Letter Cite This: Environ. Sci. Technol. Lett. 2017, 4, 551−555
pubs.acs.org/journal/estlcu
pH Dependence of the Imidazole-2-carboxaldehyde Hydration Equilibrium: Implications for Atmospheric Light Absorbance Jessica M. Ackendorf, Michael G. Ippolito, and Melissa M. Galloway* Department of Chemistry, Lafayette College, 701 Sullivan Road, Easton, Pennsylvania 18042, United States S Supporting Information *
ABSTRACT: Imidazole-2-carboxaldehyde (IC) has been identified as an aqueous “brown carbon” absorber and a possible atmospheric photosensitizer. IC exists in a pH-dependent equilibrium between its aldehyde and geminal diol form; the diol form is the dominant species in solution at pH
