Presiding 1:05—630. Synthesis of highly oxygenated natural products. S. Rychnovsky 1:40—631. Molecular recognition of membrane components by polyether toxins and polyenemacrolides. M. Murata, N. Matsumori, S. Matsuoka, K. Konoki 2:15—632. Anti-MRSA agents from Heterotheca inuloides. I. Kubo 2:30—633. Mutlivalent polymer of vancomycin: Enhanced antibacterial activity against VRE. H. Arimoto, K. Nishimura, M. Nishijima, T. Kinumi, D. Uemura 2:45—634. Laulimalide, the newest microtubule-stabilizing agent: Biological activities and synthetic approaches. B. S. Davidson, B. T. Messenger, G. T. Nadolski, A. Sivaramakrishnan 3:00—635. Taxezopidines J, K, and L: New taxoids from Taxus cuspidata inhibiting microtubule depolymerization. H. Shigemori, C. A. Sakurai, H. Hosoyama, J. Kobayashi 3:15—636. Chemical synthesis and functional study of bacterial lipopolysaccharides. S. Kusumoto, K. Fukase, M. Oikawa, Y. Suda 3:50—637. The cycloimines: A structurally diverse and expanding class of marine toxins. J. Wright Hilton Hawaiian Village Honolulu Suite III, Tapa Conference Center Organic and Combinatorial Chemistry on Solid Supports (052)

T. Takahashi, Presiding 1:05—638. Combinatorial synthesis of bioactive compounds using solution-phase and solid-phase. T. Takahashi 1:35—639. Preparation of new polymer supports for combinatorial synthesis and their applications in the synthesis of small organic libraries. Y-S. Lee, J. Cho, H. Park, S-Y. Lee, J-W. Byun, J-U. Kim 2:00—640. Development of J anda J el and its application in a multipolymer system for the synthesis of tertiary amines. P. H. Toy, K. D. Janda 2:25—641. New methods for the solidsupported synthesis of biologically active molecules: Applications to drug discovery. J. Nuss 2:50—642. Conotoxin libraries. P. Alewood 3:15—643. Protein secondary structure combinatorial libraries. M. Kahn 3:45—644. Solid-phase synthesis of unnatural amino acids utilizing Mizoroki-Heck reaction and asymmetric hydrogenation. T. Doi, N. Fujimoto, J. Watanabe, T. Takahashi 3:55—645. Withdrawn. Hilton Hawaiian Village Tapa Ballroom III, Tapa Conference Center

I. Shinkai, Presiding 1:05—664. Transmetalation reactions of alkenylzirconocenes: Synthetic applications. P. Wipf 1:45—665. Heterodimerization of olefins and acetylenes: New protocols and new control elements. T. V. Rajanbabu, N. Nomura, J. Jin, M. Nandi, H. Park, S. Greau 2:25—666. New hydroxyalkyl-bisoxazolinylpyridine ligands for rutheniumcatalyzed asymmetric cyclopropanation of styrene and diazoacetates. H. Nishiyama 3:05—667. Enantioselective synthesis of -alanine derivatives. C. Maryanoff 3:05—668. Chemistry of novel helicenes. M. Yamaguchi 3:25—669. 2-Methoxy-2-(1-naphthyl) propionic acid, a powerful chiral auxiliary for enantioresolution of alcohols and determination of their absolute configurations by the 1 H NMR anisotropy method. N. Harada, M. Watanabe, Y. Kasai, H. Taji, A. Sugio, S. Kuwahara, A. Ichikawa

M. Komatsu, Presiding

Hilton Hawaiian Village lolani Suite VII, 2nd Floor, Tapa Conference Center Molecular Oxygen and Organic Peroxides in Chemistry and Biology (122)

E. Clennan, Presiding 1:05—676. Singlet oxygene ene reactions: A theoretical odyssey inspired by C. S. Foote. K. N. Houk 1:45—677. Structure and reactivity of persulfoxide and related intermediates. Y. Sawaki, M. Hayashi, Y. Watanabe, K. Ishiguro 2:10—678. Selectivity in photosensitized oxidation of olefins within supramolecular systems. C-H. Tung 2:35—679. Addition of molecular oxygen to olefin and cyclopropane cation radicals: Factors controlling the regio- and stereochemistry. R. Akaba, M. Kamata 2:55—680. Singlet oxygen microscope. P. Ogilby 3:35—681. Processes competing in the sensitization of singlet oxygen by triplet states. R. Schmidt 4:00—682. Collision-induced spectra and reactivity of molecular oxygen. B. Minaev, A. Loboda Hilton Hawaiian Village lolani Suite l/lI, Tapa Conference Center Organic and Biological Electrochemistry: Fundamentals and Applications (133)

J. Lessard, Presiding 1:05—683. Electron-transfer kinetics for reconstituted and mutated myoglobins at an indium oxide electrode. I. Taniguchi 1:35—684. Syntheses and characterization of nonnatural redox proteins as electron transferring interface molecules. H. Shinohara, E. Yokota, T. Kusaka, M. Moriwake, S. Ishida, T. Hohsaka, M. Sisido 2:05—685. Thermodynamic regulation in short-chain Acyl-CoA dehydrogenases. M. Stankovich, J. Pellett, D. Becker 2:35—686. Photochemical reduction of NADP+ by reconstituted myoglobins. K. Nishiyama, M. Uchiyama, C. Li, Y. Mie, I. Taniguchi 3:05—687. Synthesis and electrochemical properties of coenzyme incorporating ferrocene unit. T. Kijima, T. Suzuki, T. Izumi 3:35—688. Fabrication of gold-platinum codeposited electrode and its characterization as a transducer of enzyme sensor. M. Someya, S. Toyama, R. Usami, K. Horikoshi, S. Yamauchi, Y. Ikariyama 3:55—689. Development of biosensors based on bilayer membranes with digital oscilloscope. K. Abe, M. Hirano, J. F. Rusling


H. Zimmerman, Presiding 1:05—691. Photochemistry of permethylated oligosilanes. J. Michl, H. A. Fogarty, M. K. Raymond, C-H. Ottosson 1:40—692. Conformational analysis of singlet-triplet state mixing in organic diradicals: Parameterization of spin-orbit coupling. A. Kutateladze 2:15—693. Recent advances in organic photochemistry: Mechanistic and exploratory organic photochemistry. H. Zimmerman, I. Alabugin, V. Cirkva, E. Nesterov, V. Smolenskaya 2:50—694. Novel photochemistry of saccharine-derived sultams. D. Dopp 3:25—695. Synthetic methods based on organic photochemistry. P. Mariano 4:00—696. Structures and reactions of carbenes studied by ab initio calculations, matrix isolation spectroscopy, and laser flash photolysis. H. Tomioka Hilton Hawaiian Village Coral Ballroom IV, Mid-Pacific Conference Center Phase-Transfer Catalysis (060) Poster Session 1:00-3:00 647. N-alkylation of 2-mercaptobenzimidazole derivatives under phase-transfer catalytic conditions. M-L. Wang, W-W. Chen 648. Azacrown ethers that possess the glucose moiety and their catalytic properties for the asymmetric phase-transfer catalyst. S. Shirakami, T. Itoh 649. Synthesis of polymer-immobilized heteropoly acids a PTC complex and its catalytic activity. T. lizawa, T. Asai 650. Multiphase catalytic hydrodechlorination as a useful tool for the detoxification of hazardous organic pollutants. S. Zinovyev, P. Tundo, S. Raccanelli, A. Perosa 651. Microemulsion phase formed in quaternary salt/oil/water/inorganic salt fourcomponent systems and its role in phasetransfer catalysis. N. Ohtani, Y. Hosoda, D. Tsuchimoto, T. Yamashita 652. Oxidation of sulfides to sulfoxides and sulfones with 30% hydrogen peroxide under organic solvent- and halogen-free conditions. K. Sato, M. Hyodo, M. Aoki, X-Q. Zheng, R. Noyori 653. Formation of salt-free ylids and active sulfur by using TDA-1. K. Okuma 654. Asymmetric a-alkylation of amino esters and peptides using chiral pyridoxal model compounds having anionophore function. H. Iwaki, K. Miyashita, K. Tai, N. Sasaki, T. Imanishi 655. p-Replacement reaction of serine derivatives using pyridoxal model compounds having an ionophore function. K. Miyashita, H. Iwaki, H. Murafuji, N. Sasaki, T. Imanishi 656. Crown ether/carboxylic acid conjugates as new receptors for bifunctional amino acids. H. Tsukube, H. Fukui, Y. Mizutani, S. Shinoda 657. Chain-growth polycondensation in water-organic solvent system with phasetransfer catalyst. N. Hiyama, S. Hiraoka, T. Yokozawa 658. Julia-Colonna asymmetric epoxidation reaction of benzalacetophenone catalyzed by soluble oligo-L-leucines. T. Manabe, R. Takagi, S. Kojima, K. Ohkata 659. Syntheses and application of N{9)-{m or p)-benzyldicinchonidinium bromide. S-S. Jew, B-S. Jung, M. You, M-K. Park, D-H. Kim 660. Phase-transfer catalysis for tandem synthesis of bifunctional molecules for nonlinear optical applications. X-R. Bu, X. Li, J. Santos, E. A. Mintz, R. Mason 661. Asymmetric Michael reaction utilizing chiral quaternary ammonium salt under phase-transfer catalyzed conditions. K. Katayama, T. Shioiri, S. Arai 662. Development of asymmetric Darzens reaction utilizing phase-transfer catalyst. Y. Suzuki, T. Shioiri, S. Arai 663. Efficient in situ generation of quaternary ammonium fluorides under phase-transfer conditions: Application to catalytic asymmetric aldol reactions. K. Doda, T. Ooi, K. Maruoka


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Hilton Hawaiian Village Coral Ballroom IV, Mid-Pacific Conference Center Cycloaddition and Annulation Strategies (144) Poster Session

4:00-6:00 697. Recent advance in the development of hetero Diels-Alder reactions for efficient synthesis of purine analogs. Q. Dang 698. Synthesis of optically active cyclobutane derivatives through 2+2 cycloaddition reaction of styrene derivatives using a Fe(lII) salt catalyst. H. Ohara, T. Itoh, M. Nakamura, E. Nakamura 699. Diels-Alder strategies for the synthesis of hapalindole alkaloids. M. Kerr, M. Brown, A. Kinsman 700. Stereoselective olefination of ketones via opening of (3-lactone enolates derived from ynolates. M. Shindo, Y. Sato, K. Shishido 701. Novel synthesis of 2-naphthols via ynolates. Y. Sato, M. Shindo, K. Shishido 702. Intramolecular Diels-Alder strategy for the synthesis of fungal metabolites with HIV-1 integrase. K. Shishido, K. Yuki. N. Satoyoshi, M. Shindo 703. Acid-catalyzed annulation of vinylsilanes bearing a hydroxy group with aldehydes. T. Takahashi, K. Miura, A. Hosomi 704. Photochemical generation of oquinodimethanes from o-functionalized benzyltrialkylstannanes. H. Sano, D. Asanuma, M. Kumagai, M. Kosugi 705. Withdrawn. 706. [3+2] and [2+2] cycloaddition of allyslilane with carbonyl compounds: Stereoselective synthesis of tetrahydrofurans and oxetanes. K. Shibuya, M. Yamanaka, H. Kagoshima, T. Akiyama 707. Intramolecular rearrangement of the [(allyloxy)silyl]lithiums: [2,3]Sila-Wittig rearrangement and cyclopropanation reaction. A. Kawachi, H. Maeda, H. Nakamura, K. Tamao 708. Diastereoselective synthesis of sevenmembered cyclic enol ether derivatives by tandem Michael-Wittig reactions. T. Nagao, T. Ichihashi, T. Suenaga, T. Fujimoto, I. Yamamoto, A. Kakehi, R. Iriye 709. Thermal cycloaddition reaction of /V-allenyl sulfonamide toward alkenes. Y. Horino, Y. Ohharra, Y. Tamaru 710. Synthesis using S-ethenylsulfilimines: The construction of N.O-N.S-, and N,Ndihetero-five-membered rings onto heterorings. S-l. Hata, K. Ikeda, T. Takahashi, T. Yamamoto 711. New reactants for Diels-Alder cycloadditions via retrocycloadditions of substituted 1,3-dioxins. R. Funk, R. Aungst, J. Fuchs, J-H. Maeng 712. Synthesis of spirol[4.5]decane ring system by spiroannulation of 2-(trimethylsilylmethyl) pentadienal. C. Kuroda, H. Koshio 713. Photocycloaddition of styrene derivatives to crownophanes. S. Inokuma, J. Nishimura 714. Synthetic approaches to fasicularin and FR901483 via novel amidoacrolein cycloaddition reactions. L. R. Funk, J-H. Maeng 715. Kinetic approach to the ring construction from S-ethenylsulfilimines (ESI) and diprotic nucleophiles (DPN). K. Ikeda, N. Utatsu, S-l. Hata, Y. Nakamura, T. Yamamoto Hilton Hawaiian Village Coral Ballroom IV, Mid-Pacific Conference Center Bioorganic Reaction Mechanisms (163) Poster Session 4:00-6:00 716. Origin of the a-effect: Dissection of ground state and transition state contributions. I-H. Urn 717. Oxypeptide nucleic acid: A novel peptide nucleic acid that shows high sequence specificity and all-or-none-type hybridization. M. Kuwahara, M. Arimitsu, M. Shigeyasu, M. Sisido 718. A chiral europium(lll)-TTA complex on an avidin tetramer. M. Taki, M. Sisido 719. Model studies on the mechanism of reductive acetylation in pyruvate dehydrogenase complex. K. Okada, M. Tazaki

134


720. Kinetic characterization of a mettalo-|3lactamase from A. sobria. R. Mosi, C. Bailey, S. Idzan, M. Johnston, R. Wong, T. Walsh, S. Fricker 721. Enantioselective separation of anethol bromohydrin and hydration of anethole epoxide by microsomes. T. Ishida, J. Caldwell, S. Ninomiya 722. Mechanism for p-galacotsidase catalyzed hydrolysis of aryl 2-deoxy-|3-Dgalactopyranosides. J. P. Richard, M. Toteva, C. Heo 723. Fluorine-tagged thia-fatty acids: Versatile mechanistic probes for desaturasemediated reactions. D. Hodgson, P. Buist, B. Dawson Hilton Hawaiian Village Coral Ballroom III, Mid-Pacific Conference Center Organic Chemistry General Session (09G-P1) Poster Session 1:00-3:00 724. Synthesis of carboxylic acids over solid super acid, sulfated zirconia. H. Mori, Q. Xu, Y. Souma, A. Mori 725. A highly diastereoselective birchreduction alkylation reaction of functionalized benzopyranones. D. A. Gao, A. G. Schultz 726. Tandam radical addition to nitrogen heterocycles. J. Byers, J. Kosterlitz, P. Steinberg 727. Catalytic enantioselective reaction using a disulfonamide derived from cc-amino acid. N. Imai 728. Kinetics for esterification of aliphatic dicarboxylates via solid-liquid phasetransfer catalysis. H-M. Yant, P-l. Wu 729. Transition-metal-catalyzed olefination. H. Lebel, V. Paquet 730. Oxymercuration of unsymmetrically substituted norbornenes: A remarkable remote substituent effect. W. Tarn, P. Mayo 731. Intramolecular 1,3-dipolar cycloadditions of norbornadiene-tethered nitrile oxides. W. Tarn, C. Yip 732. Intramolecular 1,3-dipolar cycloadditions of norbornadiene-tethered nitrones. W. Tarn, G. Tranmer 733. DIBAL catalyzed reactions of p-hydroxybenzyl alcohols via a benzoquinone methide. W. Baik, S-J. Kim, H-J. Lee 734. Tandem aldol reaction-radical cyclization sequence of ethyl acetoacetate and cyclohexene-1-carboxaldehyde. S. Koo, J-D. Yang, M-S. Kim, M. Lee 735. Stereochemical behaviors of cyclopropyl a-sulfonyl carbanions. K. Higashi, R. Tanikaga, K. Ishikawa 736. Preparation and reaction of 1,3bis(alkylthio) allenes and tetrathiacyclic bisallenes. N. Kamigata, K. Sakamaki, D. Miyasaka, T. Shimizu 737. One-pot synthesis using supported reagents system: Synthesis of 2-aminothiazoles from oc-bromoketones using KSCN/Si02-amine salt/AI203. T. Aoyama, M. Kodomari, Y. Suzuki 738. Reactions of 1,2-dithiete with unsaturated compounds. T. Shimizu, H. Murakami, N. Kamigata 739. Direct preparation of vinyl halides from ketones and acetyl halides in the presence of silica-gel-supported zinc chloride. M. Kodomari, T. Nagaoka, Y. Furusawa 740. Alkylations and intramolecular cyclizations of electron-deficient aromatics via photostimulated oxidative free-radical chain reactions. I. Jeon, B-H. Kim, B-M. Kim, H-J. Park, Y-M. Jun 741. Stereoselective reduction of a-bromopenicillanates by tributylphosphine. A. Ishiwata, L. Kotra, K. Miyashita, T. Nagase, S. Mobashery 742. Homologation of oxo-steroids with a combination of trimethylsilyldiazomethane and boron trifluoride etherate. S. Hiranuma, H. Seto, S. Fujioka, H. Koshino, T. Shimizu, S. Yoshida 743. A convenient method for the preparation of furans by the phosphine-intiated reactions of enynes bearing a carbonyl group. H. Kuroda 744. Exploring the scope of an antibodycatalyzed asymmetric 1,3-dipolar cycloaddition reaction. J. D. Toker, P. Wentworth Jr., K. D. Janda

745. Application of solid supported liquidliquid extraction (SLE): Purification of a library of substituted 3,6-diaminopyridazine-4-carboxamides from acidic, basic, and water-soluble impurities. B. Zhang, C. Johnson 746. Tridentate chelation-controlled asymmetric synthesis of 1,2-diol. H. D. Kim, Y-K. Kim 747. Competing chelation modes in the palladium-catalyzed enantioselective allylic alkylation with new hybrid ligands. Y-K. Kim, K-H. Ahn 748. New methods for [2,3]-Wittig rearrangement mediated by samarium diiodide. K. Hioki, D. Nakata, S. Tani, M. Kunishima 749. Development of new processes for the use of organometallic reactants with only catalytic quantities of the metal. R. E. Maleczka, Jr. 750. Nucleophilic addition of amines to the 4and 5-position of imidazole nucleus. T. Osaki, S. Ohta, I. Kawasaki 751. Catalytic oxidation of ketones to a, (3unsaturated ketones by cyclophepta[/?]pyrimido[5,4-Gf]pyrrole-8(6H),10(9H)diones. Y. Tajima, M. Nitta 752. Synthesis of terpenyl-p-d-maltosides with Koenigs-Knorrfs procedure using silver carbonate supported on silica gel. R. Atsumi, T. Miyakoshi 753. Diphenylammonium triflate (DPAT): Efficient catalyst for esterification of carboxylic acids and for transesterification of esters with nearly equimolar amounts of alcohols. K. Wagasugi, Y. Tanabe, T. Misaki, K. Yamada 754. Activation mechanism with regard to the preparation of activated carbon from phenolic fiber by alkali. K. Kurakane, K. Onoe, Y. Takiguchi, S. Kobayashi, T. Yamaguchi 755. Regioselectivity of the anionic [1,3] rearrangement of an 8-methylenebicyclo[3.2.1] oct-6-en-2-ol and attempts to prepare both [5-6] and [5-5] fused-ring compounds selectively. Y. Ogawa, T. Inayama, E. Tayama, M. Ueno, T. Sato, T. Uyehara 756. Synthesis of silyl ether and silyl enol ethers utilizing 2-methyl-1-phenyl-1silacyclopentane. H. Ueno, Y. Nagao, K. Kozawa 757. Reaction of 4-bis(2',6'-dimethoxyphenyl) methylene-2,5-cyclohexadienone with organolithiums. T. Mukoudani, M. Asahara, T. Enabi, M. Wada 758. Efficient method for the silylation of alcohols using silazanes/cat. pyridinium trifrate. T. Misaki, M. Kurihara, A. Nakamura, Y. Tanabe 759. Effective method for direct and powerful cross aldol addition using TiC14/Bu3N/cat. TMSCI. N. Matsumoto, T. Higashi, Y. Tanabe 760. Specific decarbonylative a,a-diarylation of a-alkoxycarboxylic acids in P205-MsOH and related acidic media. T. Hino, N. Yonezawa, T. Ikeda 761. Stille cross coupling approached to P lactams. K. Wells, M. Jensen, C. Yang, Y. Hsiao, N. Rivera, J. Chung, N. Yasuda, D. Hughes, P. Reider 763. Encoded split and pool polyamine libraries: Synthesis and applications. S. Manku, F. Wang, D. G. Hall 764. Stereoconvergent preparation of each stereoisomer of hydroxydiquinanes based on the anionic [1,3] rearrangement of bicyclo[3.2.1]oct-6-en-2-ols and the tandem anionic [1,3]-oxy-Cope rearrangement. H. Hashimoto, K. Seki, M. Ueno, T. Sato, T. Uyehara 765. Preparation and synthetic application of functionalized gfem-dimetallic species via addition of metal enolates to vinylmetals. K. Hara, T. Hatakeyama, M. Nakamura, E. Nakamura 766. Generation and reactions of 9-silaphenanthrene derivative. M. lida, M. Oba, K. Nishiyama


767. Additive effect on photoallylation of electron-deficient alkenes by use of allylic silanes via photoinduced electron transfer. T. Hayamizu, M. Ikeda, H. Maeda, K. Mizuno 768. Indirect electro-oxidation of anthracene to anthraquinone in the presence of double redox mediators in a two-phase system. M-L. Tsai 769. Intra- and intermolecular transesterification of phosphoesters by metal-ion complexes. S-l. Kondo, T. Yamamoto, Y. Yano 770. Synthesis of indeno[2,3-fc]thiophenes and acenaphtho[1,2-fc]thiophenes by domino thermal radical cycloaromatization of nonconjugated thienotetrayne and -hexayne. H. Inai, K. Miyawaki, T. Kawano, I. Ueda 771. Design, synthesis, and metal ioninduced self-assembly of functionalized 1,3-bis((2-pyridyl)ethynyl)benzene ligands. T. Kawano, C-X. Du, I. Ueda 772. Solvolyses of p-arylethyl esters having strong electron withdrawing groups at aand/or p-positions. M. Okamura, Y. Umezawa, S. Tsuboya, S. Usui 773. Bis(benzo[/?]fluorene) derivatives: First synthesis and inclusion properties of 6,6'bis(5-phenylbenzo[b]fluoren-5-ol) derivatives. F. Ueno, J. Ueno, M. Nishikawa, M. Suehiro, T. Kawano, I. Ueda 774. Bis(benzo[b]fluorene) derivatives: First synthesis of 11,11'-bis(benzo[b]fluorene) derivatives. M. Nishikawa, F. Ueno, K. Miyawaki, T. Kawano, I. Ueda 775. Dimerization of alkyl-1,2-benzoquinones via quinone methides. H. Iwamoto, A. Takuwa 776. Novel diastereoselective synthesis of 2-amino-1,3-diol derivatives from serine. T. Murakami 777. Lewis acid-catalyzed allylation of ketimines with tetraallylstannanes. N. Sasamoto, T. Nogami, K. Sato, Y. Chounan 778. Syntheses of thioglycosides and 1 -thioglucose by decomposition of a thioiminium salt prepared from acetobromoglucose and thioamides. T. Takido, M. Seno, T. Fujihira, J. Otsuki, H. Kamijoh 779. Asymmetric synthesis of tertiary alcohols from allylpyrrolidine-/V-oxide via [2,3]sigmatropic rearrangement. K. Honda, N. Osawa, S. Inoue 780. Electrophilic chemistry of aminoalcohols, amino-acetal, and amino-ketals. G. Sanchez, Jr., D. Klumpp, S. De Leon, M. Garza 781. Electrophilic chemistry of croconic acid and squaric acid. S. J. De Leon, D. A. Klumpp, M. E. Garza, G. K. S. Prakash, G. A. Olah 782. New synthetic method for 4-hydroxy-2pyridones via a retro-ene reaction. A. Arai, K. Ito, S. Miyajima 783. Synthesis of (5S)-tricyclic penems. E. Hu, N. Kim 784. Photochemical reactions of an isolable dialkylsilylene. S. Ishida, T. Iwamoto, M. Kira 785. Synthesis of the c/d open-ring macrocyclic analog of ergot alkaloids via a key intramolecular Heck reaction. V. Snieckus, B. Chauder, A. Kalinin 786. Hydrosilation of perfluoroolefins by homogeneous catalysts in dense carbon dioxide. J-C. Choi, L-N. He, T. Sakakura 787. Olefin metathesis in the synthesis of C-linked disaccharides as glycosidase inhibitors. C-C. Lin, G-T. Fan, T. Subramanian, T-S. Hus 788. Facile method for the preparation of secondary amines using novel titanium(IV) isopropoxide and sodium borohydride reagent system. H. Kumpaty, S. Bhattacharyya 789. Selective hydrogenation of benzophenones to benzohydrols: Asymmetric synthesis of unsymmetrical diarylmethanols. M. Koizumi, T. Ohkuma, R. Noyori 790. A chiral propionaldehyde homoenolate equivalent which reacts with imines with excellent stereoselectivity: Efficient and practical synthesis of optically active y-amino carbonyl compounds. S. Okamoto, T. Xin, S. Fujii, F. Sato 791. Structural analysis of complexes related to asymmetric hydrogenation of (2)-methyl a-(acetamido)cinnamate using Ru(CH 3 COO)2(binap). M. Tsukamoto, M. Kitamura, Y. Bessho, R. Noyori 792. Enchancement of the glycosidation reactivity of 1-O-acyl sugars BF3YOEt2. T. Yamanoi, K. Mizuno, Y. Iwai, T. Inazu

793. Novel phase-transfer catalysis of cascade gem-dichloroaziridines reaction. R. Kostikov, A. Khlebnikov 794. Kinetics and mechanism for the benzylation of (Y)-substituted pyridines in acetonitrile and DMF. J-H. Byun, S-H. Yeo, S-D. Yoh 795. Migratory aptitude of silicon in the reaction of acylsilanes with sulfur ylides and a-sulfinyl carbanions: Control of product's selectivity and formation of regio-defined enolsilanes. M. Okada, M. Honda, M. Segi, T. Nakajima 796. Selective acid-catalyzed rearrangement of cyclopropylacylsilanes and related compounds. M. Honda, T. Nishizawa, M. Segi, T. Nakajima 797. Synthesis of polyfunctionalized compounds utilizing hydrozirconation of 1-alkynes having a phenylseleno group. Y. Nishino, I. Yokoe, M. Suzuki, M. Segi, T. Nakajima 798. Asymmetric Baeyer-Villiger oxidation with hydrogen peroxide using a planarchiral bisflavin perchlorate catalysts. S. Ono, Y. Imada, S-l. Murahashi 799. Asymmetric oxidation of alkanes and alkenes using novel manganese complexes bearing chiral binaphthyl unit. S. Noji, N. Komiya, S-l. Murahashi 800. Acid-catalyzed cycloaromatization of enediyne model compounds via enyneallene intermediate. A. Shigenaga, I. Suzuki, H. Nemoto, M. Shibuya 801. Organic synthesis in solid media without solvent: Silica-gel-mediated allylation and olefination of aldehydes. Y-Z. Jin, J. Inanaga 802. A novel catalytic role of molecular iodine in the oxidation of benzylic alcohols: Microwave-assisted reaction. B. Banik, C. Mukhopadhyay, F. Becker 803. Practical asymmetric synthesis of substituted 1-phenylalkylamines: A kinetic and thermodynamic controlled hydrogenation process. H-Y. Li, P. Ma, G. Wilkie, L. He, L. Anzalone, P. Sheeran, R. Watemire, P. Confalone 804. Synthesis of optically active phenylglycine derivatives from Ss-(+)-/V(benzylidene)-p-toluenesulfonamide by using Lewis acids and fert-amines. H. Moriguchi, R. Ma, I. Suzuki, H. Nemoto, M. Shibuya 805. Catalytic asymmetric intramolecular hetero Diels-Alder reactions of methyl (£)-4methoxy-2-oxo-butenoate with unsaturated alcohols. H. Koga, E. Wada 806. Exclusive 1,4-aryl migration in the aminyl radical cyclizations. H. Hasegawa, H. Senboku, K. Orito, M. Tokuda 807. Stereoselective electrochemical carboxylation of vinyl bromides by the use of nickel catalyst. C. Kuang, H. Senboku, M. Tokuda 808. Cross-coupling reactions by the use of highly reactive electrogenerated zinc. A. A. Jalil, N. Kurono, S. Takasugi, M. Tokuda 809. Highly enantioselective synthesis of cyclopentenone using (S)-3-(p-tolysulfenyl)2-oxo-propylidene)triphenylphosphorane. M. Hatanaka, T. Kurata, H. Kitano, Y. Shinohara, K. Matsumoto 810. Thermal intramolecular cycloaddition of 5-alkenylfulvenes. M. Hatanaka, Y. Takehara, M. Hattori, T. Morita, K. Matsumoto 811. Solid-state condensation dimerization of 1,3-dimethylthymine glycol. Y. Takao, Y. Hamaguchi, T. Ito, H. Hatta, S-l. Nishimoto 812. Stereoselective synthesis of a-glucosides and p-mannosides via temporary molecular tethering. C. M. P. Seward, A. J. Fairbanks, I. Cumptsey, M. Aloui 813. Stereospecific synthesis of C-glycosides via Tebbe methylation and Claisen rearrangement. H. Y. Godage, A. Fairbanks 814. New insight into the Darzens condensation. V. Mamedov, H. Hamamoto, I. Z. Nukhametova, E. A. Gorbunova, S. Tsuboi 815. Convenient synthesis of y-hydroxy-a,(3unsaturated esters from brominated (3-ketoesters. Y. Shiomi, A. Watanabe, H. Yamashita, N. Hayashi, S. Tsuboi 816. Synthesis of new C2-symmetric chiralbridged biferrocenes. V. Snieckus, H. Szillat 817. Utilization of c f d 1 (CC13F) for the synthesis of propargyl alcohols, fluoromethyl phenyl sulfone, and florfenicol. K. Hashimoto, K. Kataoka, A. K. Saikia, S. Tsuboi

818. Anionic Friedel-Crafts equivalents: Synthesis dibenzazepinones, dibenzoxepinones, dibenzothiopinones, and dibenzophosphorinones by directed remote and lateral metalation reactions. V. Snieckus, S. Macneil, W. Familoni, P. Moreau, B. Wilson 819. Efficient synthetic methods using organoselenium reagents. K-l. Fujita, T. Hideo, O. Akihiro, I. Yoshikazu, T. Yoichi 820. 3-aza-Cope rearrangement of quaternary n-ally enammonium salts: Stereospecific 1,3-allyl migration from nitrogen to carbon on a tricyclic template. B. Maryanoff, D. McComsey 821. A new synthesis of benzoindolizine derivatives. R. Fujita, W. Noriyuki, T. Hiroshi 822. Experimental evidence of the intervention of oxetane in the ketene-olefin cycloaddition. J. Takachi, T. Machiguchi 823. Preparation and exploitation of a new chiral cyclopentenol chiral building block. H. Tanaka, K. Ogasawara, N. Yoshida, H. Sakagami, T. Kamikubo 824. Preparation of cyclopentenoid chiral building blocks employing asymmetric hydrogen transfer reaction. R. M. Kanada, K. Ogasawara, T. Taniguchi 825. Preparation and exploitation of polyoxygenated cyclopentanoid chiral building blocks. T. Unno, K. Ogasawara, T. Taniguchi, M. Takahashi, R. Muto, H. Nakashima, K. Tanaka, M. Sato 826. Preparation and exploitation of isolevoglucoseone-type building block. K. Kadota, K. Ogasawara, T. Taniguchi, M. Takeuchi, A. S. Elazab, K. Kurusu 827. Enantioselective synthesis of a-hydroxyphosphorus compounds through addition of phosphorus nucleophiles to aldehydes catalyzed by chiral metal alkoxides. T. Yamagishi, S. Shibuya, T. Yokomatsu, K. Suemune 828. Synthesis of spirocyclic p-methylene-ylactone via hydroxymethylation of functionalized allysilane. K. Akiyama, C. Kuroda, T. Kunishima, T. Amemiya 829. Novel, elongated phosphoranes by C-C bond formation. K. Umeno, D. Ohira, E. Inohae, K. Arima, S. Mataka, T. Thiemann 830. Electrochemical fluorination of piperazine derivatives having a methoxycarbonyl alkyl group. T. Abe, H. Baba, I. Soloshonok 831. Carbonylation of alcohols by Nation and a [Ag(CO)]+/Nafion catalyst. N. Tsumori, H. Mori, Y. Souma 832. Alkylation of aziridinylmagnesiums catalyzed by Cu(l) iodide and a synthesis of amines. R. Matsue, T. Satoh 833. A new synthesis of alkenes and allenes by sulfoxide-metal exchange. N. Hanaki, T. Satoh 834. Synthesis of carbonyl disulfides of new class. F. Kiyoko Hilton Hawaiian Village Coral Ballroom I, Mid-Pacific Conference Center Natural Products of Chemistry: Biological Activity and Synthesis (042)

D. Uemura, Presiding 1:05—1052. Synthetic studies of ravidomycin. K. Suzuki 1:40—1053. Chemistry, biology, and medicine of natural and designed molecules. K. C. Nicolaou 2:15—1054. Highly diastereoselective synthesis of trans-syn-cis tricycles via the tandem oxy-cope/ene reaction. L. Barriault, J. Warrington 2:30—1055. Total synthesis of reveromycin A. T. Shimizu, T. Nakata 2:45—1056. Progress toward the total synthesis of zaragozic acid A: Use of a template-directed C-H bond insertion strategy for the preparation of the 2,8dioxabicyclo[3.2.1]octane core. D. Wardrop, A-l. Velter, R. E. Forslund 3:00—1057. New convergent approaches to the synthesis of natural frans-fused polycyclic ethers. K. Fujiwara, D. Takaoka, K. Kusumi, H. Morishita, K. Kawai, K. Saka, A. Murai 3:15—1058. Synthesis and bioorganic chemistry of natural products. M. Isobe 3:50—1059. Toward the synthesis of the novel marine toxin azaspiracid. C. Forsyth, J. Aiguade-Bosch, A. Dounay, J. Hao

Hilton Hawaiian Village Tapa Ballroom III, Tapa Conference Center Discovery and Development of Asymmetric Synthesis and Chiral Technology (065)

