Peroxynitrite Uncloaked? Volume 11, Number 7, July 1998, pp 716−717

R. Radi for bringing the error to his attention. TX9804987. 10.1021/tx9804987. Published on Web 10/22/1998. 1391. Chem. Res. Toxicol. 1998, 11, 1391...
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Chem. Res. Toxicol. 1998, 11, 1391

Additions and Corrections Peroxynitrite Uncloaked? [Volume 11, Number 7, July 1998, pp 716-717] WILLEM H. KOPPENOL* Page 716. The correct rate constant for the reaction of carbon dioxide with peroxynitrite is not 2 × 103 M-1 s-1, as quoted in the second paragraph, but 5.8 × 104 M-1 s-1. The combined rate of disappearance of peroxynitrite via thiols and peroxynitrite is now approximately 100 s-1, and a hypothetical scavenger at a concentration of 10 µM would need to have a rate constant of 1 × 108 M-1 s-1 to scavenge 90% of the peroxynitrite. W.H.K. thanks Prof. R. Radi for bringing the error to his attention. TX9804987 10.1021/tx9804987 Published on Web 10/22/1998

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