M. Martinelli, Presiding 1:05—1060. New P-chirogenic diphosphine ligands and their use in catalytic asymmetric reactions. T. Imamoto 1:45—1061. Mechanism of asymmetric hydrogenation of a-(acylamino)acrylic esters catalyzed by BINAP-ruthenium(ll) diacetate. M. Kitamura 2:25—1062. Asymmetric hydrogenation and its application. T. Miura 3:45—1064. Asymmetric catalysis with chiral ruthenium complexes having a multifunction. T. Ikariya Hilton Hawaiian Village Tapa I, Tapa Conference Center New Developments in Heterocyclic Chemistry (066)

M. Komatsu, Presiding 1:05—1065. A new look at pyridinium salt photochemistry. P. Mariano 1:45—1066. New developments in chemistry of 1-oxides and 1,1-dioxides of thiophenes and selenophenes and related compounds. J. Nakayama 2:25—1067. Recent studies on organic reactions mediated by tetrasulfur tetranitride (S4N4) and its antimony(V) chloride complex (SN4aSbCI5). K. Kim, K. Y. Cheol 3:05—1068. Progress toward syntheses of several welwitindolinone alkaloids. J. Wood, M. W. Weiss, A. A. Holubec, M. Inoue, K. Tamaki, T. Ovaska 3:45—1069. Stereoselective construction on symmetric heterocyclic scaffolds: Synthesis of alkaloids and carbohydrates via enantioselective deprotonation of ketones. M. Majewski Hilton Hawaiian Village lolani l/lI Organic and Biological Electrochemistry: Fundamentals and Applications (133)

J. Lessard, Presiding 1:05—1109. Regioselective anodic fluorination of sulfides having chiral auxiliaries. T. Fuchigami, T. Maeda, H. Ishii 1:35—1110. Intermolelcular C-C bond formation by the electrochemical oxidation of sulfides. S. Kim, Y. Kitano, M. Tada, K. Chiba 1:55—1111. Reaction of Grinard reagents to electrogenerated iminium cation pool. M. Okajima, S. Suga, J-l. Yoshida 2:15—1112. Paired electro-oxidative decarboxylation of D-gluconic acid to D-arabinose. C-F. Chou, C-C. Yang, T-C. Chou 2:35—1113. Polypyrrole modified carbon fiber flow cell system. A. Konno, K. Inoue 3:05—1114. Electrochemical synthesis of polystannanes and their related polymers with linear and network structures. M. Okano, K. Watanabe, H. Fukai 3:35—1115. Electrochemical syntheses of pyridinium-conjugated assembly based on nucleophilic substitution to aryl cation radicals. Y. Li, K. Kamata, J. Abe, T. lyoda 3:55—1116. Quinone-quinol equibilibria in solutions of 2-(b-hydroxyenthyl) amino1,4-benzoquinones: Spectrophotometry and polarographic study. P. Zuman, H. Berg Hilton Hawaiian Village Coral Ballroom IV, Mid-Pacific Conference Center Transition-Metal-Facilitated Reactions Leading to Organic Heterocycles (182) Poster Session

4:00-6:00 1124. Novel [3+2] cycloaddition reactions of alkenyl Fischer carbene complexes with imines. H. Kagoshima, T. Akiyama

1125. Azomethine imines resulting from rhodium-induced intramolecular interactions of diazene nitrogen atoms diazoketone-derived carbenoids or carbenes. J. G. Schantl, A. S. Rettenbacher 1126. Intramolecular cyclization of orthofunctionalized allylbenzenes catalyzed by ruthenium complex. T. Ohta, K. Hori, H. Kitagawa, A. Miyoshi, Y. Kataoka, I. Furukawa 1127. Enantioselective synthesis of (3-amino acids from secondary amines. Addition of ketene silyl acetals to nitrones catalyzed by chiral titanium complexes bearing BINOL and phenols. Y. Yonemushi, T. Kawakami, K. Harada, Y. Imada, S-l. Murashashi 1128. Highly enantioselective palladiumcatalyzed ene-type cyclization of 1.6enhynes. M. Hatano, T. Masahiro, M. Koichi 1129. Acylhydrazones for the synthesis of nitrogen-containing compounds. R. Hirabayashhi, S. Kobayashi 1130. Carbonylative [5+1] cycloaddition of cyclopropyl imines with carbon monoxide catalyzed by ruthenium carbonyl. A. Kamitani, N. Chatani, T. Morimoto, S. Murai 1131. Ruthenium carbonyl-catalyzed intermolecular [2=2=1] cyclocoupling of imines, alkenes or alkynes, and carbon monoxide. M. Tobisu, N. Chatani, T. Asaumi, S. Murai 1132. Ruthenium carbonyl-catalyzed [2+2+1] cycloaddition of ketones, olelfins, and carbon monoxide, leading to functionalized Y^butyrolactones. T. Asaumi, N. Chatani, M. Tobisu, S. Murai 1133. Reations of a silylynolte with aziridines. K. Iwamoto, M. Kojima, N. Chatani, S. Murai Hilton Hawaiian Village lolani Suite V/VI, Tapa Conference Center Reactive Intermediates and Unusual Molecules (001) H. Tomioka,

Presiding

1:05—617. Ion radical reactions in polymeric media. J. Dinnocenzo, K. McManus, J. Gilmore, A. Peer, G. Dombrowski, T. Erdogan, S. Farid, D. Robello 1:30—841. Reactive organic species of relevance to the chemistry of interstellar space. R. McMahon 2:00—619. Preparation and reactivity of oxonium ylides in crystals. M. GarciaGaribay, H. Dang 2:30—620. Reaction of ethereal oxonium ylides derived from carbenes and carbenoids: From C-O to C-C bond formation. A. Oku, T. Mori, Y. Sawada 3:00—621. Bond-coupled electron-transfer reactions. J. Goodman 3:30—622. Structure and reactivity of isolable group 14 divalent species. M. Kira, S. Ishida, T. Iwamoto, C. Kabuto 4:00—623. Heteroatomic high-spin molecules: Preparation and exchange interactions. K. Okada

SUNDAY MORNING Hilton Hawaiian Village lolani Suite V/VI, Tapa Conference Center Reactive Intermediates and Unusual Molecules (001)

H. Tomioka, Presiding 8:05—835. Planner tetracoordinate carbon and related systems. L. Radom, R. Danne 8:30—618. (Mis-)adventures in radical cation chemistry. H. D. Roth 9:00—837. Synthesis, structure, and reactivity of the first stable silabenzene. N. Tokitoh 9:30—838. Tri-f-bu-triangulene: First nonkekule polynuclear hydrocarbon in the detection of the triplet ground state. K. Nakasuji, J. Inoue, T. Kubo, K. Yamamoto, Y. Morita, K. Fukui, K. Sato, D. Shiomi, T. Takui 10:00—839. The build-up of huge (non)altemant polycyclic aromatic hydrocarbons under high temperature conditions: The interplay between theory and experiment. L. Jenneskens, R. Havenith 10:30—840. m-Benzyne, p-benzyne, and other unusual aromatic radicals. W. Sanders, H. Wenk, A. Balster, M. Exner



135


11:00—836. Stable versions of transient push-pull carbenes. G. Bertrand Hilton Hawaiian Village Coral Ballroom I, Mid-Pacific Conference Center Natural Products of Chemistry: Biological Activity and Synthesis (042)

D. Uemura, Presiding 8:05—849. Total synthesis of penitrem d: A complex synthetic target. A. Smith III 8:40—850. Chemistry of biologically and physiologically intriguing phenomena. D. Uemura 9:15—851. Stereocontrolled syntheses of anfAp-aminoalcohols, (2S,3R)3-hydroxyproline, D-erythro-sphingosine, and phytosphingosine. S. Kang, Y. Hwang 9:30—852. Synthetic studies of ingenol: Synthesis of in,out-tricyclo[7.4 1.01,5]tetradecan-14-one. H. Kigoshi, Y. Suzuki, K. Aoki, D. Uemura 9:45—853. One-pot multistage transformations: A rapid entry into major groups of taxoids. A. Simeon 10:00—854. Stereoselective synthesis of trisubstituted alkenes: A new synthetic approach to the natural and unnatural retinoic acids. J. Uenishi, M. Katsuaki, F. Hiroki 10:15—855. Studies on a catalytic asymmetric synthesis of strychnine. M. Shibasaki 10:50—856. Chemistry-medicine continuum: New medicinal leads, new reactions, and new drug delivery systems. P. Wender Hilton Hawaiian Village Tapa Ballroom III, Tapa Conference Center Discovery and Development of Asymmetric Synthesis and Chiral Technology (065)

I. Shinkai, Presiding 8:35—857. Practical asymmetric synthesis of morphine alkaloids and pancratistatin: An update. T. Hudlicky 9:15—858. Using nature's catalysts: The chemoenzymatic synthesis of bioactive molecules. C. Johnson 9:35—859. New strategies for the enantioselective synthesis of nitrogen heterocycles. G. Sulikowski 9:55—860. Asymmetric synthesis for sepracor's ICEs. C. Senanayake 10:35—861. Efficient enantioselective synthesis of MMP inhibitor ABT-770. S. Wittenberger, A. Bailey, D. Hill, C-N. Hsiao, R. Kurukulasuriya 10:55—862. Asymmetric autocatalysis and origin of chirality of an organic compound. K. Soai Hilton Hawaiian Village Tapa Ballroom I, Tapa Conference Center New Developments in Heterocyclic Chemistry (066)

M. Komatsu, Presiding 8:35—863. New stereoselective methods for heterocyclic compounds. A. Charette 9:15—864. Chameleonic reactivity of allenes toward cycloaddition reactions. Y. Tamaru 9:55—865. New synthetic methods for medium-sized heterocycles. J-K. Cha 10:35—866.1,4-Silatropic strategy for generation of 1,3-dipoles. M. Komatsu 11:15—867. Recent investigations into the chemistry of reduced 1,1'-bisisoquinolines. R. Read, Z. Judeh Hilton Hawaiian Village lolani Suite l/lI, Tapa Conference Center Organic and Biological Electrochemistry: Fundamentals and Applications (133)

J. Lessard, Presiding 8:05—868. Understanding coupled electrontransfer and spin-exchange reactions. F. Schultz, J. Turner 8:35—869. 2x2 Square scheme and redoxdriven ligand exchange in cytochrome c. B. Feinberg, S. Tuanh, M. Ryan 9:05—870. New studies in electron transfer/ structure relationships. W. Geiger 9:35—871. Nucleophilic cyclopentadienylring alkylation after an electron-transfer chain catalysis. L. Liu, L-S. Luh, J. Peng 10:05—872. Electrochemical investigation of derealization in the system C=N-N=C. P. Zuman, J. Ludvik 10:35—873. Fates of electrogenerated radicals in the presence of nitric oxide (NO). D. Peters, C. Ji

136


11:05—874. Electrochemical and chemical generation of aziridines from imines. A. Fry, M. Biscoe Hilton Hawaiian Village Honolulu Suite I, Tapa Conference Center Organic Photochemistry (141)

H. Zimmerman, Presiding 8:35—875. Enantioselective photosynthesis in inclusion complex crystals with a chiral host compound. F. Toda 9:10—876. Maximization of chemiluminescence efficiency of lophine series. M. Kimura 9:45—877. Photoinduced heterolytic bond cleavages. P. Wan 10:20—878. Well-known photoreactions: New perspectives for synthetic applications. J-P. Pete 10:55—879. Potential energy surfaces for photoisomerization reactions of aryl olefins. F. Lewis, R. Kalgutkar, W. Wiegel, W. Liu, X. Zuo 11:30—880. Recent developments in solidstate organic photochemistry: Novel reactions and structure-reactivity relationships. J. R. Scheffer Hilton Hawaiian Village lolani Suite VII, 2nd Floor, Tapa Conference Center Boundary Between Long Bond and Short Nonbonds (208)

J. Siegel, Presiding 8:05—881. X-ray structural analyses on 1,1diarylbenzocycloalkene-2,2-dinitriles and the related compounds. T. Suzuki, K. Ono, T. Tsuji 8:20—882. Molecular structures of 9-benzhydryl and 9-trityltriptycenes as structural analogs of penta- and hexaphenylethanes. S. Toyota, T. Shimasaki 8:35—883. Extremely long C-C bonds in naphthocyclobutene and benzodicyclobutadienes. F. Toda 9:10—884. Steric compression and liberation. R. Pascal 9:45—885. Hydridic-to-protonic hydrogen bonds as determinants of structure and reactivity. J. Jackson, R. Custelcean, S. Gatling 10:20—886. Interactions of titanium group metals with saturated carbon atoms. R. Ernst 10:55—887. Oligonuclear metal string complexes: The potential application for molecular metalwires. S-M. Peng, C-C. Wang, C-Y. Mou, C-H. Chen Hilton Hawaiian Village Rainbow III Organic Chemistry General Session (09G-03)

M-J. Wu, Presiding 8:05—889. Enantioselectivity during Michael additions of allyl sulfone carbanions. Stereoselective synthesis of 5-membered rings. A. Hassner, E. Ghera, T. Ychezkel, R. Kumareswaran 8:25—890. Enantioselective Yang photocyclization in the solid-state and the competition between p- and y-hydrogen abstraction. T. Kang, E. Cheung, J. Scheffer, J. Trotter 8:45—891. Synthesis of new synthons for organofluorine compounds from halothane containing sulfur functional groups II. I. Kumadaki, M. Kato, K. Sata, M. Omote, A. Ando 9:05—987. Alkynyliodonium salts in organic synthesis. K. Feldman, K. Masters, M. Laci, J. Saunders, R. Di Florio 9:25—988. Catalytic oxidative carbonylation of amines to ureas. A. D. Main, F. Qian, J. E. Mccusker 9:45—989. Mixed alkali metal alkoxide/ phenoxide clusters. R. Kissling, V. Gagne 10:05—990. Anionic cycloaromatization of enediynes and related molecules initiated by methoxide addition. M-J. Wu 10:25—991. Generation of small-molecule heteocyclic libraries employing a novel cyclization on solid support. G. Figliozzi, F. Woolard 10:45—992. Microwave-assisted decarboxylation of malonic acids and diesters in water. D. Yerow, C. Zara 11:05—993. Electrochemical preparation of 1,2-diketones for automated synthesis. M. Ishifune, Y. Murai

11:25—994. Synthesis of ethyl butyrate by sol-gel-entrapped lipase. W-S. Lin Hilton Hawaiian Village Coral Ballroom III, Mid-Pacific Conference Center Organic Chemistry General Session (09G-P2, P3, P4) Poster Session 9:00-11:00 894. Preliminary study on Eurycoma longifolia anti-oxidant constitutents using solidphase microextraction/capillary GC-MS. C. Wilfred 895. Study on the stereoselectivity of lipases from psuedomonas about the primary alcohols containing quaternary chiral carbon. C. S. Cheong, D. S. Im, S. H. Lee, B. H. Youn 896. Molecular recognition between (3-sheets in proteins and in model systems. J. S. Nowick, Q-C. Bui, D. M. Chung, W. E. Kemnitzer, K. Maitra, S. Maitra, K. D. Stigers, Y. Sun, J. H. Tsai 897. Building fluorescent sensors by template polymerization: The preparation of fluorescent sensors for saccharides. B. Wang, S. Gao, W. Wang 898. Mechanistic studies of chondroitin AC lyase from Flavobacterium heparinum. C. Rye, S. Withers 899. Studies on diarylalkanoids effective on Anisakis simplex larvae. J. Suzuki, I. Yasuda, I. Murata, K. Nishitani, T. Takino, K. Inou, Y. Inoue, N. Yoshimura 900. Generation and reactions of highly strained bicyclo[2.2.1]hept-2-en-5-yne. T. Kitamura, M. Kotani, T. Yokoyama, Y. Fujiwara 901. Photoreaction of the seven-membered azatriene system: 2,5- and 3,6-di-ferfbutyl-3H-azepine and 2-azatropone. S. Takami, K. Satake, Y. Tawada, S. Kashino, M. Kimura 902. Self-assembling cyclic ureas. L. S. Shimizu, K. D. Shimizu 903. Effects of metal recognition on 1,3dipolar cycloaddition of crowned diphenyldiazomethanes with electron-deficient olefins. T. Oshima, Y. Kanematsu, K. Kokubo 904. Stereoselective synthesis of optically active tetrahydrofuran- and butyrolactonetype lignan using threo-selective aldol condensation. S. Yamauchi, Y. Kinoshita 905. Construction of new unsaturated organosilicon systems: Intramolecular dimerization of silylenes. T. limura, T. Sanji, H. Sakurai 906. Diastereoselective addition of alcohols to diastereotopic silylenes. H. Fujiyama, T. Sanji, H. Sakurai 907. Facile synthesis of [n.m.3] propellanes through tandem free-radical cyclization reaction. J. Bahn, H. Y. Lee 908. Host-guest interaction of functional calix[4] resorcinarenes with cationic guests. M. Igarashi, Y. Ono, M. Takahashi, K. Shibata, K. Kikukawa 909. Efficient synthesis of bis-calix[4]arenes with novel linkages. G. T. Hwang, B. H. Kim 910. Synthesis, characterization, and structural study of calix[4]arene-nucleoside hybrids. S. J. Kim, B. H. Kim 911. Facile preparation of multisubstituted ureas. J-l. Yamaguchi, T. Suyama, Y. Murayama 912. Allosteric molecular recognition utilizing dimeric porphyrins. M. Ikeda, M. Takeuchi, S. Shinkai 913. Polycationic cyclodextrin derivatives: Host-guest binding interactions. J. I. Cohen, S. Castro, R. Engel 914. Total synthesis of hexahydrodibenzofuran natural product: A potent melanin biosynthesis inhibitor. N. Ohta, M. Yamashita, I. Kawasaki, S. Ohta 915. Total synthesis of marine imidazole alkaloids: Naamidine and pyronaamidine. S. Nakamura, S. Ohta, H. Mieko, M. Matsui, T. Yoshida, N. Tsuno, M. Yamashita, I. Kawasaki 916. Gibbestatin B, inhibitor of Gibberellininduced alpha-amylase expression in cereal seed. K-l. Hayashi, H. Kondo, M. Inoguchi, H. Nozaki 917. Plant polyphenols exhibiting DNA topoisomerase II inhibition. H. Nozaki, K. Hayashi, S. Ikeda, M. Yamada, M. linuma 918. Synthesis of optically active "Hasmolactone with lipase. N. Oshiro, T. Miyakoshi

919. Hydrogen-based monosaccharide sensing by polypyridine receptor. S-l. Tamaru, M. Takeuchi, S. Shinkai, A. B. Khasanov, T. W. Bell 920. Synthesis of 3-pentadecylcatecholglycosides. K. Shoji, T. Miyakoshi 9 2 1 . Stereoselective synthesis of (2S,3S,4S)- and (2R,3S,4S)-3,4dihydroxyproline via the nitrone from L-tartaric acid. Y. Takahashi, K. Fukuda, K. Suzuki, A. Yamanobe, J. Yoshimura, M. Yamaura 922. Development of molecular recognizing agents via tandem Claisen rearrangement: Application to anion sensing and chiral recognition. H. Yoshida, K. Hiratani, K. Saigo 923. Powerful and selective Ti (Zr)-Claisen condensation and application to the synthesis of natural products. R. Hamasaki, S. Funakoshi, Y. Tanabe 924. Levoglucosenone functionalization toward biologically active derivatives. Z. Witczak 925. Functional flavin receptors: Regulation of redox properties of flavin through hydrogen bonding. Y. Yano, T. Kajiki, T. Hayashi, S-l. Kondo 926. Toward the total synthesis of scabrosin diesters and analogs. P. B. Huleatt, C. L. L. Chai, J. A. Elix 927. Synthesis of rotaxanes by "lock and unlock" of disulfide linkage. T. Oku, Y. Furusho, N. Kihara, T. Takata 928. Facile construction of oxaphenalene skeleton by peri ring closure: Total synthesis of Mansonone F. Y-G. Suh, D-Y. Shin, K-H. Min, J-K. Jung, O-H. Park, W-l. Lee, J-Y. Moon 929. C-10 functionalized triquinacenes: Synthesis, chemistry, and molecular recognition. P. Wilson, J. Cadieux 930. Studies toward the synthesis of CP225,917 and 263,114. N. Ohmori, T. Watanabe, T. Miyazaki, S. Tanaka, S. Kojima, K. Ohkata 931. Toward the total synthesis of arteminolide; studies on the [5+2] oxidopyrilium ion cycloaddition reaction of allenes and electron rich olefins. J-H. Sohn, B. G. Kim, H-Y. Kim, H-Y. Lee 932. Screw-sense-selective self-assembly of polynuclear triple-stranded helicates from extended chiral ethynylpyridine ligands and Cu(l) ions. T. Kato, T. Kawano, I. Ueda 933. Preparation of sulfur-containing trehaloselipids. H. Kojima, S. Nishio, S. Hanai, M. Yokoji 934. Hydrolysis of the amide bond with proline and analogous amines as the /7-moiety by carboxypeptidase y. Y. Kanosue, Y. Hiraga, K. Ohkata 935. Surface modification of polymer by active oxygen generator. T. Murakami, M. Takahashi, N. Kawashima 936. Bis(benzo[fc>]fluorene) derivatives (II): Synthesis of 1,4-bis(8'-ferf-butyl-5'hydroxy-5'-phenylbenzo[6]fluoren-6'ylethynyl)benzene by the cycloaromatization of nonconjugated polyenyne system. H. Akitsu, K. Miyawaki, T. Kawano, I. Ueda 937. Synthesis and cyclization of nonconjugated benzotetrayne-bearing fluorescent probe. Y. Ueda, K. Miyawaki, T. Kawano, I. Ueda 938. Evaluation of extended-releasing NO ability of aromatic A/-nitrosamines. M. Tanno, S. Sueyoshi, K. Fukuhara, N. Miyata 939. NO generation of /V-hydroxy-L-arginine analogs in oxidative conditions. S. Sueyoshi, M. Tanno, N. Miyata 940. Synthesis and mobility control of catenanes constructed using hydrogenbonding interaction. N. Watanabe, Y. Furusho, N. Kihara, T. Takata 941. Profiles of gene and protein expression in the radula sac of chiton. M. Sasaki, M. Hamaguchi 942. Syntheses of deuterated /V-alkylmaleimides for the purpose of quantitative analysis of peptides by stable isotope differential mass spectrometry. S. Niwayama, H. Matsumoto 943. Design and synthesis of a chemical model of a protein beta-sheet sandwich. D. M. Chung, J. Liu, J. Nowick 944. Practical synthetic methods of glutathione monoethyl ester via its sulfonates. S. Kato, I. Chujo, Y. Mimura, T. Ogasa, M. Kasai 945. Conjugate addition and polymerization as effective end-capping of psuedorotaxanes. N. Kihara, H. Kawasaki, T. Takata

946. Acylative end-capping approach to the rotaxane synthesis. N. Kihara, H. Kawasaki, T. Takata 947. Syntheses and conformational analysis of acyclic carboxylic ionophores containing naphthylene ring. H. Hattori, K-l. Onoue, N. Chikaraishi-Kasuga, K. Yamaguchi 948. Synthesis of rotaxanes by acylative end-capping of pseudorotaxane with active esters. N. Nakakoji, N. Kihara, T. Takata 949. Unexpectedly lowered acidity of ammonium group on rotaxane and its acylative neutralization. Y. Tachibana, N. Kihara, T. Takata 950. Synthesis and inclusion properties of capped hexahomotrioxacalix[3]arene with ester groups on the lower rim. T. Yamato, M. Takeshita, F. Zhang 951. Synthesis of optically active 5-(fbutyldimethylsiloxy)-2-cyclohexenone and its 4-substituted derivatives: Synthesis of 1a,25-dihydroxyvitamin D3. T. Hanazawa, M. Koiwa, S. Okamoto, F. Sato 952. Synthesis of 2-pyrone derivatives from carbon dioxide and a,(3-unsaturated ketones in the presence of organometallic compounds. H. Nakajima, M. Zhou, Y. Yoshida, S. Ishii, H. Noguchi 953. Reaction of 4-silatriafulvene with cyclopropenone giving a highly strained 1 -silabicyclo[3.2.0]heptatriene derivative. Y. Kon, M. Kira, C. Kabuto, K. Sakamoto 954. Rhizopus oryzae-mediated enantioselective synthesis of hydroxy ketones. A. Demir, H. Hamamci, F. Doganel-Polat, B. Asikoglu 955. Generation of C 10 H 4 species in a lowtemperature argon matrix. T. Sato, H. Niino, A. Yabe 956. Magnetisms after irradiation of poly(phenyleneethynylene) substituted by phenyldiazomethyl and nitronylnitroxide groups in matrix solution. T. Akita, N. Koga 957. Synthesis and properties of 1,4,5,8,9,12-hexaazatriphenylene derivatives. N. Matsumoto, H. Une, T. Sawada, T. Thiemann, K. Takahashi, S. Mataka 958. Syntheses and inclusion properties of upper-rim-connected bis(calix[4]arenes). K. Araki 959. Synthesis of enediyne model compounds producing toluene diradicals possessing a highly radical character via enyne-allene intermediates. M. Kawano, I. Suzuki, H. Nemoto, M. Shibuya 960. Synthesis of enediyne model compounds bearing the protected cyanohydrin moiety. Y. Tsuchiya, I. Suzuki, H. Nemoto, M. Shibuya 961. Cycloartane glycosides from baneberry. B. Surridge, M. Benn, W. Majak 962. Detailed mechanistic studies and synthetic applications of a retaining p-mannosidase. D. L. Zechel, D. Stoll, S. P. Reid, O. Nashiru, T. Mohammadzadeh, R. A. J. Warren, S. G. Withers 963. Progress toward the synthesis of novel cyclic polysaccharides. J. Ferguson, C. Marzabadi 964. Synthesis of 2-methylamino-acyclopropanepropanoic acid. T. Altamore 965. DNA alkylation with ionic intermediates obtained by thermal cycloaromatization of nonconjugated aromatic entetrayne derivative. H. Kawatsura, T. Sugane, I. Ueda 966. Synthesis of macrocyclic bisphenol derivatives composed of benzoxazole moieties and their fluorescence behaviors. S-K. Lee, H. Houjou, E. Koyama, K. Hiratani 967. Structure-activity relationship of propargylic sulfones exhibiting DNA intercalating and cleavage activity. A. Ishii, W-M. Dai, C. W. Chow, L. Zhou, C. W. Lau, Q. Li, W. Hamaguchi, H. Hatta, S-l. Nishimoto 968. Synthesis of fluorescence-labeled oligosaccharides as tools for the investigation of enzyme kinetics. I. Cumpstey, A. J. Fairbanks, R. R. France, M. R. Wormald, T. D. Butters 969. Antibacterial and phytochemical investigations of three Jamaican folklore plants: Mikania micrantha, Coccoloba krugii, and Alysicarpus vaginalis. P. Facey, R. Porter, K. Pascoe 970. Synthetic efforts toward a derivatized porphyrin oxidation catalyst with sterically driven regiochemistry. M. Pollard, J. C. Vederas 971. Probing wavelength regulation of rhodopsin. B. Borhan, R. Crist, D. Weliky, J. Yang

972. Sequence-dependent microenvironment-associated chemistry of proteins: Another dimension in protein-function prediction? C. M. Yang 973. Tandem cyclization reaction of alkylidene carbenes to triquinanes. Y. Kim, L. Hee-Yoon 974. Total synthesis of kelsoene. A. Orellana, E. Piers 975. Aromatic architecture: Use of the /V-methylamide structure as a molecular splint. I. Azumaya, D. Tsukazaki, H. Kagechika, K. Yamaguchi, H. Takayanagi 976. Preparation of a bicyclo [3.2.1] octenohe-type. H. Nagata, K. Ogasawara, N. Miyazawa 977. Exploitation of a synthetic equivalent of chiral c/s-1,4-dihydroxycyclohexane-2,5diene. M. Honzumi, K. Ogasawara, T. Taniguchi, M. Shoji, A. Sugawara 978. Studies on sialic acid: Syntheses of di/V-glycoloylneuraminic acid and its derivatives. I. Yumura, S. Noriko, T. Hiroaki, F. Kimio 979. Regioselective syntheses of alkylpolyhydroxycoumaronochrome derivatives. H. Wada, A. Oda, M. Isukayama, M. Nishiuchi, K. Yamashita, Y. Kawamura, M. Tsukayama 980. Synthesis of the polyethers modified with germanium. T. Shiroishi, K. Tanaka, Y. Takeuchi 981. Syntheses of azacrown ethers with side-chain-containing germanium. R. Suzuki, K. Tanaki, Y. Takeuchi, M. Takashi 982. Synthesis and its transport property of calix[4]arenes with germanium atom in the side chain. T. Sakurai, K. Tanaka, Y. Takeuchi 983. High-resolution solid-state Ge-73 NNR of some organogermanium compounds. M. Nishikawa, K. Tanaka, Y. Takeuchi, T. Takayama 984. Synthesis of arylgermanes with sidechains containing germanium at ortho or meta position. T. Kaneko, K. Tanaka, Y. Takeuchi, T. Matsumoto 985. Synthesis and use of the enantiomers of 4-(1 '-2H)-ethylphenol as molecular probes for the mechanism of p-cresol methylhydroxylase. J. C. Craig, E. T. Everhart, W. S. Mclntire 986. Toward the total synthesis of the mycotoxin fumonisin B-|. M. D. McLeod, F. Issa 1134. Unique bonding and reactivity of tetrametal complexes, Pd(0)-No(ll)-Pd(0) and Rh(l)-Mo(ll)-Mo(ll)-Rh(l). C-M. Che 1135. A bond path: Universal indicator of bonded interactions. R. F. W. Bader 1137. Unexpected features of the experimental charge density in molecular crystals. R. Destro, M. Bazaghi, E. Ortoleva 1138. Direct observation of d-holes and Cu-Cu bonding in Cu 2 0. J-M. Zuo 1139. Structural features and electrondensity distributions of hypervalent S-X bonds. F. Iwasaki, M. Yasui 1140. Characterization of a short single well N - H - 0 hydrogen bond by neutron diffraction: Study of the mixed crystal 2[4,4'bipy-H0.][1245-H3]. I. D. Williams, S. M-F. Lo, T. Mak, J. A. Cowan, J. A. K. Howard, G. J. Maclntyre, S. A. Mason

SUNDAY AFTERNOON Hilton Hawaiian Village Honolulu Suite I, Tapa Conference Center Organic Photochemistry (141)

H. Zimmerman, Presiding 1:05—1117. Amino acids as building blocks in photochemical syntheses. A. Griesbeck 1:40—1118. Photochemical electrophileolefin combination, aromatic substitution (photoEOCAS) reaction. D. R. Arnold, D. Mangion 2:15—1119. Novel reactions of 1,4unsaturated compounds promoted by triplet sensitization and photoinduced electron transfer. D. Armesto, M. Ortiz, A. Agarrabeitia, S. Aparicio-Lara, O. Caballero 2:50—1120. Synthetic applications of intramolecular meta-photocycloaddition of areneethene nonconjugated bichromophores. A. Gilbert, D. Amey, S. Cleridou 3:25—1121. Control of photochemical reactions: Zeolite as a reaction medium. V. Ramamurthy

4:00—1122. Strategies for enhancing the optical yield in photosensitized enantiodifferentiating uni- and bimolecular reactions. Y. Inoue, S. Asaoka, H. Ikeda, S. Shiraishi, T. Wada Hilton Hawaiian Village Tapa Ballroom II, Tapa Conference Center New Strategies to TransitionMetal-Catalyzed or Mediated Organic Synthesis (024)

H. Kurosawa, Presiding 1:05—1036. Coordination of Lewis acid to Ti2-enonepalladium(0) leading to continuous structure variation from rj2-olefin type to r)3- allyl type. S. Ogoshi, H. Kurosawa, T. Yoshida 1:45—1037. Theory and practice of organometallic reactions. E. Nakamura 2:25—1038. Novel highly selective sequential approach to multifunctional benzenes: A renaissance of the well-known trimerization reaction? V. Gevorgyan 3:05—1039. Nickel(0)-catalyzed regioselective dimerization of conjugated enynes and allenes. S. Saito, Y. Yamamoto 3:45—1040. Stereospecific and regioselective transformation mediated by rhodium complexes having a Cp'-P ligand. Y. Kataoka, A. Shibahara, Y. Iwato, Y. Nakagawa, K. Tani 4:05—1041. Catalytic transformations employing C5Me5Rh(olefin)2. M. Brookhart, C. P. Lenges, O. Daugulis, E. Eggeling, M. Prosenc Hilton Hawaiian Village Coral Ballroom III, Mid-Pacific Conference Center Molecular Oxygen and Organic Peroxides in Chemistry and Biology (122) Poster Session

1:00-3:00 1070. Age-dependent changes in lipid peroxide levels in senescence-accelerated mice. S. Matsugo, K. Matsushima, K. Sasaki, S. Tokumaru 1071. Oxidation of phenols in the presence of metal complexes-hydrogen peroxide system. Y. Kurusu 1072. Synthesis and anti-malarial activity of yingzhaosu A analogs from unsaturated hydroperoxy acetals. T. Tokuyasu, A. Masuyama, M. Nojima, H-S. Kim, Y. Wataya 1073. Synthesis and antimalarial activity of 1,2,4,5-tetraoxacycloalkanes. Y. Hamada, A. Masuyama, M. Nojima, H-S. Kim, Y. Wataya 1074. Synthesis of novel macrocyclic peroxides. T. Ito, A. Masuyama, M. Nojima 1075. New oxidation system in water by using micellar amphiphilic cc-alkoxy hydroperoxide. K. Fukuoka, A. Masuyama, M. Nojima 1076. Mn(lll)-based synthesis of cyclic peroxides containing nitrogen heterocycles. H. Nishino 1077. New "parasite-targeted" Artemisinin derivatives. P. O'Neill, S. Hindley 1078. Application of phosphite ozone adducts to the synthesis of new antimalarial endoperoxides. S. Rawe, P. O'Neill 1079. C-10 Phenoxy derivatives of dihydroartemisinin. P. O'Neill, S. Hindley, A. Miller 1080. Primary and p-secondary kinetic isotope effects in oxidation of secondary alcohols with dioxiranes: Radical or hydride transfer mechanism? I. Smonou, Y. Angelis, N. Hatzakis 1081. Site specificity in the thionin-sensitized oxygenation of trissubtituted alkenes within zeolite Na-Y. M. Stratakis, G. Froudakis 1082. Peroxynitrite-induced chemiluminescent aerobic oxidation of 1,3-dicarbonyl compounds. E. Bechara, F. Knudsen, L. Royer, C. Penatti 1083. Synthesis and cytotoxicity of novel artemisinin derivatives. Y. Li, F. Shan, J-M. Wu, J. Ding, D. Xiao, W-Y. Yang, G. Atassi, D. H. Caignard 1084. A new catalytic route employing endoperoxides for the synthesis of diastereomerically- and enantio-pure cyclopropanes. D. Taylor 1085. Naphthalene endoperoxide as a source of 1180-labeled singlet oxygen. P. Di Mascio, G. R. Martinez, J-L. Ravanat, M. H. G. Mederos, J. Cadet

1086. Product distribution and the mechanism of P450 in the model system with artificial hemin and toluenes: The reactivity of t-BuOOH on the oxidation reaction. T. Nakano, K. Tagata, Y. Mitarai, Y. Mori, H. Kakuda 1087. Synthesis and biomimetic Fe(ll) chemistry of C-10 carba analogues of dihydroartemisinin. M. Pugh, P. M. O'Neil 1088. Oxidation of cellular DNA by a chemical source of singlet oxygen. J-L. Ravanat, P. Di Mascio, G. R. Martinez, J. Cadet 1089. Reactions of singlet oxygen and singlet oxygen mimics with a variety of substituted ethylenes. K. O'Shea, G. Alume, G. Fuentes 1090. Magnetic field effects on the organicoxygen molecule photosystem in liquids and polymers. N. Dam, P. R. Ogilby 1091. Time-resolved transmission microscope for singlet oxygen. L. K. Amdersen, P. R. Ogilby 1092. Mechanism of photosensitized oxidation of phenols. B. K. Ohta, C. S. Foote 1093. Hydroperoxygenation of alkylbenzene with molecular oxygen catalyzed by N-hydroxyphthalimide and 2,2'-azobis(4methoxy-2,4-dimethylvaleronitrile. K. Sugamoto, T. Yamamoto, Y-l. Matsushita, T. Matsui 1094. Functional linkages between the tumor suppressor protein P53 and Mnsod. B. Bedogni, G. Pani, R. Anzevino, R. Colavitti, B. Palazzotti, M. E. DeLeo, S. Borrello, T. Galeotti 1095. Improved synthesis of artemisininderived, chemically robust, troxane dimers. K. R. Crawford, G. H. Posner, J. Northrop 1096. Synthesis and evaluation of novel spin traps. R. Sato, K-l. Nakahashi, M. Takeishi 1097. Photooxygenation in the interior of a zeolite. E. Clennan, J. Sram 1098. New mechanism for singlet oxygen induced oxidative bond cleavage. D. Aebisher, E. L. Clennan, A. Toutchkine 1099. A theoretical study of the reduction of endoperoxides with phosphines. K. Nahm 1100. Studies of sulfoxide photodeoxygenation. A. Greer Hilton Hawaiian Village lolani Suite V/VI, Tapa Conference Center Free Radicals: From Molecules to Materials (128)

R. Hicks, Presiding 1:05—1101. Short- and long-range magnetic order in thiazyl radicals between 50 and 150K. J. Rawson, F. Palacio, R. Less, G. McManus, P. Oliete, N. I. Feeder, J. Davies, N. Smith, C. Pask 1:35—1102. Radical anions and dianions of substituted 3,6-dimethylenecyclohexane1,2,4,5-tetrones as organic building blocks for metal-organic complex magnetic materials. J. E. Jackson, A. W. Misiolek, A. S. Ichimura, R. H. Huang, R. A. Gentner 1:55—1103. Organic radicals with mesogenic cores. S-l. Nakatsuji, M. Mizumoto, H. Ikemoto, H. Akutsu, J-l. Yamada 2:15—1104. Organic free radicals with nonconventional magnetic and optical properties. J. Veciana, J. F. Letard, D. Luneau, M. Minguet, I. Ratera, D. Ruiz-Molina, D. Amabilino, C. Rovia 2:35—1105. Interplay of theory and experiment: Design of molecules for ferrimagnetic organic metals. F. Wudl, K. Houk, J. Sedo, A. Weitz 3:05—1106. Design, synthesis, and characterization of neutral radical molecular conductors based on the phenalenyl system. X. Chi, M. E. Itkis, B. O. Patrick, C. P. Brock, T. M. Barclay, A. W. Cordes, R. W. Reed, R. T. Oakley, R. C. Haddon 3:25—1107. Stable cation radicals of triarylphosphine, arsine, and stibine: Synthesis, structure, and application as redox and spin centers. S. Sasaki, F. Murakami, R. Chowdhury, M. Yoshifuji 3:34—1108. Tris[p-(/V-oxyl-A/-fert-butylamino) phenyl]amine, -methyl, and -borane have doublet, triplet, and doublet ground states, respectively. H. Iwamura, T. Itoh, K. Matsuda, K. Hon


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Hilton Hawaiian Village Coral Ballroom III, Mid-Pacific Conference Center Marine Natural Products Chemistry (110) Poster Session

1:00-3:00 1754. Total synthesis of 2-isocyanoallopupukeanane and 9-isocyanoneopupukeanane. T. L Ho, L R. Kung, G. H. Jana 1755. Chemical genetics and marine natural products. P. Karuso, A. Piggott 1756. Sponge allelochemical induces ascidian settlement but inhibits metamorphosis. M. Garson, K. Green, B. Russell, R. Clark, M. Jones, G. Skilleter, B. Degnan 1757. Chlorinated peptides from the tropical marine sponge Dysidea herbacea. M. Garson, B. Stapleton 1758. New 13C-NMR chemical shift prediction system using database considering stereochemistry by CAST notation and its application to marine natural products. H. Koshino, H. Satoh, K. Funatsu, J. Uzawa, T. Nakata 1759. Chemical and biological studies on antioxidative alkaloids in Okinawan sponges. T. Ichiba, I. I. Ohtani, C. Miyagi, Y. Aniya 1760. Absolute configurations of kalihinane diterpenoids. Y. Kajiwara, H. Miyaoka, M. Shimomura, N. Yamada, Y. Yamada 1761. Isolation and structure of the new neuritogenically active gangliosides molecular species from the sea cucumber Stichopus japonicus. K. Yamada, M. Kaneko, F. Kisa, T. Miyamoto, R. Higuchi 1762. lantherans and ianthesines: Novel polybrominated aromatic substances from a marine sponge lanthella sp. as Na.KATPase inhibitors. M. Ojika, Y. Okamoto, S. Kato, Y. Sakagami 1763. New malyngamides from the Hawaiiam cyanobacterium Lyngbya majuscula. Y. Kan, B. Sakamoto, T. Fujita, H. Nagai 1764. UV-B absorbing substance in aquatic animals. R. Kuwahara, M. Kaneniwa, Y. Murata, M. Yokoyama 1765. New polyoxygenated steroids from the gorgonian Isis hippuris. J. Tanaka, A. Trianto, T. Higa 1766. Approaches toward the synthesis of polyhalogenated monoterpenes of the halomon class. D. A. Stevens, M. E. Jung 1767. Applications of cyroprobe technology to marine natural products. K. L. Colson, I. W. Burton, J. Walter 1768. Synthetic studies toward the antiviral marine natural product hennoxazole A. F. Yokokawa, T. Asano, T. Shioiri 1769. Synthetic studies toward total synthesis of micropeptin T-20. A. Inaizumi, T. Shioiri, F. Yokokawa 1770. Total synthesis of flavocristamide A. N. Irako, T. Shioiri 1771. Absolute stereochemistry of a new cyclic depsipeptide. Y. Takada, J. Kimura, G. Goetz, Y. Nakao, P. Scheuer 1772. Microbial origins and tumor targeting of cytotoxins. S. J. H. Hickford, J. W. Blunt, M. H. G. Munro 1773. New metabolites from the Australian marine sponge Stylotella aurantium. J. Simpson, M. Garson Hilton Hawaiian Village Rainbow III Organic Chemistry General Session (09G-04)

J. Konopelski, Presiding 1:05—1141. Synthetic approach to amphidinolide A: Invention and application of organostannane-mediated reactions. R. E. Maleczka 1:25—1142. Total syntheses of diterpenoids cyathane A4 and sarcodonin G. M. W. Gilbert, E. Piers, K. L. Cook 1:45—1143. Rapid entry into major groups of taxoids. S. Arseniyadis 2:05—1144. Chemoenzymatic synthesis of a highly functionalized bicyclo[4.3.1]dec6(7)-ene related to the carbobicyclic core of CP-263,114 and CP-225,917. K. McRae, M. Banwell, A. Willis 2:25—1145. Synthesis of the core ring structure of sequoiatones via an intramolecular, hetero Diels-Alder reaction of an allene. N. Drapela, M. Kath, J. Swenson, K. Polanski, R. Schleiffarth, R. Cohen, B. Neff 2:45—1146. Studies on the synthesis of pyrrole-based marine natural products. D. Wong, M. Banwell, A. Bray

138


3:05—1147. Efforts toward the synthesis of the ligand of the active site of cytochrome coxidase. G. I. Elliott, J. P. Konopelski 3:25—1148. Progress toward the total synthesis of diazonamide A. J. P. Konopelski, N-Y. T. Stessman, E. M. Moore, G. I. Elliott 3:45—1149. Stereoselective synthesis of functionalized c/s-hydrindanes from 2-exocarbomethoxytricyclo[5.2.1.02,6]deca-3,8diene-5-ones. S. Suri Chander, S. Rodgers, K. S. Prakash 4:05—1207. Synthesis of novel chiral spirans and tentative approach of the mechanism of their formation. B. Deng 4:25—1208. Withdrawn. Hilton Hawaiian Village Coral Ballroom IV, Mid-Pacific Conference Center Organic Chemistry General Session (09G-P5) Poster Session

4:00-6:00 1150. Theoretical study of orientation and mechanical. S. Wu, W. Lee 1151. Negative solvatochromism of azo dyes derived from (dialkylamino)thiazole dimers. J. J. Kim, M. Matsui, K. Shibata 1152. Regioselectivity in the cyclodextrin mediated Diels-Alder reactions: A computational study. W-S. Li, W-S. Chung, I. Chao 1153. The rate of ion-pair return in aqueous solution: 18 0-scrambling study of 1-(4methylphenyl)ethyl pentafluorobenzoate. Y. Tsuji, T. Mori, J. Richard, M. Fujio, Y. Tsuno 1154. ARGENT: A new system for computeraided prediction of unprecedented reaction types. S. S. Tratch, M. S. Molchanova, N. S. Zefirov 1155. Ultrafast photoinduced electrochromism in cast films of polymeric 4,4'bipyridinium salts with diiodides due to radical formation and back electron transfer. T. Nagamura, H. Inoue, H. Sakaguchi 1156. Strong and stable absorption changes in both visible and near-infared regions due to radical formation in 4 , 4 ' bipyridinium with a vinyl or 2,5-thienyl bridge. T. Nagamura, K. Fujimoto, K. Yamaji, H. Inoue, M. Shibata, K. Okamoto 1157. Specific intramolecular charge resonance band observed at room temperature in solution by steady photolysis of 1,3fc/s(4-(4-nitrostyryl)pyridinium)propane tetraphenylborates. T. Nagamure, S. Park, S. Kashihara, H. Kawai 1158. Effects of solvents and substituents on tautomeric equilibria of p-substituted benzoylacetones. T. Kondo, S. Masuda, K. Minagawa, H. Osaka, M. Tanaka 1159. The synthesis of regioselectively dansyl-tosyl-modified cyclodextrins as a fluorescent sensor. M. Narita, F. Hamada 1160. Synthesis and electrochemical property of self-assembled monolayers with charge-transfer groups, n-mercaptoalkyl benzo-annelated tetrathiafulvalenes. K. Ogawa, N. Yoshimoto, K. Mori, S. Ogawa 1161. Syntheses of fluorescent diazolopyridines for EL-device. K. Takahashi 1162. Benzofuranoquinol-type fluorescent hosts: Clathrate formation and solid fluorescence enhancement behavior. Y. Ooyama, S. Watanabe, K. Yoshida 1163. Stabilities and redox behaviors of 9-phenylxanthen-9-ylium and 9-phenylthioxanthen-9-ylium ions. M. Miyamoto, M. Asahara, K. Goto, T. Erabi, M. Wada 1164. Electron-transfer properties of NAD radical analogs. K. Ohkubo, O. Inada, T. Suenobu, S. Fukuzumi 1165. Substituent effects on solvolyses of |3-(aryldimethylsilyl)ethyl system. M. Fujio, M. Uchida, H-J. Kim, F. Ryoji, Y. Tsuno 1166. Substituent effects on the solvolysis of 1 -aryl-1 -mesityl-2,2,2-trifluoroethyl system. H-J. Kim, Y. Tsuno, M. Fujio 1167. Molecular interaction of fluorinecontaining hybrid compounds. H. Fukaya, T. Ono 1168. Synthesis of functionalized fluorescent dyes and their coupling amines and mercaptans. A. Shimabukuro, Y. Ueda, F. Ueno, H. Ohmori, T. Kawano, I. Ueda 1169. |3-Silicon effects in the solvolysis of 2-(phenyldimethylsilyl)-1 -phenylethyl system. Y. Umezaki, H-J. Kim, K. Kikukawa, R. Fujiyama, M. Fujio, Y. Tsuno 1170. Substituent effect of the stability of dimethylphenylsilyl anion in the gas phase. M. Irie, K. Kikukawa, M. Mishima

1171. Synthesis and physical properties of optically active nitroxide radicals from a pyrrolidine of C2-symmetry. K. Uemae, T. Shibata, Y. Yamamoto 1172. Triplet diphenylcarbene close to being bottleable. K. Hirai, H. Tomioka 1173. Removal of organic compounds from industrial effluents by advanced oxidation process by electron beam irradiation. C. L. Duarte, M. H. Sampa, P. R. Rela, H. Oikawa, C. G. Silveira 1174. Syntheses, electrochemical properties, and reactions of novel cobaltadithiolene complexes starting from [Zn(dmit)2]2' complex. D. Takeuchi, E. Suzuki, Y. Toyota, C. Takayama, J. Gerardo, G. Alea, T. Sugiyama, Y. Yokoyama, M. Kajitani 1175. Synthesis of new chiral nitroxide radicals. S. Shimono, R. Tamrua, A. Ohshima, N. Iguma 1176. Theoretical studies on proton and electron coupled systems: Dependence of phases on structure. H. Nagao, Y. Shigeta, J. Toyoda, Y. Yoshioka, K. Yamaguchi, K. Nakasuji 1177. Excited-state interaction between two oligosilanes in a molecule. T. Naruoka, K. Sakamoto, M. Kira 1178. Substituent effects of the NMR chemical shifts on aromatic amides and related compounds. T. Yuzuri, H. Suezawa, K. Sakakibara, M. Hirota 1179. Pressure effect on complexation of p-cyclodextrin with various kinds of substituted phenols. S. Itami, Y. Sueishi, S. Yamamoto 1180. Photoinduced hydride transfer reactions between cationic dyes and leuco dyes. Y. Liu, S. Yamamoto, Y. Sueishi 1181. Pressure effect on cation migration of 2,5-di-te/t-butyl-1,4-benzoquinone radical anion IV. M. Kasahara, S. Yoshimi 1182. Thermokinetic research method for consecutive first-order reactions. X. Zeng, Y. Chen 1183. Pressure effect on bimodal inclusion complexes of cyclodextrin with nitroxide radical probes as studies with EPR. Y. Sueishi, H. Tobisako, M. Kasahara, Y. Kotake 1184. Preparation and properties of 2,4,7triarylimidazolo[4,5-c] pyridines. Y. Soeda, H. Gorrohmaru, I. Costea, T. Thiemann, S. Mataka 1185. Mechanism of base hydrolysis of bisketol phosphate triesters. K. Calvo, G. Koser, R. Moore 1186. Antraquinone dyes derived from 1,2,3,4-tetrafluoroanthraquinones. S. Taniguchi, K. Shibata, M. Matsui 1187. Chemical reaction of thermally stable compounds in sub- and supercritical water. Y. Shibasaki, H. Tagaya, J-l. Kadokawa 1188. Intermolecular D-A interactions and hydrogen bonds in the crystals of some derivatives of triptycenequinone and triptycenehydroquinone and their binary systems. J. Yamane, M. Hashimoto, K. Yamamura 1189. Photochemistry of diphenylmethylenecyclopropanes. Y. Takahashi, M. Inaba, A. Nakamura, Y. Mori, H. Tomioka 1190. Polymer-like complexes bridged by a fluorine substituent of the side arm in the 3 ' ,5 '-difluoro-4 '-hydroxybenzyl-armed monoaza-15-crown-5 ether. Y. Habata, T. Saeki, S. Akabori, X. Zhang, J. Bradshaw 1191. Photochemistry of vinylidenecyclopropanes: Reararrangement, cycloaddition, and their mechanism. K. Mizuno, T. Hirai, S. Nishioka, H. Sugita, H. Maeda, A. Sugimoto 1192. One-pot synthesis of fullerene-related chromophores: Characterization and photophysical properties of 2,6-disubstituted aceanthrylene and 2,7-disubstituted cyclopent [/7/]aceanthrylene. H. Dang, M. Levitus, S. Khan, M. A. Garcia-Garibay 1193. ESR and DFT study of free radicals in y-irradiated corticosteroid single crystals. A. Szyczewski, K. Mobius 1194. Theoretical study of the electronic structure of [Cp3M] anions (M=Mg, Ca, Sr, Ba). L. E. Sansores, N. Mireles, A. Martinez, R. Salcedo


1195. Unsaturated Si chemistry: Correlation between geometric and electronic structures of silenes. C-H. Ottosson 1196. Stability studies and characterization of spherical hexamers comprising various resorcinarenes. P. Raston, J. L. Atwood, L J. Barbour, D. E. Riederer 1197. Conformation studies on c/s-decaline derivatives: NMR analysis in solid and solution states. M. Tanikawa, A. Hatano, Y. Osa, I. Azumaya 1198. Conformation studies on c/s-decaline derivatives: Analysis by X-ray crystallography and MM2 calculation. Y. Osa, M. Tanikawa, Y. Sato, T. Kawamata, H. Takayanagi 1199. Cis confirmational preference of N-substituted aromatic amides and related compounds. R. Yamasaki, T. Aya, A. Isao, Y. Kentaro, H. Hiroyuki 1200. New particles technology for (RE)BCO-superconductor(RE=Y) using jet mill. H. Kezuka, K. Isamu 1201. Kinetic stability of pyrrolidinobuckminsterfullerene. Y. Akai, Y. Kawamura, M. Nishiuchi, M. Tsukayama 1203. Asymmetric induction in the photochemistry of frans-frans-2,3-diphenylcyclopropane-1-carboxylic acid derivatives in the crystalline state. C. W. Chong, J. Scheffer, E. Cheung, J. Trotter 1204. Crystal structure solid-state reactivity relationships and asymmetric induction in the photochemistry of anti-7-benzoylbenzio bicyclo[2.2.1.]heptane derivatives. C. Scott, J. Scheffer, J. Trotter, E. Cheung 1205. Transient spectra and photoreaction of 4-methoxybenzoyloxyl radical. S. Oishi, H. Tsubaki, T. Niya, H. Matsuzawa 1206. Automated structure verification of a substituted 4-phenylbenzopyran library using 2-D NMR techniques. G. Rosse, H. Schroeder, P. Neidig Hilton Hawaiian Village Coral Ballroom III, Mid-Pacific Conference Center Chemistry of the Organic Solid-State: Synthesis, Structure, and Reactivity (007) Poster Session 1:00-3:00 995. Clathrate formations and self-assembly by a molecular spring. Y. Kitahara, K. Takaka, H. Osuga 996. Application of mixed crystals to control photoisomerization in alkyl cobaloxime complexes. C. Vithana, Y. Ohasi, H. Uekusa, A. Sekine 997. Solvent-free Stobbe condensation reaction. K. Tanaka, F. Toda 998. One-pot synthesis of photochromic naphthopyranes in the solid state. K. Tanaka, H. Aoki 999. Crystal-to-crystal thermal conversion of tetraallene to anthrodicyclobutene. K. Tanaka, N. Takamoto, F. Toda 1000. One-pot preparation of optically active sec-alcohols, epoxides, and sulfoxides by a combination of synthesis and optical resolution in a water-suspension medium. H. Miyamoto, S. Yasaka, R. Takaoka, K. Tanaka, F. Toda 1001. Synthesis and properties of new chiral diol host derived from tartaric acid. H. Miyamoto, M. Asami, K. Tanaka, F. Toda 1002. Development of novel red dopants for improving efficiency of emission layer in organic electroluminescent devices. D. U. Kim 1003. Dyes bearing strong fluorescences, prepared from 2,5-diamino-3,6dicyanopyradine crystal structures and colors. N. Amanokura, H. Suzuki, A. Sekine, Y. Ohashi 1004. Chiral crystallization of achiral materials and the application of asymmetric synthesis in homogeneous conditions. M. Sakamoto, T. Mino, T. Fujita 1005. Correlation between solid-state NMR spectra and crystal structures of the compounds showing the preferential enrichment. H. Takahashi, T. Nakamura 1006. Solid-state photoisomerization of cobaloxime in host-guest complexes. S. Sugihara, A. Sekine, H. Uekusa, Y. Ohashi 1007. Single crystal to single crystal enantioselective photoreaction of 2,4,6triisopropyl-4'-carboxybenzophenone as a salt with L-prolinol. H. Koshima, K. Hirotsu, T. Matsuura

1008. Studies on key factors of the crystal packing of 4-(4-X-PhCH=N)-TEMPO radicals. R. Miki, N. Takashima, D. Hashizume, M. Yasui 1009. Enantioselective intramolecular aromatic [4+4] photocycloaddition in crystalline state. S. Kohmoto, H. Masu, S. Tanaka, K. Yamaguchi, K. Kishikawa, M. Yamamoto 1010. Novel method for fabrication of organic electroluminescent microcrystals. K. Baba, H. Kasai, S. Okada, H. Oikawa, H. Nakanishi 1011. Sheet structures of dipeptides of inclusion compounds and their thermal behavior. T. Takahashi, M. Akazome, K. Ogura 1012. Phase transition of organic crystals caused by conformational changes of alkyl groups: Direct observation of transition process by an in situ single-crystal diffraction method. D. Hashizume, H. Matsumoto, Y. Aoyagi, T. Yamazaki, T. Endo, M. Yasui, F. Iwasaki 1013. Preparation of ordered thin polymer films by in situ polymerization of hydrogenbonded clusters adsorbed on silicon oxide surfaces. M. Mizukami, S. Nakasone, K. Kurihara 1014. Design of nanocavities in inclusion crystals by /V-alkylammonium hyodeoxycholates. M. Katsuta, K. Sada, M. Miyata 1015. Polymorphic inclusion crystals of cholic acid with multisubstituted benzenes. N. Yoswathananont, K. Sada, M. Miyata 1016. Side-chain length effects of molecular assembly modes of various bile acids. K. Kato, K. Sada, M. Sugahara, M. Miyata 1023. Crystalline-state photoreaction of a cc-oxoamide derivative in inclusion complexes. A. Sekine, M. Kobayashi, H. Uekusa, Y. Ohashi 1024. Optically active 2,2'-substituted 9,9'bianthryls as a new family of chiral host: Synthesis, structure, and absolute stereochemistry. T. Shimasaki, S. Toyota 1025. Solvent-free Robinson annelation reaction. K. Yoshizawa, H. Miyamoto, S. Kanetaka, K. Tanaka, S. Toyota, F. Toda 1026. Sovent-free Claisen condensation and Cannizzaro reactions. K. Yoshizawa, S. Toyota, F. Toda 1027. Quinhydrone-type molecular assembly of 2,2'-dihydroxybiphenyl and benzoquinone. M. Senzaki, R. Kuroda, F. Toda 1028. Structure and optical properties of /V-methylated salts of dipyridylsulfide. R. Horikoshi, T. Mochida, H. Moriyama 1029. Wavelength dependence of crystallinestate photoracemization and photoisomerization of cobaloxime complexes. T. Takayama, H. Uekusa, Y. Ohashi 1030. Solid-state photoisomerization of cobaloxime complexes with a bulky substituent in the equatorial ligands. H. Arai, H. Uekusa, Y. Ohashi 1031. Relation between structure and photochromism of salicylideneanilines. T. Ishida, J. Harada, A. Sekine, H. Uekusa, Y. Ohashi 1032. Unusual short double bond in styrenederivative crystals. N. Yasuda, H. Uekusa, Y. Ohashi 1033. Crystal structure and topochemical polymerization reactivity of dialkyl muconates. T. Tsubouchi, A. Matsumoto, K. Tashiro, S. Saragai, S. Nakamoto 1034. Intercalation of amines into polymer crystals as organic clay. A. Matsumoto, T. Odaril, K. Sada, M. Miyata, K. Tashiro

SUNDAY EVENING Hilton Hawaiian Village Tapa Ballroom III, Tapa Conference Center Discovery and Development of Asymmetric Synthesis and Chiral Technology (065)

I. Shinkai, Presiding 7:05—1228. Chiral toolbox approach for asymmetric catalysis. X. Zhang 7:25—1229. New approach to "unnatural" amino acids. D. Ager, I. Fotheringham, T. Li, D. Pantaleone, K. Behrendt, W. Liu, R. Yoshida 7:45—1230. Catalytic asymmetric 1,3-dipolar cycloaddition reactions of nitrones with activated alkenes. S. Iwasa, S. Tsushima, T. Shimada, H. Nishiyama 8:05—1231. Chiral lignads containing fluorines: Asymmetric diethylzinc addition. B-M. Kim, J-K. Park

8:25—1232. Highly stereoselective conjugate addition of a thiol group via pyrrolidine derivatives: Application to the chiral intermediate of captopril. H-B. Lee, J-K. Hwang, Y-G. Kim 8:45—1233. Enantioselective organocatalysis: A new and broadly useful strategy for enantioselective synthesis using organic catalysts. D. Macmillan, C. J. Borths, W. S. Jen, J. J. Wiener, N. Paras, R. M. Wilson 9:05—1234. New enantioselective routes to p aminoacids. A. J. Robinson, D. Saylik, E. M. Campi, W. R. Jackson, C-Y. Lim 9:25—1235. New enantiomeric resolution phenomenon (preferential enrichment) (part 17): Mechanism and requirements. R. Tamura, H. Takahashi 9:45—1236. Asymmetric activation of racemic BINAP-Ru complex in enantioselective hydrogenation. M. Terada, T. Korenaga, K. Mikami 10:05—1237. Asymmetric synthesis of enantiomerically pure 1,2-amino alcohols by samarium iodide-mediated cross-coupling of planar chiral aldehydes with imines. M. Uemura, N. Taniguchi Hilton Hawaiian Village Tapa Ballroom I, Tapa Conference Center New Developments in Heterocyclic Chemistry (066)

Hilton Hawaiian Village Coral Ballroom I, Mid-Pacific Conference Center

11:35—848. First Rh-catalyzed ene and highly enantioselective ene reaction. X. Zhang, P. Cao

Natural Products of Chemistry: Biological Activity and Synthesis (042)

Hilton Hawaiian Village Tapa Ballroom I, Tapa Conference Center

K. Nomura, Presiding

New Strategies to TransitionMetal-Catalyzed or Mediated Organic Synthesis (024)

7:05—1222. Cis-1,2,-dihydrocatechols as starting materials for the enantioselective total synthesis of natural products. M. Banwell 7:40—1223. Challenge to the total synthesis of azadirachtin, an insect antifeedant. A. Murai 8:15—1224. Synthetic studies toward the total synthesis of anisatin. Q-Y. Hu, T-P. Loh 8:30—1225. Total synthesis of macrolides possessing 5-hydroxy-4-oxo-2-alkenoic acid moiety. Y. Kobayashi 8:45—1226. Progress on the synthesis of complex natural products. G. Sulikowski 9:20—1227. Radical approaches in oxacyclic natural product synthesis. E. Lee

MONDAY MORNING Hilton Hawaiian Village Honolulu Suite I, Tapa Conference Center Biocatalysis in Organic Synthesis (138)

M. Komatsu, Presiding

J. Stewart, Presiding

7:05—1238. Alkaloid synthesis: An approach to cylindrospermopsin. D. J. Hart, J. F. Djung, E. R. R. Young 7:45—1239. Anionic cyclization approach toward perhydroindolones: Application to the total synthesis of alkaloids. C-K. Sha, S-J. Huang, C-M. Huang, A-W. Hong, C-M. Chao, T-H. Jeng 8:25—1240. Studies on total synthesis of the marine hepatotoxin cylindrospermopsin. S. M. Weinreb 9:05—1241. Hypervalent iodine reagentinduced intramolecular cyclization of substituted phenol ethers: Synthesis of discorhabdin alkaloids. Y. Kita

8:05—1789. Synthesis of ultrafine and commodity chemicals fom simple carbohydrates. J. Frost, K. Draths 8:35—1790. Biocatalysis process development for preparation of chiral pharmaceutical intermediates: Challenges of poorly soluble substrates. K. Gbewonyo, M. Stanik, P. Y. Kim, M. Sturr, M. Chartrain, R. Greasham, D. Robinson 8:55—1791. Large-scale synthesis of unnatural amino acid derivatives: Traditional chemistry meets contemporary bioscience. D. Ager, I. Fotheringham, D. Pantaleone, P. Taylor, W. Liu, F. R. Alexandre, N. Turner 9:15—1792. Functional group elaboration toward the chemoenzymatic synthesis of a-amino acids. T. Sugai, M. Bakke, A. Otake 9:35—1793. Enzyme/metal combo reaction for asymmetric catalytic transformation. M-J. Kim, J. Park 10:05—1794. Dioxygenase-mediated preparation of synthons for asymmetric synthesis of carbohydrates and alkaloids. T. Hudlicky 10:35—1795. Biocatalytic preparation and uses of chiral sulfoxides. B. Holland 11:05—1796. Peroxidase-catalyzed epoxidation of alkenes. A. Mulchandani, D. H. Brian

Hilton Hawaiian Village Honolulu Suite I, Tapa Conference Center Organic Photochemistry (141)

H. Zimmerman, Presiding 7:05—1242. Intramolecular energy transfer in multifunctional steroids. H. Morrison, L. Timberlake, W. S. Li 7:4fJ—1243. Radical cations as biomimetic triggers of polycyclization cascades: Mechanistics and synthetic applications. M. Demuth, F. Goeller, X. Xing, V. Rosales, D. Uzun 8:15—1244. New synthetic methodology employing 4- and 2-pyrone photochemistry. F. West Hilton Hawaiian Village lolani Suite V/VI, Tapa Conference Center Reactive Intermediates and Unusual Molecules (001)

Hilton Hawaiian Village Tapa Ballroom I, Tapa Conference Center New Strategies to TransitionMetal-Catalyzed or Mediated Organic Synthesis (024)


H. Kurosawa, Presiding

7:05—1209. Inner-phase arylcarbene rearrangements. R. Warmuth 7:30—1210. Spin control in reactions of carbenes and oxygen. Y. Sawaki, K. Ishiguro, T. Makihara, T. Nojima, K. Hirabayashi 8:00—1211. Conformational and electronic effects in the decomposition of isoxazol5(2H)-ones. R. Prager, G. Elsey, M. Fong 8:30—1212. Comparison of the reactivities of atomic carbon and C 2 0 toward alkenes. P. Shevlin, H. Wu, J. Zeng, G. Xu 9:00—1213. Reactive intermediates and electrostatic effects via electrospray ionization-Fourier transform mass spectrometry. S. Kass 9:30—1214. Gas-phase studies of organic radicals and biradicals. H. Kenttamaa 10:00—1215. Reactive intermediates in chemical, biological, and atmospheric reactions of ozone and nitric oxide. K. N. Houk 10:30—1216. Photolysis of a "Carboranonaphthalene". M. Jones, Jr., A. Z. Bradley, A. J. Link 11:00—1217. Photolysis of a "Carboranonaphthalene". M. Jones, Jr.

8:35—842. New transition-metal-catalyzed cycloadditions: Synthetic and mechanistic studies and catalysts for C-C bond formation in water. P. Wender 9:15—843. New reactions of nickel metallacycles. J. Montgomery 9:35—844. Iridium-chiral diphosphine complex-catalyzed highly enantioselective Pauson-Khand-type reaction. T. Shibata, K. Takagi 9:55—845. Cationic platinum-dppp complexcatalyzed conversion of 1,6-enynes to 1-vinylcyclopentenes with anomalous carbon-carbon bond formation. S. Oi, I. Tsukamoto, Y. Inoue 10:35—846. Applications of Chromimun(O)promoted cycloaddition reactions to natural product synthesis. J. Rigby 11:15—847. Nickel-catalyzed asymmetric multiple-component coupling reaction. S-l. Ikeda


H. Kurosawa, Presiding 8:35—1255. Olefin metathesis catalysts for the rapid synthesis of olefins. R. Grubbs 9:15—1256. Ruthenium-catalyzed [2+2] cycloadditions. W. Tarn, R. Jordan 9:35—1257. Ruthenium complex-catalyzed reactions of olefins and acetylenes. T-A. Mitsudo 10:35—1258. Biomimetic aerobic oxidations with ruthenium and copper catalysts. S-l. Murahashi, N. Komiya 11:15—1259. Mechanistic studies of catalytic hydrogenation by a Ru(ll) hydroxyhydride complex. C. P. Casey, S. Singer 11:35—1260. New developments in osmiumcatalyzed aminohydroxylation. V. V. Fokin, K. B. Sharpless Hilton Hawaiian Village Coral Ballroom IV, Mid-Pacific Conference Center Photoremoveable Protecting Groups and Caged Compounds: Principles and Applications (035) Poster Session 4:00-6:00 1042. Phototriggers as protein cross-linking agents II. P. Conrad, R. Givens, R. Herpel, G. Timberlake 1043. Synthesis and photochemical properties of dendritic caged compounds. S. Watanabe, T. Nakano, M. Sato, M. Iwamura 1044. New method for adding reagents: An application of caged compounds to analytical chemistry. H. Shiono, H. Nohta 1045. Introduction of carboxy and hydroxy groups to the surface of silicon wafers by silane coupling agents bearing photodegradable 2-nitrobenzyl ether and ester. T. Futami, N. Kitamura, J . Ozaki, K. Yamaguchi 1046. Properties of liposomes composed of phospholipids containing various 2-nitrobenzyl ester groups at the end of the alkyl chain. Y. Sasaki, S. Nakamura, N. Goto, K. Yamaguchi 1047. Caged amino acids and peptide for 2-photon excitation. G. Mashio, T. Furuta, H. Wakasugi, M. Iwamura 1048. Photoregulation of dehydrogenases: Syntheses, photochemistry, and enzymatic properties of coumarin-caged NAD+. Y. Takahashi, T. Furuta, M. Matsushita, M. Iwamura 1049. Novel phototriggers based on the photochemistry of nitroaromatic compounds. Y. V. H'lchev, J. D. Simon, J. Wirz 1050. Triplet sensitized laser flash photolysis of BNN3, caged nitric oxide. K. Fujimori, M. Yoshida, M. Ikegami, T. Arai Hilton Hawaiian Village Honolulu Suite III, Tapa Conference Center Chemistry of the Organic Solid-State: Synthesis, Structure, and Reactivity (007)

F. Toda, Presiding 8:05—1245. Opening reactions on fullerenes: Insertion of small atoms and molecules. Y. Rubin, T. Jarrosson, M. D. Bartberger, G-W. Wang, S. Martin, K. N. Houk 8:35—1246. Structures and photodimerizations of 1-alkylthymine crystals. Y. Inaki, N. Tohnai, M. Miyata, E. Michizuki, N. Yasui, Y. Kai 8:50—1247. Recent novel advances in solidstate organic photochemistry. H. Zimmerman, I. Alabugin, E. Nesterov, V. Smolenskaya 9:20—1248. Intramolecular 1,4-migration in the solid state induced by cogrinding 9,10d i h y d r o a n t h r a c e n e - 9 , 1 0 - d i o l s with p-toluenesulfonic acid. K. Kobayashi, R. Sekiya 9:35—1249. Photofunctional materials: Ti0 2 and diamond. A. Fujishima 10:05—1250. Pedal-like conformational change at photodimerization in cocrystals of trans-cinnamamide with phthalic acid. S. Ohba, I. Yoshikatsu


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20—1251. Crystalline metal complexes as templates for solid-state reactions. B. M. Foxman 50—1252. Supramolecular control of sold state reactivity. J. L. Reid, L. R. Macgilivray, J. A. Ripmeester 05—1253. Environmentally benign solidstate reactions. G. Kaupp 35—1254. Viologen-based inclusion crysals. T. lyoda, H. Shinotsuka, M. M. Matsushita, T. Kawai on Hawaiian Village ral Ballroom III, Mid-Pacific Conference nter tural Products of Chemistry: Biological tivity and Synthesis (042) ster Session

0-11:00 J7. Constituents of solidago altissima. K. Sato 58. Chemical studies on the plant leaf novement. M. Ueda 59. Synthesis of quinoid antibiotics using Drganocadmium reagents. C. T. Wigal, J. 3oyer, J. Krum, M. C. Myers, A. Fazal TO. Attends A and B, novel bicyclic triols, solated from the Chinese bivalve Pinna attenuata: Isolation, structure, and syndetic studies. K. Suenaga, D. Uemura, N. Takada, K. Araki M. Total synthesis of Gibberellin A 12 and irst total syntheses of Gibberellin A,, and \U2- M. Toyota, M. Ihara 72. Synthetic study of haterumalide NA. M. Kita, H. Kigoshi, D. Uemura 73. Novel palladium-promoted cascade reactions triggered by strain release of the tour-membered ring systems and applications to the natural product synthesis. M. Voshida, M. Ihara 74. Callysatin a and leptomycin b: Inhibitors of nuclear protein export. S. Aoki, N. Murakami, M. Sugimoto, T. Nakajima, M. Kawanishi, K. Matsui, K. Higuchi, M. Kobayashi 75. Isolation and synthesis of cosmetic substances for skin depigmentation from African dietary leaves, Celosia argentea. A. Sawabe, T. Okamoto, M. Iwasaki, Y. Matsubara, M. Morita, T. Tada, F. Hattori, 5. Shiohara, K. Shimomura, Y. Fujihara, M. Nomura, K. Nishimura 76. Structural analyses of a precursory substance of bitterness: New polyisoarenepolyols from an edible mushroom by mass spectrometry. M. Morita, A. Sawabe, T. Okamoto, T. Kiso, H. Kishine, Y. Dhtsubo, S. Ouchi 77. Feeding stimulant for the starfish Acanthaster planci. T. Teruya, K. Suenaga, T. Koyama, K. Yamada, D. Uemura 78. Synthesis of (-)-indothiolactam-V, a new thioamide analog of tumor-promoting (-)-indolactam-V, and its binding to PKC 31 domains. Y. Nakagawa, K. Irie, H. Ohigashi, H. Hayashi, P. A. Wender f9. Monoterpenoids: A potent inducer of apoptosis in cultured plant cells. S. Izumi, f. Hirata 30. Syntheses of cyclic bis(bibenzyls), plagiochins A D and riccardin A by the intramolecular Pd(0) catalyzed Stille-Kelly reaction. Y. Fukyama, H. Yaso, T. Mori, N. Sato, H. Takahashi, H. Minami 31. Novel rearranged vibsane-type diterpenes, neovibsanins from Viburnum awabukr. Chemical correlation and neurotrophic activity. Y. Fukuyama, H. Minami, M. Kubo 32. Structure and neurotrophic activity of novel sesquiterpene dilactones from the pericarps of lllicum merrillianum. Y. Fukuyama, J-M. Huang, H. Minami, R. Yokoyama 33. Pinnamine, a novel marine alkaloid, solated from Pinna muricata. N. Takada, M. Iwatsuki, K. Suenaga, D. Uemura 34. Total synthesis of squalamine. H-S. Kim, B-S. Choi B5. Liver injury-suppressing substances from avocado Percea americana. H. Kawagishi, Y. Fukumoto, P. He, K. Sugiyama 36. Cross-linked analogs of amphotericin B: Bioactivity and spectroscopic properlies. S. Matsuoka, N. Eiraku, N. Yamaji, N. Matsumori, M. Murata B7. Chiral polyamines and nucleotide: Structure of weakly interacting complex. T. Demura, T. Azuma, M. Murata

140


1288. Synthetic study of longithorones, the farnesylated p-quinones. Y. Sekiguchi, K. Nakanishi, J-l. Nemoto, M. Hoshikawa, T. Kato 1289. Efficient entry into the tricyclic core of halichlorine. Y. Fukuda, M. Shindo, K. Shishido 1290. Studies toward asymmetric total synthesis of misakinolide A. H. Hayakawa, M. Miyashita 1291. Highly stereoselective total synthesis of PM-toxin A and B: Corn host-specific pathotoxins. H. Hayakawa, M. Hosaka, M. Miyashita 1292. Novel protein toxins from box jellyfishes. J. Nagai, K. Takuwa, T. Nakajima 1293. Cinchona alkaloid catalyzed asymmetric Baylis-Hillman reaction and its application to natural product synthesis. Y. Iwabusci, M. Furukawa, T. Sugihara, M. Ushiyama, T. Esumi, S. Hatakeyama, M. Nakatani 1294. Mechanism of flower color variation of Hydrangea macrophylla. K. Yoshida, Y. Toyama, K. Kameda, Y. Shimizu, E. Fujimori, H. Haraguchi, T. Kondo 1295. Exploring the structural basis of neurotoxicity in C17-polyacetylenes isolated from water hemlock. Y. Oshima, K. Uwai, K. Ohashi, Y. Takaya, T. Ohta, T. Tadano, K. Kisara, K-l. Shibusawa, R. Sakakibara 1296. Chiral molecular recognition in complexation of protodelphin, a supramolecular flower pigment from Salvia patens. T. Kondo, K-l. Oyama, K. Yoshida 1297. Synthesis of espicfolin and its analogs. E. Honda, H. Uno, K. Sakamoto, K. Fukuhara, N. Ono 1298. Regioselective preparation of 1,6- and 1,8-dihydroxy-9,10-anthraquinones from the common intermediates: Synthesis of aloesaponarin I and K1115A. H. Uno, Y. Nagamachi, E. Honda, A. Masumoto, N. Ono 1299. Constituents of Dictyostellium cellular slime molds. Y. Takaya, H. Kikuchi, Y. Terui, C. Yakuwa, J. Komiya, Y. Saito, K-l. Furukawa, K. Seya, S. Motomura, A. Ito, Y. Oshima 1300. Synthetic study of termite defensive chemicals I: Conformational analysis of secotrinervitane skeleton. N. Saito, Y. Uotsu, M. Hoshikawa, T. Kato 1301. Synthetic studies on antitumor marine steroid aragusterols: Synthesis of c/d ring moiety of aragusterols. H. Mitome, H. Miyaoka, Y. Yamada 1302. Exploration of germination and growth regulators in cereal husks of wheat and rice seeds. Y. Shimizu, K. Sasaki, T. Kurahashi, M. Shinohara, T. Kato 1303. Synthesis of urushiol components and analysis of urushi sap. Y. Kamiya, T. Miyakoshi 1304. Possible role of 2-phenylethyl. S. Watanabe, K. Hayashi, K. Yagi, H. MacTavish, I. Gubb 1305. Synthetic study of termite defensive chemicals II. An efficient construction of trinervitane and kempane skeletons. S. Takagi, M. Tanaka, M. Hoshikawa, T. Kato 1306. Synthetic studies on the left of ciguatoxin using acetylene cobalt complex-1. K. Kira, M. Isobe 1307. Synthetic studies on the central part of ciguatoxin using acetylene cobalt complex-3. S. Takai, M. Isobe 1308. Synthetic studies on the right part of ciguatoxin using acetylene cobalt complex-2. T. Baba, T-Z. Liu, M. Isobe 1309. Synthetic study of blepharismins and their related molecules. T. Kojima, T. Ohishi, I. Yamamoto, T. Matsuoka, H. Kotsuki 1310. Progress toward the total synthesis of altohyrtins (a.k.a spongistatins) (2): Synthesis of the C29-C44 fragment. N. Kanoh, T. Terauchi, T. Tanaka, M. Morita, K. Kimijima, Y. Nakamura, G. Hayashi, M. Nakata 1311. Progress toward the total synthesis of altohyrtis (a.k.a. spongistatins) (1): Synthesis of the C1-C28 fragment. T. Terauchi, I. Sato, W. Syoji, T. Tsukada, T. Tsunoda, N. Kanoh, M. Nakata 1312. Synthetic studies on immunosuppressant FR901483. T. Kan, T. Fujimoto, S. leda, T. Fukuyama 1313. Novel stereocontrolled glycosidations using a heterogeneous and environmentally benign solid acid: Sulfated zirconia (S04/Zr0 2 ). K. Toshima, K-l. Kasumi, S. Matsumura

1314. Phenolic oxidation of halogenated phenols toward synthesis of biologically active natural products. K. Mori, M. Takahashi, S. Yamamura, S. Nishiyama 1315. Preparation of both enantiomers of w-3 epoxy unsaturated fatty acids. T. Nakai, T. Ishimatsu, M. Hoshikawa, T. Kato 1316. Synthesis of bioactive dehydrodiketopiperazines catalyzed by a novel actinomycetous enzyme system. S. Yanagisawa, K. Akazawa, T. Nitoda, H. Kanzaki 1317. Search for insect chitinase inhibitors of fungal origin. T. Nitoda, A. Kurata, H. Kurumatani, H. Kanzaki 1318. Synthetic study of stevastelin B, a novel immunosuppressant. N. Kohyama, Y. Yamamoto 1319. Oxazolomycin diacetate: Inhibitor against agrobacterial attachment to plants. T. Tsurumoto, K-l. Wada, T. Nitoda, H. Kanzaki 1320. Syntheses of C-glycosyl flavones and conversions of C-glycosyl phloroacetophenones to spiroketal derivatives. T. Kumazawa, T. Minatogawa, M. Chiba, N. Asahi, S. Matsuba, S. Sato, J-l. Onodera 1321. Chemistry of zerumbone: Favorskiitype ring-contracting transannular reaction and ring scission. T. Kitayama, M. Takatani, T. Okamoto, Y. Kawai, T. Yokoi, S. Sawada 1322. Novel microbial metabolism of a morphine antagonist cyclo(Gly-Leu). K. Miyoshi, N. Mizuta, T. Nitoda, H. Kanzaki 1323. Promoters of sediment formation in raw soy sauce: Structure and synthesis. H. Kitahara, S. Itoh, M. Tomita, Y. Motomura, T. Uchiyama, K. Okubo 1324. Total synthesis of symbioramide from L-serine. H. Azuma, K. Ogino 1325. Synthetic study of carthamin, the red pigment in safflower petals. S. Sato, T. Kumazawa, S. Matsuba, J-l. Onodera 1326. Bioactive compounds from marine organisms collected at Sada Cape. M. Kuramoto, T. Fujita, N. Ono 1327. Stereoselective synthesis of aromatic terpenoids: Synthesis of neuritogenic pyrano-isobenzofuranone NG-121. S. Inoue, F. Iwasaki, K. Honda 1328. Conceptually new oxa-sulfone analogs of the hormone 1cc,25-dihydroxyvitamin D3. K. R. Crawford, G. H. Posner, P. Dolan, T. W. Kensler, M-L. Siu-Caldera, G. S. Reddy, S. Peleg 1329. Chemistry of zerumbone: Ring opening by retro-Mannich reaction. T. Yokoi, S. Sawada, T. Kitayama, R. K. Hill 1330. Triterpenes from the twig bark of Shinko (Japanese pear). H. Tomosaka, T. Kaneko, H. Tamimoto, T. Hayashi, H. Toi 1331. Synthetic study of scyphostatin. R. Takagi, H. Nishitani, W. Miyanaga, S. Takenami, K. Ohkata 1332. Efficient syntheses of cyclitols from (-)quinic acid. Y. Ohtani, T. Fuji, T. Shinada, Y. Ohfune 1333. Analyses of biosynthetic mechanisms and cloning of biosynthethic genes for polyethers. M. Izumikawa, M. Murata, K. Tachibana, T. Fujita, H. Naoki, I. Fujii, Y. Ebizuka 1334. Termitomycesphins A-F: Novel neuritogenic cerebrosides from the edible Chinese mushroom Termitomyces albuminosus. J. Qi, M. Ojika, Y. Sakagami 1335. Synthesis of unnatural phosphatidylinositol and phosphatidylinositol 3,4,5trisphosphate having optimal diacylglycerol substructure for enzymatic reaction. A. Nishikawa, K. Morita, N. Nakatsu, Y. Fukui, Y. Hashimoto, N. Morisaki, R. Shirai 1336. Synthesis of newfound bioactive glycoglycerolipids. S. Nagayama, H. Ishida, K. Nakata, T. Inazu 1337. Potential antimycobacterial agents isolaed from the leaves of noni {Morinda citrifolia L.). J. Saludes, M. Garson, S. Franzblau, A. Aguinaldo 1338. Novel sulfone-based cyclization approach to dendrobatid alkaloids. T. Back, K. Nakajima, J. Taylor, R. Bethell, M. Hamilton, J. Wulff


1339. Synthetic study of repeating partial structures of peptidoglycan. S. Inamura, K. Fukase, S. Kusumoto 1340. High-throughput synthesis and biological activity of complex glycocconjugates, lipid A and its analogs. Y. Fukakse, S-Q. Zhang, M. Oikawa, Y. Suda, K. Fukase, S. Kusumoto 1341. Toward a synthesis of the ustiloxin/ phomopsin family of cyclic peptide antitumor agents. C. Hutton, J. Turner, K. Soapi 1342. Synthesis and NMR study of R e labelled lipid A analogs. M. Oikawa, T. Shintaku, H. Sekljic, N. Fukuda, K. Fukase, S. Kusumoto 1343. Antibiotic discovery from cultured Australian microfungi. R. Barrow, M. Kotiw 1344. First total synthesis of Re lipopolysaccharide. H. Yoshizaki, K. Sato, N. Fukuda, M. Oikawa, K. Fukase, S. Kusumoto 1345. Cytotoxic activities of steroidal saponins against HL-60 leukemia cells. Y. Mimaki, Y. Sashida 1346. Syntheses of salacinol and its derivatives. J. Takada, H. Yuasa, H. Hashimoto 1347. Synthetic studies on optically active tetrodotoxin and its analogs. M. Asai, T. Nishikawa, M. Isobe 1348. Progress toward the total synthesis of (-)-TAN1251A and (-)-FR901483. D. J. Wardrop, A. Basak, W. Zhang 1349. Synthetic study and structural elucidation of khafrefungin. T. Wakabayashi, K. Mori, S. Kobayashi 1350. Rearrangement approach to the AB ring system of taxol. T. Morimoto, T. Suzuka, J. Matsui, R. Tatsumi, K. Kakiuchi 1351. Synthetic studies on (+)-lysergic acid. T. Kurokawa, T. Fukuyama 1352. Total synthesis of (+)-gelsemine. S. Yokoshima, T. Hidetoshi, T. Fukuyama 1353. Novel synthesis of 2,3-disubstituted indoles and its application to total synthesis of indole alkaloids. H. Tokuyama, T. Ueda, M. T. Reding, S. Kobayashi, E. J. Zylstra, T. Fukuyama 1354. Synthetic study on ecteinascidin 743. A. Endo, S. Tohma, T. Kan, T. Fukuyama 1355. First total synthesis of the marine alkaloids (±)-fasicularin and (±)-lepadiformine based on stereocontrolled intramolecular acylnitroso-Diels-Alder reaction. S. Aoyagi, C. Kibayashi 1356. Synthesis of a phospholipid-bearing very long chain polyunsaturated fatty acyl group. N. Baba, S. Haider, K. Alam, Y. Mori, S. Nakajima, S. Shimizu 1357. Natural products synthesis featured by intramolecular Diels-Alder reactions. K-l. Takao, T. Murata, Y. Suzuki, R. Munakata, K-l. Tadano 1358. Synthesis of Cdc25A inhibitor dysidiolide. R. Shirai, M. Takahashi, K. Dodo, Y. Hashimoto 1359. Biomimetic construction of fused tricyclic ethers by cascaded encfo-cyclization of the hydroxy triepoxide. T. Tokiwano, K. Fujiwara, A. Murai 1360. Synthetic studies on pectenotoxins. D. Awakura, K. Fujiwara, S. Amano, A. Murai 1361. Synthetic studies on Lycopodium alkaloid, magellanine. Y. Niimi, M. Ishizaki, O. Hoshino 1362. Cytotoxic cholestane glycosides from Ornithogalum saundersiae bulbs. Y. Sashida, M. Kuroda, Y. Mimaki 1363. Chemistries of heterospirostanols and their structure-activity relationships against antihuman platelet agglutination. A. Tobari, E. Hayama, E. Koyanagi, M. Kawase, A. Takasaki, Y. Nagamura, S. Saito 1364. Synthetic studies toward the broussonetine D and H. J. Park, M. Brimble, C. Taylor 1365. Total synthesis of phomopsins. H. Tanaka, M. Stohlmeyer, T. Woiwode, T. Wandless 1366. Total synthesis of optically active FR900482 and its analogs. M. Suzuki, M. Kambe, E. Arai, H. Tokuyama, T. Fukuyama 1367. Geometric sex pheromones with an epoxy ring. M. Yamamoto, T. Ando 1368. Structures and biological activities of constitutents from the Brazilian medicinal plant Brosimum acutifolium. A. Ohsaki, S. Asano, J. Takashima 1369. Convenient preparation of optically active diepoxyhenicosene(leucomalure), lymantrid sex pheromone. T. Ando, M. Yamamoto, H. Yamazawa, N. Nakajima

1370. Synthesis of podophyllotoxin with plant cell cultures. M. Takemoto, K. Achiwa, J. P. Kutney 1843. Synthetic studies toward broussonetine H. J. H. Park, M. A. Brimble, C. M. Taylor Hilton Hawaiian Village Coral Ballroom IV, Mid-Pacific Conference Center Discovery and Development of Asymmetric Synthesis and Chirai Technology (065) Poster Session 9:00-11:00 1371. Theoretical studies on asymmetric hydrogenation reactions of olefins. S. Mori, T. Vreven, K. Morokuma 1372. Highly enantioselective and diastereoselective Ireland-Claisen rearrangement: Synthesis of antisuccinic acid derived mmp inhibitors. W. Zhe, F. Jin, S. Campagna, R. L. Dorow, T. E. Smyser, J. Fortunak, P. N. Confalone 1373. Old catalyst: New chemistry. D. Ager, S. Laneman, P. Leeming, V. Wall 1374. Rationalization of the mechanism of chirai discrimination for the inclusion complexes of p- and y-cyclodextrins with a series of chirai aromatic amino acid derivatives. G. A. Hembury, M. Rekharsky, A. Nakamura, Y. Inoue 1375. Induction and inversion of supramoleular chirality in bis(zinc porphyrin) studied by CD and 1 H NMR spectroscopy. V. Borovkov, J. M. Lintuluoto, Y. Inoue 1376. Diastereoselective 1,4-addition reactions of bis(iodozincio)ethane to a,bunsaturated ketones. H. Yamamoto, S. Matsubara, K. Oshima, K. Utimoto 1377. Hydroxyl-directed, Sml2-induced conversion of carbohydrates into carbocycles. F. Matsuda 1378. Very unique and practical optical resolution of 3-amino-4-hydroxymethylpyrrolidine derivatives. N. Ohta, K. Okano, T. Makino, S. Shimizu 1379. Enantioselective epoxidation of olefins catalyzed by sterically hindered manganese salen complexes derived from BINOL. K-H. Ahn, S. Park, S. Choi, H. Kim, C-J. Moon 1380. Chirai samarium NMR shift reagent suitable for high-field NMR. K. Omata, S. Aoyagi, K. Kabuto, Y. Sasaki 1381. Chirai bipyridine N,N'-dioxide derivatives as catalysts for enantioselective addition of allyltrichlorosilane to aldehydes. M. Nakajima, M. Saito, S. Hashimoto 1382. Total synthesis of (-)-cylindrocyclophanes A and F via remarkable olefin metathesis dimerizations. C. M. Adams, A. B. Smith III, S. A. Kozmin, D. V. Paone 1383. Enantioselective reactions in supercritical fluids. R. Brown, E. McKoon, D. Wynne, P. Jessop 1384. Synthesis of C2-symmetric chirai DMAP-related molecules for asymmetic catalysis. K. Kumamoto, M. Furukawa, H. Sakai, H. Kotsuki 1385. Synthesis and application of ferrocenebased chirai mixed-donor ligands. T-J. Kim, D-H. Kim, H-S. Shim 1386. Asymmetric synthesis of a-alkylphenylglycines. S-H. Lee, E-K. Lee, S-M. Jeun 1387. Pd-catalyzed asymmetric hydrogenation of fluorinated imines in fluorous alcohol. H. Abe, K. Uneyama, H. Amii 1388. Resolution of 2-amino-1-butanol and synthesis of d-ethambutol. L. C. Tavares, M. A. Assis 1389. Formal total synthesis of (+)-calonectrin. A. Uda, K. Konishi, K. Tomioka 1390. Efficient synthesis of chirai bisphosphines employing stereo- and chemoselective cyclization of bisalkenylphosphine oxides. Y. Nagaoka, H. Inoue, N. El-Koussi, K. Tomioka 1391. Catalytic asymmetric conjugate addition reaction of arylthiol to enone. K. Nishimura, M. Ono, Y. Nagaoka, K. Tomioka 1392. Stereospecific Lewis-acid-promoted reactions between aldehydes and 3-deuterio-allyl-tin and -silicon reagents. Y. Nishigaichi, A. Takuwa 1393. Stereoselective coupling of alkynes to aldehydes via titanium taddolate complexes. L. Thompson, K. Knight 1394. Efficient methodology for the stereoselective preparation of homoallylic 22S or 22R sterols. Q. Y. Hu, T-P. Loh

1395. Copper-catalyzed asymmetric alkylation of imines with diethylzinc. H. Fujihara, K. Nagai, K. Tomioka 1396. Chirai aminoether-controlled asymmetric epoxidation of enones with organohydroperoxide. Y. Tanaka, K. Tomioka 1397. Novel catalytic asymmetric oxidation of sulfides to sulfoxides in water using iodoxybenzene. T. Maegawa, H. Tohma, S. Takizawa, H. Morioka, Y. Kita 1398. Asymmetric decomposition of isoxazolidine derivatives catalyzed by optically active palladium(ll) complex. T. Ohta, H. Kamizono, K. Hori, I. Furukawa 1399. Disatereoselective additions of organometallic reagents to chirai imines and 1,3oxazolidines. T. Yamauchi, K. Higashiyama, S. Ohmiya 1400. Asymmetric synthesis of aziridine derivatives and their ring-opening reactions. K. Higashiyama, T. Yamauchi, S. Ohmiya 1401. Experimental and theoretical study of asymmetric cyclopropanation. L. Cai, H. Mahmoud 1402. Asymmetric Baeyer-Villiger oxidation of cyclobutanones using diethylzinc/ oxygen/chiral aminoalcohols. S. Fujioka, T. Shinohara, H. Kotsuki 1403. Total synthesis of neplanocin A by benzylthiolate-initiated Michael-Aldol tandem cyclization. M. Ono, K. Nishimura, K. Tomioka 1404. Stereoselective cyclization using palladium(ll) catalyst via hemiacetal intermediates. M. Miyazawa, Y. Hirose, T. Nakano, H. Yokoyama, S. Yamaguchi, Y. Hirai 1405. Catalyzed asymmetric conjugate addition of amines. A. Miura, S. Kanemasa 1406. Design, preparation, and application of novel chirai phosphine ligands bearing pyrroloimidazole moiety. K. Shibatomi, Y. Uozumi 1407. Combinatorial approach to /V-chiral amine catalysts promoting asymmetric acylation. K. Yasoshima, K. Mizutani, T. Miyachi, Y. Uozumi 1408. Asymmetric hetero-Diels-Alder reaction catalyzed by chirai lanthanoid complexes. T. Hayano, H. Furuno, T. Sakaguchi, J. Inanaga 1409. Chirai Lewis-acid-catalyzed, enantioselective addition of allenyltins to imines. T. Uzawa, H. Kagoshima, T. Akiyama 1410. Asymmetric Michael addition by a double activation method using Rfl-DBFOX/ Ph aqua complexes and amines. K. Ito, Y. Oderaotoshi, S. Kanemasa 1411. Practical regioselective synthetic method for (£)-enol ether and the application. H-G. Park, D-H. Kim, M. You, M-K. Park, S. S. Jew 1412. Design and synthesis of polymersupported heterobimetallic multifunctional asymmetric catalysts. T. Sekiguti, O. Kazuhiro, H. Youichi, I. Yoshimasa, A. Takahyoshi, S. Hiroaki 1413. New tandem Pd-catalyzed cyclization via Wacker process. H. Sasai, M. Arai, M. Kuraishi, A. Takayoshi 1414. Design and synthesis of chirai spiro bis(isoxazoline)ligands (SPRIXs). M. Kuraishi, M. Arai, M. Kazuyoshi, A. Takayoshi, S. Hiroaki 1415. Stereospecific substitution of chirai pyridinylethyl methanesulfonates with N,S,0, and C nucleophiles. M. Hamada, U. Junichi 1416. 3,4-c/s-selective conjugate addition of alkyl groups to (S)-4-(tert-butyldimethylsilyl)oxy-2-cyclopentenones. T. Yakura, K. Tomoko, M. Nobuhiro, F. Emi, H. Yuka, I. Masazumi, U. Junichi 1417. Synthesis and polarized properties of di(1-azurenyl)dicyano-p-quinodimethanes. S. Kikuchi, S. Ito, N. Morita, K. Imafuku 1418. Development of stereoselective synthetic organic reactions using sugars as chirai auxiliaries. K. Totani, T. Nagatsuka, R. Munakata, S. Yamaguchi, K-l. Takao, K-l. Tadano 1419. Chirality efficient syntheses of bridged NADH analogs and their highly enantioselective reduction. N. Kanomata, Y. Ochiai, S. Anada 1420. Asymmetric synthesis of pyrimidyl alkanol with high enantiometric excess induced by inorganic ionic sodium chlorate. I. Sato, K. Kadowaki, K. Soai 1421. Asymmetric autocatalytic reaction initiated by chirai cyclophane derivatives. S. Tanji, A. Ohno, I. Sato, K. Soai

1422. Dibenzofuran modified chirai bidentate Ti(IV) catalyst for asymmetric allylation of carbonyl substrates. H. Hanawa, K. Satoshi, M. Keiji 1423. Synthesis of chirai N-P-N-type ligands and application to asymmetric reactions. T. Yamagishi, T. Kiyooka, D. Masui, M. Yamaguchi 1424. Concerning the mechanism of the double aldol reaction. A. Abiko, S. Masamune 1425. Diastereoselective addition of organometallics to (fl)-2-(2-methyl-3-phenyl-2azabutyl)benzaldehyde. S. Masuda, G. K. S. Prakash, G. A. Olah, T. Nakajima Hilton Hawaiian Village Tapa Ballroom III, Tapa Conference Center Marine Natural Products Chemistry (110) Paul J. Scheuer Symposium: Celebrating a Half-Century of Research at the University of Hawaii

K. Nomura, Presiding 8:05—1427. Marine natural products: A rich source of bioactive chemotypes for drug discovery. R. Andersen 8:50—1428. Chemistry of marine fungi: Developing a new biomedical resource. W. Fenical, P. R. Jensen 9:35—1429. Recent research in marine natural products. J. Shin, Y. Seo, K. W. Cho, J-R. Rho, H-S. Lee 10:00—1432. New cyclic peptides from the Indonesian sponge Theonella swinhoei. I. I. Ohtani, M. C. Roy, T. Ichiba, J. Tanaka, T. Higa, R. Satari 10:05—1430. Novel glucosidase inhibitors from a marine sponge Penares sp. S. Matsunaga, T. Maki, N. Fusetani, R. Van Soest, Y. Nakao 10:35—1431. Bioactive metabolites produced by marine organisms: Alkaloids, sesterterpenes, and small peptides. J. I. Jimenez, P. J. Scheuer 11:05—1433. Protease inhibitors from the marine sponge Theonella mirabilis. Y. Nakao, S. Matsunaga, N. Fusetani Hilton Hawaiian Village lolani Suite V/VI, Tapa Conference Center Free Radicals: From Molecules to Materials (128)

K. Nomura, Presiding 8:05—1434. Third generation of neutral radical conductors. R. Oakley 8:35—1435. Electron donor-acceptor biradicals: Electron transfer and spin-crossover. K. Ishiguro, S. Harada, N. Sekine, M. Ozaki, Y. Sawaki 8:55—1436. Redox-gradient dendrimers for directed charge-transport and chargestorage. S. C. Blackstock, G. J. Szulczewski, T. D. Selby, K-Y. Kim 9:15—1437. Solid-state structure and electronic structure of dimers of [TCNE]. J. Miller, P. Lafuente, J. Novoa 9:35—1438. Manipulating spin system derived from spin-polarized donor. T. Sugawara 10:05—1439. New chelating verdazyl radicals. D. Brook, L. Oamen, S. Goodman 10:25—1440. Theoretical studies on the relative contributions of SOMO-SOMO and other interactions in radical clusters. Y. Takano, Y. Kitagawa, T. Kawakami, K. Yamaguchi 10:45—1441. Approach to photochemical formations of ferromagnets in a heterospin system. N. Koga Hilton Hawaiian Village Honolulu Suite I, Tapa Conference Center Biocatalysis in Organic Synthesis (138)

K. Nomura, Presiding 8:05—1461. Evolution in the test tube as a means to create enantioselective enzymes for organic chemistry. M. T. Reetz 8:35—1462. Laboratory evolution of oxygenases. F. Arnold, P. Cirino, A. M. Aguinaldo, V. Sieber, H. Joo, E. Farinas, U. Schwaneberg 9:05—1463. Combinatorial enzyme libraries by molecular breeding. S. Raillard


9:35—1464. Pathway engineering and its role in the synthesis of materials. K. Sanford 10:05—1465. Chirai alcohols production by enantioselective reduction with NADHdependent phenylacetaldehyde reductase (PAR). N. Itoh 10:25—1466. Asymmetric reduction of ketones by Geotrichum candidum. T. Matsuda, T. Harada, K. Nakamura 10:45—1467. Preparation of both enantiomers of cc-D-phenylacetic acid by the aid of arylmalonate decarboxylase and the studies on the role of cys188. H. Ohta, M. Karoi, H. Satoshi, K. Hitoshi, T. Sugai 11:05—1468. Preparation of novel trehalose derivatives-based enzymatic conversion and their potential application as trehalase enzyme inhibitor. K. Sode, E. Akaike, K. Kojima, W. Tsugawa Hilton Hawaiian Village Coral Ballroom IV, Mid-Pacific Conference Center Organic Photochemistry (141) Poster Session 9:00-11:00 1469. Photochemistry as a synthetic tool. P. Mariano 1470. Acid-switched photochemistry of mesityl and aryl alkanoates: Transesterification versus decarboxylation. T. Mori, Y. Inoue, T. Wada, Q-X. Guo, T. Wada, Q-X. Guo 1471. Photochemical rearrangements of arylomethylphosphinites. W. Bhanthumnavin, W. G. Bentrude 1472. Paterno-Buechi photocyclization of 2-siloxyfurans and carbonyl compounds. E. Torii, M. Abe, M. Nojima 1474. Steric and stereoelectronic effects in photoreactions of halogenated quinones with donor olefins. K. Kokubo, T. Masaki, T. Oshima 1475. Thermally irreversible crystalline photochromism of dithienylethenes. S. Kobatake, K. Shibata, K. Uchida, M. Irie 1476. C60-sensitized bis-silylation and bisgermylation. Y. Maeda, R. Sato, S. Takahashi, T. Wakahara, T. Akasaka, M. Fujitsuka, O. Ito, M. Kako, Y. Nakadaira, K. Kobayashi, S. Nagase, E. Horn 1477. Photochemistry of anthrylethynylsalicylaldehydes. S. Kawabata 1478. Mechanism of [3+2]-photocycloaddition of 1,4-dicyanonaphthalene and 9,10-dicyanoanthracene with alkenes. Y. Kubo, S. Hikino, M. Takuma, H. Shiratori 1479. Substitutent effect on the photochemical rearrangement of 1,6-(/v-aryl)aza[60]fulleroids to 1,2-(/V-arylaziridino)[60]fullerenes. A. Ouchi, R. Hatsuda, M. Sakuragi 1480. Photochemical reaction of 2-trimethylsilylmethylphenylketones. M. Saito, Y. Ishikawa, M. Yoshioka 1481. Propellane-type aromatic amines as advanced organic electroluminescent materials. M. Kimura, K. Shimada, S. Kuwano, Y. Sawaki 1482. Intramolecular (2+2) photocycloaddition of arylalkenes to pyrene via exciplexes. H. Maeda, A. Sugimoto, K. Mizuno 1483. Stereoselective electron-transfer quenching of excited singlet state of chirai quinolinium cation by viologens. R. Ueda, T. Nakazawa, K. Tsukahara 1484. Unprecedented intramolecular photocycloaddition of alkenes to phenanthrene and naphthalene rings. K. Mizuno, R. Nakashima, H. Maeda, A. Sugimoto 1485. Photo-Claisen-type rearrangement of aryl naphthylmethyl ether derivatives. Y. Yoshimi, H. Maeda, K. Mizuno, N. Ichinose, T. Tanaka, S-l. Kawanishi 1486. Picosecond time-resolved fluorescence spectroscopy of (Z)-1-(2-anthryl)-2phenylethene and its model compounds: Understanding the photochemistry by distinguishing between the s-cis and s-trans rotamers. A. Nishigaki, T. Karatsu, H. Itoh, K. Fukui, A. Kitamura, S. Matsuo, H. Misawa 1487. Decarboxylative photocyclization: Synthesis of pyrrolizidines. T. Heinrich, A. Griesbeck 1488. pH and cation-dependent fluorescence of various bis(carboxyalkyl)- and bis(thioalkyl)-perylene-3,4,9,10-tetracarboxydiimides and 4,5,-dimethoxyphthalimides. S. Schieffer, A. G. Griesbeck 1489. Synthesis and photochemistry of /V-acyl alpha-amino acid derivatives. P. M. Cygon, A. G. Griesbeck


141


1490. Photochemical synthesis of [1,4]benzodiazepines and pyrrolo-[1,4]benzodiazepines. W. Kramer, A. G. Griesbeck 1491. Photoinduced allylstannylation, silylation, and alkylation of 1,2-dicarbonyl compounds with Afunctional allylsilane/ allylstannane reagents. A. Takuwa, H. Iwamoto, Y. Nishigaichi 1492. Photoinduced switching in electroactive catenanes. R. Stackow, G. Mattersteig, J. Stoddart, C. S. Foote 1493. Diastereoselective [2+2] photocycloaddition of chiral cyclohexenone-3-carboxylates to ethylene. K. Kakiuchi, T. Ikki, K. Endo, T. Morimoto, K. Tsutsumi 1494. Photochemistry of fungal metabolite ochratoxin A. Y. V. Il'lchev, T. Ye, J. D. Simon, R. A. Manderville 1495. Intramolecular charge-transfer fluorescence of disilanylacetophenone induced by lanthanide metal ions. R. Badugu, T. Li, W. Setaka, K. Sakamoto, H. Hashimoto, M. Kira Hilton Hawaiian Village Coral Ballroom I, Mid-Pacific Conference Center Use of Chemical Information in Organic Synthesis (175)

K. Nomura, Presiding 8:05—1496. KOSP, a novel empirical synthesis design system. K. Satoh 8:35—1497. WODCA: A system for designing the synthesis of single compounds and of combinatorial libraries. J. Gasteiger 9:05—1498. Complementary use of synthesis design systems (AIPHOS, KOSP, and TOSP) in the Internet. K. Funatsu 9:35—1499. Chiron computer program: New options for synthesis planning and chemical diversity. S. Hanessian, B. Larouche 10:05—1500. Reaction prediction study database: Formal computer-simulation of the thinking way of chemists. H. Satoh 10:35—1501. Use of a combinatorial method to investigate the influence of environment on reactivity. G. M. Eichenbaum, B. Bienfait, W-D. Ihlenfeldt, P. F. Kiser, J. M. Davies, M. D. Greaves, J. R. Lee, H. M. Geysen Hilton Hawaiian Village Tapa Ballroom II, Tapa Conference Center Transition-Metal-Facilitated Reactions Leading to Organic Heterocycles (182)

K. Nomura, Presiding 8:05—1502. Metallocarbenoid-induced cyclizations of acetylenic diazocarbonyl compounds for heterocyclic synthesis. A. Padwa, C. Straub 8:35—1503. Low-valent transition-metal hydride catalysts as alternatives to base: Synthesis of heterocyclic compounds. S-l. Murahashi, T. Naota, H. Takaya 9:05—1504. Insertion, cyclocarbonylation, and cycloaddition reactions. H. Alper 9:35—1505. Ligand control of the Rh(l) catalyzed intramolecular [4+2] cycloaddition. T. Livinghouse, H. Heath 10:05—1506. Catalytic carbonylative cyclocoupling. N. Chatani, S. Murai 10:35—1507. Palladium-catalyzed aromatic and saturated carbon-heteroatom bond formation. J. Hartwig 11:05—1508. Studies on catalytic asymmetric syntheses of wortmannin and decursin. M. Shibasaki Hilton Hawaiian Village lolani Suite VII, 2nd Floor, Tapa Conference Center Organic Chemistry General Session (09G-05)

T. Sugahara, Presiding 8:05—1509. Synthetic studies toward the total synthesis of tedanolide: Assembly of C(13)-C(23) subunit. L. Feng, T. P. Loh 8:25—1510. Pulcherrimine, a novel bittertasting amino acid from the sea urchin Hemicentrotus pulcherrimus ovaries. N. Sata, M. Yuko, K. Ryuji 8:45—1512. Efficient preparation of 5-substituted-3-arylpyridines: A class of cox-2-specific inhibitors. R. D. Larsen, I. W. Davies, E. G. Corley, J-F. Marcoux, K. Rossen, P. Pye, J. Wu, M. Robbins, M. Journet, D. Cai, R. P. Volante, P. J. Reider

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9:05—1514. Enantiocontrolled synthesis of kainoid amino acids utilizing (-)-3ketodicyclopentadiene(KDP). H. Nakagawa, K. Ogasawara, T. Sugahara 9:25—1516. Diastereocontrolled synthesis of (-)-pentenomycin I and (+)-arniceone from ketodicyclopentadiene (KDP). T. Sugahara, K. Ogasawara, Y. lura 9:45—1518. Cascading single-step stereoselective construction of the a-alloyohimbine framework. H. Sakagami, K. Ogasawara 10:05—1520. Tethering approaches to cis1,2-glycosides. A. Fairbanks, M. Aloui, C. Seward, I. Cumpstey 10:25—1522. Synthesis and whitening effects of the new derivatives from cashew nut shell oil. M. Nomura, F. Yoshihito, K. Kazuo 10:35—1523. Withdrawn. 10:35—1524. Pyrano xanthones from the leaves of Garcenia dulcis. S. Kosela 10:55—1526. Chromium-containing pigments with nasicon-related structures. F. J. Berry, L. E. Smart, N. Costantini Hilton Hawaiian Village South Pacific Ballroom I, Mid-Pacific Conference Center Organic Chemistry General Session (09G-02)

W. Stalick, Presiding 8:35—1511. Synthesis of (-)-hispidospermidin guided by a postulated biogenesis. J. Tamiya, E. J. Sorensen 8:55—1513. Highly efficient synthesis of 11frans-13-c/s retinoic acid via Lewis acid modified Wittig reaction. X. Wang, A. Bhatia, T. Towne, A. Hossain, J. Chen, Q. Zeng, Y Wang 9:15—1515. Facile synthesis of highly funtionalized y-carbolines. W. Stalick, J. Wynne 9:35—1517. Efficient syntheses of 2,3diamino acid derivatives and ring-opening reactions of trans- and c/s-oxazoline-5carboxylates. J. Yoon, S-H. Lee, K. Nakamura, Y-S. Lee 9:55—1519. Synthesis of 2-aryl-4thioquinoliziniums and structurally related heterocycles. E. Niedzinksi, M. Springsteel, M. Kurth, M. Nantz 10:15—1521. Methylidene piperazine-2,5diones as versatile intermediates in new carbon-carbon bond formation. C. Chai, B. A. Burkett, A. R. King 10:35—1525. Selective olefin formation utilizing the Peterson reaction. S. Kojima, H. Inai, T. Hidaka, K. Ohkata, T. Fukuzaki 10:55—1527. Synthetic approaches to 9-tritylmethylene-fluorene. D. Phillips, T. Bell 10:55—1528. Studies toward the enantioselective cyclopropanation of allylic alcohols using dioxaborolane ligands. C. Molinaro, A. B. Charette 11:15—1529. Reaction of aniline with acridine and biological activity of those products. H. Saito, Y. Ishihara, J. Takano Hilton Hawaiian Village Coral Ballroom IV, Mid-Pacific Conference Center Organic Photochemistry (141) Poster Session 9:00-11:00 244. Photofixation of C 0 2 on phenanthrene through photoinduced electron-transfer reaction. M. Kanehara, K. Tsujimoto 245. Photochemical reaction on the surface of polymeric materials and its application to achieve their reformation. M. Miyamnoto, Y. Sonobayashi, K. Nishimura, S. Miki 246. Photochemical oxidation of quinoline and isoquinoline derivatives substituted by an alkylcarbamoyl group. Y. Takahashi, T. Ikegami, T. Inayoshi, I. Ono 247. Photoreductive repair of thymidine glycol to thymidine sensitized by reduced form of flavin adenine dinucleotide. S. Terada, T. Ito, H. Ide, H. Hatta, S-l. Nishimoto 248. 0 2 generation in C60-photosensitized oxidation of NADH and analogs by oxygen. I. Nakanishi, Y. Yamakoshi, K. Ohkubo, S. Fukuzumi, N. Miyata 249. T) state Z/E-isomerizations of olefins: Correlation between substituent aromaticity and isomerization mechanism. C-H. Ottosson, M. Brink, H. Mollerstedt

250. Kinetic approach to the ring construction from S-ethenylsulfilimines (ESI) and diprotic nucleophiles (DPN). K. Ikeda, N. Utatsu, S-l. Hata, Y. Nakamura, T. Yamamoto 251. Photochemistry of troponoids with excited 9,10-dicyanoanthracene. A. Mori, K. Hiroko, K. Nobuo, W. Shu-Ping 252. Protinduced electron-transfer reactions between Ceo and cyclic disiliranes (c-R2SiX-SiR2; X = CH 2 , O, S, NPh, and SiR2. Y. Sasaki, F. Mamoru, I. Osamu, W. Takatsugu, A. Takeshi, K. Masahiro, N. Yasuhiro, M. Yutaka 253. Meta effect in photo-induced electron transfer initiated chemiluminescence (PETIC) of 2-methoxyphenyl-2-methoxy-3, 3-spiroadamantyl-1,2-dioxetanes (I) and 2-oxophenyl-2-methoxy-3,3-spiroadamantyl-1,2-dioxetanes (II). K. Fujimori, T. Wakasugi, K. Morihashi, M. Matsumoto, S. Murata, R. Katoh, S. Iwai

MONDAY AFTERNOON Hilton Hawaiian Village Coral Ballroom IV, Mid-Pacific Conference Center Organic and Biological Electrochemistry: Fundamentals and Applications (133) Poster Session

1:00-3:00 1442. Electrochemical oxidation of 1,2disubstituted and 1,2,3-trisubstituted azulenes. A-H. Chen 1443. Photoelectrochemical behavior of triarylcarbenium salts having some methoxyphenyl groups on an ITO electrode. E. Osaki, T. Ohtsuki, N. Tomita, M. Wada, T. Erabi 1444. Modification and photoelectrochemical behavior of 9-arylxanthenyl radicals having some methoxy or methyl substituents on an ITO electrode. Y. Yokoyama, M. Miyamoto, K. Gotoh, M. Asahara, M. Wada, T. Erabi 1445. Electrochemical cycloaddition in perfluorinated micellar system in organic solvents. Y. Kono, M. Kitayama, S. Kim, R. Uchiyama, Y. Kitano, M. Tada, K. Chiba 1446. New polycyclic indole derivatives synthesized by electroreduction of nitroindoles in the presence of pyridines. J. M. Chapuzet, J. Lessard, G. BedouillatDelorme, M. Lavoie 1447. Use of acridone derivatives as advanced organic electroluminescent materials. K. Suzuta, M. Kimura, Y. Sawaki 1448. Carbon-carbon bond formation using TDAE/transition metal system. M. Kuroboshi, S. Kishimoto, K. Goto, K. Hosoi, Y. Waki, H. Tanaka 1449. Enantioselective organic electrolysis promoted by asymmetric surfactant. Y. Kodama, S. Ito 1450. Electrochemical responses of gold electrodes modified with self-assembled monolayers containing redox active functional groups. Y. Sato, F. Mizutani 1451. Electrocatalytic reduction of oxalic acid to glyoxalic acid on nanocrystalline Ti0 2 electrode. D. Chu, G. Shen, X. Zhou, C. Lin, H. Lin 1452. Divergent electrochemical carboxylation of vinyl triflates. H. Senboku, Y. Fujimura, H. Kanaya, H. Kamekawa, M. Tokuda 1453. Electrochemical studies of mutated myoglobins. Y. Mie, T. Uno, I. Taniguchi 1454. Electrochemistry of myoglobin chemically modified with succinic anhyride. M. Kishita, Y. Mie, I. Taniguchi 1455. Electrochemical and biological properties of myoglobins reconstituted with diacethylheme and corrphycene. C. Yamada, Y. Mie, S. Neya, I. Taniguchi 1456. Sequential electroreduction of 4,4'dinitrodiphenyl ether assisted by rotational alteration of the diaryl ether bond. B. Uno, T. Kawashima, N. Okumura 1457. Preparation and properties of the selfassembled monolayer anthraquinone gold electrode. N. Takai, M. Goto, B. Uno 1458. Molecular and electronic structural properties of hydrogen-bonded complexes of the electrogenerated o-quinone dianions with methyl alcohol. N. Okumura, B. Uno 1459. Efficient electrochemical dicarboxylation of alkenes and polycyclic aromatic compounds. H. Komatsu, H. Senboku, M. Tokuda

1460. Preparation of chlorella ferredoxin (Fd) and electrochemistry and thermochemical behavior. H. Ikebe, K. Nishiyama, Y. Mie, I. Taniguchi Hilton Hawaiian Village Coral Ballroom IV, Mid-Pacific Conference Center New Developments in Heterocyclic Chemistry (066) Poster Session

1:00-3:00 1553. Cycloadditions of Lewis acid-induced A/-methyleneanilines as azadienes with 1,2bistrimethylsilyloxycyclobutene and oxidative ring expansion to 1,2,4,5-tetrahydro-1benzazocine-3,6-diones. H-J. Ha 1554. Annulation of indoles with cyclopropanes and aziridines. M. Kerr, I. Barrett, D. England, K. Kuss 1555. Azolium salts catalyzing benzoin condensation in water. M. Hamaya, K-l. Iwamoto, M. Ogawa, A. Miyashita, M. Sato 1556. Effect of substituent of benzylamine on oxidative deamination reaction with PQQ. H. Kikuta, Y. Ohshiro 1557. Intramolecular interaction of convergent functional-groups in KempAs triacid derivatives. H. Izumi, S. Futamura 1558. Novel aromatic nucleophilic substitutions of trifluoroacetylated dimethylaminoquinolines and their application to the simple syntheses of fluorine-containing heterocyclic compounds. E. Okada, N. Tsukushi, N. Shimomura, T. Sakaemura, T. Ashida 1559. Axially chiral benzodiazepines: Versatile chiral auxiliary. I. Stibor, P. Lhotak, R. Holakovsky, V. Michlova 1560. Recent development in chemistry of thiophenium and benzothiophenium ions. T. Kitamura, B-X. Zhang, M. Yamane, Y. Fujiwara 1561. Reductive electrophilic reactions of thiophenecarboxylate promoted by samarium diiodide. J-M. Fang, S-M. Yang, S. K. Nandy 1562. Lewis acid-mediated diastereofaceselective 1,3-dipolar cycloaddition of nitrile oxides. H. Yamamoto, S. Watanabe, M. Hasegawa, K. Zenitani, M. Noguchi, S. Kanemasa 1563. 4-acylisoxazoles: Unique chemical behavior and applications in synthesis. C. K. Y. Lee, C. J. Easton, L. Radom, P. Savage, G. W. Simpson, A. Scott 1564. Novel cyclization reaction of trifluoroacetylated aldehyde dialkylhydrazones. Y. Kamitori 1565. Synthesis of four possible stereoisomers of 1,2-epoxy-3-hydroxyerythrinans: Total synthesis of an alkenoid-type erythrinan alkaloid, (+/-)-erythratidine. S. Hosoi, M. Nagao, Y. Tsuda, T. Ohta, K. Isobe, T. Sano 1566. Synthesis of ring-fused nitrogencontaining heterocycles via sequential (tandem) cycloaddition or cyclization. T. Saito, S. Kobayashi, T. Takahashi 1567. Practical synthesis of (S)-4thiopyrrolidin-2-one. A noble sulfurcentered rearrangement of 4-thio-3hydroxybutanoate. T. Saito, Y. Kobayashi, T. Akiba 1568. Photocycloadditions of 2-pyridones: Beyond the photodimer. S. Sieburth, Y. Chen, L. Kuznetsova, C-F. Li, Y-H. Lim, K. Mcgee, Jr., F. Zhang, M. Zhu, D. Rucando 1569. Synthesis of quinazoline derivatives by cycloaddition of /V-aryl substituted ketenimines and cyanamides. M. Shimizu, A. Oishi, Y. Taguchi, T. Takagi, M. Shibakami, Y. Gama, I. Shibuya 1570. Syntheses of flavins and fused pyrimidines hybridized steroids. T. Nagamatsu, H. Yamada 1571. Thermal rearrangement of substituted phenylketene ethyleneacetals to butyrolactones. M. Oda, K. Morimoto, R. Ohta, S. Nishii, S. Kuroda 1572. Preparation of the new types of crown ether possessing tropolone nucleus. S. Kikumoto, T. Kato, Y. Fukushi, T. Kato 1573. Reaction of oc-halocycloalkanone and cycloalkanone with (3-aminothiol. M. Matsushita, T. Takahashi, T. Kanazawa, A. C. Horiuchi 1574. Synthesis of functionalized thiaheterohelicenes under nonphotochemical conditions. H. Osuga, K. Tanaka

1575. Structures and reactions of 2H- and 4H-selenopyranium tetrafluoroborates. E. Honda, T. Kataoka, T. Iwamura, S-l. Watanabe, K. Ujiki 1576. New method for the synthesis of 2-acyl-1,3-dithianes via a reaction of ketones with 1,2-dithiolanes under f-butoxide catalysis. M. Tazaki, K. Okada, T. Uemura 1577. Synthesis and fluorescence behavior of tetrraazathiapentalene derivatives bearing pyrene chromophore. H. Hayashi, N. Matsumura, K. Mizuno 1578. Self-metathesis and cross-metathesis of aromatic heterocycles. T. Kawai, M. Komaki, T. lyoda 1579. Asymmetric aziridination of alkenes with a chiral nitridomanganese complex. M. Nishimura, S. Minakata, H. Okada, I. Ryu, M. Komatsu 1580. Synthesis and properties of novel tetraazathiapentalene derivatives. N. Matsumura, Y. Okumura, H. Hayashi, K. Mizuno 1581. 7i-Facial selection for the electrophilic reactions of isopropylidenenorbornadiene fused with pyridazine and pyrazine rings. K. Miki, T. Kobayashi 1582. Reaction mechanism on regioselective synthesis of 3-substituted chromone derivatives. S. Ito, T. Niiya, I. Yokoe, Y. Sugita 1583. Stereoselective preparation of 2-oxy1,3-oxazolidin-4-ones and their synthetic use. Y. Omata, A. Kamimura 1584. Reaction of the 3-substituted 1,4benzothiazine derivatives bearing the methylthio group with several amines. Y. Amano, T. Miyakoshi 1585. Facile synthesis of macrocyclic 1,5diarylvinamidines. H. Mitsudera, A. Kamimura 1586. Reaction of 1,2,3-selenadiazole with olefin. S. Hanita, Y. Hada, Y. Nishiyama, N. Sonoda 1587. Selenium-catalyzed reductive A/-heterocyclization of A/-(2-nitrobenzoyl) amides with carbon monoxide. M. Hirose, Y. Nishiyama, N. Sonoda 1588. Stereoselection for the electrophilic addition reactions of isopropylidenenorbornene fused with five-membered heteroaromatic rings. T. Tsuzuki, T. Kobayashi 1589. Synthesis of nitrogen heterocycles by intramolecular Michael type amination. T. Suwa, I. Shibata, A. Baba 1590. Unusual 1,2-rearrangement of tosyl group in the cyclization of indolyl-substituted 4-methylthio-2-tosylbuta-1,3-diene. S. Matsumoto, K. Ogura, T. Kishimoto 1591. Synthesis and characterization of porphyrin derivatives with trifluoromethyl group at the meso-position: Partially distorted porphyrins. K. Aoyagi, T. Haga 1592. Synthesis of 3,4-dihalogenated indoles from tips-protected gramine. A retroMannich-directed orthometalation synthetic connection. V. Snieckus, B. Chauder, A. Larkin 1593. Novel chemistry of 2- and 3-nitroindoles. G. Gribble, T. Kishbaugh, E. Pelkey, H. Trujillo 1594. Effective synthesis of heterocycles from y-iodoolefins using chloramine-T as a . nitrogen source. S. Minakata, D. Kano, H. Kawamoto, I. Ryu, M. Komatsu 1595. Efficient iodine-catalyzed aziridination of olefins with chloramine-T in aqueous media. D. Kano, S. Minakata, R. Fukuoka, I. Ryu, M. Komatsu 1596. Preparation of A/-heterocyclic compounds from p-oxothiono esters or a-oxoketene O./V-acetals. I. Furukawa, T. Abe, H. Fujisawa, Y. Nakai, T. Ohta 1597. Lanthanide catalyzed asymmetric 1,3dipolar cycloaddition of nitrones to alkenes using 3,3'-bis(2-oxazolyl)-1,1 ' - b i - 2 naphthol (BINOL-box) ligands. T. Ohta, H. Kodama, J. Ito, K. Hon', I. Furukawa 1598. Novel generation of silacarbonyl ylides by trapping of silylene with carbonyl compounds and their cycloaddition leading to silaheterocycles. T. Fukushima, N. Sakai, S. Minakata, I. Ryu, M. Komatsu 1599. Generation and cycloaddition of azomethine ylides from polymer-supported a-silylimines. T. Akaki, K. Nagai, J-l. Yonemori, S. Minakata, M. Komatsu 1600. New convenient synthesis of quinazoline derivatives. H. Suenaga, H. Sakai, H. Kotsuki 1601. Stereoselective synthesis of tetrahydrofurans and pyrrolidines by silicondirected cyclization of allylsilanes. M. Sugano, Y. Ishida, H. Kagoshima, T. Akiyama

1602. Synthesis of novel chiral DBU-related molecules for asymmetric catalysis. H. Yasuoka, A. Sugino, H. Sakai, H. Kotsuki 1603. Application of Mannich-type condensation reactions with use of protonic acids as synthetic auxiliaries: Reexamination of Kametani phthalimidine synthesis. I. Takahashi, R. Miyamoto, M. Hatanaka, S. Hosoi, T. Ohta 1604. Preparation and properties of 2,2bis(trimethylsilyl)-1,3-dithia-2-silacyclopent4-ene and related compounds. S. Tsutsui, M. Takahashi, K. Sakamoto 1605. Mg-promoted cross-coupling of a, p-unsaturated carbonyl compounds with aliphatic aldehydes. H. Maekawa, I. Nishiguchi, A. Risaki, Y. Segawa 1606. [3+2] Cycloaddition between nitrile oxides or nitrile imines and selenoaldehydes generated by retro Diels-Alder reaction. M. Segi, M. Kojima, K. Tanno, T. Nakajima 1607. Red fluorescent oxadiazolopyridines. H. Gorohmaru, K. Takahashi, T. Sawada, T. Thiemann, S. Mataka 1608. Nitrone synthesis through the Lewis acid-catalyzed conjugate additions of oximes. K. Nakama, S. Kanemasa 1609. Cyclization reaction of 2-alkynylbenzyl alcohol and 2-alkynylbenzylamine derivatives promoted by tetrabutylammonium fluoride (TBAF). K. Hiroya, R. Jouka, M. Kameda, A. Yasuhara, T. Sakamoto 1610. Study of rotation barrier in 1-(2indolyl)-8-substituted naphthalenes. Y. Kanamori, K. Hiroya, A. Yasuhara, T. Sakamoto 1611. Another new synthetic route to 7-(Nsubstituted-amino)-2-methylquinoline-5,8diones. D. Y. Chi, H. Y. Choi, K. C. Lee, E. Y. Yoon, D. J. Kim 1612. Synthesis of unsubstituted 1,2,3,4tetrahydropyrano[2,3-6]quinoline. D. Y. Chi, B. S. Moon, B. S. Lee, K-H. Chung, S. Kim 1613. Synthesis of 8-oxoberbines by palladium-catalyzed direct carbonylation. T. Nakamura, H. Ushito, K. Orito, M. Tokuda 1614. Palladium-catalyzed carbonylation of amines. H. Ushito, T. Nakamura, K. Orito, M. Tokuda 1615. Intramolecular aromatic aminations using a phosphine-free palladium-catalyst. R. Harada, K. Orito, M. Tokuda 1616. Design and synthesis of novel fluorescent nitrogen-containing heterocycles: Fluorescence property of phenazine-A/oxides. T. Mutai, Y. Tagata, K. Araki 1617. Intramolecular oxonium-ene reaction of allylic lactol ether catalyzed by mesoporous solid acid. H. Ohmura, M. Koichi 1618. Ring cleavage of A/-cyanomethyl1,2,3,4-tetrahydroisquinolinium methiodides by amines. T. Nakada, H. Hiroshi, K. Naho, N. Kiyoshi 1619. Synthetic studies on cyclic guanidine compounds. K. Nagasawa, A. Georgieva, T. Ishiwata, T. Nakata 1620. Reduction of 11 H-indolo[1,2Ab]indazol-11-one-with thiol-boron trifluoride diethyl etherate. K. Kaneko, K. Osamu, S. Kazuhiro, Y. Yuka, K. Hajime, K. Akira 1621. p-Sulfinyl group on phenol rings as an ambient functional group for carboncarbon bond formation reaction of phenols: A versatile syntheses of benzofuran neolignans. N. Morita, S. Akai, K. No, Y. Kita 1622. Highly efficient synthesis of macrocycles: Addition of bis(acylketene) to Afunctional nucleophiles. M. Sato, K-l. Iwamoto, A. Sato, Y. Kyoba, A. Miyashita 1623. New method for synthesis of heterophanes. T. Oda, K-l. Iwamoto, E. Murakami, N. Kawashima, M. Sato 1624. Synthesis of 4-pyrone derivatives by cycloaddition of acylketene to ynamine. K. Kondo, K. Iwamoto, M. Sato 1625. Synthesis of optically active 2-azabicycloctane derivatives utilizing the Diels-Alder reaction of 1,2dihydropyridines. O. Onomura, Y. Matsumura, T. Maki, Y. Nakamura 1626. Synthesis and structural properties of 13-membered polyamine alkaloids utilizing chiral [3-lactams. H. Matsuyama, N. Ohira, T. Takei, A. Kurosawa, K. Hara, Y. Kuwatani, M. Yoshida, M. lyoda 1627. New preparation of N-sulfonylaziridines using trimethylsilyldiazomethane. R. Hori, T. Shioiri, T. Aoyama

1628. Unusual bromination of 2-methylthio-3vinylindolizines and thieno[2,3-b]indolizines. A. Kakehi, S. Ito, H. Suga, Y. Kobayashi Hilton Hawaiian Village Tapa Ballroom I, Tapa Conference Center Marine Natural Products Chemistry (110) Paul J. Scheuer Symposium: Celebrating a Half-Century of Research at the University of Hawaii

R. Okuda, Presiding 1:05—1629. New developments on the cryptophycins, new anticancer agents from cyanobacteria. R. E. Moore 1:50—1630. Development of an antitumoral glycolipid and its mode of action. T. Natori 2:20—1631. Recent progress in the total synthesis of diazonamide A. P. Wipf 2:50—1632. Studies directed toward the total synthesis of azaspiracid. F. Bernal, K. C. Nicolauo, N. Diedrichs, P. M. Pihko 3:05—1633. Conjugate addition of sulfur nucleophiles to marine natural product puupehenone. J. K. Zjawiony, I. Katsuyama, M. T. Hamann, D. J. Gochfeld, J. Hu 3:20—1634. Total synthesis of optically active dysidiolide. Y. Yamada, H. Miyaoka, Y. Kajiwara 3:35—1635. New marine natural products with activity against infectious diseases and as noncolligative freezing point depressants. M. Hamann 3:50—1636. Search for marine natural products reversing multidrug resistance in tumor cell. M. Kobayashi, S. Aoki, A. Setiawan, R. Ishida, K. Higashiyama, M. Okano, T. Nakajima, M. Morita, N. Murakami Hilton Hawaiian Village lolani Suite VA/i, Tapa Conference Center Free Radicals: From Molecules to Materials (128)

R. Hicks, Presiding 1:05—1637. Oxophenalenoxyl radicals: New stable neutral radicals based on phenalenyl. K. Nakasuji, Y. Morita, J. Kawai, T. Ohba, N. Haneda, S. Maki, K. Sato, D. Shiomi, T. Takui 1:35—1638. Evidence for conformational^ gated magnetic exchange in a spiroconjugated biradical. N. L. Frank, O. Kahn, R. Clerac, C. Coulon, S. Golhen, L. Ouahab, M. Green 1:55—1639. Magnetic interactions in metal complexes with imino nitroxyl diradicals. H. Oshio, T. Ito 2:15—1640. Phosphahaverdazyls: Putting a new "spin" on verdazyl radicals. R. Hicks, G. Patenaude 2:35—1641. New organic building blocks for open-shell molecules and materials. D. Shultz 3:05—1642. Photoswitching of intramolecular magnetic interaction: A diarylethene photochromic spin coupler. K. Matsuda, M. Irie 3:25—1643. High spin architectures using paraphenylenediamine radical cations. R. A. J. Janssen, M. Struijk, P. J. Van Meurs 3:45—1644. Photoinduced spin alignment between the triplet excited state of diphenylanthracene and the dangling nitroxide radical and the ground-state magnetic property as studied by time-resolved and CW-ESR and SQUID measurement. Y. Teki, S. Miyamoto, M. Nakatsuji, Y. Miura Hilton Hawaiian Village Coral Ballroom I, Mid-Pacific Conference Center Use of Chemical Information in Organic Synthesis (175)

G. Grethe, Presiding 1:05—1695. Reaction information for the practicing synthetic chemist: How to get relevant answers. G. Grethe 1:35—1696. More reactions, more databases: Are they really more useful? The need for integration in reaction information retrieval. E. Zass 2:05—1697. Interlinking applications with the primary, secondary, and tertiary literature. S. Young 3:35—1698. Uncovering reaction information in the world's literature and patents: The latest refinements from CAS. R. Schenck, R. Swann

4:05—1699. Polymerization information in polymer database system "PoLylnfo". C. Maeda, K. Nagasaka Hilton Hawaiian Village Tapa Ballroom II, Tapa Conference Center Transition-Metal-Facilitated Reactions Leading to Organic Heterocycles (182)

P. Wyn Jennings, Presiding 1:05—1701. New rhodium-catalyzed allylic substitution chemistry. P. A. Evans 1:35—1702. Palladium-catalyzed new synthesis of indole and furan derivatives. Y. Yamamoto 2:05—1703. Cycloaddition/nucleophilic trapping reactions of cobalt stabilized propargyl dication equivalents. J. Green, Y. Lu 2:35—1704. Palladium-catalyzed asymmetric synthesis of some natural alkaloids. M. Mori 3:05—1705. Efficient and selective routes to lactones, lactams, and related heterocycles via Pd-catalyzed cyclization and their applications to the synthesis of natural products. E-l. Negishi 3:35—1706. Silicon-based cross-coupling strategy for heterobiaryl synthesis. T. Hiyama 4:05—1707. Enantioselective reactions of metal-heteroatom multiple bonds with organic molecules. R. G. Bergman, Z. K. Sweeney, J. L. Salsman, R. A. Andersen, J. S. Johnson, S. R. Jenkins Hilton Hawaiian Village Tapa Ballroom I, Tapa Conference Center Prospects for Automated Solution-Phase Synthesis in the 21st Century (030)

K. Nomura, Presiding 1:05—1539. Flow-line automated apparatus for solution phase synthesis. T. Sugawara 1:45—1540. A/-Oxyl-mediated electrooxidation of alcohols in a silica-disperse aqueous system. H. Tanaka, M. Kuroboshi, Y. Kawakami, K. Goto 2:05—1541. Application of expert system technologies to automated chemistries. M. Stillman, S. Lahiri, H. Du 2:25—1542. Solution-phase parallel synthesis based on the cation pool method. J-l. Yoshida, S. Suga, S. Suzuki, N. Kinomura, K. Fujiwara, M. Okajima 2:45—1543. Automation for the process of chemical research and development. N. Imaki 3:05—1544. Electroreduction of esters for automated synthesis. H. Yamashita, S. Kashimura, M. Ishifune, N. Yamashita 3:25—1545. Parallel solution-phase synthesis on an automated platform. K. Machida, A. MacDonald, J. Labadie 3:45—1546. Fluorous synthesis techniques: From separating mixtures to making mixtures. D. P. Curran 4:20—1845. Construction of a high-throughput preparative chemical synthesis system consisting of a robotic arm with modular reactors and workup stations. K. Nokihara, O. Shinnji, K. Yukiyoshi, K. Hiroki, K. Nobusuke, S. Shogo, B. Albert, Y. Shizue, N. Yasuo Hilton Hawaiian Village Honolulu Suite II, Tapa Conference Center Photoremoveable Protecting Groups and Caged Compounds: Principles and Applications (035)

K. Nomura, Presiding 8:05—1261. General method for photoinitiating protein folding in a nondenaturing environment. S. I. Chan, K. C. Hansen, R. S. Rock 8:40—1262. Hydroxy and amino-cinnamate phototriggers. N. Porter 9:10—1263. Caged leucyl-leucine methyl esters that control apoptosis of immune cells: Development of caged-drugs and a new drug delivery system. M. Iwamura, S. Watanabe, H. Mizuta 9:45—1264. Light-directed activation of caged myosin in muscle fibers. G. Marriott, J. C. Rueeg, H. Koegler 10:15—1265. Engineered channels and enzymes for controlling cell signaling. H. Bayley 10:55—1266. Caged proteins: Manipulation of signal transduction pathways. D. Lawrence


143

ORGN/PHYS/TECHNICAL PROGRAM

Hilton Hawaiian Village Honolulu Suite I, Tapa Conference Center Biocatalysis in Organic Synthesis (138)

Hilton Hawaiian Village lolani Suite VII, 2nd Floor, Tapa Conference Center


Organic Chemistry General Session (09G-06)

1:05—1645. Enzymatic approach to carbohydrate-based drug discovery. C-H. Wong 1:35—1646. Glycosyltransferases in oligosaccharide synthesis. M. Palcic 2:05—1647. Recent lipase-catalyzed synthesis of optically active intermediates. Y. Hirose 2:35—1648. Lipase-catalyzed synthesis of chiral amines or esters of 1,1f-binaphthyl derivatives. T. Izumi, T. Kijima, N. Aoyagi 2:55—1649. Asymmetric synthesis of novel trifluorinated allylic alcohols through chemo-enzymatic reaction strategy. T. Itoh, K. Kudo, F. Tamai 3:15—1650. Synthesis of useful chiral compounds by using a low-temperature method of lipase-catalyzed resolution. T. Sakai, T. Ema, M. Utaka 3:35—1651. Esterification catalyzed by a lipid-coated lipase in supercritical fluids. T. Mori, A. Kobayashi, Y. Okahata 3:55—1652. 2-Haloacid dehalogenase: Structure, function, and mechanism. N. Esaki, T. Kurihara, T. Yoshimura, K. Soda

L-C. Lo, Presiding

Hilton Hawaiian Village Honolulu Suite III, Tapa Conference Center Chemistry of the Organic Solid-State: Synthesis, Structure, and Reactivity (007)

K. Nomura, Presiding 1:05—1530. Single-crystal-to-single-crystal enantioselective [2+2] photodimerization of coumarin and thiocoumarin in inclusion complexes. K. Tanaka, F. Toda 2:05—1531. Thermodynamic control of stoichiometry in organic mixed crystals by hydrothermal synthesis: 1:2, 1:1, 3:2, and 2:1 adducts of bipyridines and polybenzoic acids. I. D. Williams, S. S-Y. Chui, T. M. Fasina, A. W-H. Siu, S. M-F. Lo, L-Y. Shek, H-M. Yip, J. A. K. Cha 2:20—1532. Self-assembly of aromatic acids: How to control the dimensions of the supramolecular structures in the crystal lattice. S. Valiyaveettil, A. Hoong Kar Min, Z. Ning 2:50—1533. Clathrate inclusion within flexible molecular pens. R. Bishop, D. Craig, N. Rahman, M. Scudder 3:20—1534. Host framework isomerizations driven by packing coefficient of host cavity in chloic acid inclusion crystals. K. Sada, K. Nakano, Y. Kurosumi, M. Miyata 3:35—1535. Packing structures of twisted molecules. N. Hayashi 3:50—1536. Chiral crystallization of achiral molecules in two-component systems. H. Koshima 4:20—1537. New enantiomeric resolution phenomenon (preferential enrichment) (Part 15): Mechanism of polymorphic transformation. R. Tamura, H. Takahashi, K. Misaki, H. Miura 4:35—1538. Anisotropically ordered solid films of perylene dyes generated via selforganization into a liquid-cystalline phase. S-W. Tarn-Chang, I. Iverson Hilton Hawaiian Village Honolulu Suite II, Tapa Conference Center Photoremoveable Protecting Groups and Caged Compounds: Principles and Applications (035)

K. Nomura, Presiding 1:05—1547. Progress in caged neurotransmitters. J. E. T. Corrie 1:40—1548. Transport mechanism of the glutamate transporter and the ADP/ATP carrier by use of caged substrates. E. Bamberg, C. Grewer, T. Gropp, M. Klingenberg 2:15—1549. Illuminating reactions controlling communications between brain cells using light-activatable neurotransmitter precursors (caged neurotransmitters). G. Hess 2:50—1550. Caged cholinergic ligands for dynamic crystallographic studies on acetycholinesterase. M. Goeldner, A. Specht, S. Loudwig, D. Bourgeois, T. Ursby, M. Weik, L. Peng 3:25—1551. Novel caging groups for bioactive amino compounds and their applications. H. Shiono, H. Nohta 4:00—1552. p-Hydroxyphenacyl phototrigger: In a class by itself. R. Givens

144


1:05—1708. Evaluation of a-methylasparagine as a substitute for asparagine in turn motifs. S. A. Hopkins, D. L. Guzman, J. P. Konopelski 1:25—1709. Mechanism-based selection and labeling of biocatalysts: Design and synthesis of an activity probe for sialidases. L-C. Lo 1:45—1710. Hydrogen bonding in biotin amides. G. Crisp, Y-L. Jiang 2:05—1711. Noncovalent approach to the nucleation and stablization of b-sheets. B. Gong 2:25—1712. Metal ion-assisted base pairing in DNA. E. Meggers, P. G. Schultz, F. E. Romesberg 2:45—893. Functionalization of C60 fullerene by hypervalent iodine reagents. C. Wilfred 3:05—1713. Aroma analysis of food and quality control: A comparison of methods. S. Van Ruth, C. O'Connor 3:25—1714. Reduction of lake water eutrophication caused by nitrogen and phosphorous from a nearby paddy field using a circular irrigation system. K. I. Suga, T. Omasa, Y. Katakura, M. Kishimoto 3:45—1715. Antibody catalysis of the 1,3dipolar cycloaddition reaction. P. Wentworth, Jr., J. Toker, K. Janda 4:05—1716. Polyphenols: Synthesis, characterization, and investigation of the structure-property relationship. B. Venkataramanan, S. Valiyaveettil 4:25—1717. Bond-labeling studies of butyrate biosynthesis in anaerobic bacteria. R. L. White, F. S. Lee, R. D. Witherell

MONDAY EVENING Hilton Hawaiian Village Tapa Ballroom III, Tapa Conference Center Marine Natural Products Chemistry (110) Paul J. Scheuer Symposium: Celebrating a Half-Century of Research at the University of Hawaii R. Okuda,

Presiding

7:05—1730. Pilgrimage from macro to micro and back to macro. M. Munro, J. Blunt, T. Cole 7:50—1731. Mining natural molecular diversity. J. Davies 8:35—1732. Phylogeny and biosynthetic potential of bacteria hosted by the sponge Theonella swinhoei. B. S. Moore, J. Hopke 9:05—1733. Peptides and depsipeptides from a reef-inhabiting cyanobacterium from Guam. H. Luesh, R. E. Moore, V. J. Paul 9:20—1734. Stereochemistry and biosynthesis of amphidinolide c. T. Kubota, H. Ishiyama, M. Tsuda, J. Kobayashi 9:35—1735. Novel cyclopropane containing cerebroside from the red alga Amphiroa fragilissima. B. N. Pramanik, A. K. Bose, M. S. Manhas, P. S. Parameswaran, C. G. Naik, P. L. Bartner, P. A. Shipkova, T. M. Chan, Y-H. Ing 9:50—1736. Pterocellins: Novel heterocyclic pigments from the marine bryozoan Pterocella vesiculosa. M. Prinsep, B. Yao Hilton Hawaiian Village Coral Ballroom III, Mid-Pacific Conference Center Biocatalysis in Organic Synthesis (138) Poster Session 7:30-9:30 1653. Asymmetric synthesis of partly fluorinated molecules via lipase-catalyzed reaction. E. Akasaki, T. Itoh, N. Ishida 1654. Formation of chiral ketones by the hydrogenation of the C-C double bond of enones with reductases from Nicotiana tabacum. T. Hirata, K. Shimoda 1655. Lipase-catalyzed optical resolution of 2,2,2-trifluoro-1 -phenylethylamine. K. Kato, Y-F. Gong, H. Kimoto 1656. Stereochemical behaviors of 2-substituted cyclohexanols in lipasemediated acetylations. Y. Matsumoto, R. Tanikaga, M. Sakaguchi

1657. Asymmetric reduction of fluorinated ketones with biocatalysts. K. Nakamura, T. Matsuda, R. Yamanaka, M. Hori 1658. Biotransformation of organic compounds by plant suspension cells. H. Hamada 1659. Substrate specificities of some prenyl chain elongating enzymes with respect to 3-alkyl group homologs of isopentenyl diphosphate. M. Nagaki, H. Kimura, Y. Maki, T. Nishino, T. Koyama 1660. Lipase-catalyzed kinetic resolution of primary alcohols. M. Kawasaki, M. Goto, T. Kometani 1661. Antibody-catalyzed removal of the p-nitrobenzyl ester protecting group: The molecular basis of broad substrate specificity. T. Tsumuraya, S. Kurihara, T. Wakabayashi, K. Suziki, M. Kuroda, L. Liu, Y. Takaoka, I. Fujii 1662. Lipase-catalyzed optical resolution of p-chiral phophorus compound and its application. Y. Ueno, K. Shioji, K. Okuma 1663. Reduction of ketones and photosynthetic living cells. R. Yamanaka, T. Matsuda, H. Hamada, K. Nakamura 1664. Preparation of a ceramics carrier toyonite for the immobilization of lipase and characterization of the lipase supported on the carrier. M. Kamori, Y. Yamashita, Y. Naoshima 1665. Great productivity in enantioselective reduction of aryl ketones with highly active yeasts. A. Hanatani, M. Tanaka, M. Takehara, Y. Inoue, H. Hirohara 1666. Synthetic study of enantiomerically enriched oxazolidinones via /v-carbamylamino alcohol as the intermediate. M. Suzuki, C. Nagasawa, H. Ohta, T. Sugai 1667. Access to Wieland-Miescher ketone and analogs in enantiomerically pure forms via a yeast-mediated reduction and its application to natural product synthesis. K-l. Fuhshuku, N. Funa, H. Ohta, T. Sugai 1668. Single mutations of tyrosine-81 in farnesyl diphosphate syntase from Bacillus stearothermophilus affect the substrate specificities. Y. Maki, M. Komabayashi, N. Ohya, H. Hemmi, T. Nishino, T. Koyama 1669. Novel asymmetric dealkoxycarbonylation of 3-oxo-8-azabicyclo[3.2.1]octane2,4-dicarboxylates using porcine liver esterase. T. Nakai, S. Nakamura, T. Katoh, M. Node 1670. Bacterial epoxide hydrolases in organic chemistry. S. F. Mayer, A. Steinreiber, K. Faber 1671. Determination of the absolute configuration of novel 1,1,2-trifluoro-1-alken-3-ols. Y. Takagi, T. Itoh, T. Oshiki 1672. Screening of thermophilic fungi for hydrolase activity and enantiotope selective acylation of 2-substituted-1,3-diols. G. Szakacs, L. Poppe, V. Bodai, R. Peredi, J. Balint, L. Novak 1673. Studies on the mechanism of the stereoselective catalysis of lipases. S. Shinohara, T. Yoshikawa, Y. Inoue, M. Takehara, H. Hirohara 1674. Cytochrome C crown ether complexes as effective biocatalysts in enantioselective sulfoxidation. H. Tsukube, A. Suzumura, T. Yamada, S. Shinoda 1675. Thiazolium-dependent catalytic antibodies produced using a covalent modification strategy. F. Tanaka, R. A. Lerner, C. F. Barbas III 1676. Stereocontrolled reduction of a- and (3-keto esters with micro green algae. K. Ishihara, H. Yamaguchi, N. Adachi, N. Nakajima 1677. Enzymatic synthesis of optically active azirine derivatives and their selective functional group transformation. M. Takahama, S. Takada, T. Ema, T. Sakai 1678. Enhancement of efficiency in the lipase-catalyzed optical resolution by using porous ceramics support at low temperature. K. Hayashi, T. Ema, T. Sakai 1679. Is there a need for a specific "DielsAlder-ase"? A. Wittkopp, P. R. Schreiner

The Organizing Committee requests that (here be no smoking in meeting rooms or committee meetings

1680. Asymmetric reduction of cc-keto esters with thermophilic actinomycete: Purification and characterization of oc-keto ester reductases from Streptomyces thermocyaneoviolaceus IFO 14271. H. Yamaguchi, K. Ishihara, K. Nakumura, N. Nakajima 1681. 1-Ethoxyvinyl esters as novel, efficient acyl donors for lipase-catalyzed enantioselective transesterifications of racemic alcohols and prochiral diols. S. Akai, T. Naka, Y. Takebe, Y. Kita 1682. Bioconversion of endocrine disrupters with biocatalysts. M. Hori, R. Yamanaka, N. Nakajima, T. Matsuda, K. Nakamura 1683. Synthesis of lactoside derivative for the saccharide elongation by biosynthetic pathway. K. Hatanaka, M. Kobayashi, T. Yamagata, T. Sato 1684. Highly enantioselective synthesis of optically active diols by microbial hydrolysis of cyclic carbonates. M. Shimojo, Y. Sato, K. Matsumoto, M. Hatanaka 1685. Enzyme-mediated enantioselective hydrolysis of cyclic carbonates with functional groups. K. Matsumoto, Y. Nakamura, M. Hatanaka 1686. Biocatalyzed synthesis of some natural products from chlorophenylpyruvic esters. S. Tsuboi, H. Hamamoto, M. Kitamoto, N. Hayashi 1687. Transglycosylations catalyzed by lipidcoated glycoside hydrolases in supercritical fluids. Y. Okahata, T. Mori, M. Li, M. Funasaki 1688. Total syntheses of (R)- and (S)-elvirol based on enzymatic resolution of primary alcohol. M. Ono, H. Akita, T. Kashiwagi 1689. Influence of leaving group of an acyl donor on enzymatic peptide synthesis. K. Kawashiro, S. Sakai 1690. Enzymatic kinetic resolution of vicinal diols. H. Kaga, K. Hirosawa, T. Takahashi, K. Goto 1691. Directed evolution of a lipase with high enantioselectivity toward Solketal (2,2dimethyl-1,3-dioxolane-4-methanol), an impotant chiral c-3 synthon. R. J. Kazlauskas, A. M. F. Liu, C. Guerard, A. Mezzetti, E. Togan-Tekin, C. SchmidtDannert, R. D. Schmid 1692. Synthetic study of driman-type chiral synthon based on enzymatic function. M. Nozawa, A. Hiroyuki 1693. Efficient synthesis of enantiomerically pure 4-fluoro-3-hydroxybutanamides. M. Sato, K. Suxuki, Y. Suzuki, M. Mori, H. Ono, C. Miyazaki 1694. Reaction searching for biochemistry and organic synthesis. W. D. Ihlenfeldt Hilton Hawaiian Village Honolulu Suite III, Tapa Conference Center Chemistry of the Organic Solid-State: Synthesis, Structure, and Reactivity (007)

K. Nomura, Presiding 7:05—1718. Structural control of the assembly of new molecular solids. L. F. Lindoy 7:35—1719. Novel example of spontaneous optical resolution in diastereoselective crystallization of saddle-shaped porphyrins. Y. Mizuno, T. Aida, K. Kinbara, K. Saigo, K. Yamaguchi 7:50—1720. Black organic crystals. R. Kuroda, F. Toda, M. Senzaki 8:20—1721. Synthesis and optical properties of macrocyclic compounds with carbazole trimer units. A. Gunji, I. Yoshihiro, S. Hiroyuki, W. Tatsuo 9:35—1722. Rapid X-ray diffraction measurement and structure analysis using micro strip gas chamber. H. Uekusa, Y. Ohashi, A. Ochi, T. Tanimori 10:35—1723. Abnormally distorted structures: Elongated C-C bonds and bowed aromatic rings. M. Kato, K. Tanaka, F. Toda 11:05—1724. Optical probes of crystal growth mechanisms: Intrasectoral zoning. B. Kahr 11:35—1725. Molecular meccano kit. J. F. Stoddart, S. J. Cantrill, A. R. Pease

Hilton Hawaiian Village Honolulu Suite II, Tapa Conference Center Photoremoveable Protecting Groups and Caged Compounds: Principles and Applications (035)

K. Nomura, Presiding 7:05—1726. Caging without light. G. D. Prestwich 7:45—1727. Synthesis, evaluation, and applications of novel ort/ionitroprotecting groups. C. Holmes, Y. Pan 8:25—1728. Caged compounds with fast photochemical deprotecting reaction. K. Fujimori 9:05—1729. Molecular disassembly: Phototake-apartable molecular objects. A. Kutateladze, Y. Wan, A. Kurchan, L. Barnhurst Hilton Hawaiian Village Honolulu Suite I, Tapa Conference Center Organic Photochemistry (141)

H. Zimmerman, Presiding 7:05—1737. Photochemical ring opening of cyclobutene: Stereospecific (conrotatory) ring opening via the n R(3s)Rydberg state. W. J. Leigh, B. H. O. Cook, A. Litovitz 7:40—1738. Enhancement of redox reactivities of photoexcited states by complexation with metal ions. S. Fukuzumi 8:15—1739. Photochemical reactions in supercritical carbon dioxide. A. Weedon, D. Andrew, B. Desislet, S. Saha

TUESDAY MORNING Hilton Hawaiian Village Tapa Ballroom III, Tapa Conference Center Marine Natural Products Chemistry (110) Paul J. Scheuer Symposium: Celebrating a Half-Century of Research at the University of Hawaii

R. Okuda, Presiding 8:05—1774. Neurotoxic lipopeptides from marine cynanobacteria. W. Gerwick, T. Okino, M. Wu, N. Sitachitta, L Nogle, B. Marquez, T. Williamson, K. Colson, T. Murray 8:50—1775. Chemistry in marine ecotoxicology. T. Yasumoto 9:35—1776. Chemical defenses of marine benthic cyanobacteria: Effects on consumers. V. J. Paul, E. Cruz-Rivera, R. W. Thacker 10:20—1777. Functional roles of natural products from marine sponges. B. Baker, B. Furrow, J. Tipton, J. Baker, J. McClintock 10:35—1778. Okadaic acid-binding proteins from the sponge Halichondria okadai: A clue to the molecular mechanisms of selfresistance. N. Sugiyama, K. Fukatsu, K. Konoki, K. Tachibana 10:50—1779. Interactions between brevetoxins and nucleophiles: Significance in metabolism and detoxification. Y. Shimizu, T. Sano 11:05—1780. Unique structures of two polyether compounds, azaspiracid and gymnocin-A. M. Satake, K. Ofuji, M. Shoji, Y. Oshima, T. Yasumoto Hilton Hawaiian Village lolani Suite V/VI, Tapa Conference Center Free Radicals: From Molecules to Materials (128)

R. Hicks, Presiding 8:05—1781. Control of exchange coupling in organic molecules and polymers. A. Rajca 8:35—1782. Electrochemical studies on heterocyclic free radicals. R. Boere 8:55—1783. Spin coupling in diaminonaphthalene diradical dications. S. C. Blackstock, T. D. Selby, K. Y. Kim 9:15—1784. Ferromagnetic self-assembly by heterocyclic nitronyl nitroxide radicals bearing NH site. N. Yoshioka, H. Nagashima, Y. Takeda, S. Taniyama, N. Matsuoka, H. Inoue 9:35—1785. Magnetic molecular bistability in organic radical crystals. K. Awaga, W. Fujita 10:05—1786. UB1LYP as an accurate and efficient tool for computing the total hyperfine tensors of neutral monocyclic, bicyclic, and tricyclic radical building blocks of neutral conductors. S. M. Mattar, A. D. Stephens

10:25—1787. Protonation-induced spinunpairing in a benzoquinone diimine derivative carrying a triphenylamine. M. Sandberg 10:45—1788. Magnetic force microscopic images of nm-sized poly(radicalsubstituted styrene) particles. T. Michinobu, E. Tsuchida, H. Nishide Hilton Hawaiian Village Coral Ballroom I, Mid-Pacific Conference Center Use of Chemical Information in Organic Synthesis (175)

G. Grethe, Presiding 8:05—1797. Database for transition states of chemical reactions. K. Hori 8:35—1798. De novo design of synthetically accessible ligands. P. Johnson, J. Marchaland, K. Boda 9:05—1799. Mining reaction databases. R. Synder 9:35—1800. Endeavor: Chemical intelligence in the automatic design of targeted combinatorial libraries. J. C. Baber 10:00—1801. How to design target molecules using on-line information. Z. Zhao, T. Wilks, M. Wang 10:25—1802. Internet/intranet tools for developing synthetic methodology. T. Wright 10:50—1803. Cheminformatic tools enabling high-throughput medicinal chemistry. J. C. Phelan Hilton Hawaiian Village Tapa Ballroom I, Tapa Conference Center Prospects for Automated Solution-Phase Synthesis in the 21st Century (030) K. Nomura,

Presiding

8:35—1740. Automated synthesizer for sequential reactions. J. Otera 9:15—1741. Design of an automated synthesis apparatus for moisture-sensitive reaction in solution phase. S. Nishimura, H. Sasaki, A. Tanaka, H. Miyoshi, N. Sawada 9:35—1742. Improvement of automated synthesizer for solution-phase parallel synthesis at low temperature. S. Suga, K. Fujiwara, H. Sasaki, S. Suzuki, J-l. Yoshida 9:55—1743. Variety of microreactors: Integration and parallelization. T. Fujii 10:15—1744. Multifunctional phase tag for solution-phase synthesis. K. Itami, K. Mitsudo, T. Nokami, T. Koike, T. Kamei, S. Suga, J-l. Yoshida 10:35—1745. Robotic workstation for automated organic synthesis. I. Dohgane 10:55—1746. Synthesis of perfluorinated allylic compounds by radical allylation and their purification over fluorous reversephase silica. S. Kreimerman, I. Ryu, T. Niguma, S. Minakata, M. Komatsu, Z. Luo, D. P. Curran 11:15—1747. Doing, sensing, and thinking with automated synthesis systems. H. Du, J. Lindsey Hilton Hawaiian Village Honolulu Suite II, Tapa Conference Center Photoremoveable Protecting Groups and Caged Compounds: Principles and Applications (035)

K. Nomura, Presiding 8:05—1748. Controlling physiological messenger action with multiphoton uncaging reactions. R. Y. Tsien, T. M. Dore, D. Magde, V. Lev-Ram, Y. Kovalchuk, A. Konnerth 8:40—1749. Novel caged fluorophores: Synthesis and applications. K. Gee 9:15—1750. pHP-caged ATP for the rapid activation of the Na+, K+-ATPase. K. Fendler, S. Geibel, A. Barth, S. Amslinger, A. Jung, C. Burzik, R. Clarke, R. Givens, K. Fendler 9:55—1751. Photoremovable protecting groups for two-photon uncaging: Design, syntheses and photochemical properties of coumarin-caged compounds. T. Furuta, K. Nishiyama, M. Iwamura, R. Y. Tsien 10:30—1752. 4-Thiouracil as a nucleic acidprotein photocrosslinking agent. S. Seifried 11:05—1753. Force generation and detachment of single kinesin molecules activated by. T. Yanagida, H. Higuchi

Hilton Hawaiian Village South Pacific Ballroom III, Mid-Pacific Conference Center




M. Denk, Presiding

J. Coxon, Presiding

8:35—1813. Dehydrogenation of animals as pathway for the synthesis of diaminocarbenes. M. K. Denk, J. Brownie, J. M. Rodenzo, S. Gupta, A. J. Lough 8:55—1817. Reactions of buckminsterfullerene with Arduengo's carbenes: Formation of carbene dimers. K. Takeda, Y. Kawamura, M. Nishiuchi, M. Tsukayama 9:15—1820. Generation and reactions of monoalkylfullerenyl cations. T. Kitagawa, M. Hanamura, H. Konno, H. Sakamoto, K. Takeuchi 9:35—1823. Structure-reactivity relationship on the Menschutkin reaction under high pressure. S. D. Yoh 9:55—1826. Study of the mechanism of the reaction of anacomeric 2-lithio-2-methyland 2-lithio-2-phenyl-1,3-dithiane and chlorodiphenylphosphine. B. Gordillo, Z. Dominguez, N. Sanchez 10:15—1829. Electrophilic chemistry of tetrahydropyridines and related systems. D. Klumpp, S. De Leon, S. Lau 10:35—1831. Chemosensor based on guestresponsive exciplex emission of heteromodified y-cyclodextrins. F. Hamada, M. Narita 10:55—1835. Synthesis and time-resolved optical spectroscopy of novel porphyrincontaining dendrimers. D. A. Modarelli, C. S. Rajesh, G. J. Capitosti, S. J. Cramer, C. Guerrero 11:15—1837. Spaced-out binding sites: Structural requirements for trapping reactive intermediates in the hydrogen bonddirected assembly of rotaxanes. J. K. Y. Wong, D. A. Leigh, F. G. Gatti, A. J. Wilson 11:35—1840. Effect of oxygen-containing substituents of phenolic antioxidants. T. Kajiyama, Y. Ohkatsu 11:55—1841. Proposed mechanism for the heterogeneous permanganate oxidation of arenes. N. Noureldin, L. Dalrymple

8:35—1814. Unique character of twisted 1.3 dienes: Vinyl hydrogens highly activated by a-7t orbital interaction. H. Mori, K. Ikoma, T. Matsuo, S. Katsumura 8:35—1825. Withdrawn. 8:55—1816. Ab initio study of temperaturedependent structure of 4-silatriafulvene and its derivatives. M. Takahashi, K. Sakamoto, M. Kira 9:15—1819. Theoretical and experimental study of the acid-catalyzed rearrangement of epoxides. J. Coxon, A. J. Thorpe 9:35—1822. Transient phenomena of reactive intermediates. T. Majima, N. Ichinose 9:55—1828. In situ observation of molecular swapping in a crystal by X-ray crystallography. M. Kawano, Y. Ohashi, J. Abe 10:15—1832. Steric and electronic contributions to carbon-13 chemical shifts of substituted adamantanes, diamantanes, and triamantanes. K. Leal, P. Seidl 10:35—1834. New data on reactivity of the nitrogen and oxygen ylides generated by carbenes. R. Kostikov 10:55—1838. Oxidation, hydrogenation, and hydrolysis of stable diamino carbenes. M. Denk, J. M. Rodezno, J. H. Brownie, S. Gupta, L. Studnicki, A. J. Lough 11:15—1839. Stereochemistry of the singlet oxygen alkene-ene reaction: Asymmetric induction due to H/D isotopic competition. M. Orfanopoulos 11:35—1842. Helical structure and optical rotation. B. Deng, H. Jijun

Hilton Hawaiian Village lolani Suite VII, 2nd Floor, Tapa Conference Center Organic Chemistry General Session (09G-07)

R. Blanch, Presiding 8:05—1811. Synthesis of novel supramolecular structures based on cucurbit[/7]urils. R. Blanch, A. Arnold, A. Day, T. White 8:25—1812. Synthesis and structure of a colossal quinone and related nanomaterials. K. V. Kilway, J. A. Watson, Jr., R. D. Ingalls 8:45—1815. Nucleation and growth mechanism of electroformation of polypyrrole. B-J. Hwang, R. Santhanam, Y. L. Lin 9:05—1818. Molecular electronics: Synthesis of a gate-throttle-wire module and its electron-transport properties. J. R. Smith, T. Brotin, J. Pecka, J. R. Miller, J. P. Kirby, A. Reisinger, J. Michl 9:25—1821. Electropolymerization of polyaniline used to fabricate an amperometric nitrogen dioxide gas sensor. J-S. Do 9:45—1824. Microsegregation in polyelectrolyte gels. N. Sitnikova, O. E. Philippova, T. G. Pieper 10:05—1827. Amine, polyamide, and anhydride curing of epoxy sucroses. N. D. Sachinvala, D. L. Winsor, N. R. Bertoniere 10:25—1830. Novel organosoluble cardo copolyimides. Y. S. Vygodskii 10:45—1833. Thermolysis of a heavy alkylate byproduct for the production of light aromatic hydrocarbons. R. M. Habib, F. I. Kenawi, S. S. Mutawaa 11:05—1836. Removal of VOCs emitted from coating process using electron-beam irradiation. J-C. Kim, H-J. Jeong, S-J. Kim, K-W. Lee, S-Y. Cho, J-S. Choi, K-W. Lee, K-J. Kim

Hilton Hawaiian Village Tapa Ballroom II, Tapa Conference Center Transition-Metal-Facilitated Reactions Leading to Organic Heterocycles (182)

P. W. Jennings, Presiding 8:35—1804. Synthesis of cyclic compounds by active metal species derived from tin precursor. A. Baba, I. Shibata, M. Yasuda 9:05—1805. Metal-catalyzed reactions of silacyclopropanes as selective methods for organic synthesis. K. Woerpel, J. Cirakovic, T. G. Driver, A. K. Franz 9:35—1806. Approaches toward furancontaining natural products using asymmetric Pd-catalyzed polyene cyclizations. B. A. Keay, S. Y. W. Lau, N. G. Andersen 10:05—1807. Group 3- and lanthanide metallocenes as catalysts for heterocyclic synthesis. G. Molander 10:35—1808. Pd-catalyzed synthesis of polysubstituted butenolides, vinylic oxiranes, and furans. S. Ma 11:05—1809. Organometallic-based bond constructions in natural and unnatural products chemistry. B. H. Lipshutz, P. Papa, D. Leinweber, R. Vivian, C. Olsson, K. Noson, W. Chrisman, P. Blomgren 11:35—1810. New metal catalyzed routes to medium and large heterocycles. W. R. Jackson, E. M. Campi, D. J. Bergmann, A. F. Patti, T. Ventrice

PHYS AREA 10-PHYSICAL AND THEORETICAL CHEMISTRY THURSDAY MORNING Sheraton Waikiki Niihau Room, 2nd Floor Solvated Molecules and Ions: From Clusters to Condensed Phases (004)

D. Salahub, Presiding Photographing of slides and/or taping of talks is prohibited unless permission is obtained from individual presenters

8:35—1. Water clusters: Terahertz and IR cavity ringdown spectroscopy results. R. J. Saykally

OCTOBER 2, 2000 C&EN 1 4 5

PHYS/TECHNICAL PROGRAM

9:15—2. Molecular-level understanding of the dissociation of strong oxo-acids in water. S. Xantheas 9:55—3. Probing molecules on ice: Determination of the ionization constant of HCI on ice. H. Kang, T-H. Shin, S-C. Park, S-J. Han 10:15—4. Spectroscopy of hydrogen-bonded clusters of halide ions and ammonia. M. Okumura, C-K. Wong, J. Lobo 10:35—5. Hydrogen bonding and charge resonance interactions in aromatic cluster ions. K. Ohashi 11:15—6. Effective fragment potential method: Theory and applications. M. Gordon Sheraton Waikiki Kauai Ballroom, 2nd Floor Recent Progress in the Science and Technology of Fullerenes and Nanotubes (016)

Y. Achiba, Presiding 8:05—7. Perspectives on carbon nanoparticles: A missing link. E. Osawa 9:05—8. Carbon nanotubes: Morphology and growth. S. lijima 10:05—9. Electronic structure of doped nanotubes and superconducting fullerides. S. Saito 10:35—10. Growth and structure of singlewall carbon nanotubes and giant fullerenes. Y. Achiba 11:05—11. Withdrawn. Sheraton Waikiki Hilo Room, 2nd Floor Chemical Applications of Synchrotron Radiation (022)

T. Ohta, Presiding 8:35—12. Spectroscopy and dynamics of molecular superexcited states. Y. Hatano 9:00—13. Chemical dynamics probed with tunable undulator radiation. A. Suits, F. Qi, O. Sorkhabi 9:25—14. SR-pump and laser-probe experiments for the photodissociation dynamics of gaseous molecules. K. Mitsuke 9:50—15. Light-induced excited spin-state trapping with X-ray absorption spectroscopy. Y. Wang, J. J. Lee, H. S. Sheu 10:15—16. Control of chemical reactions by core excitation. K. Tanaka, E. Ikenaga, K. Isari, T. Sekitani, S-l. Wada 10:40—17. Imaging in chemical dynamics in conjunction with synchrotron radiation. M. Ahmed, T. Baer, D. Peterka, P. Regan 11:00—18. Mechanism of hydrogen ion desorption induced by oxygen 1s resonant transitions of condensed water studied by high-resolution electron-ion coincidence spectroscopy. K. Mase, S. Tanaka, T. Urisu, T. Sekitani, E. Ikenaga, K. Tanaka 11:15—19. W-values of rare gas atoms for monochromatic photons in the soft X-ray region. I. H. Suzuki, N. Saito Sheraton Waikiki Kohala/Kona Rooms, 2nd Floor Laser Control and Manipulation of Molecules (103) Kent R. Wilson Memorial Symposium

R. J. Gordon, Presiding 8:30—Introductory Eulogy. R. J. Gordon 8:45—1316. Algorithm for closed-loop control of quantum dynamics. H. Rabitz 9:15—1345. Quantum control of enantiomer preparation from racemates. Y. Fujimura 9:45—1331. Coherent control with femtosecond three-pulse four-wave mixing. M. Dantus, V. Lozovoy, B. Grimberg, I. Pastirk 10:15—1326. Developments in coherent control: Nanoscale molecular deposition. P. Brumer, M. Shapiro 10:45—1340. Coherent manipulation of atomic motion at a metal surface. H. Petek, S. Shah, S. Ogawa 11:15—1325. Quantum coherence in nonlinear optical processes. J. Cao 11:45—1320. Dynamics of two-level systems in a laser standing wave. C. J. Lee

Sheraton Waikiki Koko Crater Room Fluids at Interfaces (114)

D. Henderson, Presiding 8:35—28. Ions in biological channels. B. Eisenberg 9:00—29. Dynamics of electrified fluid interfaces. M. Philpott, S. Izvekov, I. Goliney, T. Lin 9:30—30. Computer simulations of electrolyte solutions at interfaces: Status, limitations, challenges. E. Spohr 10:00—31. Ewald summation for systems with slab geometry. I-C. Yeh, M. Berkowitz 10:30—32. Simulation of model aqueous electrolytes near a charged surface. R. Rowley, P. Crozier 11:00—33. Computer simulations of confined electrolytes. K-Y. Chan, Y. Tang, I. Szalai, M.Lee 11:30—34. Electronic structure and liquid structure at metal oxides-water interfaces. T. Truong Sheraton Waikiki Molokai Ballroom, 2nd Floor Computational Quantum Chemistry: Theoretical and Experimental Perspectives (125)

J. Goddard, Presiding 8:05—35. Homoconjugation with the adamantane cage. G. Olah, G. Rasul, G. Prakash 8:35—36. Theoretical studies of reaction mechanisms of transition-metal-mediated reactions. G. Frenking 9:05—37. Experiments and theory concerning atoms inside cages. M. Saunders, R. J. Cross 9:35—38. What electronic structure calculations can tell us about the reactivities of organic and organometallic compounds: Some case studies. W. Borden 10:05—39. a-Helices and molecular wires: Semiempirical MO-simulations. T. Clark 10:35—40. Cyclic electron delocalization. P. Schleyer Sheraton Waikiki Akaka Falls Room, 2nd Floor Physical and Theoretical General Session (10-G1)

K. Makoshi, Presiding 8:35—48. Isomeric higher and smaller fullerenes: A profound enthalpy/entropy interplay. X. Zhao, Z. Slanina, E. Osawa 8:55—49. Withdrawn. 8:55—50. Heat capacity of protein reproduced by a combination of extended scaled particle theory and the PoissonBoltzmann equation. M. Irisa 9:15—51. Unified theory of excitation and deexcitation of adsorbate vibrations. K. Makoshi, N. Mingo, T. Mii, H. Ueba 9:35—52. Dioxin sorption mechanism over 2:1 dioctahedral smectites: A DFT study. A. Chatterjee, T. Iwasaki, T. Ebina 9:35—53. Withdrawn. 9:55—54. Algorithm of a catalyst reaction simulator "LUMMOX". T. Motoki, A. Shiga 10:15—55. HMX reactivity: Effects of the condensed-phase environment. J. Lewis, K. Glaesemann, G. Voth 10:35—56. Reaction class transition-state theory. T. Troung 10:55—57. Investigations of the reaction kinetics on nanometer-sized catalyst particles using Monte Carlo simulations. H. Persson, P. Thormahlen, V. Zhdanov, B. Kasemo 11:15—58. Algebraic force-field Hamiltonian expansion approach to vibrations of linear and bent triatomic molecules. T. Sako, K. Yamanouchi, F. lachello Sheraton Waikiki Maui Ballroom, 2nd Floor


Sheraton Waikiki Puna Room, 2nd Floor Electrochemical Surface Science at Molecular/Atomic Resolution (033)

K. Uosaki, Presiding 8:35—20. Structures of 2- and 5-pyrimidinthiols modified gold single-crystal electrodes for cytochrome c and azurin electrochemistry. I. Taniguchi 9:05—21. Construction of homogeneously mixed monolayers of thiols on Au. K. Shimazu, T. Kawaguchi 9:20—22. Fabrication of nanostructured interfaces composed of a self-assembled monolayer of alkanethiols and underpotentially deposited metals. H. Yoneyama, D. Oyamatsu, H. Kanemoto, S. Kuwabata 9:50—23. Chirality recognition by a claymodified electrode. A. Yamagishi, N. Wakabayashi, M. Taniguchi, S. Takahashi 10:05—24. Potential modulated infrared study of the redox dynamics of an anthraquinone monolayer on Au. M. Osawa, H. Noda, K. Ataka 10:35—25. Evidence for local surface chemistry of amorphous carbon. B. Pettinger, A. Kudelski 11:05—26. Computational and experimental studies of carbon monoxide electrooxidation. M. Koper 11:35—27. Electrochemical nuclear magnetic resonance spectroscopic investigations of nanoscale Pt-based electrocatalysts, and Pt-CO bonding characteristics. A. Wieckowski, C. Rice, E. Oldfield, Y. Y. Tong

THURSDAY AFTERNOON Sheraton Waikiki Kauai Ballroom, 2nd Floor Recent Progress in the Science and Technology of Fullerenes and Nanotubes (016)

Y. Achiba, Presiding 1:05—59. New fullerene chemistry. C. A. Reed, D. Sun 1:35—60. Synthesis and isolation of higher fullerene oxide dimers C140OH and C1520H. T. Kudo, Y. Akimoto, H. Takahashi, K. Shinoda, B. Jeyadevan, K. Tohji, T. Nirasawa, A. Kasuya, Y. Nishina, W. Kraetschmer, S. Giesa 1:55—61. Computing isomeric fullerenes: A profound enthalpy/entropy interplay behind their relative populations. Z. Slanina, X. Zhao, E. Osawa 2:15—62. Molecular design and applications of novel supramolecular nanocontainers for fullerenes. T. Nishioka, K. Tashiro, T. Aida, K. Saigo, K. Yamaguchi 2:35—63. New avenues in fullerene chemistry: The azafullerenes. N. Tagmatarchis, H. Shinohara

Structure and Dynamics of Photogenerated Intermediates in Solution: Vibrational and Electronic Studies (147) J . Saltiel, Presiding 8:05—41. Solvent-induced dynamic polarization, vibrational dephasing, vibrational band width, and chemical reaction rates of reactive intermediates. H-O. Hamaguchi

146

8:40—42. Ultrafast intermolecular electrontransfer quenching of photoexcited viologens in polar solvents. J. Peon, X. Tan, J. D. Hoerner, K. M. Huchton, C. Xia, B. Kohler 9:05—43. Organic reactive intermediates monitored via electronic absorption and fluorescence spectroscopies. E. F. Hilinski 9:30—44. Conformational dynamics and vibrational relaxation in the excited state: A tale of two molecules. T. Gustafon, E. M. Kyllo, X. Tan, T. Frost, G. Buntinex, O. Poizat, C. Lefumeux, G. Burdzinki 10:05—45. Geminate recombination of the p-aminophenylthiyl radical in solution phase. Y. Hirata 10:30—46. Ultrafast studies of nitric oxide and electron transfer in solution. G. Walker 10:55—47. Ultrafast vibrational dynamics in condensed systems. K. Yoshihara, I. V. Rubtsov, T. Zhang, S. Kumazaki, H. Nakajima, S. Aono


2:55—64. Polyanionic high-spin C 6 o fullerenes and their clusters as studied by Cw/pulsed ESR spectroscopy. S. Nakazawa, M. Franco, M. Lazana, M. Shohoji, K. Sato, D. Shiomi, T. Takui 3:15—65. Solid-state reactions of fullerene C 60 with N-containing aromatics using a high-speed vibration milling technique. Y. Murata, N. Kato, K. Komatsu 3:35—66. Structure and electronic properties of photopolymerized Ceo films. J. Onoe, T. Nakayama, T. Hara, K. Takeuchi, M. Aono 3:55—67. Possible precursors of endohedral-metallofullerene. S. Maruyama, M. Kohno, S. Inoue 4:15—68. Cluster solids with carbon and heterocarbon polyhedral networks. K. Tanigaki Sheraton Waikiki Hilo Room, 2nd Floor Chemical Applications of Synchrotron Radiation (022)

T. Ohta, Presiding 1:05—69. Time-resolved diffraction studies of transient metastable and electronically excited states. P. Coppens 1:35—70. Impact of synchrotron radiation in protein crystallography. S. Wakatsuki 2:00—71. Application of synchrotron radiation to catalyst research. K-J. Chao 2:25—72. Development of in situ polarization-dependent total reflection fluorescence XAFS technique and its application to catalysis science. K. Asakura 2:50—73. Understanding redox active systems through in situ XAFS spectroelectrochemistry. M. Antonio, L. Soderholm, C. Williams 3:15—74. NEXAFS and related studies on functional organic molecular systems. Y. Ouchi 3:40—75. Studying solid-state reactions using time-resolved synchrotron X-ray diffraction. D. O'Hare, R. Walton, F. Millange, L. Lixu, S. Cowell, M. Geselbracht 4:00—76. High-resolution photoemission studies of sulfur interaction with model catalytic surfaces. J. Hrbek, J. A. Rodriguez, T. Jirsak, J. Dvorak Sheraton Waikiki Kohala/Kona Rooms, 2nd Floor Laser Control and Manipulation of Molecules (103)

N. Nakashima, Presiding 1:05—1335. Ultrafast deformation of geometrical structures of small polyatomic molecules in intense laser fields. K. Yamanouchi 1:35—1344. Intramolecular electron transfer in intense laser fields. H. Kono 2:05—1330. Role of molecular structure in strong field photochemistry. R. Levis, M. Dewitt, R. Billotto, N. Moore, A. Markevitch 2:35—1338. Strong field molecular optics. M. Ivanov, D. Villeneuve, M. Spanner, S. Aseyev, P. Corkum 3:05—1318. Slowing and trapping molecules by nonresonant induced dipole forces. B. Friedrich 3:35—1341. Alignment of molecules by strong laser pulses. H. Stapelfeldt 4:05—1327. New method of orientational relaxation spectroscopy of liquid crystals using optical excitation of molecular rotation. S. Takagi, H. Tanaka Sheraton Waikiki Koko Crater Room, 2nd Floor Fluids at Interfaces (114)

D. Henderson, Presiding 1:05—77. Spectroscopy and dynamics at the liquid-liquid interface. I. Benjamin 1:35—78. Novel liquid-liquid transitions and interfaces in molten carbon. J. Glosli, F. Ree 2:05—79. Lattice-gas model for liquid-liquid interfaces. W. Schmickler, S. Frank, T. Huber 2:35—80. Ice-water interface. A. D. J. Haymet 3:05—81. Theories for fluids based on ring sum diagrams: The variational mean spherical scaling approach. L. Blum, J. Hernando 3:35—82. Theory and simulation of electron transfer across the electrode-electrolyte interface. G. Voth

4:05—83. Hydrophobic interaction in SPC water. D. Bratko, R. Curtis, H. Blanch, J. Prausnitz Sheraton Waikiki Molokai Ballroom, 2nd Floor Computational Quantum Chemistry: Theoretical and Experimental Perspectives (125)

J. Goddard, Presiding 1:05—84. Computational explorations of thermal and catalyzed sigmatropic shifts. K. Houk 1:35—85. Orbital controlled stereoselections in sterically unbiased cyclic systems. T. Ohwada 2:05—86. Modulating structures and reactivity through cation-7t interactions. R. Sunoj, J. Chandrasekhar 2:35—87. Development and applications of the ONIOM method to modeling of large moleular systems. K. Morokuma 3:05—88. /V-Heterocyclic carbene complexes for the Heck reaction. B. Yates, D. McGuinness, K. Cavell, N. Saendig 3:35—89. Reaction pathways of polymetallic organometallic reactions. E. Nakamura Sheraton Waikiki Puna Room, 2nd Floor Photon- and Electron-Induced Processes on Surfaces (198)

H-L. Dai, Presiding 1:05—103. Surface structures of liquids. Y. R. Shen 1:35—104. Photoinduced nonlinear optical response of semiconductor interfaces. E. Borguet, V. Fomenko, D. Bodlaki 1:55—105. Femtosecond time-resolved second harmonic generation from semiconductor surface region. K. Watanabe, Y. Matsumoto 2:10—106. In situ photonic probe of adsorbates on some colloidal interfaces. H-F. Wang, T. Troxler, H-L. Dai 2:30—107. Surface reaction dynamics of formate species probed by time-resolved sum frequency generation vibrational spectroscopy. K. Domen, K. Kusafuka, A. Bandara, J. Kubota, A. Wada, C. Hirose 3:00—108. State-resolved dynamics of photoinduced desorption and surface reaction. M. White, R. Rao, R. Beuhler 3:30—109. Photo- and thermal-induced surface-aligned desorption. T. Matsushima 4:00—110. Nonlinear yields of diatomics photodesorbed by femtosecond pulses: Density matrix theory and calculations. D. Micha, A. Santana-Vargas, A. Salam 4:20—111. Development of high-resolution electron-ion coincidence spectroscopy for study of ion desorption induced by coreelectron transitions. K. Mase, K. Isari, T. Sekitani, K. Tanaka Sheraton Waikiki Akaka Falls Room, 2nd Floor Physical and Theoretical General Session (10-G2)

Z. Zhu, Presiding 1:05—112. Low-temperature intermolecular proton exchange in tris-(2-methylallyl)chromium. O. Swang, R. Blom 1:25—113. First glimpses of corrosion on an atomic level. A. Rigos, J. Cline, T. Arias, J. Tester, R. Latanision 1:45—114. Atomic and molecular reaction statics. Z. Zhu 2:05—115. Molecular dynamic simulation on a molecular switch driven by gases. S. De O. Dantas, P. Barone, P. Coura 2:25—116. First principle study on reactions of diamond(IOO) surfaces with hydrogen and methyl radical. H. Tamura, H. Zhou, Y. Hirano, S. Takami, M. Kubo, R. Belosludov, A. Miyamoto 2:45—117. Chemical reaction dynamics of CH 2 , C 2 H, C 2 H 3 with 0 2 . and NO. F. Kong 3:05—118. Laser-induced blue state of bacteriorhodopsin: Mechanistic and color regulatory roles of protein-protein interactions, protein-lipid interactions, metal ions, and pH. D. Sammeth, M. Masthay, J. Kofron, B. Blain, M. Helvenston, G. Gerholt, M. C. de Baca 3:25—119. Flourescence-detected magnetic resonance study on photoinduced electron-transfer reaction in a poly(A/vinylcarbazole) aggregation. H. Murai, T. Itoh, K. Maeda

3:45—120. Photoinduced electron transfer at photosynthetic reaction centers investigated by charge equilibration genetallized for charge separation. O. Kitao, K. Aoki, T. Ogawa 4:05—121. Structural biophysics of biological photoreceptors. U. Genick, E. Getzoff, J. Chory, J. Noel 4:25—122. Asymmetric electrostatic field of photosynthetic reaction center investigated by charge equilibration. O. Kitao, K. Aoki, T. Ogawa

10:55—129. Australian synchrotron research program: Current status and future directions. G. Foran, R. Garrett, J. Boldeman, J. Hester, D. Cookson, A. Stampfl, H. Tong Sheraton Waikiki Puna Room, 2nd Floor Electrochemical Surface Science at Molecular/Atomic Resolution (033)

A. Wieckowski, Presiding

1:05—97. Infrared spectroscopy of anion complexes and clusters. E. Bieske, D. Wild, Z. Loh, P. Wolynec, P. Weiser 1:45—98. Cluster-size reassignments in the S^-SQ spectra of (benzene)n. Y. Ohshima, T. limori 2:05—99. Probing intermolecular interactions by cluster vibrational spectroscopy. P. M. Felker 2:45—100. Spectroscopy, structure, and vibrational predissociation dynamics of the p-difluorobenzene-H 2 0 van der Waals complex. A. Knight 3:25—962. Infrared depletion spectroscopy of the ternary aniline clusters of aniline-Xwater. T. Nakanaga, N. Piracha, H. Ohmura, F. Ito 3:45—102. Vibrational relaxation dynamics of well-characterized benzonitrile clusters. N. Mikami, T. Ebata, R. Yamamoto, M. Kayano

8:35—130. Deuterium isotope analysis of methanol oxidation kinetics on mixed metal catalysts. E. Smotkin 9:05—131. Mechanistic study of methanol oxidation at Pt and Pt alloy anodes with in situ electrochemical FTIR and ex situ XPS (UPS). M. Watanabe, H. Uchida, Y. Zhu, H. Igarashi 9:35—132. Field-dependent chemisorbate bonding at electrodes: Quantum chemical calculations compared with surface vibrational spectroscopy. M. J. Weaver, S. A. Wasileski, M. T. M. Koper 10:05—133. Time-resolved second harmonic generation at electrode-electrolyte interfaces. D. Scherson, B. Pozniak, Y. Mo, Z. Wang, B. Alzarez 10:35—134. Role of atomic XAFS and shape resonances in oxygen and hydrogen electrocatalysis. W. O'Grady, D. Ramaker 11:05—135. Dynamic simulations of X-ray scattering intensities and cyclic voltammograms for halide electrosorption on singlecrystal silver. P. A. Rikvold, S. J. Mitchell, G. Brown 11:35—136. STM imaging of Sn/Pt(111) surface alloys and SnOx overlay formation. B. Koel, M. Batzill, D. Beck

Sheraton Waikiki Maui Ballroom, 2nd Floor

Sheraton Waikiki Kauai Ballroom, 2nd Floor

Structure and Dynamics of Photogenerated Intermediates in Solution: Vibrational and Electronic Studies (147)

Ordered Molecular Films for Nanoelectronics and Photonics (077)

Sheraton Waikiki Niihau Room, 2nd Floor Structure, Dynamics, and Reactions of Small Clusters (191)

D. H. Levy, Presiding

T. Okada, Presiding 1:05—90. Photolysis dynamics of noble metal nanoparticles. D-J. Jang, C. Ah, K. Kim 1:40—91. Photophysical properties and photoreactivity of bimetallic complexes in solution and bound to DNA. C. Turro, P. M. Bradley, M. A. Sivko, P. K-L. Fu 2:05—92. Excited-state proton transfer dynamics studied by femtosecond timeresolved spectroscopy. T. Tahara 2:30—93. Structure and dynamics of the excited states of Benzil: A time-resolved IR, Raman, and absorption study. H. Takahashi, M. Mizuno, K. Iwata 3:05—94. Anisotropic long-range coupling in blue copper proteins and donor-bridgeacceptor complexes from resonance Raman spectroscopy. G. R. Loppnow, M. A. Webb, E. Fraga, H-B. Kraatz, P. Galka 3:30—95. Reaction dynamics of photochromic diarylethene derivatives under ultrafast laser excitation. H. Miyasaka, M. Murakami, A. Itaya, M. Irie 3:55—96. Femtosecond time-resolved spectroscopy of intramolecular electron transfer in solution. T. Okada, T. Kikuzawa, T. Nagahara, K. Murakami, A. Osuka

FRIDAY MORNING Sheraton Waikiki Hilo Room, 2nd Floor Chemical Applications of Synchrotron Radiation (022)

T. Ohta, Presiding 8:05—123. Infrared synchrotron radiation applications. G. Williams 8:35—124. Industrial applications of synchrotron-based X-ray microbeams. E. Isaacs 9:05—125. Chemical applications of synchrotron radiation in the pharmaceutical industry. C. Abad-Zapatero 9:35—126. Canadian light source: Opportunities for surface and materials studies. G. M. Bancroft 10:05—127. Chemical application research using "New Subaru" 1.5 GeV storage ring. Y. Utsumi, T. Hattori, S. Matsui, T. Mochizuki 10:30—128. Photochemistry research using synchrotron radiation in UVSOR-IMS. T. Urisu

A. Koma, Presiding 8:05—144. Electrophosphorescent lightemitting diodes. M. Thompson, S. Forrest, P. Burrows 8:45—145. Design and fabrication of highefficiency organic electroluminescent devices. J. Kido 9:25—146. 1-D photonic crystal formed by mass-controlled layer-by-layer deposition process of polyelectrolytes and metal oxides. S. Shiratori, T. Ito 9:50—147. Innovative methods in organic light-emitting materials and device fabrication. G.Jabbour 10:30—148. Fabrication processes and characterization of field emission with carbon nanotube emitters for large-area applications. J. Kim Sheraton Waikiki Molokai Ballroom, 2nd Floor Computational Quantum Chemistry: Theoretical and Experimental Perspectives (125)

J. Goddard, Presiding 8:05—149. Biological radicals: Challenges and opportunities for computational quantum chemistry. R. Boyd 8:35—150. Theoretical study of conformational features of peptides formed by nonnatural amino acids. Y-D. Wu, Y-L. Zhao, D-P. Wang, Y. Ren 9:05—151. Free energy calculation of enzyme reactions with a DFT QM/MM method: Application to Enolase. W. Yang, Y. Zhang, H. Liu 9:35—152. Mechanisms of oxidative damage related to Alzheimer's disease. A. Rauk, D. Armstrong, D. Fairlie 10:05—153. Toward a complete basis set model for enzyme kinetics. G. Peterson 10:35—915. Recent developments in linear scaling quantum chemistry methods. G. Scuseria


Sheraton Waikiki Niihau Room, 2nd Floor Structure, Dynamics, and Reactions of Small Clusters (191)

Y. T. Lee, Presiding 8:35—162. Time-resolved studies of dynamics in anion clusters. D. Neumark 9:15—163. Photodissociation dynamics of HCI clusters: Measurement of internal energy distribution of [CIHCI]. D-C. Che, M. Hashinokuchi, T. Kasai 9:35—164. Metal oxide clusters: Growth, fragmentation, stability, structure, and chemistry. E. Bernstein 10:15—165. Cage effect in the gas phase: Solvent-induced chemistry. C. Lineberger 10:55—166. Coulomb explosions of charged clusters. S. Consta 11:15—167. Structures and reactivity of metal and semiconductor clusters. B. Simard Sheraton Waikiki Maui Room Structure and Dynamics of Photogenerated Intermediates in Solution: Vibrational and Electronic Studies (147)

T. L. Gustafson, Presiding 8:05—155. Electron transport and the importance of nonbonded interactions. D. Waldeck 8:40—156. Successful application of diffusion models to ultrafast processes in solution. K. Iwata 9:05—157. Resonance Raman investigation of photodissociation and photoisomerization reactions of diiodomethane in the solution phase. D. L. Phillips, X. Zheng 9:30—158. Resonance Raman structural evidence that the cis-to-trans isomerization in rhodopsin occurs in femtoseconds. R. Mathies, J. Kim, D. McCamant, L. Zhu 10:05—159. Energy-transfer processes from the electronic energy to the thermal energy in solution. M. Terazima 10:30—160. Biophysical studies of myoglobin and bacteriorhodopsin: Watching proteins as they function. P. Anfinrud 10:55—161. Vibrational relaxation of metalloporphyrins in solutions. T. Kitagawa, Y. Mizutani Sheraton Waikiki Akaka Falls Room, 2nd Floor Laser Control and Manipulation of Molecules (103)

Y. Fujimura, Presiding 8:35—1339. Modified STIRAP methods for controlling molecular dynamics. S. A. Rice, S. Shah, D. Tannor 9:05—1321. Control of molecular processes by periodic sweeping of laser. H. Nakamura 9:35—1332. Prospects for all-optical alignment and quantum-state control of nonpolar molecules by multiple resonance excitation techniques. A. M. Lyyra 10:05—1343. Laser control of dissociative ionization: Exact nonborn Oppenheimer simulations for H 2 + . A. D. Bandrauk, S. Chelkowski 10:35—1319. Propensity of molecules to spatially align in intense pulsed light fields. D. Mathur 11:05—1317. Molecular restructuring in intense laser fields. T. T. Nguyen-Dang, N-A. Nguyen 11:35—1336. Photodissociation of 0 2 + in intense laser fields. A. Hishikawa, S. Liu, A. Iwasaki, K. Yamanouchi Sheraton Waikiki Kohala/Kona Rooms, 2nd Floor Large Molecule Vibrational Dynamics (210)

C. Parmenter, Presiding 8:35—168. Overtone spectroscopy of jetcooled phenols studied by nonresonant ionization-detected IR spectroscopy: Doorway in IVR. M. Fujii, S. Ishiuchi 9:00—169. Acetylene: New photophysics in an old molecule. R. Field, S. Altunata, M. Canagartna, K. Cunningham, R. Thorn 9:25—170. Overtone spectral interactions between CH-stretching and methyl internal rotation. B. Henry, H. Kjaergaard, M. Petryk, R. Proos, Z. Rong, D. Tumbull, C. Zhu

OCTOBER 2, 2000 C&EN 1 4 7


9:50—171. Far-infrared and ultraviolet absorption spectra and laser-induced fluorescence spectra of jet-cooled indan and 1,3-benzodioxole and their S 0 and S^rc, 7i*) potential energy surfaces. J. Laane, Z. Arp, S. Sakurai, K. Morris, E. Bondoc, N. Meinander 10:15—172. Ultrafast vibrational energy flow in solution revealed by picosecond antiStokes Raman spectroscopy. H. Okamoto, T. Nakabayashi, M. Tasumi 10:40—173. Intramolecular dynamics and photodissociation of free radicals. H. Reisler 11:05—174. Quantum mechanical studies of vibrational dynamics in benzene and acetylene. R. Wyatt 11:30—175. Spectroscopy and dynamics of molecules near conical intersections. J. H. Frederick, C. Woywod, W. Livingood Sheraton Waikiki Koko Crater Room, 2nd Floor Solvation Structure and Reactivity in Supercritical Fluids (069) J . M. Ramsey,

Presiding

8:35—-137. Influence of local density enhancements on solute reaction rates in supercritical water. S. C. Tucker, R. Behera, B. Bashore 9:05—138. Study of inhomogeneity of supercritical fluids. K. Nishikawa 9:35—139. Water dynamics and chemical reactions in normal and supercritical water. I. Ohmine 10:05—140. Chemistry in supercritical water: Insights from theory and simulation. P. Rossky, K. Johnston 10:35—141. Hydrogen bonding structure in supercritical water via molecular dynamics. H. Inomata, T. Honma, C. Liew 11:05—142. Structure and spectroscopy in supercritical fluids. J. Skinner, S. Egorov 11:35—143. Diffractive optics based nonlinear spectroscopies: Four-wave, six-wave, and new wave spectroscopy. R. J. Miller

FRIDAY AFTERNOON Sheraton Waikiki Niihau Room, 2nd Floor Solvated Molecules and Ions: From Clusters to Condensed Phases (004)

D. Salahub, Presiding 1:05—176. Influence of solvation on reaction dynamics. A. Castleman Jr., D. Folmer, E. Wisniewski, S. Hurley 1:45—177. Solvation of single alkali atom in water clusters. K. Fuke, R. Takasu 2:25—178. Ab initio studies on the contact ion pairs of magnesium sulfate aqueous solution in supersaturated state. Y. Zhang, X. Zhang, R. Zhu, Q. Li 2:45—179. Multicanonical Monte Carlo study of the structural phase transition between water and ice. C. Muguruma, Y. Okamoto, M. Mikami 3:05—180. Size-dependent intracluster reaction of AI + (H 2 0) n (n = 6-9) cluster cations. J. S. Tse, Z. Liu, C. K. Siu 3:45—181. Dynamics of ion solvation in mixed solvents. G. N. Patey, T. J. F. Day, V. V. Murashov, G. N. Samoukovic Sheraton Waikiki Koko Crater Room, 2nd Floor Solvation Structure and Reactivity in Supercritical Fluids (069)

O. Kajimoto, Presiding 1:05—263. Atom and radical recombination processes in supercritical fluids. J. Troe 1:35—264. Solvent density dependence of the vibrational energy relaxation rate in the electronic excited state in supercritical fluids. Y. Kimura, T. Yamaguchi, D. Abe, N. Hirota 2:05—265. Vibrational relaxation of a solute in supercritical fluid solvents and in the collisionless gas phase. M. Fayer 2:35—266. Rotational dynamics of substituted benzenes in supercritical carbon dioxide. J. Adams, A. Siavosh 3:05—267. Solvation in supercritical fluids: Experiment and simulation. M. Maroncelli, R. Biswas, N. Patel, W. Song 3:35—268. Chemical thermodynamics aspects of binary cosolvent mixtures with dense-phase carbon dioxide. R. Kohli

148


Sheraton Waikiki Molokai Ballroom, 2nd Floor

Sheraton Exhibit Pavilion

Computational Quantum Chemistry: Theoretical and Experimental Perspectives (125)

Physical and Theoretical General Session (10-GP2) Poster Session

M. W. Wong, Presiding 1:05—275. Standard enthalpies of formation of IPR fullerenes and their analysis in terms of structural motifs. J. Cioslowski, N. Rao, D. Moncrieff 1:35—276. Structural determination of endohedral metallofullerenes. S. Nagase 2:05—277. Embedded cluster studies of surface chemistry. M. Gordon, C. Choi, J. Rintelman 2:35—278. Modeling the optoelectronic properties of porous silicon using ab initio cluster calculations. J. Head 3:05—279. Theoretical studies on the twophoto absorption of some stilbene derivatives. J. Feng, A-M. Ren, X. Zhao 3:35—280. Two-component spinor calculations for the fine-structure states using relativists effective core potentials. Y. Lee, Y-K. Han, Y. Kim, K. Kim, Y-K. Han 4 : 4 2 — 2 8 1 . Can fulvenes form from enediynes? P. Schreiner, M. Prall, A. Wittkopp Sheraton Waikiki Hilo Room, 2nd Floor Science and Technology of Ti0 2 Photocatalysis (146)

A. Datye, Presiding 1:05—282. Present situation and future strategy of Ti0 2 photocatalysis. A. Fujishima 1:50—283. Development of an air purifier for NOx utilizing photocatalysis. M. Yamashita, N. Koyama, Y. Miyashita, K. Takeuchi 2:10—284. Photocatalytic destruction of Staphylococcus camosus. G. Raupp, E Wajda 2:30—285. Enhanced retardation for organic pollutants by microwave assisted with UV illumination in aqueous Ti0 2 dispersions. S. Horikoshi, N. Serpone, H. Hidaka 2:50—286. Assessing the capabilities and limits of Ti0 2 photocatalytic applications. P. Pichat 3:35—287. Photocatalytic degradation of acetone on Ti0 2 -coated optical fibers. W. Choi, J. S. Chung, J. Y. Ko 3:55—288. Remediation of atmospheric environment by photocatalysis: Roadside experiments of air-purifying materials. K. Takeuchi, S. Kutsuna, T. Ibusuki 4:15—289. Gas-phase photocatalytic oxidation of methyl, ethyl, n-propyl, and isopropyl alcohols and their reaction intermediates. M. Zorn, K. Rahne, M. Zeltner, M. Anderson Sheraton Waikiki Kohala/Kona Rooms, 2nd Floor Large Molecule Vibrational Dynamics (210)

C. Parmenter, Presiding 1:05—306. Photodissociation of energetic materials and model compounds. E. Bernstein 1:30—307. S1 toluene: A facile route to IVR. D. Pratt 1:55—308. Multidimensional coherent infrared spectroscopy of small molecules and peptides in solutions. R. Hochstrasser, M. Zanni, M. Asplund 2:20—309. Collisional cooling of highly excited molecules: State-resolved energy gain pathways for water. A. Mullin, M. Elioff, R. Sansom, E. Korobkova, M. Fang 2:45—310. Experimental view of vibrationinternal rotation interactions that underlie IVR in aromatic molecules with methyl internal rotation. C. S. Parmenter, Q. Ju 3:10—311. 7i-a-Hyperconjugation mechanism on the rotational barrier of the methyl group. H. Nakai 3:35—312. Conformation-specific infrared spectroscopy of tryptamine and 3-indolepropionic acid: Folding and unfolding flexible molecules. T. Zwier, J. Carney, G. Florio, B. Dian 4:00—313. Modeling collision-induced vibrational energy transfer at low temperatures. M. Jordan

1:00-3:00 314. Quantum mechanical PoissonBoltzmann equation approach for calculating absolute pKa of amino acids and biopolymers. V. Gogonea, L. Troxler, K. M. Merz Jr. 315. Isotope effect on cyclodextrin complexation thermodynamics. M. Rekharsky, Y. Inoue 316. Investigation of molecular assembly in ordered nanoporosities using solid-state NMR. L-Q. Wang, J. Liu, Y. Shin 317. Polymerization-induced phase separation of polymer-dispersed liquid crystal. H. Nakazawa, S. Fujinami, M. Motoyama, T. Ohta, T. Araki, H. Tanaka 318. Photodissociation of 3-methyl-3chlorodiazirine: Dynamics of CN 2 ring breaking. Y. S. Choi, W-H. Park, S. H. Cho, S. K. Kim 319. Diffusion of nonassociated aromatic compounds in cyclohexane. W-M. Chiu, T-C. Chan 321. Reaction of ethylene oxide derivatives in high-pressure carbon dioxide with amide or amide carboxylic acid as catalysts. H. Kawanami, Y. Ikushima 322. Get to know your sample: Collecting higher information densities with plasmas. V. Majidi, M. Moser, W. Hang 323. Chemical modification and characterization of MCM-41 and adsorption study. G. Q. M. Lu 324. Diffusion of polar aromatic compounds in cyclohexane. T. C. Chan, J. He, W. M. Chiu 325. Behaviors of fatty acid dimers in binary mixture as observed by the self-diffusion coefficients. S. Takebayashi, H. Minami, H. Matsuzawa, M. Iwahashi 326. Properties of molecular complexes relevant to the earth's atmosphere. J. Headrick, V. Vaida 327. Photodissociation dynamics of iodoacetonitrile. S. K. Kim, Y. S. Choi, S. J. Baek, D. Lee 328. Studies of electron and ion-molecule collisions using crossed beams and ion imaging. P. Harland, B. Cameron, C. Vallance, M. Bart 329. Quantitative comparison and prediction of acid-dissociation constants in various solvents based on strength-structure relationships of acid-base interaction. S. Mishima, T. Nakajima 330. Measurement of dielectric relaxation of coordinated water in aqueous solution of (CF3)2CHOH. T. Suzuki, T. Nagasawa, S. Okouchi, Y. Ishihara, H. Uedaira 331. Mossbauer study of nanocrystalline thin films of Fe-Zr-O. D. Seifu 332. Effect of double functional groups of solute dynamics of water in aqueous solution. T. Ashida, S. Okouchi, K. Tsuchida, J. Tanimoto, Y. Ishihara, H. Uedaira 333. Proton exchange rate in aqueous solutions of fluoroethanols. N. Asai, S. Okouchi, T. Ashida, H. Uedaira 334. Self-interaction-free time-dependent density functional theory for multiphoton processes in strong fields. X. Chu, S-l. Chu 335. Analyses of prolyl isomerization on p-turn peptides by molecular dynamics simulation. N. Yamaotsu, S. Hirono 336. Effect of pressure on solubility of L-aglycine, L-a-alanine, and /.-valine in water at 298.15 K. H. Matsuo, D. Yuya, D. Ashikawa, T. Sakai, S. Sawamura, M. Kato, Y. Suzuki, T. Kawakita 337. Detection of ultrafast interaction between photoexcited electrons and admolecules at gold surface using transient reflecting grating spectroscopy. K. Shibamoto, K. Katayama, M. Fujinami, T. Sawada 338. Unimolecular reaction kinetics of CF2CICHFCH3 and CF2CICHFCD3: Evidence for a novel 1,2-FCI rearrangement pathway. G. Heard, B. Holmes, M. Burgin 339. Partial oxidation of methane with nitrous oxide in a dielectric-barrier discharge plasma reactor. S. Tanabe, K. Egashira, K. Hatakeyama, K. Okitsu, H. Matsumoto 340. STM-induced photon emission of organic molecules on metal substrates. T. Terui, S. Yokoyama, M. Zhou, H. Miki, T. Kamikado, S. Mashiko, Z. C. Dong, D. Fujita, H. Nejoh

341. Formation dynamics of bilayer lipid membranes studied by simultaneous measurements of both capacitance and image. M. Fujihara, H. Fujiwara, H. Ishii, T. Ishiwata 342. Characterization of perlite modified with Ti0 2 by alkoxide hydrolysis method. M. K. Ko, Y. Ahn 343. Study of generation mechanism for endohedral metallofullerenes using lanthanum plasma. Y. Otomo, T. Hirata, R. Hatakeyama 344. Mold effect and/or surfactant role of adsorbed O and N on Cu(100) in the growth of nanosized metal dots and nanowidth wire. K-l. Tanaka, O. Yuji, M. Yuji 345. Photocatalysis degradation of humic substances in water by UV/Ti0 2 /0 3 system. S. Dezhi 346. Bottoms cracking additives in FCC for enhancing diesel yield. X. Mingde Sheraton Exhibit Pavilion Chemical Applications of Synchrotron Radiation (022) Poster Session 1:00-3:00 182. Site-selective XAFS spectroscopy tuned to surface active sites of catalysts. Y. Izumi, H. Nagamori 183. Resonant photoemission of plutonium metal. J. Terry, R. Schulze, J. Tobin, D. Shuh 184. Formation and decay processes of superexcited hydrocarbons in the vacuum ultraviolet range. K. Kameta, M. Kato, K. Takeda, T. Odagiri, N. Kouchi, Y. Hatano 185. Bethe surface of liquid water measured by inelastic X-ray scattering. H. Hayashi, N. Watanabe, M. Takahashi, Y. Udagawa, C-C. Kao 186. Anisotropic magnetization of CO adsorbed on ferromagnetic metal thin films studied by X-ray magnetic circular dichroism. T. Yokoyama, K. Amemiya, Y. Yonamoto, D. Matsumura, T. Ohta 187. Synchrotron small-angle X-ray scattering from organo gelators. K. Sakurai, T. Ishi-I, O. Gronwald, Y. Ono, S. Shinkai 188. Auger electron spectra of Kr resonantly photoexcited from the 2p orbital into nl orbitals. I. H. Suzuki, S. I. Nagaoka, T. Ibuki, N. Saito, Y. Shimizu, Y. Senba, K. Kamimori, Y. Tamenori, H. Ohashi 189. Molecular deformation of C 0 2 in the 01s"127tu states through excitation with narrow bandpass soft X-ray. I. H. Suzuki, N. Saito, K. Ueda, M. Simon, K. Okada, Y. Shimizu, H. Okumura, H. Ohashi, Y. Tamenori, H. Yoshida, T. Ibuki, I. Koyano 190. Deposition of highly oriented Teflon thin films by synchrotron radiation etching. Y. Zhang, T. Katoh, A. Endo 191. NEXAFS study of thiophene dissociative chemisorption on Au(lll) induced by multilayer adsorption. A. Nambu, H. Kondoh, Y. Ehara, T. Yokoyama, T. Ohta 192. XEOL and optical XAFS of CaF2 at the Ca L3 2-edge. T. K. Sham, S. J. Naftel, Y. M. Yiu, B. W. Yates 193. XAFS studies of CdS-dendrimer nanocomposites. T. K. Sham, P. Zhang, R. Sammyraiken, S. Naftel 194. X-ray absorption and VUV spectroscopies of silica glasses irradiated in a nuclear reactor. T. Yoshida, T. Tanabe, H. Yoshida, T. li 195. Synchrotron X-ray fluorescence in dendroanalysis. R. Martin, K. Jones, H. Feng, T. K. Sham 196. Synchrotron X-ray fluorescence and metal transport in roots. R. Martin, S. Macfie, T. K. Sham, K. Jones, H. Feng 197. Interface structure of akali halide heteroepitaxial films studied by X-ray absorption fine structure. M. Kiguchi, T. Yokoyama, D. Matsumura, Y. Kitajima, T. Ohta 198. Structure of Tb or Eu dendrimer complexes characterized using XAFS. T. Seto, M. Kawa, K. Motoda 199. Photodissociation dynamics of C 4 H 6 systems at 193 nm. J. Robinson, W. Sun, D. Neumark 200. A new method for the measurement of X-ray absorption spectra (XAS) of insulators. T. Tanaka, N. Matsubayashi, M. Imamura, H. Shimada 201. Adsorption of 2-butenal on Pt and Pt-Sn surfaces: Influence of the chemical composition. E. Janin, S. Ringler, J. Weissenrieder, T. Kermark, D. Nordlund, H. Ogasawara, M. Gothelid

202. Elliptically polarizing undulator beamline for high-resolution spectroscopy of magnetic materials. A. Young, J. Feng, V. Martynov, H. Padmore, E. Arenholz, R. Schlueter, S. Marks, E. Hoyer 203. X-ray absorption measurement and density functional theory analysis of gallium in gallium-containing beta zeolites. A-C. Wei, L. P. Hung, C. K. Jung, L. J. Fu 206. Effects of polyelectrolyte on the Belousov-Zhabotinsky reaction. A. Kaminaga, K. Hayakawa, T. Maeda 207. Circular pattern formed in DNA-histone mixture. S. Sasaki, I. Karube 208. Effects of geometry and viscosity on spin modes in frontal polymerization of multifunctional acrylates. J. Pojman, J. Masere, E. Pettretto, M. Molden, M. Rustici 209. Withdrawn. 210. Autocatalytic chiral asymmetry generation involving conglomerate clustering process. K. Asakura, T. Soga, A. Ikumo, K. Kurihara, S. Osanai, D. Kondepudi 2 1 1 . Kinetic study of the BelousovZhabotinsky reaction. E. Steimle, L. Garcia-Rubio, J. Poteiro 212. Simplified model for the BriggsRauscher reaction mechanism. K-R. Kim, D. J. Lee, K. J. Shin 213. Time-resolved multispectroscopic image analyzer system for chemical wave patterns. T. Fukuda, T. Matsumura-lnoue

4:10—305. Ultrafast transient grating scattering studies of carrier dynamics at a silicon surface. H-L. Dai, T. Sjodin, C-M. Li, H. Petek


Sheraton Waikiki Akaka Falls Room, 2nd Floor

Nonlinear Dynamics in Chemistry (025) Poster Session

Physical and Theoretical General Session (10-G4)

1:00-3:00 214. Simultaneous measurements of calorimetry, poteniometry, and light absorption in Belousov-Zhabotinsky reactions involving ruthenium(ll) complex. S. Fujieda, Y. Mori, Y. Hasegawa 215. Cellular automation for dissipative structures realized in parallel processors. S. Yaguma, K. Takatsuka 216. Investigation of heterogeneity effect on the oscillatory behavior of the CO/H 3 P0 4 system. A. Eftekhari 217. Convection in quadratic and cubic fronts. D. Vasquez 218. Effect of illumination on the Ru(bpy)32+ catalyzed BZ reaction in CSTR. T. Matsumura-lnoue, N. Tatsuhito 219. High-speed image processing of emulsification phenomena in the water-oil interface induced by ultrasound. K. Honda, K. Takao, A. Hidetoshi, M. Yoshihito, F. Shuuko, O. Hayashi 220. Characteristic self-motion of a camphoric acid boat depending on pH of aqueous solutions. Y. Hayashima, S. Nakata 221. Effects of anions on electrochemical oxidation processes discovered by chemical instabilities. M. Schell Sheraton Waikiki Puna Room, 2nd Floor Photon- and Electron-Induced Processes on Surfaces (198)

H-L. Dai, Presiding 1:05—297. Molecular quantum structures and electron transfer at organic-metal interfaces. X. Zhu 1:35—298. Surface chemistry with "stretched molecules": Vibrational promotion of an electron-transfer reaction. A. Wodtke, D. Auerbach, C. Rettner, Y. Huang 2:05—299. Theoretical studies on photoinduced electron-transfer process at dyesensitized solar cells. T. Ogawa, O. Kitao, H. Arakawa 2:20—300. Microwave photoconductivity measurements of supported Ti02- P. Pichat, E. Mietton-Ceulemans, B. Wegewijs, T. Savenije, M. De Haas, J. Warman 2:35—301. Time-resolved spectroscopy of metal nanoparticles: Coherent excitation of "breathing" modes. G. Hartland, J. Hodak, A. Henglein 3:05—302. Photoninduced electron transfer between molecular adsorbates and semiconductor nanoparticles. T. Lian 3:25—303. Electron wave packets and surface dynamics. R. J. Miller 3:55—304. Detection of ultrafast carrier dynamics at silicon surface using femtosecond transient reflecting grating spectroscopy. K. Katayama, I. Yohei, F. Masanori, S. Tsuguo

Sheraton Waikiki Kauai Ballroom, 2nd Floor Ordered Molecular Films for Nanoelectronics and Photonics (077)

H. Tada, Presiding 1:05—269. Organic thin-film transistors. T. Jackson 1:45—270. Electronic structure of organic/ metal interfaces. K. Seki, N. Hayashi, E. Ito, H. Oji, Y. Ouchi, H. Ishii 2:25—271. P/N conduction control of organic semiconductors in ultrahigh vacuum. H. Tada, M. Takada, K. Matsushige 2:50—272. Formation of ordered, oriented layers of organic molecules on semiconductor surfaces. R. Hamers 3:30—273. Molecular interactions of an amphiphilic hemicyanine dye in a free form or attached to the polyurethane backbone at the air-water and solid-liquid interfaces. J-H. Kim, J-H. Im, J-H. Park, K-S. Lee 3:50—274. Unusually coherent phthalocyanine assemblies: Electrochemical, photoelectrochemical, and photovoltaic properties. N. Armstrong, C. Donley, R. Peterson, A. Rodighiero, P. Lee

G. Q. M. Lu, Presiding 1:05—347. Hydrogen bonding with density functional theory: Density consistent molecular basis sets. K. Markey, A. Wittkopp, P. R. Schreiner 1:25—348. Polar molecules adsorbed on H 2 0 ice surface. N. Horimoto, H. Ogasawara, M. Kawai 1:45—349. Dynamic interactions in hydrogen-bonded systems. M. J. Wojcik 2:05—350. CH-O bond interactions in thioindigo derivatives. T. Senju, M. Mochizuki, J. Mizuguchi 2:25—351. Intermolecular interactions and energy transport in organic dendrimers with light-emitting applications. T. Goodson III 2:45—352. Interaction of solvated electrons with water molecules at the early stage of laser-induced plasma generation in water. H. Yui, M. Fujinami, T. Sawada 3:05—353. Controlled doping of transitionmetal cations in alumina pillared clays. G. Q. M. Lu 3:25—354. Crystallization kinetics of benzophenone and naphthalene multilayers on Al 2 0 3 (0001). A. Nishimura, D. Saiki 3:45—355. Aromatic multithiol films characterized by AFM and XPS. W. Price, G. Yang, G-Y. Liu, J. Hao, S-W. Tarn-Chang Sheraton Waikiki Maui Ballroom, 2nd Floor Structure and Dynamics of Photogenerated Intermediates in Solution: Vibrational and Electronic Studies (147) H-O. Hamaguchi, Presiding 1:05—290. Excitation, derealization, and relaxation in linear and circular arrays of porphyrins. I. Yamazaki, A. Osuka, S. Akimoto, A. Nakano, T. Yamazaki 1:40—291. Structure and reactivity of organic intermediates as revealed by timeresolved IR spectroscopy. J. P. Toscano 2:05—292. Selective energy flow in supramolecular system and the molecular mechanism. H. Inoue 2:30—293. Structure and dynamics of carbene and nitrene intermediates. M. Platz 3:05—294. Electronic absorption, resonance Raman, and excited-state resonance Raman spectroscopy of rhenium(l) and copper(l) complexes, with substituted dipyrido^^-a^'.S'-c] phenazine ligands and their electron-reduced products. K. Gordon, A. Flood, B. Matthewson, M. Waterland 3:30—295. Photochemical cis-trans isomerization and photoinduced hydrogen atom transfer of arylethenes. T. Arai, T. Suzuki, Y. Norikane, M. Ikegami, H. Sakakibara, T. Mizutani, Y. Kaneko

3:55—296. Isopolarizability approach to the resolution of the three components in the fluorescence spectra of all frans-1,6diphenyl1,3,5-hexatriene. J. Saltiel, A. M. Turek, D. F. Sears Jr, I. Garcia Sheraton Exhibit Pavilion Electrochemical Surface Science at Molecular/Atomic Resolution (033) Poster Session

1:00-3:00 221. See previous listing. 222. Deposition of silver on bare and chemically modified gold electrodes. S. Cruchon-Dupeyrat, M. Narayanan, J. Li, G.Liu 223. Coadsorption of anions and water molecules with UPD metals. M. Futamata 224. In situ Stark effects with inverted bipolar peaks for adsorbed CO on R electrodes in 50 °C direct methanol fuel cells. E. Smotkin 225. Dendrimers having amphiphile structure in each unit: Syntheses and their monolayer properties. K. Ariga, T. Urakawa, A. Michiue, Y. Sasaki, J. Kikuchi 226. Magnetic control of photoelectrochemical reaction of modified electrodes with semiconductor nanoparticles. H. Yonemura, M. Yoshida, S. Yamada 227. Metal nanocluster formation by immersion plating. T. Sakka, J. Sasano, F. A. Harraz, D. Yoshida, Y. H. Ogata 228. Theoretical study on the electronic structure of Pd monolayer on Au electrode. M. Miyakoshi, T. Ohwaki, K. Yamashita 229. Effects of chemical treatments on the surface properties of GaN-related materials. T. Hashizume, S-Y. Ootomo, S. Oyama 230. IRRAS of sulfuric acid anion adsorbed on the stepped surfaces of platinum. N. Hoshi, A. Sakurada, S. Teruya, O. Koga, Y. Hori 231. Computer simulation of electrodeposition: Surface structure and lattice defects. Y. Kaneko, Y. Hiwatari, T. Murakami, K. Ohara 232. Theoretical study on the adsorption and charge transfer at diamond electrodes. T. Murai, T. Ohwaki, K. Yamashita 233. In situ STM observation of thiolated oligonucleotide on Au(111). K. Morita, T. Uchida, C. Sakurai, N. Teramae, K. Yamashita, S. Takenaka 234. Surface oxide growth at the Pt electrode in aqueous H 2 S0 4 : A new insight into an old problem. G. Jerkiewicz, G. Vatankhah, J. Lessard, M. P. Soriaga, Y-S. Park 235. Electrochemistry of self-assembled monolayers of dinuclear and trinuclear ruthenium complexes on gold. M. Abe, T. Inomata, A. Sato, T. Kondo, S. Ye, K. Uosaki, Y. Sasaki 236. Development of reversible chargedischarge systems by optimizing physicochemical characteristics of a lithium anode interface. M. Ishikawa, M. Morita 237. Application of self-assembled monolayer of 1,1'-binaphthalene-2,2'-dithiol with 2-D chirality to the study of chiral discrimination. N. Yamakawa, T. Nakanishi, T. Asahi, T. Matsuda, T. Osaka, B. Ohtani, K. Uosaki 238. Adsorption structures of aromatic compounds on copper single crystals. M Sugimasa, L. Wan, J. Inukai, K. Itaya 239. Optoelectrochemical hydrogenphosphate ion sensor based on electrochromism of spinel-type oxide thin-film electrode. Y. Shimizu, M. Shiotsuka, S. Takase 240. Initial stages of etching of Si electrode surfaces investigated by infrared spectroscopy. M. Niwano, Y. Kimura, Y. Kondo, J. Nemoto 241. Enhanced deposition-dissolution process of lithium metal anode by use of triazole additives. M. Umehara, K. Naoi 242. Preparation of enzyme multilayer films using lectin-sugar interactions and its application to biosensors. Y. Kobayashi, J-l. Anzai 243. IRAS study on the adsorption of aromatic carboxylic acids on atomically smooth metal films. J. Kurawaki, M. Higo, Y. Kusumoto 244. SERS study on self-assembled monolayer of ferrocenyl- and amino-alkanethiols on gold electrode. A. Ueda, K. Nishiyama, I. Taniguchi

245. Preparation of novel photofunctional thin films based on layered metal oxides. T. Takata, A. Ishikawa, M. Hara, J. Kondo, K. Domen 246. Effect of temperature on structure of the self-assembled monolayer of decanethiol on Au(111) surface. H. Wano, R. Yamada, K. Uosaki 247. Surface structures of 2- or 5-pyrimidinethiol modified gold electrodes and its application to the promoter electrode for Cu proteins. T. Takeuchi, S. Yamamoto, G. Hareau, I. Taniguchi 248. Electric properties of alkanethiol SAM investigated by conductive atomic force microscope. A. Hirai, F. Iwata, A. Sasaki, H. Sakaguchi 249. Chemical force mapping of base pair formation between AFM tip and selfassembly monolayer. K. Ijiro, H. Sunami, O. Karthaus, S. Kraemer, S. Mittler, W. Kroll, M. Shimomura 250. Photoinduced electron transfer at gold nanoparticles modified with selfassembled monolayers containing porphyrin and ferrocene groups. M. Okamura, T. Kondo, K. Uosaki 251. Effects of nitrogen on electrochemical properties of boron-doped diamond electrodes grown by MPCVD. I. Yagi, K. Tsunozaki, A. Fujishima, K. Uosaki 252. Photoinduced reconstruction of adsorbed CO on Pt(111) electrode. N. Ohta, S. Nakabayashi 253. Structural control of metal nanocluster by electric/photoinduced polarization in solution. K. Murakoshi, H. Tanaka, Y. Nakato 254. Deposition of thiol-passivated gold nanoparticles induced by second harmonic light of Nd-YAG laser. A. Hori, Y. Niidome, S. Yamada 255. Growth mechanism of phase-separated binary self-assembled monolayers of thiol derivatives on Au(111). D. Hobara, M. Yamamoto, T. Kakiuchi 256. Estimation of the pzc of gold(111) electrodes modified with thiol self-assembled monolayers by contact angle measurements. Y. Iwami, D. Hobara, M. Yamamoto, T Kakuichi 257. Electrochemical self-assembly of ZnO/ dye hybrid thin films. T. Yoshida, K. Okabe, T. Pauporte, D. Lincot, T. Sugiura, H. Minoura 258. Photoresponsive assemblies consisting of a ruthenium complex-viologen pair and gold nanoparticles. Y. Kuwahara, T. Akiyama, S. Yamada 259. Theoretical study of a bisulfate and copper cluster adsorbed onto a gold(111) surface. M. Legault, L. Blum, D. Bacelo 260. Adsorption of o- and p-xylene on Rh and Pt(111) in solution studied by in situ STM and ex situ LEED. J. Inukai, K. Suto, M. Wakisaka, M. Yamgishi, L-J. Wan, K. Itaya 261. Tunnel current characteristic of adsorbed molecules detected by scanning tunneling microscope. I. Sakata, K. Miyamura 262. In situ STM and electrochemical characterization of self-assembled monolayers of aromatic thiols on Au(111). T. Sawaguchi, Y. Sato, F. Mizutani, I. Taniguchi

FRIDAY EVENING Sheraton Waikiki Akaka Falls Room, 2nd Floor Nonlinear Dynamics in Chemistry (025)

K. Showalter, Presiding 7:05—356. Self-sustained oscillation of lipid tube induced by laser. N. Magome, S-l. Nomura, K. Yoshikawa 7:25—357. Gene expression switches, amplifiers, and oscillators. M. Dolnik 7:45—358. Mechanistic model for opencircuit metal-ion-catalyzed aluminum dissolution oscillation reactions. A. Scheeline, C. Cobb, E. De Lucia, C. East, G. Ferrer, R. Fuller, J. Josephs, I. S. Kim, M. McCutcheon, F. Onyemauwa, N. Sethi 8:05—359. Dynamic properties of selfreplicating structures. E. Peacock-Lopez 8:25—360. Spatiotemporal coupling effect during electrochemical iron oscillation. A. Karantonis, R. Baba, S. Nakabayashi, Y. Shimi 8:45—361. Control of Turing patterns by illumination. M. Dolnik, A. Horvath, A. P. Munuzuri, A. M. Zhabotinsky, I. R. Epstein


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Sheraton Waikiki Puna Room, 2nd Floor


Electrochemical Surface Science at Molecular/Atomic Resolution (033)

Physical and Theoretical General Session (10-GP1) Poster Session

K. Uosaki, Presiding 7:05—519. Time-resolved photoelectrochemical measurements at electrochemically self-assembled ZnO/dye electrodes. T. Oekermann, T. Yoshida, D. Schlettwein, T. Sugiura, H. Minoura 7:20—363. New insight into surface electrochemical processes via application of ECQCN. G. Jerkiewicz, G. Vatankhah, J. Lessard 7:35—364. Hydrogen bonding between a water molecule and electronegative additives (O or CI") on a Pt(111) surface. M. Ito, M. Nakamura 8:05—365. Electric field effects on protontransfer reactions at metal electrodes. T. Ohwaki, K. Yamashita 8:20—518. A Model for the electrochemical reduction of hydrogen in the presence of bisulfate on platinum(111). L. Blum, M. Legault, D. Huckaby Sheraton Waikiki Koko Crater Room, 2nd Floor Fluids at Interfaces (114)

D. Henderson, Presiding 7:05—373. On the structure and properties of a capillary-condensed liquid. I. Snook 7:35—374. Interactions of polymer fluids with organic crystals and colloids: An atomistic molecular dynamics simulation. R. Gee 8:05—375. Anomalous behavior of electrochemical double layers at low effective temperature. D. Boda 8:35—376. Dynamics of capillary evaporation between partially drying surfaces. A. Luzar, K. Leung 9:05—377. Surface forces in micellar solutions. D. Chan, B. Poliak, F. Grieser, D. Henderson Sheraton Waikiki Hilo Room, 2nd Floor Computational Quantum Chemistry: Theoretical and Experimental Perspectives (125)

J. Goddard, Presiding 7:05—378. Tools for exploring potential energy surfaces for chemical reactions. H. B. Schlegel 7:35—379. Potential energy surfaces for chemical reactions. M. Collins, R. Rettens, A. Duncan, M. Smith, D. Zhang 8:05—380. Combined crossed beam and ab initio investigation on the formation of carbon chains and nitriles in extraterrestrial environments. R. Kaiser 8:35—381. Accurate ab initio potential energy and dipole moment functions of the electronic ground states of ozone. D. Xie 9:05—382. Stability and decomposition or syntheses reaction pathway of N2n+1clusters. Q. Li, L. Wang 9:35—383. From molecular beams to life under extreme conditions: Applications of quantum chemistry to experimental problems. R. Maclagan Sheraton Waikiki Kohala/Kona Rooms, 2nd Floor Large Molecule Vibrational Dynamics (210)

E. C. Lim, Presiding 7:05—426. Vibrational spectroscopy with neutrons. B. Hudson 7:25—427. Theoretical perspectives of 2-D and 3-D vibrational spectroscopies. M. Cho 7:45—428. Role of mode coupling in doubly vibrational^ enhanced four-wave mixing spectroscopy. J. Wright 8:05—429. Sub-5-fs vibrational dynamics in large molecules. T. Kobayashi 8:25—430. Cavity ring-down and doubleresonance studies of thiophosgene. D. Moule, E. Lim, H. Liu, R. Judge 8:45—431. Photophysics and photodynamics of jet-cooled methylanisoles. T. Ichimura, H. Kojima, K. Miyake, K. Sakeda, T. Suzuki 9:00—432. AM1 study of the mechanism of ozone decomposition on metal surfaces. J. Lin, T. Nakajima

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7:30-9:30 433. Theoretical study of coupling of heteroaromatic CH bond with CO and alkene catalyzed by Ru3(CO)12. N. Koga 434. LEED study of the coadsorption of Mg and Li on Cu(001). M-S. Chen, S. Mizuno, H. Tochihara 435. Molecular modeling in mineral processing: Design of flotation collectors. I. Nirdosh, R. Natarajan, S. V. Muthuswami, P. Venuvanalingam, M. Ramalingam 436. Spin correlations on a site diluted square lattice Heisenberg antiferromagnet covering the percolation threshold. K. Takeda, O. Fujita, M. Mito, T. Kawae, M. Hitaka, H. Deguchi, Y. Muraoka, K. Yamagata 437. Laser photolysis studies on photodissociation of carbon-sulfur bond in aromatic sulfide. M. Yamaji, H. Shizuka 438. Nonlinear optical properties of thin organic films at air-water interface. O. Slyadneva, A. Harata, T. Ogawa 439. Characterization of vanadium oxide supported on Ti0 2 -Zr0 2 by 51V solid-state NMR and infrared spectroscopies. M. H. Lee, J. R. Sohn, E. H. Park 440. AC impedance study of a carbon fiber anode covered with an Ag film in relation to the amount of intercalation lithium. F. Kikuchi, J. Suzuki, K. Sekine, T. Takamura 441. Band structure measurements of ionic solids. M. Ford, H. Dorsett, V. Sashin, L. Mikajlo, M. Bolorizadeh, J. Shapter, A. Kheifets 442. Theoretical study on the electronic structure of Pd monolayer on Au electrode. M. Miyakoshi, T. Ohwaki, K. Yamashita 443. Study of adsorption properties of bisephenol A from polar solvent by use of zeolite Y. S. Yamakazi, A. Suzuki, K. Tsutsumi 444. Magnetic properties of silica-coated cobalt ferrite nanosize composites. T. Tago, T. Hatsuta, R. Nagase, M. Kishida, K. Wakabayashi 445. Inhibitory effects of cyclic ureido compounds on the corrosion of steels in saturated Ca(OH)2 solutions. N. Nakayama 446. Measurement and calculation of ionization cross sections for small molecules in the gas phase. M. Bart, J. Hudson, C. Vallance, P. Harland 447. Difference in the agglomeration of Ag nanoclusters in poly(methyl methacrylate) prepared by UV-irradiation and heat treatment. N. Yanagihara, M. Nakayama, Y. Tanaka, H. Okamoto, T. Hara 448. Molecular chiralty of thiaheterohelicene on gold surface imaged by STM. M. Taniguchi, S. Takahashi, H. Nakagawa, A. Yamagishi, K. Yamada 449. Potential energy surfaces for Ti0 2 and photochemical reactions Ti + 0 2 ->TiO + O. K. H. Kim, Y. S. Lee, G. H. Jeung 450. Hydrogen coverage dependence of the reaction between gaseous and chemisorbed hydrogen atoms on a diamond surface. J. Ree, K. H. Moon, Y. H. Kim, H. K. Shin 451. Molecular orbital study of proton affinity for biomolecules. H. Kagawa, Y. Tamura, S. Kawauchi, K. Mori, K. Suziki 452. On the convergence of spin-orbit contributions in the electronic structure calculations for the hydrides of sixth- and seventh-row atoms. Y. J. Choi, Y-K. Han, Y. S. Lee 453. Computer simulation on solute alignment in liquid-crystal solvent. M. Ishikawa, I. Ono, S. Mita, S. Kondo 454. Countercation effect on the structures and properties of CdS clusters. S. K. Shin, J. Park, S. Hong, T. Kim, J. Park, T. Joo 455. The relativistic CASSCF calculation for atoms and molecules. Y. S. Kim, Y. S. Lee 456. How covalent are hydrogen bonds? N. Weinberg, T. Day, L. Chan, G. Patey 457. 1 -D alignment and synthesis of phthalocyanine derivatives in mesoporous channels of MCM-41. Y. Tanamura, T. Uchida, N. Teramae 458. Synthesis and photophysical properties of donor/acceptor-linked porphyrins. S. Yokoyama, S. Mashiko, T. Yamada, S. Otomo, T. Yokoyama, H. Nejo, T. Kamikado

459. DFT study of the interaction between the HBEA zeolite and isobutane. P. Zaragoza-Rivera, J. Cabrera-Hernandez, J-M. Martinez-Magadan, R. SantamariaOrtiz 460. o-Heptane catalytic cracking inside the HZSM-5 zeolite. J-M. Martinez-Magadan, R. Santamaria-Ortiz 461. Theoretical study of the cyclohexaneHZSM-5 ring structure model interaction. A. Cuan, J-M. Martinez-Magadan, M. Galvan 462. Photochemistry of ethyl bromide: Quantum yields of photoproducts. K. Seki, M. Yoshida, M. Yagi 463. Withdrawn. 464. Theoretical study of structure and stability of HN03-water clusters: HN0 3 (H 2 0) n , n = 1-3. D. Bacelo 465. Synthesis and characterization of epoxy/silica nanohybrid for electropacking application. J. Kim, S. Gang, C. R. Choe, S. H. Lim, M. Park 466. Chemical bonding of mobile monovalent ions in Agl-based superionic conducting glasses. M. Tatsumisago, T. Minami, H. Adachi, Y. Kowada 467. Hel photoelectron and ab initio study of vitamin A and its relative compounds. S. Katsumata 468. Mesostructure control for vanadium oxide-hexadecyltrimethylammonium composite by low-temperature annealing and solvent extraction. Y. Yagi, M. Miyayama, T. Kudo, H. Zhou, I. Honma 469. Estimation of active conformations and the comparative molecular field analysis (CoMFA) of GPIIb/llla antagonists. I. Nakagome, T. Kobayakawa, N. Yamaotsu, S. Hirono 470. Application of a 4:4 quinobenzoxazineMg 2+ self-assembly model: Design of new fluoroquinolone antitumor agents. W. Duan, L. H. Hurley 471. Carbene and silylene cycloadditions to the ethylene double bond: A computational, density functional (B3LYP) study of the singlet and triplet state diradicals. L. M. Campos, H. L. Martinez 472. Coupled-cluster electronic spectra for the Ca+-acetylene complex and its alkaline earth analogs: Periodic trends or traps? S. Wesolowski, H. Schaefer III, M. Duncan, R. King 473. Synthesis of mesoporous silicate film using block copolymer as a template. H. S. Zhou, T. Yamada, K. Asai, I. Honma 474. Synthesis of zeolites containing organic groups in their lattice. Y. Takahashi, K. Yamamoto, T. Tatsumi 475. Density functional theory study on the hyperfine coupling constants of the unsaturated carbonyl radical cations. Y. Shimodo, K. Morihashi, O. Kikuchi 476. Optical-optical double resonance spectroscopy of the 1U(3P2) ion-pair state of l 2 . S. Motohiro, E. Kagi, H. Fujiwara, M. Fukushima, T. Ishiwata, 477. Constituent analysis and structure observation of alkali-C60 compound materials formed in alkali-fullerene plasma. T. Hirata, T. Oku, R. Hatakeyama, N. Sato 478. Synthesis and characterization of thermally stable Si-modified titanium oxide nanomaterials by thermal decomposition of alkoxides in organic media. M. Kohno, Y. Mathunaga, H. Kominami, Y. Kera 479. In situ observation of emission from carbon nanoparticles: Correlation with the formation process of fullerenes and carbon nanotubes. S. Suzuki, T. Isahigaki, Y. Ohtsuka, R. Sen, H. Kataura, Y. Achiba, W. Kraetschmer 480. Encapsulated and hollow onionlike structures of WS 2 and MoS2. R. Sen, A. Govindaraj, S. Suzuki, H. Kataura, Y. Achiba 481. Synthesis and electropolymerization of perfluoroalkyl unit inclusion triazine thiol. S. Ouchi, K. Mori, H. Hirahara, Y. Oishi, J. Oravec 482. Magnetic field effect to magnetic powder in the electroconductive complex. K. Nisiya, H. Hirahara, Y. Oishi, J. Oravec


483. Magnetism effect of electroconductive paints. T. Sato, H. Hirahara, K. Mori, Y. Oishi, J. Oravec 484. Corrosion prevention and functionalization of magnesium alloy by organic plating. A. Yoshida, H. Hirahara, K. Mori, Y. Oishi, Y. Sasaki, J. Oravec 485. Direct adhesion betwen triazine dithiol electropolymerized metals and acrylic rubber during vulcanization. P. Gong, H. Hirahara, K. Mori, Y. Oishi, I. Tanaka 486. Direct adhesion between zinc-plated steel cords and SBR-NR rubber blends during vulcanization. X. Shi, H. Hirahara, K. Mori, Y. Oishi, I. Fujita, H. Sekigami 487. Corrosion resistance of thin-section ductile cast iron by organic polymer plating. Z. Kang, K. Mori, H. Hirahara, Y. Oishi, M. Kanno 488. Magnetic field effect on the organic plating. H. Hirahara, N. Nawa, Y. Oishi, K. Mori 489. Matrix-isolation of aluminum and gallium molecular anions in neon matrices investigated by electron spin resonance spectroscopy. A. C. Stowe, L. B. Knight Jr., J. Kaup, A. McKinley 490. Application of density functional theory using generalized born formula to condensed-phased reactions: Solvent effect on the Claisen rearrangement of allyl vinyl ether. K. Morihashi, S. Akimoto, O. Kikuchi 491. Photochemistry of chloroethylene derivatives at 193 nm in gas phase: Measurements of absolute quantum yields of photoproducts. K. Seki, Y. Shinoda, M. Yagi 492. Morphology and Mossbauer study of fine cobalt-ferrite particles. E. J. Choi, Y. Ahn 493. High-performance photoelastic modulator and its driver for polarization modulation spectroscopy. S. Maeda, Y. Shindo 494. Numerical solution of the Schrodinger equation by intelligent methods. M. Sugawara, H. Nakanishi 495. Effects of protonation on the excited states of acridine and phenazine. M. Deguchi, D. Suzuki, K. Seki, M. Yagi 496. The comparative study of the DFT and MP2 methods for some heterocyclic rings with transannular bonding. G. Chung 497. Photoconductivity-detected magnetic resonance study on the solvent effects upon the photoinduced electron-transfer reaction of xanthone and N,Ndiethylaniline. A. Matsuyama, K. Maeda, H. Murai 498. SQUID study of ultrafine zinc ferrite particles. Y. Ahn, E. J. Choi 499. SQUID study of ultrafine cobalt ferrite particles. Y. Ahn, E. J. Choi 500. Morphology and Mossbauer study of fine zinc-ferrite particles. E. J. Choi, Y. Ahn 501. Determination of the IR spectra of alkyl peroxy radicals. J. Cabrera, S. Sharma, S. Nickolaisen 502. Theoretical calculations of anharmonic vibrational spectra of biological molecules. G. M. Chaban, J. O. Jung, S. K. Gregurick, R. B. Gerber 503. Substituent effects on the iminotautomer fluorescence of 2-aminopyrimidine derivative/acetic acid systems. A. Fujimoto, H. Astushi, K. Hideyuki, I. Naoya, I. Hironori Sheraton Waikiki Akaka Falls Room, 2nd Floor Structure and Dynamics of Photogenerated Intermediates in Solution: Vibrational and Electronic Studies (147) Poster Session 7:30-9:30 384. Dynamic intensity borrowing in J-aggregates revealed by sub-5-fs spectroscopy. T. Kobayashi 385. Picosecond infrared spectrum of 4-(dimethylamino)benzonitrile and structure of the CT excited state. H. Okamoto, H. Inishi, Y. Nakamura, S. Kohtani, R. Nakagaki 386. Dynamic behavior of aromatic radical cations in acetonitrile: A picosecond timeresolved Raman spectroscopic study. T. Nakabayashi, S. Kamo, H. Sakuragi, N. Nishi 387. Vibrationally hot ground states of TPM dyes. Y. Ando, Y. Nagasawa, T. Okada

388. Effects of intramolecular hydrogen bonding on the deactivation pathway from the singlet excited state of hemiindigo derivatives. M. Ikegami, T. Arai 389. Near-IR absorption spectrum of excimer and exciplex. R. Katoh, S. Murata 390. Picosecond time-resolved Raman study of frans-azobenzene: Isomerization mech. anism followed by S2(n7i*)

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